S.

S chemistry classes SUBECTIVE ASSIGNEMENT – SOLUTIONS

ASSIGNMENT SUBJECTIVE [ HOME WORK ]

CONC. TERMS --------- --------------------------------------------------------------------------------
Q1] Air contains 79 % Nitrogen by mass . Calculate its mass fraction & ppm in air &( 0.79 , 79 x 10 4 )
Q2] How many moles of MgSO4 7H2O must be added to 100 moles of water to obtain 10 % solution of
MgSO4 ,7 H2O ( 0.813 moles )
Q3] The river Ganga contains 60 mg of Ca+2 ions per Kg of its water . Calculate the ppm of Ca+2 ions in the water
of Ganges [ 60 ppm ]
Q4] The percentage composition ( by weight ) of a solution is 45 % X , 15 % of Y , 40% of Z . Calculate the
Mole fraction of each component of solution . ( Molecular wt of X is 18 , Y is 60 & Z is 60 ) [ X- 0.731 , y - 0.073
Q5] Calculate Formality of solution of sodium thiosulphate Na 2S2O8 solution , 1.24 g of which are dissolved in
100 cm3 of the solution [ 0.05 F ]
Q6] Calculate Molality of one liter solution of 93% H 2SO4 by Volume . The  of the solution is 1.84 g/ml [10.43]
Q7] What will be the normality of solution of CaCl2 containing 6.023 x 10 20 Cl – ions when volume of solution is
500 ml ( 4x 10-3 N )
Q8] Calculate the no of oxalic acid molecules in 100 ml of 0.02 N oxalic acid .(6.023x 10 20 )

Mixed relations --- ----------------------------------------------------------------------------------------

Q9] Calculate Molarity of an aqueous solution of sucrose which is 67% of by weight , when its density is
1.23 g / cm3 [ 0.45 M ]
Q10] Calculate Molality of 10 N solution of Al (OH ) 3 , when density of the solution is 1.20 g/ml ( 3.5 m )
Q11] 0.01 M solution of Ca(OH)2 will have normality -( 0.02 )
Q12] A 12 M HCl solution contains 37 % HCl by mass . What is the density of the solution ? [ 1.19 g / cm 3 ]
Q13] The density of a 3 M solution of K2S2O3 is 1.50 g / cm3 . Calculate a] The % by weight of Pot
thiosulphate b] Mole fraction of pot thiosulphate c] Molality of Potassium ion . [ 38 % , 0.05, 6.45 m ]
Q14] If Molality of the solution containing same solute is 5 m , calculate X B. [ 0.08]
Q15] The Conc. of Sulphuric acid in bottle labeled as conc. Sulphuric acid is 18 M . The solution has density of
1.84 g / cm3 . What is the Mole fraction & weight % of Sulphuric acid in the solution [ 95.87 % ]
Q16] Calculate the Molality of 1 M solution of Sodium Nitrate . The density of solution is 1.25 g / cm 3 [ 0.858m]
Q17] Calculate Molality of Sulphuric acid solution in which the Mole fraction of water is 0.85 [ 9.8m ]
Q18] The mole fraction of Heptane in a solution in Hexane is 0.60 . Calculate the weight % of Heptane in solution
[ 63.5 % ]

Solution Mixture
-------------------------------------------------------------------------------------------Q19] Calculate the
conc. of a solution in % that is obtained by mixing 300 g of 25 % solution of NH 4NO3 with 150 g of a 40 %
solution of NH4NO3 [ 30 % ] Q20] If 20 ml
of 1.0 M MgCl2 & 60 ml of 0. 20 M MgCl2 are mixed , what will be the Molarity & Normality of Chloride ion in
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 S.S chemistry classes SUBECTIVE ASSIGNEMENT – SOLUTIONS

the solution ? [ 0.8 M , 0.8 N ] Q21]

Calculate the resulting Molarity of the solution that is obtained by adding 5 g of NaOH to 200 ml of M/ 4 NaOH
solution [ density = 1.05g / cm3 ] The density of resulting solution is 1.08 g / cm3 [ 0.88 M ]

Normality eq ------------------------------------------------------------------------------------------------
Q22] Calculate the normality of the resulting solution made by adding two drops ( 0.1ml ) of 0.1N H 2SO4 in one
liter of distilled water ( 10-5 N )
Q23] What volume of water is required to make 0.20 N solution from 1600 ml of 0.2050 N solution [ 40 ml
Q24] What volume of 50% HNO3 having density ( 1.10g/ml ) & what volume of water is required to
prepare 20 % , 200 ml of HNO3 with density 1.01 g / ml ? [ 73.5 ml , 126.5

ml ] . Henry’s Law
---------------------------------------------------------------------------------- Q25] Henry’s const
for CO2 in water is 1.67 x10 8 k pa at 298 K . Calculate the quantity of CO2 in 500 ml of soda water
when packed under 2.5 atm pressure at 298 K [ 1.854 g ] Q26] At what
partial pressure Nitrogen will have a solubility of 0.06 g / l in water at 293 K ? Henry’s constant for N 2 is 76.48 K
bar at 293K . Assuming density of solution to be same as that of solvent ? Q27] The
-3
partial pressure of Methane over a saturated solution containing 5 x 10 g of methane is 1 atm . If Calculate
partial pressure of a gas when solution contain 5 x 10 -5 g of methane
Q28] Mole fraction of methane in Benzene is 0.00178 . calculate partial pressure of the gas under which it can
dissolve . KH for methane is 4.27 x 10 5 mm Hg [ 760 mm ]
Q29] Total pressure is one atm & temp is 250 C . Mole fraction of N2 gas in air is 0.78 & KH for N2 is 8.42 x 10-7
M / mm of Hg . What si the Conc. of N2 in a glass of water at 250 C ? [ 4.99 x 10-4 M ]

Vapor Pressure -- liquid in liquid - ----------------------------------------------------

Q30] The vapor pressure of Ethanol & Methanol are 44.5 mm & 88.7 mm of Hg respt . An Ideal solution is formed
at the same temp by mixing 60 g of Ethanol & 40 g of Methanol . Calculate the total Vapor pressure of the solution
& the Mole fraction of Methanol in the Vapor state [ 66.17 mm , 0.66 ]
Q31] An aqueous solution containing 30% by wt of liquid A ( Molecular wt = 140 ) has a vapor pressure of 160
mm at 57 0C . Find the vapor pressure of A , if that of water is 150 mm of Hg ( 10 mm)
Q32] Benzene & Toluene form ideal solution Calculate Vapor pressure of a solution containing 0.6 mole fraction
of Toluene when PB0 is 103.01mm & PT0 is 32.06 mm of Hg [ 60.44 mm ]
Q33] Cyclohexane & Ethanol at a particular temp have vapor pressure of 280 mm & 168 mm respt . If these two
solutions having Mole fraction value of Cyclohexane equal to 0.32 are mixed & the mixture has a total vapor
pressure of 376 mm , will the mixture be an ideal solution ? [ 203. 84, not ]
Q34] Two liquids X & Y form an ideal solution at 300 K . Vapor pressure of solution containing 3 moles of X
& 1mole of Y is 550 mm of Hg . At the same Temp , if 1 mole of Y is further added , to this solution , the vapor
pressure of solution increases by 10 mm of Hg . Calculate vapor pressure of Pure X & Y [ 600 & 400 ]

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 S.S chemistry classes SUBECTIVE ASSIGNEMENT – SOLUTIONS

Q35] Two liquids A & B have vapor pressure in the ratio PA0 : PB0 = 1 : 2 at a certain Temp . Suppose that we
have an ideal solutions of A & B in the mole ratio fraction ratio A : B = 1 : 2 what is the mole fraction of A in
the vapor phase in Eqbm with a solution at a given Temp [ 0.2 ]
Q36] The vapor pressure of pure liquids A & B are 450 mm & 700 mm of Hg respt at 350 K . Calculate the
composition of the liquid mixture if the total vapor pressure id 600 mm of Hg . Also calculate composition of
the mixture in vapor phase [ XA = 0.4 , XB = 0.6 , in vapor phase --- XA = 0.3 , XB == 0.7 ]

 Vapor Pressure – Solid in Liquid

--------------------------------------------------------
Q37] Why vapor pressure of aq solution is less as compared to pure solvent ?
Q38] Calculate vapor pressure lowering of aqueous 1molal glucose solution , p 0 = 760mm of Hg ( 14 torr )
Q39] What weight of non volatile solute urea needs to be dissolved in 50 gm of water , in order to decrease the
vapor pressure of water by 25 % . What will be the Molality of solution ? [ 55.56 , 18.52 ]
Q40] Calculate the Molal Lowering of vapor pressure for water at 100 0C [ 13.68 mm og Hg ]
Q41] Calculate Vapor pressure of 20 % [ w- w ] aq solution of Glucose at 273 K [ 0.975 atm ]
Q42] What weight of solute with molar mass 60 g / mole is required to be dissolved in 180 g of water to reduce
the vapor pressure to 4/5 th of pure water [ 120 g ]
Q43] The vapor pressure of CS2 at 500 C is 854 torr & a solution of 2 g of Sulphur in 100 g of CS2 has a vapor
pressure of 848.9 torr . Calculate formula of Sulphur [ S8 ]
Q44] . The vapor pressure of solution containing 7 g of Mg ( NO 3 ) 2 in 100 g of water is 746mm of Hg at
100 0C . What is the degree of dissociation of the salt at this temp ? ( 0.8)

 BOILING
POINT---------------------------------------------------------------------------
Q45] Why an Aq solution of common salt boils at higher temp as compared to boiling point of water ? Plot a
graph showing Boiling point of solution more than pure solvent
Q46] 2 gm of solute was dissolved in 100 ml of benzene [ density = 0.879 gm /ml ] . The solution boiled at 0.25 0C
higher than the boiling point of benzene . Kb = 2.520 C /molal . Calculate MB [ 229.3 ]
Q47] What is the % by weight of Naphthalene needed to raise the boiling point of benzene to 81 0C ? The boiling
point of benzene & its Molal elevation constant are 80.2 0C & 2.53 K Molal -1 respt [ 3.89 % ]
Q48] An aq solution containing 2.88 g of a non volatile solute having the stochiometric composition C nH2nOn in
90 g of water boils at 101.24 0C at 1.00 atm . What is the Molecular formula of the compound ? [ C 44H88O44 ] Q49]
0.1 Molal aqueous solution of a substance boils at 100.0520C & 1 atm pressure . Calculate latent heat of
Vaporization of water [ 53.2 Cal/gm ]
Q50] The solution of Ba( NO3 ) 2 containing 11.07 g in 100 g of water boils at 100.466 0 C . What is the apparent
degree of ionization of the salt at this temp ? Kb = 0.52 0 C ( 55.9 )

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 S.S chemistry classes SUBECTIVE ASSIGNEMENT – SOLUTIONS

Freezing point --------------------------------------------------------------------------------

Q51] Why an Aq solution has less freezing point as compared to pure water . Plot a graph & give reason .
Q52] What are anti freezing agents ? Explain their role taking one example
Q53] Why Camphor is preferred as a solvent in finding the Molecular weight of Naphalene by rast method ?
[ Kf = 39.7 ]
Q54] Calculate freezing point of a solution containing 10 g of ethanol dissolved in 1000 gm of water [ - 0.404 0C ]
Q55] A 5% solution of cane sugar [mol weight = 342 ] in water has freezing point of –20 0C . Calculate the freezing
point of 40 % solution of glucose in water if freezing point of water is 0 0C [ -3.8 ]
.Q56] In very cold weather , ethylene glycol [ mol weight = 62 ] is added to water used in car radiator so that water
may not freeze . What minimum weight of glycol must be added to 6 Kg of water to prevent it from freezing at
– 0.3 0 C Kf = 1.86 0C [ 22.32g ]
Q57] What is the weight of one mole of solute , 0.132 g of which in 29.70 g of benzene gave a freezing point
depression of 0.108 0 C . K f 5.12 K/ Molal for benzene
Q58] A 0.001molal solution of [ Pt ( NH3) 4 ]Cl4 in water had freezing point of 0.0054 0 C . If K f for water is 1.86
, calculate bonding in this compound . (i= 2.9 )
Q59] Equimolal solutions of KBr & MgCl2 are prepared in water . Freezing point of KBr is found to be
– 30 C . What is the freezing point of MgCl2 ?
Q60] 20.27 g of benzene containing 0.2965 g of benzoic acid freezes at 0.317 0 C below the freezing point of pure
benzene . Calculate degree of association of acid in benzene if K f for benzene is 5.12 0 C m-1 [ 96.84 % ]
Q61] When 11.7 g of Na Cl was dissolved in 200 g of water , shows a depression in freezing point which is double
than in depression caused by 342 g of cane sugar in 100g of water . Calculate i for NaCl ( 2)
Q62] There are two solutions containing in equal quantities of water 1] 0.5 moles of Sugar 2] 0.2 moles of CaCl 2
. both solutions freeze at the same temp . What is the degree of dissociation of CaCl 2 ? [ 75 % ]
Q63] . What weight of phenol should be dissolved in 35 g of water , so the depression in freezing point is
0.215 0C , when it undergoes 84 % association . [ 0.66 g ]

OSMOTIC PRESSURE -------------------------------------------------------------------

Q64] . Name the semi permeable membrane which can be made in lab i.e. synthetic
Q65] Which colligative property is the best to measure molecular mass of any macromolecule & why ?
Q66] How Osmotic pressure of solution depends upon Air Pressure & Temperature ?
Q67] A solution containing 4 g of poly vinyl chloride polymer in one liter of dioxane was found to have osmotic
pressure of 6.4 x 10 –4 atm at 27 0C . Calculate appox Molecular wt of polymer . ( 1.6 x 10 5 )
Q68] At 270C , 36 g of glucose per liter has an osmotic pressure of 4.92 atm . If the osmotic pressure of solution is
1.5 atm at the same temp , what would be it’s concentration ?
Q69] At 10 0 C the Osmotic pressure of urea solution is 500 mm . the solution is diluted & the temp is raised to
250 C , when the osmotic pressure is found to be 105.3mm . determine the extent of dilution . [ 5 times ]
Q70] Calculate the ratio of osmotic pressure of 0.001 M glucose & urea solution . ( one )
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 S.S chemistry classes SUBECTIVE ASSIGNEMENT – SOLUTIONS

Q71] A solution of 1.73 g of a in 100 cc of water is found to be isotonic with a 3.42 % ( wt / vol ) solution of
sucrose . calculate Molecular weight of “ A [ 173 ]
Q72] Calculate osmotic pressure of deci normal solution of BaCl 2 at 270 C , showing 80 % dissociation ( 3.2 atm
Q73] 1.7 % solution ( W/V ) of AgNO3 is isotonic with 3.4 % solution of glucose . Calculate the degree of ionization
of Ag NO3 solution ( 89% )
Q74] . A 5 % solution of substance X is isotonic with 7% solution of NaCl . Calculate molar mass of X . ( 20.8
Q75] . A 0.1 m solution of KNO3 has an Osmotic pressure of 4.5 atm at 27 0 C . Calculate the apparent degree of
dissociation of the salt in this solution . [83 % ]

 Mixed problems on Colligative properties ------------------------------------------

Q76] An aq Solution of Urea had a freezing point of – 0.52 0 c . Predict the Osmotic pressure of the same solution
at 37 0 C . Assume the Molar Conc. & the Molality are numerically equal K f= 1.86 [ 7.1 atm ]
Q77] . Calculate the freezing point of an aq solution of a non electrolyte having an osmotic pressure of 2 atm at
300 K . Kf = 1.6 K Kg Mole -1 [ -0.151 0C ]

 Vant Hoff factor

-----------------------------------------------------------------------------
Q78] Arrange the following aqueous solutions in the increasing order of their ----
-----------------------------------------1] Osmotic pressure 2] Relative lowering in Vapor pressure 3] Freezing
point 4] Boiling point
A] 60 g / liter Urea , B] 74.5 g / liter KCl C] 90 g/ liter Glucose
D] 14.2 g / liters of Sodium Sulphate E] 30 g/ liters of Acetic acid in CS 2

 Typical Ouestions
----------------------------------------------------------------------------
Q79] A very small amount of non volatile solute that does not dissociate is dissolved in 56.8 Cm 3 of benzene
[ density = 0 .889 g/ml ] . At room temp , the vapor pressure of solution is 98.88 mm of Hg . Find the Molality of
solution . If the freezing temp of solution is 0.73 0 C lower than that of benzene , what is the value of K f of benzene
[ 5.2 K Kg / mole ]

Q80] An aqueous solution contains 5 % by mass of urea & 10 % by mass of glucose . If K f for water is 1.86 K
Kg / mole , calculate Depression in freezing point [ - 3.04 0 C ]

Q81] Calculate osmotic pressure of a mixture of 100 ml of 6 % urea solution & 100 ml of 18 %( m – v ) glucose
solution at 270C . ( 24.6 atm )

Q82 ] A 100 g sample of water is found to contain 0.06 moles of NaCl & 1.3 x10 –3 moles of MgCl2 . Find the
boiling point of the sample Kb = 0.52 K Kg / mole ( 100.3180 C )

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