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A-3. Binary Interaction Parameters: Binary System (K) (K)

This document presents k constants and coefficients of determination for binary interaction parameters between various gas mixtures as a function of temperature according to the Multiflash model. The k constants k0, k1, and k2 are given for various binary systems including CO2-hydrocarbons, H2S-hydrocarbons, methane-other gases, ethane-other gases, and others. Coefficients of determination ranging from 0.235 to 1 indicate how well the temperature dependency is modeled.

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82 views1 page

A-3. Binary Interaction Parameters: Binary System (K) (K)

This document presents k constants and coefficients of determination for binary interaction parameters between various gas mixtures as a function of temperature according to the Multiflash model. The k constants k0, k1, and k2 are given for various binary systems including CO2-hydrocarbons, H2S-hydrocarbons, methane-other gases, ethane-other gases, and others. Coefficients of determination ranging from 0.235 to 1 indicate how well the temperature dependency is modeled.

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erwin_carry
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© © All Rights Reserved
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A-3.

Binary Interaction Parameters

The k constants introduced in MultiflashTM, which predict the relation between binary interaction
parameters and temperature, are presented in Table 64.
Table 64: k constants introduced in MultiflashTM and coefficients of determination of all the regressions

Binary system 𝒌𝟎 𝒌𝟏 (K-1) 𝒌𝟐 (K-2) 𝑹𝟐


CO2-CH4 0.67 -5.19x10-3 1.17x10-5 0.339
CO2-C2H6 0.51 -2.96x10-3 5.86x10-6 0.620
CO2-i-C4H10 0.57 -3.32x10-3 6.02x10-6 0.939
CO2-n-C4H10 0.60 -3.28x10-3 5.65x10-6 0.900
CO2-C3H8 -0.31 2.25x10-3 -2.44x10-6 0.694
CO2-i-C5H12 8.92 -0.05 5.74x10-5 0.956
CO2-n-C5H12 1.43 8.10x10-3 1.24x10-5 0.871
CO2-H2S 0.11 -5.46x10-4 5.60x10-6 0.789
CO2-N2 5.22 -0.04 8.52x10-5 0.678
CO2-TEG -0.02 3.65x10-4 0 0.992
H2S-i-C4H10 0.76 -4.61x10-3 7.35x10-6 0.845
H2S-i-C5H12 2.01 -0.01 1.81x10-5 0.998
H2S-n-C5H12 0.97 5.82x10-3 9.18x10-6 0.993
H2S-C6H14 0.12 -1.20x10-4 0 0.996
H2S-CH4 -0.06 4.61x10-4 0 0.948
H2S-H2O -0.27 7.87x10-4 0 1
H2S-TEG 0.06 1.32x10-4 0 0.838
CH4-C3H8 0.09 -7.62x10-4 1.66x10-6 0.313
CH4-n-C4H10 0.14 -1.27x10-3 3.02x10-6 0.897
CH4-H2O -1.40 3.44x10-3 0 0.985
CH4-N2 0.30 -4.21x10-3 1.59x10-5 0.930
CH4-C6H14 0.18 1.13x10-3 1.86x10-6 0.482
CH4-TEG 0.04 6.12x10-4 0 0.999
C2H6-CH4 0.13 -1.40x10-3 3.68x10-6 0.808
C2H6-C3H8 0.41 -3.33x10-3 6.46x10-6 0.498
C2H6-i-C4H10 0.93 -6.11x10-3 9.88x10-6 0.941
C2H6-n-C4H10 1.46 -8.62x10-3 1.29x10-5 0.504
C2H6-n-C5H12 0.73 -4.51x10-3 7.00x10-6 0.931
C2H6-C6H14 2.27 -0.01 1.71x10-5 1
C2H6-N2 -0.50 3.83x10-3 -6.55x10-6 0.937
C2H6-TEG 0.07 3.83x10-4 0 0.991
C3H8-i-C4H10 0.02 1.00x10-4 0 0.235
C3H8-H2O -0.65 1.49x10-5 0 0.999
C3H8-TEG 0.05 3.74x10-4 0 0.976
n-C4H10-N2 1.72 -0.01 1.66x10-5 0.573
n-C4H10-H2O -0.71 1.55x10-3 0 0.998
C6H14-H2O 1.16 -6.15x10-3 9.06x10-6 0.490
C6H14-N2 -1.03 7.32x10-3 -1.13x10-5 0.925
C6H14-n-C5H10 26.82 -0.18 2.94x10-4 1
TEG-H2O -2.92 7.67x10-3 0 0.998

85

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