Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - Europe

SAFETY DATA SHEET

Oil Spill Dispersant Type I

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1 Product identifier
Product name : Oil Spill Dispersant Type I
Product code : Not available.
Product description : Not available.
Product type : Liquid.
Other means of : Not available.
identification

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Oil spill remover

Uses advised against Reason

Other than described

1.3 Details of the supplier of the safety data sheet

Vecom Marine B.V.
Mozartlaan 3
3144 NA Maassluis
The Netherlands
Tel.: +31(0)10-5930210
e-mail address of person : [email protected]
responsible for this SDS
National contact

1.4 Emergency telephone number

National advisory body/Poison Centre
Telephone number : In case of emergency please contact the Dutch National Poison Control, telephone
number: 31-(0)30-2748888. (This number is only accessible to the physician treating
the patient and only in case of accidental poisoning)
Supplier
Telephone number : +31 10 5930210
Hours of operation : 09:00 - 17:00
Information limitations :

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Asp. Tox. 1, H304
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

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Oil Spill Dispersant Type I

SECTION 2: Hazards identification

Classification : Xn; R65
Human health hazards : Harmful: may cause lung damage if swallowed.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : May be fatal if swallowed and enters airways.
Precautionary statements
Prevention : Not applicable.
Response : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT
induce vomiting.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazardous ingredients : Hydrocarbons C10-13 N-Alkanes,Isoalkanes,Cyclic <2% Aromatics
Supplemental label : Repeated exposure may cause skin dryness or cracking.
elements
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Other hazards which do : Not available.
not result in classification

SECTION 3: Composition/information on ingredients

Substance/mixture : Mixture
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
Hydrocarbons C10-13 REACH #: 01- >=90 Xn; R65 Asp. Tox. 1, H304 [1]
N- 2119457273-39 R66
Alkanes,Isoalkanes,Cyclic EC918-481-9
<2% Aromatics
Oleic acid, ethoxylated EC: 500-015-7 5-10 Not classified. Eye Irrit. 2, H319 [1]
CAS: 9004-96-0
See Section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above. above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been
assigned a workplace exposure limit and hence require reporting in this section.

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Oil Spill Dispersant Type I

SECTION 3: Composition/information on ingredients

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 3 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the
preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

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Oil Spill Dispersant Type I

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO2, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture cause a health hazard.
Hazardous thermal : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

5.3 Advice for firefighters

Special protective actions : Cool closed containers exposed to fire with water. Do not release runoff from fire to
for fire-fighters drains or watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.3 Methods and materials : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see section 13). Preferably clean with a detergent.
Avoid using solvents.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe : Prevent the creation of flammable or explosive concentrations of vapours in air and
handling avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
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Oil Spill Dispersant Type I

SECTION 7: Handling and storage

sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.

7.2 Conditions for safe : Store in accordance with local regulations.

storage, including any Notes on joint storage
incompatibilities Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away
from heat and direct sunlight. Keep away from sources of ignition. No smoking.
Prevent unauthorised access. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Recommended monitoring : Not applicable
procedures
Derived effect levels
No DELs available.

Predicted effect concentrations

No PECs available.

8.2 Exposure controls

Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be achieved
controls by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and solvent vapours below the
OEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Wear safety glasses with side protection in accordance with EN 166.
Skin protection

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Oil Spill Dispersant Type I

SECTION 8: Exposure controls/personal protection

Hand protection : Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
Gloves : Wear suitable gloves tested to EN374. The quality of the chemical-resistant
protective gloves must be chosen as a function of the specific workplace
concentrations and quantity of hazardous substances. Wear protective gloves: nitrile
rubber
The recommendation for the type or types of glove to use when handling this product
is based on information from the following source:

The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Clear.
Odour : Characteristic.
Odour threshold : Not available.
pH : Not applicable.
Melting point/freezing point : Not available.
Initial boiling point and boiling : Not available.
range
Flash point : Closed cup: >62°C
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Burning time : Not applicable.
Burning rate : Not applicable.
Upper/lower flammability or : Not available.
explosive limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 0,78 to 0,8
Solubility(ies) : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Explosive properties : Not available.
Oxidising properties : Not available.

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Oil Spill Dispersant Type I

SECTION 9: Physical and chemical properties

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : Stable under recommended storage and handling conditions (see section 7).

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.

10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 3 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the
preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Hydrocarbons C10-13 N- LC50 Inhalation Vapour Rat 5000 mg/l 4 hours
Alkanes,Isoalkanes,Cyclic
<2% Aromatics
LD50 Dermal Rat 2000 mg/kg -
LD50 Oral Rat 5000 ng/kg -
Conclusion/Summary : Not available.
Acute toxicity estimates
Not available.

Irritation/Corrosion
Conclusion/Summary : Not available.
Sensitisation
Conclusion/Summary : Not available.

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Oil Spill Dispersant Type I

SECTION 11: Toxicological information

Mutagenicity
Conclusion/Summary : Not available.

Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Not available.

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard
Product/ingredient name Result
Hydrocarbons C10-13 N-Alkanes,Isoalkanes,Cyclic <2% ASPIRATION HAZARD - Category 1
Aromatics

Other information : Not available.

SECTION 12: Ecological information

12.1 Toxicity
There are no data available on the preparation itself.
Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is not classified as dangerous for the environment.
Product/ingredient name Result Species Exposure
Hydrocarbons C10-13 N- Acute EC50 >1000 mg/l Aquatic plants 72 hours
Alkanes,Isoalkanes,Cyclic
<2% Aromatics
Acute EC50 >1000 mg/l Daphnia 48 hours
Acute LC50 >1000 mg/l Fish 96 hours
Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Naphtha (petroleum), - 10 to 2500 high
hydrotreated heavy

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

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SECTION 12: Ecological information

PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN/ADNR IMDG IATA
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.

14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)

14.4 Packing - - - -
group
14.5 No. No. No. No.
Environmental
hazards
14.6 Special Transport within Transport within Transport within Transport within
precautions for user’s premises: user’s premises: user’s premises: user’s premises:
user always transport in always transport in always transport in always transport in
closed containers that closed containers that closed containers that closed containers that
are upright and are upright and are upright and are upright and
secure. Ensure that secure. Ensure that secure. Ensure that secure. Ensure that
persons transporting persons transporting persons transporting persons transporting
the product know what the product know what the product know what the product know what

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Oil Spill Dispersant Type I

SECTION 14: Transport information

to do in the event of an to do in the event of an to do in the event of an to do in the event of an
accident or spillage. accident or spillage. accident or spillage. accident or spillage.
Additional - - - -
information

14.7 Transport in bulk : Not available.

according to Annex II of
MARPOL 73/78 and the IBC
Code

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Restricted to professional users.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
VOC for Ready-for-Use : Not applicable.
Mixture
Europe inventory : All components are listed or exempted.
Black List Chemicals : Not listed
Priority List Chemicals : Not listed
Integrated pollution : Not listed
prevention and control
list (IPPC) - Air
Integrated pollution : Not listed
prevention and control
list (IPPC) - Water
Industrial use : The information contained in this safety data sheet does not constitute the user’s
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.
International regulations
Chemical Weapons : Not listed
Convention List Schedule I
Chemicals

Chemical Weapons : Not listed

Convention List Schedule II
Chemicals

Chemical Weapons : Not listed

Convention List Schedule III
Chemicals

15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

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Oil Spill Dispersant Type I

SECTION 16: Other information

CEPE code : 1
Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Asp. Tox. 1, H304 Expert judgment

Full text of abbreviated H : H304 May be fatal if swallowed and enters airways.
statements
Full text of classifications : Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
[CLP/GHS]
Full text of abbreviated R : R65- Harmful: may cause lung damage if swallowed.
phrases R66- Repeated exposure may cause skin dryness or cracking.
Full text of classifications : Xn - Harmful
[DSD/DPD]
Date of printing : 1-2-2018.
Date of issue/ Date of : 1-2-2018.
revision
Date of previous issue : 8-1-2018.
Version : 1.01
Notice to reader
This material safety data sheet contains information about the properties and safety risks of the product it
describes, as known on the date of issue. It does not constitute a guarantee of any property or quality of the
product. The information is intended exclusively as a guide to safely operating, storing and transporting the
product and what do if it is released.

The information concerns the product itself and does not apply to any application or use of it, whether or not
in combination with any other product or in any process. Responsibility for assessing the related implications
and risks rests entirely with the user. This material safety data sheet has been compiled with the greatest
possible care but is based in part on information in the public domain. For this reason Vecom is unable to
accept any liability for the accuracy or completeness of the information.

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