SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

TRS CL1
Version 2.0 Print Date 26.02.2018

Revision date / valid from 26.02.2018

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name : TRS CL1

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the : At this time, we do not yet have information on identified uses.
Substance/Mixture They will be included in this safety data sheet when available.

Uses advised against : At this moment we have not identified any uses advised
against

1.3. Details of the supplier of the safety data sheet

Company : Brenntag SRL

Str. Garii, Nr.1; Com. Chiajna, Sat Chiajna
RO 077040 Judetul IIflov
Telephone : +40 741 816503
Telefax : +021 436 04 22
E-mail address : [email protected]

1.4. Emergency telephone number

Emergency telephone : 021 318 36 06 (lu-vi, 8:30 – 16:00)

number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

REGULATION (EC) No 1272/2008

Hazard
Hazard class Hazard category Target Organs
statements
Acute toxicity (Oral) Category 4 --- H302
Skin corrosion/irritation Category 2 --- H315
Serious eye damage Category 1 --- H318
Reproductive toxicity Category 2 --- H361

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Specific target organ toxicity

Category 2 Kidney H373
- repeated exposure

For the full text of the H-Statements mentioned in this Section, see Section 16.

Most important adverse effects

Human Health : See section 11 for toxicological information.

Physical and chemical : See section 9/10 for physicochemical information.

hazards
Potential environmental : See section 12 for environmental information.
effects

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Hazard symbols :

Signal word : Warning

Hazard statements : H315 Causes skin irritation.

H319 Causes serious eye irritation.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through
prolonged or repeated exposure.

Precautionary
statements

Prevention : P201
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
P264 Wash the contact area thoroughly after
handling.

Response : P301 + P312 IF SWALLOWED: Call a POISON

CENTER/doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of
water/soap.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P314 Get medical advice/ attention if you feel
unwell.

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Disposal : P501 Dispose of contents/ container to an

approved waste disposal plant.

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Classification
(REGULATION (EC) No 1272/2008)

Hazard class / Hazard

Hazardous components Amount [%] Hazard statements
category
Ethanediol
Index-No. : 603-027-00-1 >= 30 - <= 40 Acute Tox.4 H302
CAS-No. : 107-21-1 STOT RE2 H373
EC-No. : 203-473-3
EU REACH- : 01-2119456816-28-xxxx
Reg. No.

potassium hydroxide
Index-No. : 019-002-00-8 >= 1 - <= 5 Acute Tox.3 H301
CAS-No. : 1310-58-3 Skin Corr.1A H314
EC-No. : 215-181-3

Sodium Metaborate
CAS-No. : 98536-58-4 >= 40 - <= 50 Skin Irrit.2 H315
Eye Irrit.2 H319
Repr.2 H361d

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

If inhaled : Move to fresh air. If you feel unwell, seek medical advice (show
the label where possible). Oxygen, if needed.

In case of skin contact : Wash off with plenty of water. Take off all contaminated
clothing immediately. Wash clothing before reuse. Get medical
attention immediately if irritation develops and persists.

In case of eye contact : Wash off immediately with plenty of water. Immediate medical
attention is required.

If swallowed : Do NOT induce vomiting. Drink plenty of water. Never give

anything by mouth to an unconscious person. Immediate
medical attention is required.
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4.2. Most important symptoms and effects, both acute and delayed

Symptoms : See Section 11 for more detailed information on health effects

and symptoms.

Effects : See Section 11 for more detailed information on health effects

and symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing : Water fog, Carbon dioxide (CO2), Dry chemical, Foam
media
: For large fire: Water spray, Water fog
Unsuitable extinguishing : Water jet.
media
:

5.2. Special hazards arising from the substance or mixture

Specific hazards during : May decompose in a fire giving off toxic fumes
firefighting

5.3. Advice for firefighters

Special protective : Wear personal protective equipment.Self-contained breathing

equipment for firefighters apparatus (EN 133)
Further advice : No further information available.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : Prevent unauthorized access.

6.2. Environmental precautions

Environmental : Prevent entering sewers, basements and work pits

precautions

6.3. Methods and materials for containment and cleaning up

Methods and materials for : Remove mechanically, placing in appropriate containers for
containment and cleaning disposal. Neutralize residues with diluted acids. Residual
up liquid can be absorbed on inert material.

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6.4. Reference to other sections

See also section 13: Disposal Considerations.

See section 7 for information on safe handling.
For personal protection see section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling : When diluting, always add the product to water. Never add
water to the product.

Hygiene measures : Keep away from food, drink and animal feeding stuffs.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep only in the original container. Keep containers tightly
areas and containers closed in a dry, cool and well-ventilated place. Protect from
sunlight.

Advice on protection : Take necessary action to avoid static electricity discharge

against fire and explosion (which might cause ignition of organic vapors). Remove all
sources of ignition.

Unsuitable packaging : Aluminum, Steel, copper

materials

7.3. Specific end use(s)

Specific use(s) : No information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Component: ethanediol CAS-No. 107-21-1

Other Occupational Exposure Limit Values

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC,

2009/161/EU, 2017/164/EU, Time Weighted Average (TWA):
20 ppm, 52 mg/m3
Indicative

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC,

2009/161/EU, 2017/164/EU, Short Term Exposure Limit (STEL):
40 ppm, 104 mg/m3
Indicative

Romania. OELs. Protection of workers from exposure, Time Weighted Average (TWA):

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20 ppm, 52 mg/m3

Romania. OELs. Protection of workers from exposure, Short Term Exposure Limit (STEL):
40 ppm, 104 mg/m3

Romania. OELs. Protection of workers from exposure, Skin designation:

Can be absorbed through the skin.

8.2. Exposure controls

Personal protective equipment

Respiratory protection

Advice : Required, if exposure limit is exceeded (e.g. OEL).

When using this product at elevated temperatures, wear a
respirator with a vapor filter (see section 8).
Respirator with filter for organic vapor

Hand protection

Advice : PVC gloves

Rubber gloves
Nitrile rubber

Eye protection

Advice : Safety glasses with side-shields

Wear face protection additionally to eye protection in case of
splashes.

Skin and body protection

Advice : Wear suitable protective clothing.

Environmental exposure controls

General advice : Prevent entering sewers, basements and workpits

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form : liquid

Colour : colourless
to
yellowish

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Odour : characteristic

Odour Threshold : no data available

pH : 11,5 - 13,5

Freezing point/range : -20 °C

Boiling point : no data available

Flash point : no data available

Evaporation rate : no data available

Flammability (solid, gas) : no data available

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : no data available

Relative vapour density : no data available

Density : 1,18 - 1,23 g/cm3

Water solubility : soluble

Partition coefficient: n-octanol/water : no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, dynamic : no data available

Explosivity : no data available

Oxidizing properties : no data available

9.2. Other information

Refractive index : 1,3850 - 1,3950

SECTION 10: Stability and reactivity

10.1. Reactivity

Advice : Stable under recommended storage conditions.

10.2. Chemical stability

Advice : Stable under recommended storage conditions.

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10.3. Possibility of hazardous reactions

Hazardous reactions : Stable under recommended storage conditions.

10.4. Conditions to avoid

Conditions to avoid : Excessive heat. Keep away from open flames, hot surfaces and
sources of ignition.

10.5. Incompatible materials

Materials to avoid : Strong oxidizing agents, Strong acids and strong bases, Metals
may form hydrogen gas which is explosive.

10.6. Hazardous decomposition products

Hazardous decomposition : Nitrogen oxides (NOx), Potassium oxides, Carbon oxides

products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Data for the product

Acute toxicity
Oral

Acute toxicity : 1017 mg/kg ) (Calculation method)

estimate
Acute toxicity : 1018 mg/kg ) (Calculation method)
estimate
Inhalation

no data available

Dermal

no data available

Irritation
Skin

no data available

Eyes

no data available

Sensitisation

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no data available

CMR effects
CMR Properties

Carcinogenicity : no data available

Mutagenicity : no data available

Reproductive toxicity : no data available

Specific Target Organ Toxicity

Single exposure

no data available

Repeated exposure

no data available

Other toxic properties

Repeated dose toxicity

no data available

Aspiration hazard

no data available

Component: ethanediol CAS-No. 107-21-1

Acute toxicity
Oral

no data available

Inhalation

LC50 : > 2,5 mg/l (6 h; dust/mist)

Dermal

LD50 Dermal : > 3500 mg/kg (Mouse)

Irritation

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Skin

Result : No skin irritation (Rabbit)

Eyes

Result : No eye irritation (Rabbit)

Sensitisation

Result : not sensitizing (Maximisation Test; Guinea pig)

CMR effects
Carcinogenicity

NOAEL : 1.000 mg/kg bw/day

(Rat, male and female)(Oral; 24 Months)

CMR Properties

Carcinogenicity : Animal testing did not show any carcinogenic effects.

Mutagenicity : Not mutagenic in Ames Test
Tests on bacterial or mammalian cell cultures did not show
mutagenic effects.
Did not show mutagenic effects in animal experiments.
Teratogenicity : A potential for teratogenic damage can not be excluded after
ingestion of large quantities.
Reproductive toxicity : Animal testing did not show any effects on fertility.

Genotoxicity in vitro

Result : negative (Mutagenicity (Salmonella typhimurium - reverse mutation

assay))
negative (Mouse Lymphoma Cells) (OECD Test Guideline 476)
negative (CHO (Chinese Hamster Ovary) cells) (OECD Test
Guideline 473)

Genotoxicity in vivo

Result : negative (Rat, male and female) (Dominant lethal assay)

Teratogenicity

NOAEL : 0,15 mg/L

Develop.
(Rat)No negative effects.

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Reproductive toxicity

NOAEL : > 1.000 mg/kg bw/day

Fertility
(Rat)No negative effects.

Specific Target Organ Toxicity

Single exposure

Remarks : The substance or mixture is not classified as specific target organ

toxicant, single exposure.

Repeated exposure

Remarks : Target Organs: KidneyMay cause damage to organs through

prolonged or repeated exposure.

Other toxic properties

Aspiration hazard

No aspiration toxicity classification,

Component: potassium hydroxide CAS-No. 1310-58-3
Acute toxicity
Oral

LD50 Oral : 273 mg/kg (Rat)

Inhalation

no data available

Dermal

no data available

Irritation
Skin

Result : Very corrosive (Rabbit)

Eyes

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Result : Causes serious eye damage. (Rabbit)

Sensitisation

Result : not sensitizing (Guinea pig)

CMR effects
CMR Properties

Carcinogenicity : no data available

Mutagenicity : no data available
Reproductive toxicity : no data available

Specific Target Organ Toxicity

Single exposure

Remarks : The substance or mixture is not classified as specific target organ

toxicant, single exposure.

Repeated exposure

Remarks : The substance or mixture is not classified as specific target organ

toxicant, repeated exposure.

Other toxic properties

Aspiration hazard

Not applicable,
Component: Sodium Metaborate CAS-No. 98536-58-4
Acute toxicity
Oral

no data available

Inhalation

no data available

Dermal

no data available

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Irritation
Skin

Result : no data available

Eyes

Result : no data available

Sensitisation

Result : no data available

CMR effects
CMR Properties

Carcinogenicity : no data available

Mutagenicity : no data available
Reproductive toxicity : no data available

Specific Target Organ Toxicity

Single exposure

Remarks : no data available

Repeated exposure

Remarks : no data available

Other toxic properties

Aspiration hazard

no data available,

SECTION 12: Ecological information

12.1. Toxicity

Component: ethanediol CAS-No. 107-21-1

Acute toxicity

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Fish

LC50 : 72860 mg/l (Pimephales promelas (fathead minnow); 96 h) (static

test; EPA OPP 72-1)

Toxicity to daphnia and other aquatic invertebrates

EC50 : > 100 mg/l (Daphnia magna; 48 h) (static test; OECD Test
Guideline 202)

algae

EC50 : 6500 - 13000 mg/l (Scenedesmus capricornutum (fresh water

algae); 96 h) (End point: Growth rate)

Bacteria

EC20 : > 1995 mg/l (activated sludge; 30 min) (ISO 8192)aerobic

Chronic toxicity
Fish

NOEC : 15380 mg/l (Pimephales promelas (fathead minnow); 7 d)

Aquatic invertebrates

NOEC 8,590 mg/l (Daphnia (water flea); 7 d)

Component: potassium hydroxide CAS-No. 1310-58-3
Acute toxicity
Fish

LC50 : 80 mg/l (Gambusia affinis; 96 h)

LC50 165 mg/l (Poecilia reticulata; 24 h)

Toxicity to daphnia and other aquatic invertebrates

: no data available

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algae

: no data available

Bacteria

EC50 : 22 mg/l (Photobacterium phosphoreum; 15 min)

Component: Sodium Metaborate CAS-No. 98536-58-4

Acute toxicity
Fish

: no data available

Toxicity to daphnia and other aquatic invertebrates

: no data available

algae

: no data available

12.2. Persistence and degradability

Component: ethanediol CAS-No. 107-21-1

Persistence and degradability
Persistence

Result : no data available

Biodegradability

Result : 90 - 100 % (aerobic; activated sludge; Exposure Time: 10

d)(OECD Test Guideline 301A)Readily biodegradable.
Component: potassium hydroxide CAS-No. 1310-58-3
Persistence and degradability
Persistence

Result : no data available

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Biodegradability

Result : The methods for determining the biological degradability are not
applicable to inorganic substances.
Component: Sodium Metaborate CAS-No. 98536-58-4
Persistence and degradability
Persistence

Result : no data available

Biodegradability

Result : no data available

12.3. Bioaccumulative potential

Component: ethanediol CAS-No. 107-21-1

Bioaccumulation

Result : log Kow -1,36

: Bioaccumulation is not expected.

Component: potassium hydroxide CAS-No. 1310-58-3

Bioaccumulation

Result : Bioaccumulation is not expected.

Component: Sodium Metaborate CAS-No. 98536-58-4

Bioaccumulation

Result : no data available

12.4. Mobility in soil

Component: ethanediol CAS-No. 107-21-1

Mobility

Soil : Not expected to adsorb on soil.

Air : The substance will not evaporate into the atmosphere from the
water surface.
Water : The product is water soluble.
Component: potassium hydroxide CAS-No. 1310-58-3

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Mobility

: Adsorption to solid soil phase is not expected., The product is

water soluble.
Component: Sodium Metaborate CAS-No. 98536-58-4
Mobility

: no data available

12.5. Results of PBT and vPvB assessment

Data for the product

Results of PBT and vPvB assessment

Result :
Result : This substance/mixture contains no components considered to be
either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

Component: ethanediol CAS-No. 107-21-1

Results of PBT and vPvB assessment

Result : This substance is not considered to be persistent, bioaccumulating

nor toxic (PBT)., This substance is not considered to be very
persistent and very bioaccumulating (vPvB).

Component: potassium hydroxide CAS-No. 1310-58-3

Results of PBT and vPvB assessment

Result : The PBT or vPvB criteria of Annex XIII to the REACH Regulation
does not apply to inorganic substances.

Component: Sodium Metaborate CAS-No. 98536-58-4

Results of PBT and vPvB assessment

Result : no data available

12.6. Other adverse effects

Component: ethanediol CAS-No. 107-21-1

Biochemical Oxygen Demand (BOD)

Result : 1245 mg/g

Additional ecological information

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Result : no data available

Component: potassium hydroxide CAS-No. 1310-58-3
Additional ecological information

Result : no data available

Component: Sodium Metaborate CAS-No. 98536-58-4
Additional ecological information

Result : no data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product : Dispose as special waste according to latest national

legislation for waste handling.

Contaminated packaging : Contaminated packages have to be eliminated under the

same conditions as the product.

European Waste : No waste code according to the European Waste Catalogue

Catalogue Number can be assigned for this product, as the intended use dictates
the assignment. The waste code is established in consultation
with the regional waste disposer.

SECTION 14: Transport information

14.1. UN number

1814

14.2. UN proper shipping name

ADR : POTASSIUM HYDROXIDE SOLUTION

RID : POTASSIUM HYDROXIDE SOLUTION
IMDG : POTASSIUM HYDROXIDE SOLUTION

14.3. Transport hazard class(es)

ADR-Class : 8
(Labels; Classification Code; Hazard 8; C5; 80; (E)
identification No; Tunnel restriction code)
RID-Class : 8
(Labels; Classification Code; Hazard 8; C5; 80
identification No)
IMDG-Class : 8
(Labels; EmS) 8; F-A, S-B

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14.4. Packaging group

ADR : II
RID : II
IMDG : II

14.5. Environmental hazards

Environmentally hazardous according to ADR : no

Environmentally hazardous according to RID : no
Marine Pollutant according to IMDG-Code : no

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

IMDG : Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

Component: ethanediol CAS-No. 107-21-1

EU. Regulation No : EC Number: , 203-473-3; Listed

1451/2007 [Biocides],
Annex I, OJ (L 325)

EU. Directive : ; The substance/mixture does not fall under this legislation.
2012/18/EU (SEVESO
III) Annex I

Component: potassium hydroxide CAS-No. 1310-58-3

Rotterdam Convention : ; The substance/mixture does not fall under this legislation.
on the Prior Informed
Consent (PIC) Procedure
for Certain Hazardous
Chemicals and
Pesticides in
International Trade

EU. REACH, Annex XVII, : Point Nos.: , 3; Listed

Marketing and Use
Restrictions (Regulation
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1907/2006/EC)

EU. Regulation No : EC Number: , 215-181-3; Listed

1451/2007 [Biocides],
Annex I, OJ (L 325)

EU. Regulation No. : Maximum concentration in ready for use preparation: 4,5 %;
1223/2009 on cosmetic Professional use products for straightening hair; See the text of
products, Annex III: List the regulation for applicable exceptions or provisions.
of Restricted Substances
in Cosmetic Products
Maximum concentration in ready for use preparation: 2 %;
General use products for straightening hair; See the text of the
regulation for applicable exceptions or provisions.
Maximum concentration in ready for use preparation: 5 %; Nail
cuticle products; See the text of the regulation for applicable
exceptions or provisions.
; Cosmetic products other than depilatories; See the text of the
regulation for applicable exceptions or provisions.
; Depilatories; See the text of the regulation for applicable
exceptions or provisions.

EU. Directive : Lower-tier requirements: 50 tonnes; Part 1: Categories of

2012/18/EU (SEVESO dangerous substances; H2: ACUTE TOXIC (Category 2, all
III) Annex I exposure routes; Category 3, inhalation)
Upper-tier requirements: 200 tonnes; Part 1: Categories of
dangerous substances; H2: ACUTE TOXIC (Category 2, all
exposure routes; Category 3, inhalation)

15.2. Chemical safety assessment

no data available

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H361 Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated
H373
exposure.

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Abbreviations and Acronyms

BCF bioconcentration factor

BOD biochemical oxygen demand
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR carcinogenic, mutagenic or toxic to reproduction
COD chemical oxygen demand
DNEL derived no-effect level
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
GHS Globally Harmonized System of Classification and Labelling of
Chemicals
LC50 median lethal concentration
LOAEC lowest observed adverse effect concentration
LOAEL lowest observed adverse effect level
LOEL lowest observed effect level
NLP no-longer polymer
NOAEC no observed adverse effect concentration
NOAEL no observed adverse effect level
NOEC no observed effect concentration
NOEL no observed effect level
OECD Organisation for Economic Cooperation and Development
OEL occupational exposure limit
PBT persistent, bioaccumulative and toxic
PNEC predicted no-effect concentration
STOT specific target organ toxicity
SVHC substance of very high concern
UVCB substance of unknown or variable composition, complex reaction
products or biological materials
vPvB very persistent and very bioaccumulative

Key literature references : Supplier information and data from the "Database of registered
and sources for data substances" of the European Chemicals Agency (ECHA) were
used to create this safety data sheet.
Methods used for : The classification for human health, physical and chemical
product classification hazards and environmental hazards were derived from a
combination of calculation methods and if available test data.
Hints for trainings : The workers have to be trained regularly on the safe handling
of the products based on the information provided in the Safety
Data Sheet and the local conditions of the workplace. National
regulations for the training of workers in the handling of
hazardous materials must be adhered to.

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|| Indicates updated section.

The information provided in this Safety Data Sheet is correct to our knowledge at the date of its
revision. The information given only describes the products with regard to safety arrangements
and is not to be considered as a warranty or quality specification and does not constitute a legal
relationship.
The information contained in this Safety Data Sheet relates only to the specific material designated and
may not be valid for such material used in combination with any other material or in any process, unless
specified in the text.

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