Version No.

05 - Revision Date 10/03/2015

MATERIAL SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION
Product name : GALBON S-HB , BASE Product No. : TH 6250
Manufacutrer / Supplier : TOA-CHUGOKU PAINTS CO.,LTD
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24180
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following hazardous ingredients
Ingredient name CAS No. EINECS No. % by weight Classification
Tetraethyl silicate 78-10-4 201-083-8 35 R10
Xn;R20
Xi; 36/37
Ethanol 64-17-5 200-578-6 25 R11
Xylene 1330-20-7 215-535-7 12 R10
Xn; R20/21
Xi; R38
1-methoxy-2-propanol 107-98-2 203-539-1 28 R10
Xi; R41, R37/38
R67

4. FIRST-AID MEASURES

First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

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 Version No.05 - Revision Date 10/03/2015

5. FIRE FIGHTING MEASURES

Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray. Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE

Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.

Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.

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 Version No.05 - Revision Date 10/03/2015

Storage Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Occupational exposure limits

Material STEL-15 min.ave Long term-TWA-8hr
ethanol - 1920 mg/m3
3
xylene 441 mg/m 220 mg/m3
3
1-methoxy-2-propanol 231 mg/m 154 mg/m3

Personal protection equipment

Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

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 Version No.05 - Revision Date 10/03/2015

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : ( ) Solid ( x ) Liquid Odour : Smell of solvent Density : 1.13 g/cm3
( ) Paste ( ) Powder Colour : White Flash point : 15.0 °C (Closed cup)
Solubility : Insoluble in water Explosion limits : LEL% 1.9 UEL% 19
Vapour pressure : 5800 Pa, 20 °C Autoignition temperature : 13 °C
10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.

Aquatic ecotoxicity
Material name Test Result Species Exposure
ethanol Intoxication Acute EC50 9,3 to 11,2 Daphnia-Water flea- 48 hours.
g/L Fresh water Daphnia magna.
Mortality Actute LC50 13 to 16 m/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
xylene Mortality Actute LC50 3300 to 4093 u/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
trout,donaldson-trout-
Oncorhynchus mykiss

Biodegradability Aquatic half-life Photolysis Biodegradability

ethanol - - Readily
Xylene - - Readily

Bioaccumulative potential LogP BCF Potential

Xylene 3.12 High

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 Version No.05 - Revision Date 10/03/2015

13. DISPOSAL CONSIDERATION

Do not allow into drain or watercourses. Material and/or container must e disposed of as hazardous water.
European waste catalogue : 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances.
(EWC) If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assinged. For further information,
contact your local waste authority.

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
UN number : 1263
Class : 3
Packing group : II
Label :

Additional information
ADR/RID : Hazard identification number:33
Special provision: 640D
IMDG : Emergency schedules (EmS) : F-E, S-E
Marine pollutant : No
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. REGULATORY INFORMATION

EU regulation : This product is classified and labelled for supply in accordance with the Directive 1999/45/EC as follows:
Hazard symbol :

Highly flammable
Risk phrases : R10 Flammable
R20 Harmful by inhalation.
R36/37 Irritating to eyes and respiratory system and skin.
R11 Highly flammable.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritaing to skin.
Safety phrases : S23 - Do not breathe vapour / spray
S51 - Use only in well-ventilated areas.
Industrial use : The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

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 Version No.05 - Revision Date 10/03/2015

16. OTHER INFORMATION

CEPE Classification : 1
The information in this Safety Data Sheet is required pursuant to EU Directive 91/155/EEC and its amendments.

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

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 Version No.05 - Revision Date 10/03/2015

MATERIAL SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION
Product name : GALBON S-HB , ZINC DUST Product No. : TH 6250
Manufacutrer / Supplier : TOA-CHUGOKU PAINTS CO.,LTD
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24130
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION
Very toxic to aquatic organisms, may cause long term
adverse effects in the aquatic environment.

Dangerous for
the environment

Additional hazards : Handling and/or processing of this material may generate a dust which can cause mechanical
irritationof the eyes, skin , nose and throat.
3. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following hazardous ingredients

Ingredient name CAS No. EINECS No. % by w.t Risk phrases

zinc powder - zinc dust (stabilized) 7440-66-6 231-175-3 99.7 N; R50/53
zinc oxide 1314-13-2 215-222-5 0.3 N; R50/53

4. FIRST-AID MEASURES

First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

5. FIRE FIGHTING MEASURES

Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray.
Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

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 Version No.05 - Revision Date 10/03/2015

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE

Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.

Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.

Storage Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.
Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

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 Version No.05 - Revision Date 10/03/2015

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Occupational exposure limits

Material MEL-15 min.ave Long term-TWA-8hr
3
zinc powder - zinc dust (stabilized) 10 mg/m 5 mg/m3

cadmium - 0.025 mg/m3

(EH-40 WEL)

Personal protection equipment

Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : ( ) Solid ( ) Liquid Odour : - Density : 7.00 g/cm3
( ) Paste ( x ) Powder Colour : Grey Flash point : - °C (Closed cup)
Solubility : Insoluble in water Explosion limits : LEL% - UEL% -
Vapour pressure : - °C Autoignition temperature : - °C

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 Version No.05 - Revision Date 10/03/2015

10. STABILITY AND REACTIVITY

Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
Aquatic ecotoxicity
Material name Test Result Species Exposure
zinc powder - Mortality Acute LC50 0.24 mg/L Fish-Rainbow 96 hours.
zinc dust (stabilized) Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
Mortality Acute LC50 0.45 ppm Fish-Cyprinus 96 hours.
Fresh water carpio
Mortality Acute LC50 68 ug/L Daphnia-Water flea- Daphnia-Water flea-
Fresh water Daphnia magna. Daphnia magna.

zinc oxide Mortality Acute LC50 1.1 to 2.5 ppm Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
Intoxication Acute EC50 24.4 ug/L Daphnia-Water flea- Daphnia-Water flea-
Fresh water Daphnia magna. Daphnia magna.

cadmium Intoxication Acute EC50 >1000 ppm Daphnia-Water flea- Daphnia-Water flea-
Fresh water Daphnia magna. Daphnia magna.
Mortality Acute LC50 2.1 to 4.44 ppm Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
13. DISPOSAL CONSIDERATION
Do not allow into drain or watercourses. Material and/or container must e disposed of as hazardous water.
European waste catalogue : 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances.
(EWC) If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assinged. For further information,
contact your local waste authority.

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 Version No.05 - Revision Date 10/03/2015

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Environmentally hazardous substancs, solid , n.o.s. (zinc dust stabilized / zinc oxide mixture)
UN number : 3077
Class : 9
Packing group : III
Label :

Additional information
ADR/RID : Hazard identification number: 90
Special provision: 274
IMDG : Marine pollutant : No
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. REGULATORY INFORMATION

EU regulation : This product is classified and labelled for supply in accordance with the Directive 1999/45/EC as follows:
Hazard symbol :

Dangerous for the environment

Risk phrases : R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S23 - Do not breathe vapour / spray
Industrial use : The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

CEPE Classification : 1
Full text of R-pharses : R20/21/22 Harmful by inhalation and in contact with skin and if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The information in this Safety Data Sheet is required pursuant to EU Directive 91/155/EEC and its amendments.

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

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