Oerlikon

Leybold Vacuum GmbH

Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

1. Identification of the substance/ mixture and of the company/ undertaking

Product identifiers

Trade name: LEYBONOL LVO 400

Product description: Synthetic oil (perfluoropolyether PFPE, free of additives)

Chemical characterization: Perfluorinated polyethers

CAS-No.: 69991-67-9

Relevant identified uses of the substance or mixture and uses advised against

Use: Vacuum pump oil

- Electronic industry
- Electrical industry
- Chemical industry
- For industrial use only.

Order number: Number Package Size

L40000 0,75 Liter
L40001 1 Liter

Details of the supplier of the safety data sheet

Supplier: Oerlikon Leybold Vacuum GmbH

Bonner Str. 498
D-50968 Cologne
Phone +49-221-347-0
Fax +49-221-347-1250
Internet www.oerlikon.com/leyboldvacuum

E-Mail: [email protected]

Emergency phone number: +49/ (0)700 24112112 (OLC)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (Regulation (EC)

No 1272/2008): Not classified as hazardous product under the regulation above. |

2.2 Label elements

Regulation (EC) No 1272/2008: Not labelled as hazardous product under the above regulation. |

2.3 Other hazards which do not result

in classification: Thermal decomposition can lead to release of toxic and corrosive
gases. |

Safety data sheet 300326943_002_A3 Page 1/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

3. Composition/information on ingredients

3.1 Substance

Chemical nature: Perfluorinated polyethers |

Chemical Name Identification number Concentration [%]

1-Propene, 1,1,2,3,3,3-hexafluoro-, oxidized, CAS-No.: 69991-67-9 > 99,9
polymd.

3.2 Mixture: Not applicable, this product is a substance. |

4. First aid measures

4.1 Description of necessary first-aid measures

In case of inhalation: Move to fresh air in case of accidental inhalation of fumes from
overheating or combustion.
Oxygen or artificial respiration if needed.

In case of skin contact: Wash off with soap and water.

In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes.
If eye irritation persists, consult a specialist.

In case of ingestion: Drink 1 or 2 glasses of water.

Do NOT induce vomiting.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

In case of inhalation: Effects: No known effect.

In case of skin contact: Effects: Effects of skin contacts may include:

Redness

In case of eye contact: Effects: Contact with eyes may cause irritation.
Redness

In case of ingestion: Symptoms:

Ingestion may provoke the following symptoms:
Nausea
Vomiting
Diarrhoea

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician: None |

Safety data sheet 300326943_002_A3 Page 2/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media: - Water

- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)

Unsuitable extinguishing media: - None.

5.2 Special hazards arising from

the substance or mixture: The product is not flammable.
Not explosive
In case of fire hazardous decomposition products may be produced
such as: Gaseous hydrogen fluoride (HF), Fluorophosgene

5.3 Advice for firefighters

Special protective equipment for

firefighters: Wear self-contained breathing apparatus and protective suit.
When intervention in close proximity wear acid resistant over suit.

Further information: Evacuate personnel to safe areas.

Approach from upwind.
Protect intervention team with a water spray as they approach the
fire.
Keep containers and surroundings cool with water spray.
Keep product and empty container away from heat and sources of
ignition.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Prevent further leakage or spillage if safe to do so.

Advice for emergency responders: Ensure adequate ventilation.

Material can create slippery conditions.
Sweep up to prevent slipping hazard.
Keep away from open flames, hot surfaces and sources of ignition.

6.2 Environmental precautions: Should not be released into the environment.

Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for

containment and cleaning up: Soak up with inert absorbent material.
Suitable material for picking up
Dry sand
Earth
Shovel into suitable container for disposal.

6.4 Reference to other sections: Refer to protective measures listed in sections 7 and 8.

Safety data sheet 300326943_002_A3 Page 3/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

7. Handling and storage

7.1 Precautions for safe handling: Ensure adequate ventilation.

Use personal protective equipment.
Keep away from heat and sources of ignition.
To avoid thermal decomposition, do not overheat.
Take measures to prevent the build up of electrostatic charge.
Clean and dry piping circuits and equipment before any operations.
Ensure all equipment is electrically grounded before beginning
transfer operations.

Hygiene measures: Ensure that eyewash stations and safety showers are close to the
workstation location.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Handle in accordance with good industrial hygiene and safety
practice. |

7.2 Conditions for storage, including incompatibilities

Technical measures/Storage conditions: Keep away from heat and sources of ignition.
Keep in properly labelled containers.
Keep away from combustible material.
Keep away from incompatible products
Provide tight electrical equipment well protected against corrosion.
Refer to protective measures listed in sections 7 and 8. |

Packaging material

Suitable material: Polyethylene

7.3 Specific end use(s): Contact your supplier for additional information

8. Exposure controls/ personal protection

8.1 Control parameters: Contains no substances with occupational exposure limit values
above their regulatory reporting threshold. |

Threshold limit values of by-products from thermal decomposition:

Components with workplace occupational exposure limits

Components Value type Value Basis

hydrogen fluoride TWA 1,8 ppm Europe. Commission Directive
1,5 mg/m3 2000/39/EC establishing a first list
of indicative occupational exposure
limit values
Indicative
hydrogen fluoride STEL 3 ppm Europe. Commission Directive
2,5 mg/m3 2000/39/EC establishing a first list
of indicative occupational exposure
limit values
Indicative
hydrogen fluoride TWA 0,5 ppm USA. ACGIH Threshold Limit
Values (TLV)
Danger of cutaneous absorption
Expressed as: Fluorine

Safety data sheet 300326943_002_A3 Page 4/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

hydrogen fluoride C 2 ppm USA. ACGIH Threshold Limit

Values (TLV)
Danger of cutaneous absorption
Expressed as: Fluorine
carbonyl difluoride TWA 2,5 mg/m3 Europe. Commission Directive
2000/39/EC establishing a first list
of indicative occupational exposure
limit values
Indicative
Expressed as :Fluorine
carbonyl difluoride TWA 2 ppm USA. ACGIH Threshold Limit
Values (TLV)
carbonyl difluoride STEL 5 ppm USA. ACGIH Threshold Limit
Values (TLV)

Biological Exposure Indices

Components Value type Value Basis

hydrogen fluoride BEI 2 mg/l ACGIH - Biological Exposure
Fluoride Indices (BEI)
Urine
Prior to shift (16
hours
after exposure
ceases)
BEI 3 mg/l ACGIH - Biological Exposure
Fluoride Indices (BEI)
Urine
End of shift (As soon
as
possible after
exposure
ceases)

8.2 Exposure controls

Control measures

Engineering measures: Provide local ventilation appropriate to the product decomposition

risk (see section 10).
Refer to protective measures listed in sections 7 and 8.
Apply technical measures to comply with the occupational exposure
limits.

Individual protection measures

Respiratory protection: In case of decomposition (see section 10), use an air breathing
apparatus with face mask.
Use only respiratory protection that conforms to international/
national standards. |

Hand protection: Wear protective gloves. |

Suitable material: Nitrile rubber

PVC
Neoprene gloves
butyl-rubber
Take note of the information given by the producer concerning
permeability and break through times, and of special workplace
conditions (mechanical strain, duration of contact). |

Safety data sheet 300326943_002_A3 Page 5/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

Eye protection: Tightly fitting safety goggles

Skin and body protection: Wear work overall and safety shoes. |

Hygiene measures: Ensure that eyewash stations and safety showers are close to the
workstation location.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Handle in accordance with good industrial hygiene and safety
practice. |

Environmental exposure controls: Dispose of rinse water in accordance with local and national
regulations. |

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance: Physical state: liquid

Colour: colourless
Odour odourless
Odour Threshold: no data available
pH: no data available
Melting point/range: Not applicable.
Boiling point/boiling range: > 290 °C |
Flash Point The product is not flammable.
Evaporation rate (Butylacetate = 1): no data available
Flammability (liquids): The product is not flammable.
Flammability/Explosive limit: no data available
Autoignition temperature: no data available
Vapour pressure: 0,000002 hPa ( 20 °C) |
Vapour density: no data available.
Density: 1,89 g/cm3
Relative density: 1,88 - 1,90
Solubility(ies) : Water solubility: insoluble

Solubility in other solvents:

Fluorinated solvents: soluble |
Partition coefficient: n-octanol/water: no data available
Thermal decomposition: > 290 °C |
Viscosity: Viscosity, dynamic: 280 mPa.s |
Explosive properties Not explosive
Oxidizing properties: Not considered as oxidizing

9.2 Other information

Molecular weight: 2.500 Da

Polymer Molar Mass

10. Stability and reactivity

10.1 Reactivity: No dangerous reaction known under conditions of normal use.

10.2 Chemical stability: Stable under recommended storage conditions.

Metals promote and lower decomposition temperature |

10.3 Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use.

Safety data sheet 300326943_002_A3 Page 6/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

10.4 Conditions to avoid: Avoid to use in presence of high voltage electric arc and in absence
of oxygen.
Keep away from flames.
To avoid thermal decomposition, do not overheat.

10.5 Incompatible materials: Alkali metals

Lewis acids (Friedel-Crafts) above 100°C
Aluminum and magnesium in powder form above 200°C

10.6 Hazardous decomposition

products: Gaseous hydrogen fluoride (HF)., Fluorophosgene

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity: LD50: > 15.000 mg/kg - Rat , male and female
Test substance: Molecular weight ~ 3200
Not classified as hazardous for acute oral toxicity according to GHS.
No significant adverse effects were reported |

Acute inhalation toxicity: no data available

Acute dermal toxicity: LD50: > 5.000 mg/kg - Rat , male and female
Test substance: Molecular weight ~ 3200
Not classified as hazardous for acute dermal toxicity according to
GHS.
No effect observed at this dose or concentration |

Acute toxicity
(other routes of administration): LD50: > 5.000 mg/kg - Rat , for males and females
Intraperitoneal route
Test substance: Molecular weight ~ 3200 |

Skin corrosion/irritation: Rabbit

Not classified as irritating to skin
Test substance: Molecular weight ~ 3200
2 Weeks - Rabbit
No skin irritation
Method: Repeated dermal application test.
Test substance: Molecular weight ~ 3200 |

Serious eye damage/eye irritation: Rabbit

Not classified as irritating to eyes
Test substance: Molecular weight ~ 3200 |

Respiratory or skin sensitisation: Maximisation Test (GPMT) - Guinea pig

Does not cause skin sensitisation.
Test substance: Molecular weight ~ 3200 |

Safety data sheet 300326943_002_A3 Page 7/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

Mutagenicity

Genotoxicity in vitro: Ames test

with and without metabolic activation

negative
Test substance: Molecular weight ~ 3200 |

Genotoxicity in vivo: no data available |

Carcinogenicity: no data available

Toxicity for reproduction and development

Toxicity to reproduction/Fertility: no data available |

Developmental Toxicity/Teratogenicity: no data available |

STOT

STOT - single exposure: The substance or mixture is not classified as specific target organ
toxicant, single exposure according to GHS criteria. |

STOT - repeated exposure: The substance or mixture is not classified as specific target organ
toxicant, repeated exposure according to GHS criteria.
Oral 28-day - Rat , male and female
NOEL: 1000 mg/kg
Test substance: Molecular weight ~ 3200
no systemic effect observed |
CMR effects

Mutagenicity: Not mutagenic in Ames Test |

Aspiration toxicity: no data available |

Further information: Description of possible hazardous to health effects is based on

experience and/or toxicological characteristics of several
components.
Thermal decomposition can lead to release of toxic and corrosive
gases.
The exposure to decomposition products causes severe irritation of
eyes, skin and mucous membranes. |

12. Ecological information

12.1 Toxicity

Aquatic Compartment

Acute toxicity to fish: By analogy

No toxicity at the limit of solubility |

Acute toxicity to daphnia and other

aquatic invertebrates.: By analogy
No toxicity at the limit of solubility |

Safety data sheet 300326943_002_A3 Page 8/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

12.2 Persistence and degradability

Degradability assessment: The product is not considered to be rapidly degradable in the

environment |

12.3 Bioaccumulative potential: no data available

12.4 Mobility in soil: no data available

12.5 Results of PBT and vPvB

assessment: no data available |

12.6 Other adverse effects: no data available |

Ecotoxicity assessment

Acute aquatic toxicity: No toxicity at the limit of solubility |

Remarks: Ecological injuries are not known or expected under normal use. |

13. Disposal considerations

13.1 Waste treatment methods

Product Disposal: Can be incinerated, when in compliance with local regulations.

The incinerator must be equipped with a system for the neutralisation
or recovery of HF.
Dispose of in accordance with local regulations. |

Advice on cleaning and disposal of

packaging: Empty containers can be landfilled, when in accordance with the
local regulations.

14. Transport information

ADR: not regulated

RID: not regulated

IMDG: not regulated

IATA: not regulated

ADN/ADNR: not regulated |

Note: The above regulatory prescriptions are those valid on the date of
publication of this sheet. Given the possible evolution of transport
regulations for hazardous materials, it would be advisable to check
their validity with your sales office. |

Safety data sheet 300326943_002_A3 Page 9/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Other regulations: - Regulation (EC) No 1272/2008 of the European Parliament and of

the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, as amended
- Regulation (EC) No 1907/2006 of the European Parliament and of
the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), as
amended
- European Waste Catalogue
- Waste codes should be assigned by the user based on the
application for which the product was used.

Notification status |

Inventory Information Status

United States TSCA Inventory Listed on Inventory
Canadian Domestic Substances List (DSL) Listed on Inventory
Australia Inventory of Chemical Substances (AICS) Listed on Inventory
Korea. Korean Existing Chemicals Inventory (KECI) Listed on Inventory
China. Inventory of Existing Chemical Substances in Listed on Inventory
China (IECSC)
Japan. ISHL - Inventory of Chemical Substances Listed on Inventory
Japan. CSCL - Inventory of Existing and New Listed on Inventory
Chemical Substances
Philippines Inventory of Chemicals and Chemical Listed on Inventory
Substances (PICCS)
New Zealand. Inventory of Chemical Substances Listed on Inventory
Taiwan. Chemical Substance Inventory (TCSI) Listed on Inventory
EU. European Registration, Evaluation, Authorisation If product is purchased from Oerlikon Leybold Vacuum
and Restriction of Chemical (REACH) it is in compliance with REACH.

15.2 Chemical Safety Assessment: A Chemical Safety Assessment is not required for this substance.

16. Other information

Key or legend to abbreviations and acronyms used in the safety data sheet
C Ceiling limit
STEL Short term exposure limit
TWA Limit Value - eight hours

History

Date of issue: October 05, 2009

Date of revision: September 21, 2015

Version: A3

| Indicates information that has changed from previously issued version.

Safety data sheet 300326943_002_A3 Page 10/11 Date of printing: December 14, 2015
 Oerlikon
Leybold Vacuum GmbH
Bonner Str. 498
D-50968 Cologne

SAFETY DATA SHEET

Trade name: LEYBONOL LVO 400 Date of issue: Oct 05, 2009
Date of revision: Sep 21, 2015

NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is ","
(comma).
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. Such information is only given as a guidance to help the user handle, use, process,
store, transport, dispose and release the product in satisfactory safety conditions and is not to be considered as a
warranty or quality specification. It should be used in conjunction with technical sheets but do not replace them.
Thus, the information only relates to the designated specific product and may not be applicable if such product is
used in combination with other materials or in any other manufacturing process, unless otherwise specifically
indicated. It does not release the user from ensuring he is in conformity with all regulations linked to its activity.

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