Intermediate - Redox Reactions
Intermediate - Redox Reactions
Intermediate - Redox Reactions
b) Reducing action of H 2 O2
c) Alkaline nature of H 2 O2
d) Acidic nature of H 2 O2
2. Match List I with List II and select the correct answer using the codes given below the lists
List I (Compound)List II (Oxidation state of N)
a) NO 2 (1) + 5
b) HNO3 (2) – 3
c) NH 3 (3) + 4
d) N 2 O5 (4) + 1
Codes :
a) A B C D
2 3 4 1
b) A B C D
3 1 2 4
c) A B C D
3 4 2 1
d) A B C D
2 3 1 4
3. Amongst the following identify the species with an atom in + 6 oxidation state
3−
a) MnO−4 b) Cr( CN )6
2−
c) NiF 6 d) CrO2 Cl 2
2 3
i) 6 moles Fe are oxidised to Fe ions .
ii) The solution becomes yellow
iii) The solution becomes green
2 3
iv) 3 moles of Fe get oxidised to Fe .
(a) (i), (ii) (b) (ii), (iii) (c) (i), (iii) (d) (ii), (iv)
7. In hot alkaline solution Br2 disproportionates to Br and Br O 3
3Br2 6OH
5 Br BrO3 3H 2O
hence equivalent weight of Br2 is
(molecular wt. = M)
M M
a) 6 b) 5
3M 5M
c) 5 d) 3
8. Choose the correct option:
0.64 g of an alkaline earth metal on oxidation gives 1.06 g of metal oxide. Then
i) equivalent weight of metal is 12
ii) equivalent weight of oxygen is 8
iii) atomic weight of metal is 12
iv) atomic weight of metal is 24
(a) (i), (ii), (iii) (b) (ii), (iii), (iv) (c) (i), (ii), (iv) (d) (i), (iii), (iv)
(a) (i), (ii) (b) (ii), (iii) (c) (iii), (iv) (d) (i), (iv)
H 2 S H 2 O2
2 H 2O S
1. (a) 2 0
CrO2 Cl2
3.
x 2 x 2 . 1 2 0
x 6
S8 O , S2 F2 1 , H 2 S 2
4. (a)
3
5. (d) Metallic iron is oxidised to Fe
14 H 6 Fe 2 Cr2O72
6. ( c)
2Cr 3 6 Fe3 7 H 2 O
3Br2 6 O H 5Br BrO3 3H 2O
7. (c) 0 1 5
3M
E
5
1
M O2
MO
2
8. (c) .64 g 1.06 g
.64 1.06
M 24.38
M M 16
M
12.19
Eq. mass of metal 2
Eq. of O = 8.
9. ( d)
14 H Cr2O72 6 Fe 2
2Cr 3 6 Fe3 7 H 2 O
2Cr 3 3Sn 4 7 H 2O
10. ( d)
M
100 20
M 96
M = 24.