Test No # 08 Chemical Equilibrium: Prepared By: SIR SARWAR AZIZ

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Test No # 08

Chemical Equilibrium
1. In the reaction A2(g) + 4B2(g) 2AB4(g) such that ∆h < 0; the formation of AB4(g)
will be favored at:
a) Low temperature and high pressure b) High temperature and
low pressure
c) Low temperature and low pressure d) High temperature and
high pressure
2. Consider the reaction PCl5 (g) PCl3 (g) + Cl2 (g) in a closed container at
equilibrium. At a fixed temperature, what will be the effect of adding more PCl5
on the equilibrium constant?
a) It increases b) It decreases
c) It remains constant d) Can’t be predicted with Kp
3. The oxidation of SO2 to SO3 is exothermic reaction. The yield of SO3 will
be maximum if:
a) Temperature is increased and pressure is kept constant
b) Temperature is reduced and pressure increased
c) Both temperature and pressure are increased
d) Both temperature and pressure are increased
4. If the concentration of salt is greater than the acid in buffer solution, then the
a) pH = pKa b) pH > pKa
c) pH = pKb d) pH < pKb
5. In a saturated solution of AgCl, the molar concentration of Ag+ and Cl- is 1.0 × 10-
5
M each. What is the value of Ksp.
a) 1.0 × 10-5 b) 1.0 × 10-15
-5
c) 0.1 × 10 d) 1.0 × 10-10
6. The solubility of Fe(OH)3 is ‘x’ mole per dm3. Its Ksp would be:
a) 9x3 b) 3x4
4
c) 27x d) 9x4
7. For the reaction H2(g) + I2(g) ⇌ 2HI(g). The equilibrium constant changes with
a) Total pressure b) Catalyst
c) Concentration of H2 and I2 d) Temperature
8. The decomposing of H2O4 to NO2 is carried out at 2800C in chloroform. When
equilibrium is reached. 0.2 moles of N2O4 and 0.02 moles of NO2 are present in 1:1
ratio. The equilibrium constant for the reaction N2O4 → 2NO2 is:
a) 0.01 b) 0.02
c) 0.001 d) 0.002
9. In a given system, water and ice are in equilibrium, if the pressure is applied to the
above system then:
a) More ice is formed b) Amount of ice & water will remain the same
c) More ice is melted d) Both A & B
10. The solubility product of AgCl is 2.0 × 10 mol dm-6. The maximum
-10 2

concentration of Ag+ ions in the solution is:


a) 1.41 × 10-5 mol2 dm-6 b) 2.0 × 10-10 mol2 dm6
c) 1.41 × 10-10 mol2 dm-6 d) 4.0 × 10-20 mol2 dm6
11. An excess of silver nitrate is added to the aqueous barium chloride and the
precipitate is removed by filtration. What are the main ions in the filtrate:
a) Ag+ and NO3- b) Ag+ and NO3- and Ba+2 only
- +2
c) NO3 and Ba only d) Cl- and NO3- and Ba+2 only
Prepared by: SIR SARWAR AZIZ
12. pH of 10-4 mole dm3 of HCl:
a) 2 b) 3
c) 4 d) 5
13. The most suitable temperature for preparing ammonia gas is:
a) 2500C b) 3500C
0
c) 450 C d) 5500C
14. The Hw of water at 250C is given by:
a) 10-7 b) 10-12
c) 10-10 d) 10-14
15. When HCl gas is passed through saturated solution of rock salt, the solubility
of NaCl:
a) Increases b) Decreases
c) May increases or decreases d) None of these
16. For that value of Kc almost forward reaction is complete:
a) Kc = 10 b) Kc = 1030
c) Kc = 1 d) Kc = 0
17. In which of the following equilibria will Kc and Kp have not the same value,
a) 2HI ⇌ H2 + I2 b) N2 + O2 ⇌ 2NO
c) 2SO2 + O2 ⇌ 2SO2 d) All of these
18. Correct relationship b/w Kc and Kp can be written as:
a) Kp = Kc (R)∆n b) Kp = Kc (RT)∆n
c) Kp = Kc (RT)∆n d) Kp = Kc (R/N)∆n
19. If the temperature is increased of following reaction, then will go in
N2 + 3H2 ⇌ 2NH3∆H = – Ve
a) Forward direction b) reverse reaction
c) Remain direction d) Cannot be predicted
20. If the temperature term is present in denominator of Kc expression, then which
one is correct?
a) Increase in pressure will shift the reaction backward?
b) Increase in pressure will shift the forward direction?
c) Increase in pressure will shift the forward direction?
d) Reaction will not effected

Prepared by: SIR SARWAR AZIZ

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