Phrozen ABS-like Water Washable Resin, 1. Phrozen ABS-like Water Washable Resin

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普羅森科技股份有限公司 P1

Phrozen Tech Co. Ltd. Total 5 Pages MSDS - Phrozen LCD Resin

Phrozen ABS-like Water Washable Resin, Model Gray

1. Identification of the Substance/Preparation and of the Company/Undertaking


Product Name Phrozen ABS-like Water Washable Resin, Model Gray
Synonyms -

Chemical Name Mixture of Acrylate, Photoinitiator, and Pigment

Type Liquid

Application UV/Visible Light curable resin for 3D printing

普羅森科技股份有限公司 Phrozen Tech Co. Ltd.


Manufactuers +8863-5400076 # 14
3F., No. 287, Niupu Rd., HSIN CHU CITY 30091, Taiwan
[email protected]

+886916781577
Emergency Phone
Local police number

2.Hazards Identification
Chemical Hazard Classification:Serious eye damage/eye irritation category 2B, Skin sensitizer category 1.
Symbol Contents:

Symbol:Exclamation mark.
Signal word:Warning.
Hazard Statement:Causes eye irritation, May cause allergic skin reaction.
Precautionary Statement:Store in well-ventilated place. Keep away from ignition sources-No smoking. Do not wear
contact lenses. Chemical safety goggles are recommended. Avoid eyes and skin contact. Wear suitable protective
equipment. Call a doctor or physician if you feel unwell.
Other Effects:-----------

1. 3. Ingredients
Hazardous ingredient name Concentration WT% CAS No.
Prepolymer 55 139352-65-1
1,6-Hexanediol diacrylate 26.9 13048-33-4
Acryloyl Morpholine 15 5117-12-4
Phenyl bis(2,4,6-trimethylbenzoyl)- phosphine oxide 3 162881-26-7
Pigment 0.1 1333-86-4
4. First Aid Measures
The First-aid Measures for Different Exposure Routes:
Inhalation:Remove to fresh air. If symptoms persist, obtain medical attention.
Skin Contact:Immediately wash with soap and water. Wash contaminated clothing before reuse. Get medical attention if
symptoms occur.
Eye Contact:Flush with lukewarm water at least 15 minutes. Seek medical advice.
Ingestion:Clean with water and drink plenty of water. Induce vomiting. Keep individual calm. Obtain medical attention.
The Most Important Symptoms and Hazardous Effects:Nausea and irritating.
The Protection of First-aides:Wear impervious gloves. Avoid contacting the pollutant.
ans:Do not induce vomiting. Never give anything by mouth to an unconscious person.

5. Fire-Fighting Measures
Suitable Fire Extinguishing Media:Carbon dioxide, foam or dry chemical.
Specific Hazards May Be Encountered During Fire-fighting:May cause carbon monoxide, acetone, aldehyde, ammonia and
some organism materials.
Specific Fire-fighting Methods:Move to the safe area.
Special Equipment for The Protection of Firefighters:Self-contained breathing apparatus and protective clothing should be
worn in fighting large fires involving chemicals

6.Accidental Release Measures


ions:Personal Precautions:Wear suitable protective equipment. Clean the floor to prevent from slipping and falling.
Environmental Precautions:Extinguish the flame. Do not flush into surface water or sanitary sewer system.
Advise water authority if spillage has entered water course or drainage system.
Methods for Cleaning Up:Spontaneous hazardous polymerization may occur. Eliminate sources of ignition. Use eye and
skin protection. Maintain adequate ventilation. Soak up with inert absorbent. Store in a half filled, closed container until
disposal.

7.Handling and Storage


ar suitaHandling:Wear suitable protective equipment.
dling:
id leak. Avoid leak.
p away Keep away from light and heat.
id eye Avoid eye and skin contact.
p the p Keep the place ventilated.
Storage:Keep away from flame and sunlight
Keep in a cool, well ventilated area away from heat, sparks and open flame
Keep container tightly sealed.

8.Exposure Controls/Personal Protection


Engineering Controls:If handling results in aerosol or vapor generation, local exhaust ventilation is recommended.
Do not smoke and eat in the work area. Keep the workplace clean.
Control Parameters:
Ingredients Time weighted Short-term exposure Maximum exposure Biological Standards
average exposure limits (STEL) limits (CEILING) (BEIs)
limits (TWA/8hr)
-------- -------- -------- -------- --------
Personal Protection:
Respiratory:Respiratory equipment and gas mask.
Hand protection:Use protective gloves.
Eyes:Do not wear contact lenses. Chemical safety goggles are recommended.
Skin:Avoid skin contact. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Wash
contaminated clothing before reuse.
Other Hygienic Practices:Use good personal hygiene practices. Wash hands and face before eating and drinking.
Exercise more to keep healthy. Ingest food which contains vitamins and minerals. Do physical examination regularly.
9.Physical and Chemical Properties
Physical State(Appearance, Color):Green liquid Odor:Mild
Odor Threshold:------ Melting Point:-------- C o

pH Value:------ Boiling Point:> 250 C o

Flammable (Solid, Gas):------ Flash Point:> 113 Co

Decomposition Temp.:------ C o
Test Method:
Autoignition Temperature:------ C o
Explosion Limits:
Upper(UEL):------;Lower(LEL):------
Vapor Pressure:<------mmHg (@20 C) o
Vapor Density:------ (Air=1)
Density:------g/cm3 (Water=1) Solubility in Water:------
Octanol-water Partition Coefficient, Kow:------ Evaporation Rate:------

10.Stability and Reactivity


Stability .
Hazardous Polymerization .
Incompatibility Avoid flammable, ignitable, heat source, spark, flame, strong oxidant, free radical initiator,
peroxide and basic materials.
Hazardous Decomposition Carbon monoxide, acetone, aldehyde, ammonia.
Products

11. TToxicological Information


Acute Toxicity:Inhalation:May irritate to nose and throat.
Skin:Irritating to skin if contact.
Eye:The vapor may Irritate to eye.
Ingestion:May cause headache, nausea, dizziness and tiredness.
Ingredients Concentration LD50 (Lethal Dose 50) LC50 (Lethal Concentration
% 50)
Prepolymer 55 ----------- -----------
1,6-Hexanediol diacrylate 26.9 5 gm/kg(Rat, Oral) -----------
3600 μL/kg(Rabbit,
Skin)
Acryloyl Morpholine 15 ----------- -----------
Phenyl bis(2,4,6-trimethylbenzoyl)- phosphine 3 >2000 mg/kg(Rat, Oral) -----------
oxide >2000 mg/kg(Rat, Skin)
Pigment 0.1 ----------- -----------
Local Effects:May cause irritating if skin contact for a long time.
Sensitization:--------
Chronic Toxicity or Long Term Toxicity:--------
Specific Effects:--------

12. Ecological Information

Ecotoxicity:--------
Persistence / Degradability:--------
Bioaccumulation:--------
Mobility:--------
Other Information:Avoid the products enter into drainage or soli surface. After the product curing, it can be disposed by
following local regulations.
13.Disposal Considerations
Recommended methods of Disposal:Recover or recycle if possible. Otherwise, incineration following local regulations.
1. 14. Transport Information
United Nation Number (UN No.):--------
Proper Shipping Name:--------
Class:--------
Packing Group:--------
Marine pollutant (Yes/No):No
Special delivery methods and precautions:--------
I ATA-DGR:Not Restricted AS DGR 61th edition

15.Regulatory Information
Traffic Regulation
Occupational Safety and Health Act
Regulation of Labelling and Hazard Communication of Dangerous and Harmful Materials
Standards of Permissible Exposure Limits of Airborne Hazardous Substances in Workplace
Management Regulations for the Import, Export, Transit and Transshipment of Waste
Public Hazardous Materials and Flammable Pressurized Gases Establishment Standards and Safety Control
Procedures

16. Other Information


Reference documents
MSDS prepared by
Organization name:Phrozen Tech Co. Ltd.
Address/Telephone:3F., No. 287, Niupu Rd., HSIN CHU CITY 30091, Taiwan, Taiwan (R.O.C.)
+886916781577
Date:2020/04/20
Remark:“ – “ = not available ; “ / “ = not applicable
The data contained in this bulletin is provided only as a guide for evaluation/consideration. These material characteristics are typical properties that
are based on a limited number of samples tested in the laboratory. We cannot assume responsibility for results obtained by others over whose
methods we have no control. It is the user’s responsibility to determine suitability for the user’s purpose of any product or method. We recommend that
each prospective user test his proposed application before repetitive use, using this data as a guide.

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