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Intermediate - Redox Reactions

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1.

The reaction H 2 S + H 2 O2 →2 H 2 O+S shows


a) Oxidizing action of H 2 O2

b) Reducing action of H 2 O2

c) Alkaline nature of H 2 O2

d) Acidic nature of H 2 O2

2. Match List I with List II and select the correct answer using the codes given below the lists
List I (Compound)List II (Oxidation state of N)
a) NO 2 (1) + 5

b) HNO3 (2) – 3

c) NH 3 (3) + 4

d) N 2 O5 (4) + 1

Codes :

a) A B C D

2 3 4 1

b) A B C D

3 1 2 4

c) A B C D

3 4 2 1

d) A B C D

2 3 1 4

3. Amongst the following identify the species with an atom in + 6 oxidation state
3−
a) MnO−4 b) Cr( CN )6
2−
c) NiF 6 d) CrO2 Cl 2

4. The oxidation number of sulphur in S 8 , S2 F 2 , H 2 S respectively, are


a) 0, +1 and – 2
b) + 2, +1 and – 2
c) 0, + 1 and + 2
d) – 2, + 1 and – 2
3+ 2−
5. In the reaction, 4 Fe+ 3O 2 →4 Fe +6 O which of the following statement is incorrect
a) A Redox reaction
b) Metallic iron is a reducing agent
3+
c) Fe is an oxidising agent
3+
d) Metallic iron is reduced to Fe

6. Choose the correct option:


2
Cr2 O7 is reduced to Cr by Fe . Indentify the incorrect statement from the following:
3 2

2 3
i) 6 moles Fe are oxidised to Fe ions .
ii) The solution becomes yellow
iii) The solution becomes green
2 3
iv) 3 moles of Fe get oxidised to Fe .
(a) (i), (ii) (b) (ii), (iii) (c) (i), (iii) (d) (ii), (iv)

7. In hot alkaline solution Br2 disproportionates to Br and Br O 3

3Br2  6OH  
 5 Br   BrO3  3H 2O
hence equivalent weight of Br2 is
(molecular wt. = M)
M M
a) 6 b) 5
3M 5M
c) 5 d) 3
8. Choose the correct option:
0.64 g of an alkaline earth metal on oxidation gives 1.06 g of metal oxide. Then
i) equivalent weight of metal is 12
ii) equivalent weight of oxygen is 8
iii) atomic weight of metal is 12
iv) atomic weight of metal is 24
(a) (i), (ii), (iii) (b) (ii), (iii), (iv) (c) (i), (ii), (iv) (d) (i), (iii), (iv)

9. Choose the correct option:

0.6 moles of K 2 Cr2 O7 can oxidise


i) 3.6 moles of FeSO4 to Fe2 (SO4)3
ii) 0.1 moles of FeSO4 to Fe2 (SO4)3
iii) 0.05 moles of Sn2+ to Sn4+
iv) 1.8 moles of Sn2+ to Sn4+

(a) (i), (ii) (b) (ii), (iii) (c) (iii), (iv) (d) (i), (iv)

10. Choose the correct option:


The sulphate of metal 'A' contains 20% of M. This sulphate is isomorphism with ZnSO 4. 7H2O. Which of the
following is / are true about metal M ?
i) Atomic mass of metal is 24
ii) Metal is bivalent
iii) Eq. wt. of metal 12
iv) The salt of metal is MgSO4. 7H2O
(a) (i), (ii), (iii) (b) (ii), (iii), (iv) (c) (i), (iii), (iv) (d) All are correct

Answers and Solutions

H 2 S  H 2 O2 
 2 H 2O  S

1. (a)  2  0

NO2  4  , HNO3  5  , NH 3  3 , N 2O5  5 


2. (b)

CrO2 Cl2
3.

x   2  x 2  .  1  2  0

x  6

S8  O  , S2 F2  1 , H 2 S  2 
4. (a)

3
5. (d) Metallic iron is oxidised to Fe

14 H   6 Fe 2  Cr2O72 

6. ( c)

2Cr 3  6 Fe3  7 H 2 O

 
3Br2  6 O H  5Br     BrO3    3H 2O
7. (c) 0 1 5

3M
E
5

1
M  O2 
 MO
2
8. (c) .64 g 1.06 g

Applying conversion of atoms to metal.

Let mol mass of metal be M.

.64 1.06
  M  24.38
 M M  16
M
  12.19
Eq. mass of metal 2

Eq. of O = 8.

9. ( d)

14 H   Cr2O72  6 Fe 2 
 2Cr 3  6 Fe3  7 H 2 O

14 H   Cr2 O72  3Sn2 


2Cr 3  3Sn 4  7 H 2O

10. ( d)

Let mol mass of metal be M.

M
100  20
M  96

M = 24.

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