Q1. A solution of copper (II) sulphate at 25oC contains 0.

3195 g of solute per d) What is the molar mass of the acid? [98.0 g/mol]
250 cm3 solution. Calculate the molarity of the solution. [0.008M]
Q6. 4.15 g of a sample hydrated sodium carbonate, of formula
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Q2. A student is going to prepare a 250 cm solution of oxalic acid from its Na2CO3。nH2O, is dissolved in water and the solution made up to 250.0 cm3.
pure crystals ((COOH)2。2H2O). He weighs out 1.8g of oxalic acid crystals It was found that 25.0 cm3 of this solution requires 29.0 cm3 of 0.05 M
and dissolves them in 25cm3 of distilled water. Then the solution is diluted to sulphuric acid for neutralisation. Calculate n. [n=10]
250 cm3.
a) Calculate the number of moles of oxalic acid obtained from 1.8g of its Q7. 4.77g of an impure sample of anhydrous sodium carbonate required 31.5
crystals. cm3 of 1M sulphuric acid for complete neutralisation. What is the percentage
b) Calculate the molarity of the 25cm3 solution oxalic acid. purity of anhydrous sodium carbonate in the sample? [70%]
c) Calculate the molarity of the solution of oxalic acid after it has been diluted
to 250cm3. Q8. 0.985g of an anhydrous metal carbonate (formula XCO3) required 40.0
cm3 of 0.25 M hydrochloric acid for complete neutralisation. Calculate the
Q3. 25.0 cm3 of a sodium carbonate solution was titrated against 0.50M relative atomic mass of the metal X. [137]
hydrochloric acid. 22.0 cm3 of the HCl was required for complete
neutralisation of the carbonate. Find the molarity of the sodium carbonate
solution. [0.22 M]
Q9. A 5.0 g mixture of sodium chloride and sodium carbonate reacted
Q4. Lemons contain a solution of citric acid. The formula of citric acid is completely with 50.0 cm3 of hydrochloric acid of unknown concentration. The
C6H8O7. A solution known to contain 1.6g of citric acid was found to require volume of carbon dioxide formed is 720.0 cm3. (All volumes are measured
25.0 cm3 of 1M sodium hydroxide solution for neutralisation. under Room conditions.)
a) How many a) moles of sodium hydroxide are present in 25.0cm3 of the a) Write an equation for the reaction occurred.
solution? [0.025 mol]
b) Is citric acid monobasic, dibasic or tribasic? [tri] b) Calculate the mass of sodium carbonate reacted. [3.18g]
c) Calculate the molarity (mole/dm3) of the hydrochloric acid used.
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Q5. 25.0 cm of a solution of a tribasic acid H3Y (containing 4.9 g of the acid [1.2M]
per dm3) required 37.5 cm3 of 0.1M sodium hydroxide solution for complete
neutralisation. Q10. The table below showed some information about these two glass
a) Write a full equation for the reaction. cleaners.
b) How many moles of the acid are present in 25.0 cm3 of the solution? Band Volume per bottle Price per bottle Molarity of ammonia
[1.25x10-3 mol (cm3) (M)
c) How many moles of the acid are present in 1.0 dm3 of the solution? A 350 $15 Unknown
[0.05 mol] B 600 $25 0.6
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A student performed the following experiment to determine the concentration vi) Calculate the value of n in HnA.
of ammonia in Brand A glass cleaner.
Q12. 60cm3 of 0.5M magnesium chloride is mixed with 40 cm3 of unknown
25.0 cm3 of the Brand A glass cleaner was diluted to 250.0 cm3 in a
concentration iron (III) chloride. The molarity of chloride ion in the mixure is
volumetric flask. 25.0 cm3 of the diluted glass cleaner was transferred to a
0.84M, calculate the no. of moles of iron (III) ion in the mixture. [0.008mol]
conical flask and was then titrated against 0.03M sulphuric acid. 20.0
cm3 of the acid was required to neutralize.
NH3(aq)+ H2SO4(aq) (NH4)2SO4(aq) Q13 Sulfur dioxide, SO2, is used as a preservative in wine. The sulfur dioxide
a) Balance the above equation. content of a wine can be found by titration. A chemist found that 25.0 cm3 of a
b) Calculate the concentration in mol dm-3, of ammonia in the Brand A sample of wine reacted with exactly 15.00 cm3 of 0.0010 mol/dm3 aqueous
glass cleaner. [0.48M] iodine, I2(aq). The equation for the reaction is
c) Calculate which Brand of glass cleaner is BETTER BUY. [Band B] SO2(aq) + I2(aq) + 2H2O(l)SO4 2–(aq) + 2I (aq) + 4H (aq)
– +

3
a) Calculate the concentration, in mol/dm , of sulfur dioxide in the wine.
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b) Calculate the concentration, in g/dm , of sulfur dioxide in the wine.
Q11. A drug tablet contains a weak acid. The acid can be represented by HnA
and its relative molecular mass is 120. A concentration of sulfur dioxide that is greater than 0.16 g/dm3 makes wine
unpleasant to drink. Use the value you have calculated in (d) to state whether
The following experimental procedure is used to determine the value of the wine is drinkable.
n in the acid. A drug (mass of the weak acid = 0.6g) was dissolved in
distilled water to form a solution. Then the solution was made up to
250.0cm3. It was found that 25.0cm3 of the acid solution required 20.0 14. Tartaric acid is an acid found in grape fruit juice. Its molecular formula is
cm3 of 0.05M sodium hydroxide solution for complete neutralization. C4H6O6. A solution containing 2.5g of tartaric acid was found to require
33.0 cm3 of 1.0M sodium hydroxide solution for complete neutralisation.
i) What is meant by a “weak acid”?
Find the basicity of tartaric acid. [C=12 , H=1, O=16]
ii) How many moles of sodium hydroxide are present in 20.0cm3
solution?
15. Solution X is prepared by mixing 100.0 cm3 of 2.0 M Na2SO4(aq) with 50.0
iii) Calculated the number of mole of HnA in a drug tablet. cm3 of 1.0M NaNO3(aq). What is the MOLARITY of Na+(aq) ions in X?
iv) How many moles of HnA are present in 25.0cm3 of acid 16. What is the volume of 0.5 M hydrochloric acid required to react with 1.49
solution? g of lithium oxide for complete neutralisation? [199cm3]
v) Balance the following equation:
_____ HnA(aq) + _____ NaOH(aq) _____ NanA(aq) + _____ 17. Marble is insoluble in water. The percentage purity of calcium carbonate in
H2O(l) the marble can be determined indirectly and the method is called ‘back
titration’.
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A student dissolved 1.10 g of marble in 100.0 cm3 of 0.2 M hydrochloric
acid which was kept in excess. Then, the excess hydrochloric acid required
19.70 cm3 of 0.1 M sodium hydroxide solution for complete neutralisation.
[Ca = 40, O = 16, H = 1, Cl = 35.5, Na = 23]
a) Write TWO equations for the reactions involved.
b) Calculate the number of moles of excess hydrochloric acid.
c) Calculate the percentage purity of calcium carbonate in the marble.