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Problemario

The document contains equations relating to thermodynamics and phase equilibria. It includes equations for the change in internal energy, enthalpy, and entropy with respect to temperature or pressure changes. It also includes equations of state relating pressure, volume, and temperature for gases and liquids. The document provides equations for standard enthalpy, entropy, and free energy of formation as functions of temperature.

Uploaded by

Jhoan Andre'
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61 views15 pages

Problemario

The document contains equations relating to thermodynamics and phase equilibria. It includes equations for the change in internal energy, enthalpy, and entropy with respect to temperature or pressure changes. It also includes equations of state relating pressure, volume, and temperature for gases and liquids. The document provides equations for standard enthalpy, entropy, and free energy of formation as functions of temperature.

Uploaded by

Jhoan Andre'
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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𝑑𝑈 = 𝐶𝑣 𝑑𝑇 + [(𝛼𝑇 − 𝜅𝑃)/𝜅]𝑑𝑉

𝑇𝑉𝛼 2
𝑑𝑈 = (𝐶𝑣 + − 𝑃𝑉𝛼) 𝑑𝑇 + 𝑉(𝑃𝜅 − 𝑇𝛼)𝑑𝑉
𝜅
𝐶𝑝
𝑑𝑆 = ( 𝑇 ) 𝑑𝑇 − 𝑉𝛼𝑑𝑃
𝜕𝑆 𝛽𝐶𝑣
( ) =
𝜕𝑃 𝑉 𝑇𝛼
𝐶𝑝
𝑑𝑆 = ( 𝑇 ) 𝑑𝑇 − 𝑉𝛼𝑑𝑃
𝜕𝑆 𝐶𝑝
( ) =
𝜕𝑉 𝑃 𝑇𝑉𝛼

𝑃𝑉 = 𝑛(𝑅𝑇 + 𝑃𝐵) 𝐵

𝜕𝑈
( 𝜕𝑉 ) 𝑃𝑉 = 𝑛(𝑅𝑇 + 𝑃𝐵) 𝐵
𝑇

𝑑𝑈 = 𝐶𝑣 𝑑𝑇 + [(𝛼𝑇 − 𝜅𝑃)/𝜅]𝑑𝑉

𝑑𝐻 = 𝐶𝑝 𝑑𝑇 + 𝑉(1 − 𝛼𝑇)𝑑𝑃

𝜕𝑈
𝐶𝑝 − 𝐶𝑣 = [𝑃 + ( ) ] 𝑉𝛼
𝜕𝑉 𝑇

𝑇𝑉𝛼 2
𝐶𝑝 − 𝐶𝑣 =
𝜅
Δ

→ Δ Δ Δ

0.503 × 105
∆𝐶𝑝 = −12.95 + 3.75 × 10−3 𝑇 −
𝑇2
Δ

→
∆𝐻° = 81,730 − 0.47𝑇 − 0.731 × 10−3 𝑇 2
∆𝑆° = 34.94 − 1.08 𝑙𝑜𝑔10 𝑇 − 1.46 × 10−3 𝑇
Δ

→
∆𝐺° = 18,660 − 14.42𝑇 log10 𝑇 − 6.07𝑇 + 8.24 × 10−3 𝑇 2
Δ Δ

Δ
∆𝐺° = 𝐴 + 𝐵𝑇 𝑙𝑛 𝑇 + 𝐶𝑇 + 𝐷𝑇 2
[𝜕(𝐺 ⁄𝑇)/𝜕𝑇]𝑃 = −𝐻/𝑇 2

𝑃𝑉𝑚 = 𝑅𝑇(1 − 𝑏𝑃)

(𝜕𝑈/𝜕𝑉) 𝑇 = 𝑏𝑃2
𝐶𝑃,𝑚 − 𝐶𝑉,𝑚 = 𝑅(1 + 𝑏𝑃)2

𝑉𝑚 = 𝑐1 + 𝑐2 𝑇 + 𝑐3 𝑇 2 − 𝑐4 𝑃 − 𝑐5 𝑃𝑇

𝐶𝑝 − 𝐶𝑣
(𝜕𝑈/𝜕𝑉) 𝑇
(𝜕𝑆/𝜕𝑃)𝐼
(𝜕𝑆/𝜕𝑇)𝑃
(𝜕𝐺/𝜕𝑃) 𝑇

𝑃𝑉𝑚 = 𝑅𝑇(1 + 𝑏𝑃 + 𝑐𝑃2 )

𝑃𝑉 𝑎 𝑝
= 1 + (𝑏 − )
𝑅𝑇 𝑅𝑇 𝑅𝑇

𝜕𝐻 2𝑎
( ) =𝑏−
𝜕𝑃 𝑇 𝑅𝑇

𝜕𝑆 𝑅 𝑎𝑅
( ) = −[ + ]
𝜕𝑃 𝑇 𝑃 (𝑅𝑇)2
𝐿
3679.1
ln(𝑃/𝑃𝑎) = 23.593 −
𝑇(𝐾) − 31.317
2035
ln(𝑃/𝑡𝑜𝑟𝑟) = 22.413 −
𝑇(𝐾)

1736
ln(𝑃/𝑡𝑜𝑟𝑟) = 18.352 −
𝑇(𝐾)

3754
ln(𝑃/𝑡𝑜𝑟𝑟) = 23.03 −
𝑇(𝐾)

3063
ln(𝑃/𝑡𝑜𝑟𝑟) = 19.49 −
𝑇(𝐾)

1343.516
ln(𝑃/𝑚𝑚 𝐻𝑔) = 5.475462 − − 167.515 × 10−5 𝑇
𝑇
Δ

−1,149
log10 𝑃𝑚𝑚 = + 7.481
𝑇
1343.516
log10 𝑃 (𝑎𝑡𝑚) = 5.475462 − − 167.515 × 10−5 𝑇
𝑇
Δ
Δ

∆𝐻𝑣 = 𝑎 + 𝑏𝑇 + 𝑐𝑇 2
𝐼𝑛 𝑃

−1,294
log10 𝑃𝑎𝑡𝑚 = + 1.405 log10 𝑇 − 0.0051𝑇 + 4.800
𝑇

−2,460
log10 𝑃𝑚𝑚 = + 6.69
𝑇
−6,947
log10 𝑃𝑚𝑚 = + 10.8
𝑇

𝛥𝐻𝑣𝑎𝑝 = 13,500 − 10.0 𝑇


𝛥𝐻𝑣𝑎𝑝

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