2015 Montan Waxes and Special Wax Blends For Car Polish Base Formulations en

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Wash

preserver

Car polish, liquid


Car polish, creme
Car polish, paste

Car
shampoo

Soft paste, good


cleaning effect

WHEN PERFORMANCE COUNTS

Montan waxes and special wax blends for car polish base formulations
M O NTAN WAXE S M O N TA N WA X E S

VOELPKER: TO MAKE IDEAS WORK

Introduction rain, salt and other contaminants. The care and


preservation of vehicle bodywork requires com-
With more than 100 years of production history,
pounds that clean, restore the gloss and colour
Voelpker is among the most long-standing
of the paintwork and leave behind them a hard,
wax producers in Europe and is internationally
water-resistant protective film.
renowned as a reliable manufacturer and sup-
plier of montan waxes and special wax blends.
Bleached montan waxes fulfil these requirements
True to the motto “to make ideas work”, we do
perfectly as components of automotive polishes.
everything to improve and optimize our custo-
They act as protective, hard waxes and also add
mers’ products and processes.
gloss. Due to its excellent physical and chemical
properties, montan wax is often an ideal substitu-
Montan waxes – when performance counts
te for the expensive and price-volatile Carnauba
Car polishing is essential. Every day, the paint wax. It is widely used in daily chemical industry,
of cars is radiated by the sun and in constant wax polish industry, plastics industry, sinter metal MONTAN WAXES
contact with environmental pollution like acid industry and many other industries using wax.

Structure decided in each individual case which product


should be used, depending on the age and
WARADUR® S is a mixture of linear montanic
condition of the paintwork. Old and weathered
acids (C28 - 32). WARADUR® E consists of esters
paintwork that has become matt should be tre-
Applications and effects of lubricants classes in different thermoplastics of montanic acids with ethylene glycol. As a re-
ated with products containing fine ‘cutting’ or
Acid number
Viscosity
Applications sult of the long, linear carbon chain, the montan
Chemical nature Drop point (°C)
(mg KOH/g)
@120 °C
(examples)
abrasive components, in order to remove we-
(mPas) waxes exhibit have a good thermal stability and
athered paintwork and restore the surface finish
WARADUR® S Montanic acids C28 - C32 ca. 85 ca. 140 ca. 15 Car polish a low volatility.
(cleaners). Polishes using an emulsion basis (emul-
WARADUR® B Montanic acids C28 - C32 ca. 86 ca. 114 ca. 15 Car polish sions) can be applied both to dry and wet (pre-
General information on Car care
Ethylene glycol esters of montanic acids, Car shampoo, viously cleaned) paint surfaces. For polishes using
WARADUR® ELE ca. 85 ca. 26 ca. 15
emulsifier wash preserver
Automotive care agents should restore and re- a solvent basis (oils), it is recommended that the
Ethylene glycol esters of montanic acids, Car shampoo, fresh the bodywork and paintwork of vehicles, washed vehicle be thoroughly dried before ap-
WARADUR® LGE ca. 85 ca. 24 ca. 15
emulsifier wash preserver
which under daily use of the vehicle takes on a plication. In order to save time, so-called wash
Ethylene glycol esters of montanic acids, Car shampoo,
VOELPKER® 2714 ca. 86 ca. 22 ca. 15 dull and unsightly appearance due to dirt, wet, preservers can also be used, which are added to
fatty acid esters, emulsifier wash preserver

Water based car exposure to sunlight and other effects. the rinsing water after washing the vehicle (after
polish, Solvent
WARADUR® E Ethylene glycol esters of montanic acids ca. 85 ca. 18 ca. 15 cleaning with washing agents), or auto sham-
based car polish
(liquid/paste)
Car care agents maintain the gloss of the surface poos, especially those with a continuous lubrica-
Solvent based
VOELPKER® 6211 Proprietary wax blend ca. 108 ca. 11 ca. 100 car polish (liquid/ finish, have a preserving effect on the bodywork ting effect.
paste)
itself and protect against corrosion. It should be
Table 1: Chemical nature, physical data and typical car care applications of Voelpker montan waxes and special wax blends

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M O N TAN WAXE S A PPL I C AT I O N E X A M PL E S

APPLICATION EXAMPLES

Car polish, soft paste, good cleaning effect

% by weight Raw material

6.5 WARADUR® S (or WARADUR® B)

0.5 Oleic acid

1.0 Stearic acid

6.0 Silicon oil AK 350

6.0 Petroleum

0.8 Diethylaminoethanol (DEAE)

53.2 Softened water

Other functional raw materials In the case of older bodywork, so-called cleaners 15.0 Snow Floss

are used (liquid or paste), which contain larger


Silicon oil makes the polishing easier, and also pro- Manufacture:
quantities of abrasive agent. It is sometimes neces-
motes a smooth finish and the depth of the gloss Wax melting: melt WARADUR® S, oleic acid and stearic acid at 85 °C; add the silicon oil to the solvent agent. Add the hot
sary to use somewhat coarser abrasive agents, solvent to the melted wax while agitating. Then add the diethyl-amino-ethanol to the clear solution. Pre-heat the water/
(viscosity 350 - 500 mPas). High-viscosity silicon oil abrasive agent mixture to about 50 °C and add the mixture while stirring. Continue stirring while allowing the emulsion to
such as siliceous (diatomaceous) earth or coarser
cool down to about 45 °C, and then fill into cans or tubes.
can be used to give better consistency (viscosity
gradations of chalk. Such abrasive compounds
10,000 mPas), and also increases the water-re-
however should contain no very coarse compo-
sistant properties of wax polishes. Silicon oil makes
nents, in order to avoid leaving fine scratch marks.
the paint surface more weather-resistant, allowing
raindrops to run off without leaving a mark. The sili-
Solvents have a cleaning effect and get rid of oily
con oil is usually added to the solvent agent. Car polish, liquid, can be manufactured cold
and greasy dirt. In general, white spirit is used, or
more volatile spirit with a boiling range of around % by weight Raw material
Abrasives have a cleaning effect. These are usual-
100 - 140 °C. At warm times of the year, this means 45.4 Water
ly finely ground and pulverised silicates, such as
that the polish can sometimes dry off very quick-
0.2 Carbopol EZ
Kaolin, Aerosil or Neuburg siliceous earths. The par-
ly. In this case, solvents with a higher boiling point
5.0 Sillitin N 85
ticle size and quantity of the abrasive compounds
(e.g. petroleum) can be used as additives. These
used also has an effect on the consistency of the 7.6 Tegopolish additive E 3400/5
solvent agents hardly attack the paint at all, al-
polishes. Very voluminous abrasive agents (e.g. 8.6 Tegopolish additive E 35
though the individual types of solvent should still
Aerosil) have a much better filling effect than ab- 33.2
WARADUR® ELE wax emulsion (12 %, APEO free) or
be checked for their possible effects. VOELPKER® 2714 wax emulsion
rasive compounds with less filling capacity. For the
care and maintenance of new bodywork, polishes Manufacture:
Paraffin can also improve the polishing properties
without abrasive additives are used, or very small Prepare the water. Mix the Carbopol thoroughly with siliceous earth and slowly stir into the water. When this mixture is ho-
of the formulation. mogenous, add the silicon components slowly one after the other, and finally the wax emulsion. The acrylate polymerises
quantities of very fine abrasive compound on spe- and thickens due to the basic amino-siloxan. The wax emulsion is prepared in advance using the spreading process.

cific areas.

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APPL IC AT I O N E X AMPLE S A PPL I C AT I O N E X A M PL E S

Car polish, liquid Car polish, thick liquid/creme Car shampoo Wash preserver

% by weight Raw material % by weight Raw material % by weight Raw material % by weight Raw material

2.4 WARADUR® S (B) 8.0 WARADUR® S (B) 20.0 Lutensol ON 70 WARADUR® LGE or
8.0
WARADUR® ELE (APEO free)
1.0 Oleic acid 1.0 Oleic acid 10.0 Lutensid A-LBA
2.5 Emulan A
3.0 Silicon oil Tegiloxan 1000 2.0 Silicon oil Tegiloxan 1000 45.0 Water
1.5 Lutensol AP 10
1.0 Silicon oil emulsion E 10 2.0 Silicon oil Tegiloxan 10000 WARADUR® LGE wax emulsion (12 %)
or WARADUR® ELE wax emulsion 15.0 White spirit
25.0
43.5 White spirit (crystal oil K 60) 4.0 Silicon oil emulsion E 10 (12 %, APEO free) or VOELPKER® 2714
wax emulsion (12 %) 8.0 Spindle oil
1.0 Morpholin 18.0 Benzine 100/140
4.0 Latekoll D 4 %
44.6 Softened water 10.0 Crystal oil K 60

3.5 Snow Floss 1.0 Morpholin Manufacture: Manufacture:


The active washing agents are dissolved in warm The wax emulsion is prepared in advance using the
44.0 Softened water water and then added to the wax emulsion. The spreading process. Lutensol AP 10 is first added to the
wax emulsion is prepared in advance using the hot water. Boil briefly before stirring in the mixture of
10.0 Snow Floss
spreading process. emulsifier, spindle oil and benzine. Then allow to cool
and finally add the thickening agent.
Manufacture: Manufacture:
Wax melting: melt WARADUR® S and oleic acid at Wax melting: melt WARADUR® S and oleic acid at The wash preserver is added to the rinsing water when
85 °C; add the silicon oil to the solvent agent. Add the 85 °C; add the silicon oil to the solvent agent. Add the washing the vehicle (approx. 0.2 vol %).
hot solvent to the melted wax while agitating. Then add hot solvent to the melted wax while agitating. Then add
the diethylaminoethanol to the clear solution. Pre-heat the diethylaminoethanol to the clear solution. Pre-heat
the water/silicon oil emulsion/abrasive agent mixture to the water/silicon oil emulsion/abrasive agent mixture to
about 50 °C and add the mixture while stirring. Continue about 50 °C and add the mixture while stirring. Continue
stirring while allowing the emulsion to cool down to stirring while allowing the emulsion to cool down to
about 45 °C, and then fill into cans or tubes. about 45 °C, and then fill into cans or tubes.

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APPL IC AT I O N E X AMPLE S M O N TA N WA X E S

Car polish, liquid

% by weight Raw material

3.8 VOELPKER® 6211

0.6 Silicon oil Tegiloxan 350

0.4 Dow Corning fluid 530

2.2 Dow Corning fluid 531

63.0 Benzine 100/140

30.0 White spirit 140/200

Manufacture:
For the manufacture of fine-particle wax dispersions, melt VOELPKER® 6211 at approx. 110 °C. Then add the solvent agent,
in which the silicon oils have first been dissolved, while stirring gently, at such a rate as to produce a clear solution. The tem-
perature should not be allowed to fall below 75 - 80 °C. Then cool down to room temperature as quickly as possible while still
stirring thoroughly. Further homogenisation (Ultra-Turrax) produces dispersions which create specially tight-sealing wax films.

If the clear wax solutions are cooled only until they begin to cloud, and then allowed to cool more slowly, this generally pro-
duces semi-solid pastes or gels, which however still consist of very fine particles.

WARADUR® MONTAN WAXES:


Car polish, paste GENERAL ADVANTAGES AT A GLANCE

% by weight Raw material

2.0 VOELPKER® 6211 • Ideal for polish applications


0.5 WARADUR® E • Act as protective, hard waxes and also add gloss
4.5 Luwax A • Ideal for high quality applications
3.0 Micro hard wax (85 - 92 °C) • Easy to emulsify
17.0 Paraffin 52/54 • Excellent physical and chemical properties
2.0 Silicon oil Tegiloxan 350 • Ideal substitute for the expensive and price-volatile Carnauba wax
71.0 White spirit 140/200

Manufacture:
For the manufacture of fine-particle wax dispersions, melt VOELPKER® 6211 together with the other waxes at approx.
110 °C. Then add the solvent agent, in which the silicon oils have first been dissolved, while stirring gently, at such a rate
as to produce a clear solution. The temperature should not be allowed to fall below 75 - 80 °C. The clear wax solutions are
then cooled only until they begin to cloud, and then allowed to cool more slowly.

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WARADUR® S Product Information
Product Description
WARADUR® S consists of straight chained monocarboxylic acids with a chain length in the range of mainly C28 – C32.

General Advantages
High polarity, high hardness, easy to saponify, easy to emulsify.
High effectiveness at low concentrations: WARADUR® S is suitable for a wide range of plastics applications, mainly as external release agent, dispersing agent,
gloss booster and surface improver. WARADUR® S is suitable for engineering plastics, thermosets, etc.

Examples of Use
 Thermoplastics: ABS and copolymers
 Thermosets: Epoxy resins, phenolic resins
 Dispersing agents for colour masterbatches
 Solvent for black or coloured dye basis
 Polishes
 Cosmetics (INCI: Montan Acid Wax)

Delivery Specifications *
Characteristics Unit Target value Method
Acid value * mg KOH/g 135 – 160 ISO 2114
Saponification value * mg KOH/g 155 – 180 ISO 3681
Drop point * °C 82 – 88 ASTM 3954
Colour – pale yellow AA 3.2.1.505
Viscosity @ 120 °C mPas 10 – 15 AA 3.2.1.520
Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5

Packaging and Handling


Physical form Flakes, also available as powder
Packaging Paper bag or Big Bag
Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight.
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer.
Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated.

Safety
WARADUR® S
 is made from a fossil biological source
 is not classified as carcinogenic, mutagenic or reprotoxic; no health or environmental hazards are known, provided it is applied in industrial and professional settings
For more information, consult SDS.

Delivery Time and Availability


Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market.

Legislation
Food contact legislation:
 Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food
Other legislation:
 RoHS and CONEG compliant
 Listed in all relevant National Inventories
For further information, please contact [email protected].

The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the
accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our
products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights.
The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased.
Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com

10 11
WARADUR® B Product Information WARADUR® ELE Product Information
Product Description Product Description
WARADUR® B consists of straight chained monocarboxylic acids with a chain length in the range of mainly C28 – C32. WARADUR® ELE is a special wax blend, consisting of esters of long-chain fatty acids (mainly C28 – C32) with multihydroxyl alcohols. The corresponding esters
exhibit chain length in the range of mainly C34 – C66. Product for the preparation of aqueous dispersions. A proprietary emulsifier mixture (APEO free) is already
General Advantages incorporated in this blend.

High polarity, high hardness, easy to saponify, easy to emulsify General Advantages
High effectiveness at low concentrations: WARADUR® B is suitable for a wide range of plastics applications, mainly as external release agent, dispersing agent,
gloss booster and surface improver. WARADUR® B is suitable for engineering plastics, thermosets, etc. WARADUR® ELE is easy to emulsify. Non-ionic emulsions can prepared up to concentrations of 25 – 30 %. Because the wax is self-emulsifying, emulsions are
easily prepared by stirring the solid pastilles into hot water.
Examples of Use Technical support available upon request.

 Thermoplastics: ABS and copolymers Examples of Use


 Thermosets: Epoxy resins, phenolic resins
 Dispersing agents for colour masterbatches  Polishes: Emulsions of WARADUR® ELE can be used in dry-bright floor polishes and cleaners for household, industrial and institutional use. They can also be
 Solvent for black or coloured dye basis used in leather polishes and car care products.
 Polishes  Leather industry: Additive for leather finishes, for improving handle, flexibility, gloss. Dressing for shoes.
 Wood industry: Mould release for aminoplast resins applied as laminates to furniture.
Delivery Specifications *  Paper and Packaging: Anti-blocking agent for PVCD and other polymers.
 Plastics industry: Slip agent for injection moulding, and for foam mouldings made from hot-cured polyurethane foam.
Characteristics Unit Target value Method  Technical information brochure about emulsions preparation available upon request.
Acid value * mg KOH/g 90 – 120 ISO 2114
Saponification value * mg KOH/g 135 – 155 ISO 3681 Delivery Specifications *
Drop point * °C 82 – 88 ASTM 3954 Characteristics Unit Target value Method
Colour – pale yellow – yellow AA 3.2.1.505
Acid value * mg KOH/g 25 – 35 ISO 2114
Viscosity @ 120 °C mPas 10 – 15 AA 3.2.1.520
Saponification value * mg KOH/g 110 – 140 ISO 3681
Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5
Drop point * °C 82– 88 ASTM 3954
Colour – pale yellow AA 3.2.1.505
Packaging and Handling
Viscosity @ 120 °C mPas 10 – 20 AA 3.2.1.520
Physical form Flakes Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5
Packaging Paper bag or Big Bag
Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight. Packaging and Handling
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer. Physical form Flakes
Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated.
Packaging Paper bag or Big Bag
Safety Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight.
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer.
WARADUR® B Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated.
 is made from a fossil biological source
 is not classified as carcinogenic, mutagenic or reprotoxic; no health or environmental hazards are known, provided it is applied in industrial and professional settings Safety
For more information, consult SDS.
Consult SDS.
Delivery Time and Availability
Delivery Time and Availability
Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market.
Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market.

Legislation Remark: Voelpker’s R&D department is permanently developing new special wax blends for the preparation of aqueous dispersions. Please contact us for your
individual requirements.
Food contact legislation:
 Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food Legislation
Other legislation:
Food contact legislation:
 RoHS and CONEG compliant
 Product for technical applications
 Listed in all relevant National Inventories
Other legislation:
For further information, please contact [email protected].
 RoHS and CONEG compliant
 Ingredients listed in all relevant National Inventories
For further information, please contact [email protected].

The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the
accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our
products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights. products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights.
The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased. The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased.
Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com

12 13
WARADUR® LGE Product Information VOELPKER® 2714 Product Information
Product Description Product Description
WARADUR® LGE is a special wax blend, consisting of esters of long-chain fatty acids (mainly C28 – C32) with multihydroxyl alcohols. The corresponding esters VOELPKER® 2714 is a special wax blend, consisting of esters of long-chain fatty acids (C16 – C32) with multihydroxyl alcohols. The corresponding esters exhibit
exhibit chain length in the range of mainly C34 – C66. Product for the preparation of aqueous dispersions. A proprietary emulsifier mixture is already incorporated chain length in the range of C34 – C66. Product for the preparation of aqueous dispersions. A proprietary emulsifier mixture (APEO free) is already incorporated
in this blend. in this blend.

General Advantages General Advantages


WARADUR® LGE is easy to emulsify. Non-ionic emulsions can prepared up to concentrations of 25 – 30 %. Because the wax is self-emulsifying, emulsions are VOELPKER® 2714 is easy to emulsify. Non-ionic emulsions can prepared up to concentrations of 25 – 30 %. Because the wax is self-emulsifying, emulsions are
easily prepared by stirring the solid pastilles into hot water. easily prepared by stirring the solid pastilles into hot water.
Technical support available upon request. Technical support available upon request.

Examples of Use Examples of Use


 Polishes: Emulsions of WARADUR® LGE can be used in dry-bright floor polishes and cleaners for household, industrial and institutional use. They can also be  Polishes: Emulsions of VOELPKER® 2714 can be used in dry-bright floor polishes and cleaners for household, industrial and institutional use. They can also be
used in leather polishes and car care products. used in leather polishes and car care products.
 Leather industry: Additive for leather finishes, for improving handle, flexibility, gloss. Dressing for shoes.  Leather industry: Additive for leather finishes, for improving handle, flexibility, gloss. Dressing for shoes.
 Wood industry: Mould release for aminoplast resins applied as laminates to furniture.  Wood industry: Mould release for aminoplast resins applied as laminates to furniture.
 Paper and Packaging: Anti-blocking agent for PVCD and other polymers.  Paper and packaging: Anti-blocking agent for PVCD and other polymers.
 Plastics industry: Slip agent for injection moulding, and for foam mouldings made from hot-cured polyurethane foam.  Plastics industry: Slip agent for injection moulding, and for foam mouldings made from hot-cured polyurethane foam.
 Technical information brochure about emulsions preparation available upon request.  Technical information brochure about emulsions preparation available upon request.

Delivery Specifications * Delivery Specifications *


Characteristics Unit Target value Method Characteristics Unit Target value Method
Acid value * mg KOH/g 20 – 30 ISO 2114 Acid value * mg KOH/g 17 – 25 ISO 2114
Saponification value * mg KOH/g 127 – 147 ISO 3681 Saponification value * mg KOH/g 105 – 125 ISO 3681
Drop point * °C 82– 88 ASTM 3954 Drop point * °C 85 – 88 ASTM 3954
Colour – pale yellow AA 3.2.1.505 Colour – pale yellow AA 3.2.1.505
Viscosity @ 120 °C mPas 10 – 20 AA 3.2.1.520 Viscosity @ 120 °C mPas 10 – 20 AA 3.2.1.520
Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5 Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5

Packaging and Handling Packaging and Handling


Physical form Flakes Physical form Pastilles
Packaging Paper bag or Big Bag Packaging Paper bag or Big Bag
Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight. Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight.
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer. The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer.
Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated. Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated.

Safety Safety
Consult SDS. Consult SDS.

Delivery Time and Availability Delivery Time and Availability


Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market. Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market.
Remark: Voelpker’s R&D department is permanently developing new special wax blends for the preparation of aqueous dispersions. Please contact us for your Remark: Voelpker’s R&D department is permanently developing new special wax blends for the preparation of aqueous dispersions. Please contact us for your
individual requirements. individual requirements.

Legislation Legislation
Food contact legislation: Food contact legislation:
 Product for technical applications  Product for technical applications
Other legislation: Other legislation:
 RoHS and CONEG compliant  RoHS and CONEG compliant
 Ingredients listed in all relevant National Inventories  Ingredients listed in all relevant National Inventories
For further information, please contact [email protected]. For further information, please contact [email protected].

The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the
accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our
products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights. products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights.
The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased. The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased.
Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com

14 15
WARADUR® E Product Information VOELPKER® 6211 Product Information
Product Description Product Description
WARADUR® E is a hard ester wax with a crystalline structure, consisting of esters of montanic acids with multihydroxyl alcohols. Montanic acids are straight VOELPKER® 6211 is a special wax blend based on polymer waxes, hydrocarbon waxes and stearates.
chained monocarboxylic acids with a chain length in the range of mainly C28 – C32. The corresponding esters exhibit chain length in the range of mainly
C58 – C66. General Advantages
General Advantages Depending from the concentration, clear solutions of VOELPKER® 6211 in hot organic solvents crystallize to form very finely divided liquid dispersions, gels or
pastes when the heated solution is cooled under stirring. The received wax preparations have a very slightly solvent retention when the wax dispersion is dried.
WARADUR® E improves the flowability of a wide range of plastics and at the same time also reduces the demoulding force. Acts as dispersing agent, gloss booster, On a surface they form very dense, buffable films.
surface improver. Provides low volatility, good thermostability and low migration rates. WARADUR® E is easy to saponify and emulsify and can be buffed to a
high gloss. Also provides good paste- and dispersion forming properties with organic solvents. Examples of Use
Examples of Use  VOELPKER® 6211 films are impermeable to air, corrosive gases, water, salt solutions, acids, alkalis, coolants and other aggressive substances. These films are
therefore very good for protecting metal surfaces from corrosion, e.g. during transportation by sea or during storage of new tools, machinery and motors to
 WARADUR® E is extremely versatile and suitable for a wide range of plastics applications as a multi-purpose additive in engineering plastics, thermosets, PVC preserve the coated surface of new motor vehicles, refrigerators, washing machines etc. and for car underbody protection. VOELPKER® 6211 is also used as
etc. For more information consult the technical leaflet: Montan waxes in plastics: "When performance counts". stop-off wax, e.g. in galvano applications.
 WARADUR® E can be used to manufacture polishes based on aqueous emulsions of (saponified) wax with or without emulsifiers. It is used in its saponified  Very finely divided, liquid wax dispersions can be prepared that dry to form a very glossy and dense, easy to polish film. This is very important for polishes
form in leather care products, polishes and abrasive pastes (e.g. car polishes), etc. It performs particularly well in co-emulsions of wax and solvents in water. applied to floors and car bodywork or other substrates (other tin surfaces, furniture, parquetry), which requires a good film formation.
WARADUR® E can be used in combination with microcrystalline waxes, paraffin wax, hydrogenated plant oils and others.  Dispersions of VOELPKER® 6211 can be used in injection moulding as a mould release agent for thermosets, e.g. polyurethanes.
 Other applications: paper coating, cosmetics (INCI: Glycol Montanate), metal work, compacting aids in powder metallurgy.  The consistency of the wax dispersion can be adjusted from liquid to pasty by choosing the adequate proportion and concentration of VOELPKER® 6211 and if
necessary other additional waxes.
Delivery Specifications *  Technical information brochure available upon request.

Characteristics Unit Target value Method Delivery Specifications *


Acid value * mg KOH/g 15 – 20 ISO 2114 Characteristics Unit Target value Method
Saponification value * mg KOH/g 140 – 160 ISO 3681
Drop point * °C 82 – 88 ASTM 3954 Acid value * mg KOH/g 10 – 14 ISO 2114
Colour – pale yellow AA 3.2.1.505 Saponification value * mg KOH/g 17 – 25 ISO 3681
Viscosity @ 120 °C mPas 15 – 20 AA 3.2.1.520 Drop point * °C 104 – 112 ASTM 3954
Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5 Colour – off-white AA 3.2.1.505
Viscosity @ 120 °C mPas 90 – 120 AA 3.2.1.520
Packaging and Handling Density g/cm3 1.00 – 1.02 Ph. Eur. 2.2.5

Physical form Flakes, also available as powder Packaging and Handling


Packaging Paper bag or Big Bag
Physical form Pastilles
Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight.
Packaging Paper bag or Big Bag
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer.
Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated. Storage Store at ambient temperature on a dry place. Protect from heat/overheating and direct sunlight.
The minimum remaining period is 1.5 years and is defined as the minimum shelf life at the customer.
Safety Thereafter, tests of the chemical characteristics are recommended. The maximum shelf life of 5 years is indicated.

WARADUR® E Safety
 is made from a fossil biological source
 reached the criteria for inherent biodegradability (OECD Guideline 301 D, Closed Bottle Test) VOELPKER® 6211 is not classified as carcinogenic, mutagenic or reprotoxic; no health or environmental hazards are known, provided it is applied in industrial and
 is not classified as carcinogenic, mutagenic or reprotoxic; no health or environmental hazards are known, provided it is applied in industrial and professional settings professional settings.
For more information, consult SDS.
Delivery Time and Availability
Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market. Delivery Time and Availability
Standard delivery time: 2 – 3 weeks. Preconditions can be met for achieving shorter delivery times on standard products when demanded by the market.
Legislation Remark: Voelpker’s R&D department is permanently developing new special wax blends for the preparation of solvent-based dispersions. Please contact us for
Food contact legislation: your individual requirements.
 FDA 175.105 Adhesives ("montan wax")
 FDA 177.2600 Rubber articles intended for repeated use ("montan wax") Legislation
 FDA 178.3770 For use in lubricants in the fabrication of vinyl chloride plastic food contact articles
 Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food Food contact legislation:
 Product for technical applications
Other legislation:
 RoHS and CONEG compliant Other legislation:
 Listed in all relevant National Inventories  RoHS and CONEG compliant
 Ingredients listed in all relevant National Inventories
For further information, please contact [email protected].
For further information, please contact [email protected].

The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or guarantee the
accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to whom we supply our
products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights. products directly or indirectly to ensure that their use of the products complies with existing regulations, laws, legislations and proprietary rights.
The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased. The information given by Völpker Spezialprodukte does not exempt the customer from carrying out inspections and analyses on goods purchased.
Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com Völpker Spezialprodukte GmbH · Fabrikstraße 1 · 39393 Völpke · Germany · Telephone +49 39402 962-0 · www.voelpker.com

16 17
Raw material supplier information Space for your notes:

Abrasives Solvents

Snow floss Siliceous earth Petroleum White spirit containing aromatics with a
Lehmann & Voss, Hamburg boiling range of 200 - 240 °C

Sillitin N 85 Siliceous earth Benzine 100/140 White spirit without aromatics with a
Hoffmann Mineral, Neuburg boiling range of 100 - 140 °C

Crystal oil K 60 White spirit, mixture of aliphatic,


Waxes naphthenic and aromatic hydrocarbons
with a boiling range of 182 - 212 °C
Paraffin 52/54 Hydrocarbon wax Deutsche Shell, Hamburg
Ter Hell, Hamburg

Luwax A Ethylene homopolymer wax Emulsifiers


BASF SE, Ludwigshafen
Emulan A Emulsifier
WARADUR® B Montan acid wax BASF SE, Ludwigshafen
Völpker Spezialprodukte GmbH, Völpke

WARADUR® ELE (APEO free) Montan ester wax, contains emulsifier Surfactants
Völpker Spezialprodukte GmbH, Völpke
Lutensol ON 70 Non-ionic surfactant based in linear fatty
WARADUR® LGE Montan ester wax, contains emulsifier alcohol
Völpker Spezialprodukte GmbH, Völpke BASF SE, Ludwigshafen

WARADUR® S Montan acid wax Lutensol AP 10 BASF SE, Ludwigshafen


Völpker Spezialprodukte GmbH, Völpke
Lutensit A-LBA Anionic surfactant amine salt of
VOELPKER® 2714 Special montan wax blend, contains alkylbenzene-sulfonate
emulsifier BASF SE, Ludwigshafen
Völpker Spezialprodukte GmbH, Völpke

VOELPKER® 6211 Special wax blend Thickeners


Völpker Spezialprodukte GmbH, Völpke
Carbopol EZ Polyacrylic acid, rheology modifier
Lubrizol
Silicon oils
Latekoll D Water-based acrylate solution
Silicon oil AK 350 Linear, non-reactive polydimethylsiloxane BASF SE, Ludwigshafen
with a viscosity of approx. 350 mm²/s
Wacker Chemie AG

Tego Polish Additive E 3400/5 40 % Amino siloxane emulsion


Evonik

Tego Polish Additive E 35 35 % Silicon oil emulsion


Evonik

Silicon oil Tegiloxan 1000 Methyl-silicon oil, 1,000 mPa s


Evonik

Silicon oil Tegiloxan 10000 Methyl-silicon oil, 10,000 mPa s


Evonik

18 19
VÖLPKER
Spezialprodukte GmbH
Fabrikstraße 1 | 39393 Völpke | Germany
Tel. +49 (0) 39402 962-0
Fax +49 (0) 39402 215
[email protected]
www.voelpker.com

DESIGN
www.artfaktor.de

2nd edition | January 2016

Disclaimer
The information contained herein is believed to be accurate and reliable as of the date issued. However, we do not warrant or gu-
arantee the accuracy or reliability, in particular not for any specific intended use by the customer. It is the responsibility of those to
whom we supply our products directly or indirectly to ensure that their use of the products complies with existing regulations, laws,
legislations and proprietary rights. The information given by Völpker Spezialprodukte does not exempt the customer from carrying out
inspections and analyses on goods purchased.

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