Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

1. PRODUCT AND COMPANY IDENTIFICATION

Product information
Trade name : RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Use of the : Insecticide

Substance/Mixture
Company : S.C. Johnson and Son, Limited
1 Webster Street
Brantford ON N3T 5R1

Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231-
number 5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC)
(613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance / Odor : opaque / aerosol / characteristic

Immediate Concerns : Caution

Avoid contact with skin, eyes and clothing.
Keep away from heat, sparks and flame.
Do not puncture or incinerate.
Do not store at temperatures above 120 Deg. F (50 Deg C), as
container may burst.
Avoid breathing vapours, mist or gas.
Contents under pressure.

Potential Health Effects

Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : May cause:

Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : May be harmful if inhaled.

Ingestion : May cause irritation to mouth, throat and stomach.

May cause abdominal discomfort.

Aggravated Medical : Persons with pre-existing skin disorders may be more

Condition susceptible to irritating effects.
Individuals with chronic respiratory disorders such as asthma,

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

chronic bronchitis, emphysema, etc. may be more susceptible

to irritating effects

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or
the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent

Isobutane 75-28-5 10.00 - 30.00
Propane 74-98-6 1.00 - 5.00
Piperonyl butoxide 51-03-6 1.00 - 5.00
d-(Cis/Trans) Allethrin 584-79-2 0.10 - 1.00
Tetramethrin 7696-12-0 0.0001 - 0.10

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : Flush immediately with plenty of water for at least 15 to 20

minutes. Remove contact lenses. Get medical attention if
irritation develops and persists.

Skin contact : Flush immediately with plenty of water for at least 15 to 20

minutes. Get medical attention if irritation develops and
persists.

Inhalation : Remove to fresh air. If breathing is affected, get medical

attention.

Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so

by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or

media carbon dioxide.

Specific hazards during : Aerosol Product - Containers may rocket or explode in heat of
firefighting fire. Container may melt and leak in heat of fire.

Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

self-contained breathing apparatus. In case of fire and/or

explosion do not breathe fumes.

Flash point : < -7 °C

< 19.4 °F
Method: Tag Closed Cup (TCC)
Note: Propellant

Lower explosion limit : Note: No data available

Upper explosion limit : Note: No data available

NFPA Classification : NFPA Level 1 Aerosol

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition.

Wear personal protective equipment.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : Soak up with inert absorbent material.

If damage occurs to aerosol can:
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Sweep up and shovel into suitable containers for disposal.
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Avoid contact with skin, eyes and clothing.
Do not puncture or incinerate.
Do not enter places where used or stored until adequately
ventilated.
Avoid breathing vapours, mist or gas.
For personal protection see section 8.
Do not spray toward face.
Do not use in areas without adequate ventilation.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Smoking, eating and drinking should be prohibited in the
application area.

Advice on protection : Keep away from heat and sources of ignition.

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

against fire and explosion

Storage
Requirements for storage : Do not store at temperatures above 120 Deg. F (50 Deg C), as
areas and containers container may burst.
Keep in a dry, cool and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Components CAS-No. mg/m3 ppm Non- Basis
standard
units
Isobutane 75-28-5 - 1,000 ppm - ACGIH
STEL

Propane 74-98-6 - 1,000 ppm - ACGIH

TWA

Personal protective equipment

Respiratory protection Use only with adequate ventilation.
Substantial amounts of mist/vapors can be controlled with
local exhaust ventilation or respiratory protection.

Hand protection : No special requirements.

Eye protection No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling. Smoking, eating
and drinking should be prohibited in the application area.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : aerosol

Color : opaque

Odor : characteristic

pH : No data available

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

Boiling point : No data available

Freezing point : No data available

Flash point : < -7 °C

< 19.4 °F
Method: Tag Closed Cup (TCC)
Propellant

Evaporation rate : No data available

Auto-ignition temperature : No data available

Lower explosion limit : No data available

Upper explosion limit : No data available

Vapour pressure : No data available

Density : 0.81 g/cm3

Water solubility : soluble

Partition coefficient: n- :
octanol/water No data available

10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : None known.

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases

products and vapours.

Hazardous reactions : Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50

estimated
> 5,000 mg/kg

Acute inhalation toxicity : LC50

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

estimated
6.7 mg/l

Acute dermal toxicity : LD50

estimated
> 2,000 mg/kg

Chronic effects
Carcinogenicity : No data available

Mutagenicity : No data available

Reproductive effects : No data available

Teratogenicity : No data available

Sensitisation : Substances is not a sensitizer.

12. ECOLOGICAL INFORMATION

Ecotoxicity effects : No data available

13. DISPOSAL CONSIDERATIONS

Observe all applicable Federal, Provincial and State

regulations and Local/Municipal ordinances regarding
disposal.
Consumer may discard empty container in trash, or recycle
where facilities exist.

14. TRANSPORT INFORMATION

Land transport
ƒ U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name AEROSOLS, Flammable
Class: 2.1
UN number 1950
Packaging group: None.
Note: SC Johnson ships this product as INSECTICIDES OR INSECT

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

REPELLENTS, NOI, OTHER THAN POISON.

Sea transport
ƒ IMDG:
Proper shipping name AEROSOLS, Flammable
Class: 2
UN number: 1950
Packaging group: None.
EmS: F-D, S-U
Note: Limited quantities derogation may be applicable to this product,
please check transport documents.

Air transport
ƒ ICAO/IATA:
Proper shipping name AEROSOLS, Flammable
Class: 2.1
UN/ID No.: UN 1950
Packaging group: None.
Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions
when shipping this item by air.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

Notification status : All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Canada Regulations : This product has been classified in accordance with hazard
criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products
Regulations.

16. OTHER INFORMATION

HMIS Ratings
Health 1

Flammability 4

Reactivity 0

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID® HOME INSECT KILLER (REG NO 20796 P.C.P. ACT)

Version 3.0 Print Date 01/08/2016

Revision Date 12/01/2015 MSDS Number 350000004252

NFPA Ratings
Health 1

Fire 4

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health
Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS)
regulations. The information supplied is designed for workplaces where product use and
frequency of exposure exceeds that established for the labeled consumer use.

Further information
This document has been prepared using data from sources considered to be technically reliable.
It does not constitute a warranty, expressed or implied, as to the accuracy of the information
contained herein. Actual conditions of use are beyond the seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all
Federal, State, Provincial and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment &

Regulatory Affairs (GSARA)

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