H&M Chemical Restrictions: Global Quality Department 16 May 2013
H&M Chemical Restrictions: Global Quality Department 16 May 2013
H&M Chemical Restrictions: Global Quality Department 16 May 2013
Part 2, 3, 5 and 7 are divided into materials. The restrictions in Part 3 also apply to
Part 9 and 11 product types. The restrictions in Part 7 also apply to Part 5 and 6
product types. If the product is sold in a packaging, it must also comply with part 2. All
products must comply with Part 1. Each limit in H&M Chemical Restrictions is valid for
homogeneous parts of the concerned product if not otherwise stated.
All details on your product must comply with H&M Chemical Restrictions, see example
below. The examples do not claim to be complete.
Apparel/Accessories/Footwear Products
Padding:
− Follow Fusing, Padding, Feather and Down
restrictions in Part 3
Cosmetic Products
Lip gloss:
− Follow restrictions for Cosmetic Products in Part 4.
PE lid:
− Follow PE plastic restrictions in Part 5
PP bottle:
− Follow PP plastic restrictions in Part 5
Hard Products
Toys
All toys, soft and hard, and art materials (pens, crayons and
paint) for children:
− Follow restrictions for Toys in Part 9.
− Follow restrictions for respective material in Part 3,
Apparel / Accessories / Footwear / Soft Products,
− Pens, crayons, paint etc. are also chemical products.
Follow restrictions in Part 8.
Chemical Products
Glue for Eye lashes, art materials (pens, crayons and paint),
room scent, shoe polish, cleaning/washing products:
− Follow restrictions for Chemical Products in Part 8.
By accepting H&M Standard Purchase Conditions, the Supplier commits to comply with
H&M Chemical Restrictions. It is the Supplier’s responsibility to assure compliance with
H&M Chemical Restrictions and to inform all their downstream suppliers and
subcontractors about the content of H&M Chemical Restrictions.
Inspect and test any product, any part of production and/or packaging, by any
listed or appropriate method, at any time or at any stage of production.
Cancel the Order, or, if the products are already delivered, return the products
to the Supplier if the product, production and/or packaging do not correspond to
the H&M Chemical Restrictions.
Hold the Supplier responsible for any damage caused by the ordered product if
the product, production and/or packaging do not correspond to the H&M
Chemical Restrictions.
Receive the Safety Data Sheets (SDS) for all substances and preparations (dyes,
colorants, solvents, chemicals etc.) used in the production of a specific Order.
In the case of contradictory test results, H&M test result will prevail.
Part 2, Packaging
More information is found in “H&M PIM – Packing Instructions Manual”1.
Definitions
Not Detected The substance must not be present in the finished product at
concentrations above the analytical reporting limit.
Usage Ban The substance must not be used in production and it must not
be added to the product.2
Kinematic viscosity Describes how fast a fluid is spread on a flat surface in relation
to its mass, i.e. weight.
1
Download the document at H&M Group Supplier Portal.
2
Impurities at low concentrations of these substances may be accepted only if technically unavoidable
due to e.g. raw materials, formation in the manufacturing process, storage or packaging.
cfu Colony forming units. The content of bacteria, mould and yeast in a
product is measured by counting the number of colonies formed in
the sample. This is the unit for this counting.
cl Centilong
cSt centiStokes, which is the same as 1mm2/s. This is the unit used for
kinematic viscosity.
- Substances which are especially harmful for the workers and/or the environment e.g.
Organic Solvents and APEO.
- Substances restricted in products but still shown to be released in the textile supply
chain, e.g. Azo Dyes and Phthalates.
- H&M policy decisions e.g. PFC and Sandblasting.
Clause 1: Substances are not allowed to be found in H&M production sites and used in H&M
production
If a group of substances is marked with an asterisk* in the table below each included substance
is specified in Appendix A.1.
Chloroparaffins
3
Diethylphthalate is exempted in cosmetic production.
4
Supplier must always get an approval from H&M Global Quality Department before using any non-water based
systems.
If a group of substances is marked with an asterisk* in the table below each included substance
is specified in Appendix A.2. Test methods and reporting limits are listed in Appendix B.3.
Requirement/Restricted Limit/Requirement
substance
5
The container/packaging of cosmetic products includes both primary and secondary packaging, but excludes
transportation packaging.
6
Mainly used in silica gel.
7
Mainly used in humidity reducing sachets.
8
A list of approved flame retardants can be found at H&M Group Supplier Portal. Any other flame retardant must
be approved by H&M Global Quality Department before using.
9
If supplier believes fumigation is necessary, contact H&M Global Quality Department. More info and restrictions
regarding fumigation can be found in “H&M PIM – Packing Instruction Manual”.
10
A list of approved alternatives for water repellent treatments can be found at H&M Group Supplier Portal. Any
other alternative must be approved by H&M Global Quality Department before using.
Impurities of Perfluorinated Compounds (PFCs)* in functional finishes at low concentrations are accepted if
technically unavoidable in the manufacturing process.
Primary container/package Package shall not release any substances to, and/or
react with the content, i.e. package must be inert.
Substances defined as 1000 ppm, except if lower limit applies as per other
hazardous due to intrinsic parts of this document.
properties: persistent, bio-
accumulative and toxic (PBT),
very persistent and very
bioaccumulative (vPvB),
carcinogenic, mutagenic and
toxic for reproduction (CMR),
endocrine disruptors (ED) or
equivalent concern
Glass
Leather
11
http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
12
REACH Regulation (EC) No 1907/2006 http://eur-lex.europa.eu/en/index.htm
Chloroparaffins
Dyes
Cadmium (Cd)
Lead (Pb)
Sum ≤ 100 ppm
Mercury (Hg)
Chromium VI (Cr6+)
Phenols
13
Except Polycarbonate (PC)
Benzo(a)pyrene 1 ppm
Sum of other listed PAHs The sum < 10 ppm
Chloroparaffins
Dyes
Organotin Compounds*
14
For 100% polyester the total Sb limit applies (for 50% polyester the limit is 130 ppm etc.). For all other textile
materials the extractable Sb limit applies.
15
For polyamide, polyamide blends (min 5% PA) and worsted wool the extractable Cr limit applies.
For all other materials, chromium based dyes are not accepted, and the total Cr limit applies.
16
Extractable Cu limit applies only to woven baby wear up to size 98.
17
For 100% polyester the total Sb limit applies (for 50% polyester the limit is 130 ppm etc.). For all other textile
materials the extractable Sb limit applies.
18
Extractable Cu limit applies only to woven baby wear up to size 98.
Requirement/Restricted Limit/Requirement
substance
19
All antibacterial treatments on finished products are banned even if not listed in Appendix A.3. Please contact
H&M Global Quality Department regarding any queries about this.
20
A list of approved flame retardants can be found at H&M Group Supplier Portal. Any other flame retardant
must be approved by H&M Global Quality Department before using.
21
A list of approved alternatives for water repellent treatments can be found at H&M Group Supplier Portal. Any
other alternative must be approved by H&M Global Quality Department before using.
Impurities of Perfluorinated Compounds (PFCs)* in functional finishes at low concentrations are accepted if
technically unavoidable in the manufacturing process.
22
http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
Substances defined as 1000 ppm, except if lower limit applies as per other
hazardous due to intrinsic parts of this document.
properties: persistent, bio-
accumulative and toxic (PBT),
very persistent and very
bioaccumulative (vPvB),
carcinogenic, mutagenic and
toxic for reproduction (CMR),
endocrine disruptors (ED) or
equivalent concern
23
Children up to 14 years of age.
24
Regulation (EC) No 1223/2009 on cosmetic products. Until 11 July 2013 Annexes of Directive EC/76/768 apply.
25
EU directive 2009/48/EC – Directive on the Safety of Toys.
26
REACH Regulation (EC) No 1907/2006 http://eur-lex.europa.eu/en/index.htm
Chlorobenzenes
Chloronaphthalenes
2 ppm, per listed substance group
Chlorotoluenes
Chloroxylenes
Chloroparaffins
Dyes
27
Impurities of Cationic Surfactants* in functional finishes at low concentrations are accepted if technically
unavoidable and formed in the manufacturing process.
28
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
29
Test method; EN 71-3/A1/AC:2009
Formaldehyde
Organotin Compounds*
30
Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured
according to test method listed in Appendix B.1.
31
For 100% polyester the total Sb limit applies (for 50% polyester the limit is 130 ppm etc.). For all other textile
materials the extractable Sb limit applies.
32
For polyamide, polyamide blends (min 5% PA) and worsted wool the extractable Cr limit applies.
For all other materials, chromium based dyes are not accepted, and the total Cr limit applies.
33
Extractable Cu limit applies only to woven baby wear up to size 98.
Phenols
Leather
Chlorobenzenes
Chloronaphthalenes
2 ppm, per listed substance group
Chlorotoluenes
Chloroxylenes
Chloroparaffins
Dyes
34
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
35
Test method; EN 71-3/A1/AC:2009
Phenols
Chloroparaffins
36
Surface coating includes paint and print, excluding reactive print and electroplating.
37
Except Polycarbonate (PC)
38
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
39
Test method; EN 71-3/A1/AC:2009
Formaldehyde
Organotin Compounds*
Benzo(a)pyrene 1 ppm
Sum of other listed PAHs The sum < 10 ppm
Polychlorinated Biphenyls (PCB)
The sum < 0.5 ppm
Polychlorinated Triphenyls (PCT)
40
Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured
according to test method listed in H&M Implementation Toolkit for H&M Chemical Restrictions Part 1 –
Apparel/Accessories/Footwear/Interior Products.
41
In acetate material used only for adult’s spectacles low amounts of phthalates can be accepted.
42
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
43
Test method; EN 71-3/A1/AC:2009
44
Decorative items are items that are not needed for a specific function.
45
Functional items are those needed for a specific function, for example belt buckles, buttons, zippers and rivets
used to strengthen seems.
Cadmium (Cd)
Lead (Pb)
Sum ≤ 100 ppm
Mercury (Hg)
Chromium VI (Cr6+)
Lead (Pb): 50 ppm
In jewellery and hair accessories
Phenols
46
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
47
Test method; EN 71-3/A1/AC:2009
Organotin Compounds*
48
Only children’s jewelleries and children’s hair accessories intended for children up to 14 years of age.
49
Test method; EN 71-3/A1/AC:2009
50
Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured
according to test method listed in H&M Implementation Toolkit for H&M Chemical Restrictions Part 1 –
Apparel/Accessories/Footwear/Interior Products.
Restriction / Requirement
For adults:
Glass or Crystal that exposes humans to unsafe amounts of Lead (Pb), considering worst case
scenario, i.e. if swallowed, may not be used.
Recycled Material
For recycled materials51, the restrictions are the same as for other materials, with below
mentioned exceptions. These exceptions are only valid for orders where H&M explicitly specify
on the product that recycled material is used.
51
Recycled materials is both pre- and post-consumer waste defined as follows:
• Pre-consumer waste: The reintroduction of manufacturing scrap, such as waste from textile production,
back into the yarn manufacturing process.
• Post-consumer waste: A waste produced by the end consumer of a material stream such as used PET
bottles or worn out garments.
This appendix gives an overview of the restricted substances with known CAS numbers.
The Appendix is divided in parts. Some Parts in the restriction list do not have an Appendix A.
Substance groups marked with an asterisk* in any part of the restriction list are specified here.
Content
Restricted Substance
Name CAS no.
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP):
Nonylphenol Ethoxylates (NPE) Various
Octylphenol Ethoxylates (OPE) Various
Nonylphenoles (NP) Various
Octylphenoles (OP) Various
Chloroparaffins
Name CAS no.
Short chained (SCCPs) C10-C13 85535-84-8
Flame Retardants
Name CAS no.
Tris(2,3-dibromopropyl)phosphate (TRIS) 126-72-7
Bis(2,3-dibromopropyl)phosphate 5412-25-9
Tris-(aziridinyl)-phosphineoxide (TEPA) 5455-55-1
Polybrominated Diphenyl Ethers (PBDE) Various
Tetrabromobisphenol A (TBBP A) 79-94-7
Polybrominated Biphenyls (PBB) Various
Tri-o-cresyl phosphate 78-30-8
Tris(2-chloroethyl)phosphate (TCEP) 115-96-8
Hexabromocyclododecane 3194-55-6
2,2-Bis(bromomethyl)-1,3-propanediol 3296-90-0
Tris(1,3-dichloroisopropyl)phosphate (TDCP) 13674-87-8
Triphenyl phosphate (TPhP) 115-86-6
Organic Solvents:
Name CAS no.
Benzene (Benzol) 71-43-2
1,4-Butanediol 110-63-4
Dimethylacetamide (DMAC) 127-19-5
Dimethylformamide (DMF) 68-12-2
Ethylene glycol monoethyl ether 110-80-5
n-Hexane 110-54-3
4,4’methylenebis(2-chloraniline) (MOCA) 101-14-4
Phenol 108-95-2
Toluene (Toluol) 108-88-3
Organotin Compounds
Name CAS no.
Dibutyltin (DBT) 1002-53-5
Dioctyltin (DOT) -
Tributyltin (TBT) 56573-85-4
Tricyclohexyltin (TCyHT) 6056-50-4
Trioctyltin (TOT) 250252-89-2
Triphenyltin (TPhT) 668-34-8
Tripropyltin (TPT) -
Other tri-substituted organotins Various
Phthalates
Name CAS no.
Butyl benzyl phthalate (BBP) 85-68-7
Dibutyl phthalate (DBP) 84-74-2
Diethyl phthalate (DEP) 84-66-2
Di(2-ethylhexyl) phthalate (DEHP) 117-81-7
Diisobutyl phthalate (DIBP) 84-69-5
Diisodecyl phthalate (DIDP) 26761-40-0
Diisononyl phthalate (DINP) 28553-12-0
Di-n-hexyl phthalate (DnHP) 84-75-3
Di-n-octyl phthalate (DnOP) 117-84-0
All other phthalates (all other esters of o-phthalic acid) Various
Phenols
Name CAS no.
Pentachlorophenol (PCP) and its salts and esters 87-86-5
Tetrachlorophenol (TeCP) and its salts and esters 58-90-2, 25167-83-3
o-Phenylphenol (OPP) 90-43-7
Polychlorinated Compounds
Name CAS no.
Polychlorinated Biphenyls (PCB) 1336-36-3
Polychlorinated Triphenyls (PCT) 61788-33-8
Polyvinylchloride (PVC)
Name CAS no.
Polyvinylchloride (PVC) 9002-86-2
Polyvinylidenchloride 9002-85-1
Polychloroprene 9010-98-4
Bisphenol-A (BPA)
Name CAS no.
Bisphenol-A (BPA) 80-05-7
Cationic Surfactants
Name CAS no.
Distearyldimethyl ammouniumchloride (DSDMAC) 107-64-2
Ditallowdimethyl ammoniumchloride (DTDMAC) 68783-78-8
Dihydrogenated tallowdimethyl ammouniumchloride 61789-80-8
(DHTDMAC)
Chloroparaffins
Name CAS no.
Short chained (SCCPs) C10-C13 85535-84-8
Medium chained (MCCPs) C14-C17 85535-85-9
Cobalt Dichloride
Name CAS no.
Cobalt Dichloride 7646-79-9 / 16544-92-6 (dihydrate) / 7791-13-1
(hexahydrate)
Dimethylformamide (DMF)
Name CAS no.
Dimethylformamide (DMF) 68-12-2
Dimethylfumarate (DMFu)
Name CAS no.
Dimethylfumarate (DMFu) 624-49-7
Disperse Dyes
Name CI NO CAS no.
Disperse Blue 1 64 500 2475-45-8
Disperse Blue 3 61 505 2475-46-9
Disperse Blue 7 62 500 3179-90-6
Disperse Blue 26 63 305 3860-63-7
Disperse Blue 35 12222-75-2
Disperse Blue 102 12222-97-8
Disperse Blue 106 12223-01-7
Disperse Blue 124 61951-51-7
Disperse Brown 1 23355-64-8
Disperse Red 1 11 110 2872-52-8
Disperse Red 11 62 015 2872-48-2
Disperse Red 17 11 210 3179-89-3
Disperse Orange 1 11 080 2581-69-3
Disperse Orange 3 11 005 730-40-5
Disperse Orange 11 60 700 82-28-0
Disperse Orange 37 11 132 12223-33-5
Disperse Orange 76 (previously designated Orange 37) 51811-42-8
Disperse Orange 149 85136-74-9
Disperse Yellow 1 10 345 119-15-3
Disperse Yellow 3 11 855 2832-40-8
Disperse Yellow 9 10 375 6373-73-5
Disperse Yellow 23 26 070 6250-22-3
Disperse Yellow 39 12236-29-2
Disperse Yellow 49 54824-37-2
Elements
Name CAS no.
Antimony (Sb) 7440-36-0
Arsenic (As) 7440-38-2
Selenium (Se) 7782-49-2
Formaldehyde
Name CAS no.
Formaldehyde 50-00-0
Isocyanates
Name CAS no.
Diphenylmethane diisocyanate (MDI) 101-68-8
Hexamethylene diisocyanate (HMDI) 822-06-0
Isophorone diisocyanate (IPDI) 4098-71-9
Tetramethylxylene diisocyanate (TMXDI) 2778-42-9
2,4-Toluene diisocyanate (2,4 TDI) 584-84-9
2,6-Toluene diisocyanate (2,6 TDI) 91-08-7
Metals
Name CAS no.
Barium (Ba) 7440-39-3
Cadmium (Cd) 7440-43-9
Chromium (Cr) 7440-47-3
Cobalt (Co) 7440-48-4
Copper (Cu) 7440-50-8
Lead (Pb) 7439-92-1
Mercury (Hg) 7439-97-6
Nickel (Ni) 7440-02-0
Octamethylcyclotetrasiloxane
Name CAS no.
Octamethylcyclotetrasiloxane 556-67-2
Organotin Compounds
Name CAS no.
Dibutyltin (DBT) 1002-53-5
Dioctyltin (DOT) -
Tributyltin (TBT) 56573-85-4
Tricyclohexyltin (TCyHT) 6056-50-4
Trioctyltin (TOT) 250252-89-2
Triphenyltin (TPhT) 668-34-8
Tripropyltin (TPT) -
Other tri-substituted organotins Various
disodium (6-(4-anisidino)-3-sulfonato-2-(3,5-
dinitro-2-oxidophenylazo)-1-naphtholato)(1-(5-
chloro-2-oxidophenylazo)-2-
naphtholato)chromate(1-);
trisodium bis(6-(4-anisidino)-3-sulfonato-2-(3,5-
dinitro-2-oxidophenylazo)-1-
naphtholato)chromate(1-)
Other Dyes
Name CI NO CAS no.
Acid Red 26 16 150 3761-53-3
Basic Red 9 42 500 569-61-9
Basic Violet 14 45 510 632-99-5
Direct Black 38 30 235 1937-37-7
Direct Blue 6 22 610 2602-46-2
Direct Brown 95 30 145 16071-86-6
Direct Red 28 22 120 573-58-0
Solvent Yellow 1 11 000 60-09-3
Solvent Yellow 2 11 020 60-11-7
Solvent Yellow 3 11 160 97-56-3
p-Phenylenediamine 76 060 106-50-3
Phenols
Name CAS no.
Pentachlorophenol (PCP) and its salts and esters 87-86-5
Tetrachlorophenol (TeCP) and its salts and esters 58-90-2, 25167-83-3
o-Phenylphenol (OPP) 90-43-7
Polychlorinated Compounds
Name CAS no.
Polychlorinated Biphenyls (PCB) 1336-36-3
Polychlorinated Triphenyls (PCT) 61788-33-8
Polyvinylchloride (PVC)
Name CAS no.
Polyvinylchloride (PVC) 9002-86-2
Polyvinylidenchloride 9002-85-1
Polychloroprene 9010-98-4
Triclosan
Name CAS no.
Triclosan 3380-34-5
Anti-bacterial Substances
Name CAS no.
Silver (Ag) and its salts and compounds 7440-22-4, Various
Triclocarban 101-20-2
Triclosan 3380-34-5
All other substances used for anti-bacterial treatments Various
Bisphenol-A (BPA)
Name CAS no.
Bisphenol-A (BPA) 80-05-7
Cationic Surfactants
Name CAS no.
Distearyldimethyl ammouniumchloride (DSDMAC) 107-64-2
Ditallowdimethyl ammoniumchloride (DTDMAC) 68783-78-8
Dihydrogenated tallowdimethyl ammouniumchloride 61789-80-8
(DHTDMAC)
Chloroparaffins
Name CAS no.
Short chained (SCCPs) C10-C13 85535-84-8
Medium chained (MCCPs) C14-C17 85535-85-9
Dimethylformamide (DMF)
Name CAS no.
Dimethylformamide (DMF) 68-12-2
Dimethylfumarate (DMFu)
Name CAS no.
Dimethylfumarate (DMFu) 624-49-7
Disperse Dyes
Name CI NO CAS no.
Disperse Blue 1 64 500 2475-45-8
Disperse Blue 3 61 505 2475-46-9
Disperse Blue 7 62 500 3179-90-6
Disperse Blue 26 63 305 3860-63-7
Disperse Blue 35 12222-75-2
Disperse Blue 102 12222-97-8
Disperse Blue 106 12223-01-7
Disperse Blue 124 61951-51-7
Disperse Brown 1 23355-64-8
Disperse Red 1 11 110 2872-52-8
Disperse Red 11 62 015 2872-48-2
Disperse Red 17 11 210 3179-89-3
Disperse Orange 1 11 080 2581-69-3
Disperse Orange 3 11 005 730-40-5
Disperse Orange 11 60 700 82-28-0
Disperse Orange 37 11 132 12223-33-5
Disperse Orange 76 (previously designated Orange 37) 51811-42-8
Disperse Orange 149 85136-74-9
Disperse Yellow 1 10 345 119-15-3
Disperse Yellow 3 11 855 2832-40-8
Disperse Yellow 9 10 375 6373-73-5
Disperse Yellow 23 26 070 6250-22-3
Disperse Yellow 39 12236-29-2
Disperse Yellow 49 54824-37-2
Elements
Name CAS no.
Antimony (Sb) 7440-36-0
Arsenic (As) 7440-38-2
Selenium (Se) 7782-49-2
Flame Retardants
Name CAS no.
Tris(2,3-dibromopropyl)phosphate (TRIS) 126-72-7
Bis(2,3-dibromopropyl)phosphate 5412-25-9
Tris-(aziridinyl)-phosphineoxide (TEPA) 5455-55-1
Polybrominated Diphenyl Ethers (PBDE) Various
Tetrabromobisphenol A (TBBP A) 79-94-7
Polybrominated Biphenyls (PBB) Various
Tri-o-cresyl phosphate 78-30-8
Tris(2-chloroethyl)phosphate (TCEP) 115-96-8
Hexabromocyclododecane 3194-55-6
2,2-Bis(bromomethyl)-1,3-propanediol 3296-90-0
Tris(1,3-dichloroisopropyl)phosphate (TDCP) 13674-87-8
Triphenyl phosphate (TPhP) 115-86-6
Isocyanates
Name CAS no.
Diphenylmethane diisocyanate (MDI) 101-68-8
Hexamethylene diisocyanate (HMDI) 822-06-0
Isophorone diisocyanate (IPDI) 4098-71-9
Tetramethylxylene diisocyanate (TMXDI) 2778-42-9
2,4-Toluene diisocyanate (2,4 TDI) 584-84-9
2,6-Toluene diisocyanate (2,6 TDI) 91-08-7
Metals
Name CAS no.
Barium (Ba) 7440-39-3
Cadmium (Cd) 7440-43-9
Chromium (Cr) 7440-47-3
Cobalt (Co) 7440-48-4
Copper (Cu) 7440-50-8
Lead (Pb) 7439-92-1
Mercury (Hg) 7439-97-6
Nickel (Ni) 7440-02-0
N-Nitrosamines
Name CAS no.
N-Nitrosodimethylamine 62-75-9
N-Nitrosodiethylamine 55-18-5
N-Nitrosodipropylamine 621-64-7
N-Nitrosodibutylamine 924-16-3
N-Nitrosopiperidine 100-75-4
N-Nitrosopyrrolidine 930-55-2
N-Nitrosomorpholine 59-89-2
N-Nitroso-N-methylaniline 614-00-6
N-Nitroso-N-ethylaniline 612-64-6
Octamethylcyclotetrasiloxane
Name CAS no.
Octamethylcyclotetrasiloxane 556-67-2
Organotin Compounds
Name CAS no.
Dibutyltin (DBT) 1002-53-5
Dioctyltin (DOT) -
Tributyltin (TBT) 56573-85-4
Tricyclohexyltin (TCyHT) 6056-50-4
Trioctyltin (TOT) 250252-89-2
Triphenyltin (TPhT) 668-34-8
Tripropyltin (TPT) -
Other tri-substituted organotins Various
disodium (6-(4-anisidino)-3-sulfonato-2-(3,5-
dinitro-2-oxidophenylazo)-1-naphtholato)(1-(5-
chloro-2-oxidophenylazo)-2-
naphtholato)chromate(1-);
trisodium bis(6-(4-anisidino)-3-sulfonato-2-(3,5-
dinitro-2-oxidophenylazo)-1-
naphtholato)chromate(1-)
Other Dyes
Name CI NO CAS no.
Acid Red 26 16 150 3761-53-3
Basic Red 9 42 500 569-61-9
Basic Violet 14 45 510 632-99-5
Direct Black 38 30 235 1937-37-7
Direct Blue 6 22 610 2602-46-2
Direct Brown 95 30 145 16071-86-6
Direct Red 28 22 120 573-58-0
Solvent Yellow 1 11 000 60-09-3
Solvent Yellow 2 11 020 60-11-7
Solvent Yellow 3 11 160 97-56-3
p-Phenylenediamine 76 060 106-50-3
Phenols
Name CAS no.
Pentachlorophenol (PCP) and its salts and esters 87-86-5
Tetrachlorophenol (TeCP) and its salts and esters 58-90-2, 25167-83-3
o-Phenylphenol (OPP) 90-43-7
Polychlorinated Compounds
Name CAS no.
Polychlorinated Biphenyls (PCB) 1336-36-3
Polychlorinated Triphenyls (PCT) 61788-33-8
Polyvinylchloride (PVC)
Name CAS no.
Polyvinylchloride (PVC) 9002-86-2
Polyvinylidenchloride 9002-85-1
Polychloroprene 9010-98-4
This Appendix specifies the test methods that should be used when testing for the restricted
substances. Test methods listed in any Part of the restriction list are not listed in this appendix.
The Appendix is divided in parts. Some Parts in the restriction list do not have an Appendix B.
Content
Textiles, leather:
Agreed method of BVCPS, INTERTEK, MTS and SGS 50 mg/kg
Textiles, leather:
Methanol extraction followed by GC/MS 5 mg/kg
AP
Plastic, prints:
THF/ACN extraction followed by GC-MS 5 mg/kg
Total Amount:
Solvent extraction and analysis by LC-MS 0.2 mg/kg
Leather:
EN ISO 17075:2007
3 mg/kg
Aging test: Draft CEN/TC 309 WG 2N 90: 2007-10
Paper:
Chromium VI (Cr6+)
EN ISO 17075:2007 3 mg/kg
Textile:
EN ISO 17075:2007 0.5 mg/kg
Dyes
Textiles:
EN 14362-1: 2012
10 mg/kg
EN 14362-3: 2012 (determination of 4-
aminoazobenzene)
Azo Dyes & Pigments
Leather:
EN ISO 17234-1:2010
10 mg/kg
EN ISO 17234-2:2011 (determination of 4-
aminoazobenzene)
Navy Blue:
BVCPS inhouse method:
Other Azo Dyes Extraction with an organic solvent and analysis by 10 mg/kg
LC/DAD/MS
DIN 54231:2005-11
BVL B 82.02-10: 2007-03 1-5 mg/l
Other Dyes
p-phenylenediamine:
Methanol extraction and analysis by GC-MS 10 mg/kg
Aniline:
Extraction with an organic solvent followed by
Dye related compounds 10 mg/kg
GC/MS analysis
TEPA:
Potassium Hydroxide digestion followed by GC-MS
10 mg/kg
Headspace analysis of Ethyleneimine
Formaldehyde Leather:
ISO 17226-1:2008
20 mg/kg
EN ISO 17226-2:2008/AC:2009
Paper:
EN 645:1994 and EN 1541:2001 20 mg/kg
Wood:
EN 717-3:1996 5 mg/kg
ISO 10283:2007
Isocyanates 3 mg/kg
Draft DIN 54233-3:2010-02
Extraction with artificial sweat solution and Metal Reporting limit: 0.1 mg/kg
Determination by ICP-MS analysis Except Hg/Cd: 0.02 mg/kg
Nickel:
Nickel release by EN 1811:2011/AC:2012.
Metals, Extractable Amount
Abrasion of coated items by EN 12472:2005 + 0.05 µg/cm2/week
A1:2009.
a
Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to
test method.
Leather:
PCP, TeCP, OPP:
BVL B 82.02-08 (modified)
Acetone extraction, derivatisation followed by GC-
PCP: 0.05 mg/kg
MS analysis
TeCP: 0.05 mg/kg
OPP: 0.5 mg/kg
Draft ISO 17070 PCP :2012
determining the content of pentachlorophenol
(PCP), its salts and esters in leather
ZEK 01.04-08
Polyaromatic Hydrocarbons
Extraction with toluene followed by GC-MS analysis 0.2 mg/kg
(PAH)
Beilsteins test and infrared spectroscopy (IR) with
PVC or without chemical separation qualitative