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REPRODUCED BY
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NATIONAL TECHNICAL INFORMATION SERVICE
SPRINGFIELD, VA. 22161
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Carbon steels and low-alloy carbon steels have been the primary source
for materials used to construct locks, dams, and hydroelectric plant
structures. Some components for these facilities have also been fabricated
from 300-series austenitic stainless steels and the martensitic grades of 400-
s e n e s stainless steels. Advanced technology alloys that have better
corrosion resistance and higher strength than alloys developed earlier can be
advantageous for water resource projects. This report presents typical
UNCLASSIFIED
UNCLASSIFIED
Block 6a (Cont'd)
Block 6c (Contfd)
UNCLASSIFIED
PREFACE
COL Carl 0. Magnell was Commander and Director of USACERL, and Dr.
L. R. Shaffer was Technical Director.
1
CONTENTS
Page
PREFACE.................................................................. 1
PART Iî INTRODUCTION................................................... 3
Background
Objective
Approach
TABLES 1-8.............................................................. 47
REFERENCES....... 57
2
MECHANICAL PROPERTIES AND CORROSION BEHAVIOR OF STAINLESS STEELS
FOR LOCKS, DAMS, AND HYDROELECTRIC PLANT APPLICATIONS
PART I: INTRODUCTION
Background
I. Carbon steels and low-alloy steels have been the primary source for
materials used to construct locks, dams, and hydroelectric plants. To a much
Lesser extent, components tor these facilities traditionally have been
fabricated from 400-series martensitic stainless steels (e.g., Types 410 and
416) and 300-series austenitic stainless steels (e.g., Types 302, 303, 304,
308, and 316). Although the 300-series stainless steels normally have
excellent corrosion resistance in most freshwater environments (Table 1, Kamp
and Schmitt 1966) their yield strengths (about 35,000 psi in the annealed
condition) are somewhat low for many applications. Further, at a number of
locks and dams, bolts and nuts fabricated from the same 300-series material
have exhibited serious galling problems in the threaded area. The 300-series
stainless steels (including Type 316, which is formulated with a small amount
of molybdenum added to resist pitting attack) also have a tendency to pit ih
waters containing more than about 1000 parts per million (ppm) chloride. They
are also susceptible to oxygen differential, concentration-cell corrosion
under deposits and in crevices. Fortunately, the austenitic grades of
stainless steel do not experience chloride-induced, stress-corrosion cracking
at temperatures less than about 150° F (Pecknar and Bernstein 1977). They
also exhibit excellent resistance to freshwater erosion corrosion.
3
steels have failed due to hydrogen-induced cracking because the components
were only slightly overprotected by the cathodic protection systems designed
to mitigate corrosion.
Objective
Approach
4
6. Researchers discussed these Stainless steels with U.S. Army Corps of
Engineers personnel and obtained additional information from various guide
specifications and as-built drawings.
5
PART II: COMPOSITION AND PROPERTIES
b. Replacement of equipment.
d. Shutdown of equipment.
f. Contamination of a product.
10. Some of these indirect losses can cost much more than the
difference between a material that would have performed satisfactorily and one
that would not. Therefore, it is important to consider potential indirect
losses due to corrosion when selecting material.
e OF RECLAMATWM U
ti ^
exposed surfaces. This allows the stainless steels to exhibit potentials that
are more noble (electrically positive) than they would have in the active
(corroding) condition. In the passive condition, stainless steels have
electrochemical characteristics similar to those of a noble metal such as
gold. If this passive film is locally destroyed and cannot be readily
repaired, pitting attack can be expected to occur in certain environments
(especially, chloride-containing, aqueous environments). Similar localized
corrosion in the form of oxygen-differential, concentration-cell corrosion can
occur in crevices and under deposits (i.e., in occluded cells) where there is
insufficient oxygen to maintain the passive film. The absence of oxygen in
occluded cells causes the stainless steel to become electrochemically active
(i.e., become anodic) and exhibit a negative potential relative to that area
where the passive film is still intact. This form of corrosion can be
especially deleterious because it is usually facilitated by a large driving
voltage between the passive and active regions and an undesirably large
cathode-to-anode area ratio.
8
(i.e., the values of Etp - E^) and increases the magnitudes of ic and i^
(Segan et al. 1982). Similar adverse phenomena occur, in general, when the
temperature of the environment is increased and/or the pH is lowered. The
deleterious effects of high operating temperatures, acidic environments, and
the presence of chlorides on stainless steels have been verified and explained
through laboratory testing. Additional laboratory testing has also shown that
all of the stainless steels listed in Table 4 spontaneously passivate in
aerated Columbia River water and corrode in the passive potential region at
very low uniform corrosion rates (i.e., corrosion rates associated with i^
values of 2.8 to 8.2 x 10~^ ampere/cm^, Segan et al. 1982).
Galvanic Corrosion
9
18. The initial driving voltage for galvanic corrosion will normally
decrease with time because of polarization at the anodes and cathodes. This
decrease in the driving voltage, in turn, reduces the galvanic corrosion
current density at the anodes and lowers their corrosion rates. Table 6
(Segan et al. 1982) lists the galvanic corrosion current densities obtained
for equal anodic and cathodic areas of ASTM A36 steel connected to selected
grades of stainless steel. Based on these data, galvanic corrosion of ASTM
A36 steel is not significantly affected by the chemistry or metallurgical
condition of the stainless steel involved. The corrosion current densities
for the ASTM A36 steel vary between 1.4 and 2.5 x 10-^ ampere/cm^.
Cavitation
19. Tests conducted in accordance with ASTM G32 have allowed stainless
steels and a low-alloy carbon steel to be ranked according to their cavitation
resistance (Table 7, Segan et al. 1982). Not unexpectedly, NITRONIC 60 had
the best cavitation resistance of the materials evaluated. Similar cavitation
resistance results have been obtained for stainless steels exposed to jet-
impingement by river water. The relative cavitation depth damages for
NITRONIC 60, 17-4PH, Type 316, and CA-6NM were reported as being 1.0, 1.9,
3.7, and 6.6, respectively (Schumacher 1986). These data clearly indicate
that cast NITRONIC 60 could be a viable alternative for CA-6NM where
cavitation is a concern.
Galling
20. When two metal surfaces are rubbed together under heavy pressure,
and without lubrication, it is expected that galling (or even seizing) may
result.
21. The "button and block" galling test has been used to evaluate the
adhesive wear resistance of various stainless steels under nonlubricated
conditions (Schumacher 1977). Specimens were considered galled if deep
scoring and heavy surface damage were evident during examination of the
surfaces at 10X magnification. The lightest load that caused galling was used
to calculate the "threshold galling stress." Threshold galling stresses for
10
selected stainless steel combinations are included in Table 8 (Schumacher
1977).
22. The data In Table 8 establish that many contacting stainless steel
combinations are highly susceptible to galling. Most important, the data show
that NITRONIC 60 can be used in contact with many stainless steels without
concern for galling. Galling problems associated with the use of Type 304
nuts and bolts could very well be eliminated by fabricating one of the
components from NITRONIC 60.
11
PART IV: CASE STUDIES
23. These case studies present two successful examples which indicate
that properly selected, corrosion-resistant stainless steels are viable
options for roller assemblies on tractor-type dam gates (such as intake gates)
and for dam gate seal materials.
24. The first case study demonstrates the successful use of high
strength corrosion-resistant "aerospace" stainless steels for tractor-type dam
gate components (Komp and Schmitt 1966).
25. Until about 20 years ago, the rollers for tractor-type dam gates
(sometimes referred to as intake gates) were conventionally fabricated from
Type 410 stainless steel that had been heat treated to the strength level
provided by a hardness of 259 to 307 Brinell. The heavier-than-usual
hydrostatic loads (over 4,000,000 lb) on the tractor-type gates for Oahe Dam
on the Missouri River necessitated the use of either larger Type 410 stainless
steel rollers or rollers of increased strength and hardness. During
engineering design, it was quickly established that rollers fabricated from
Type 410 would be too large, and the desired size rollers could not be
fabricated from any martensitic 400-series stainless steel without some
undesirable loss in corrosion resistance. Further, there had been some
incidents of cracking in rollers fabricated from Type 410. After serious
consideration and evaluation of many candidate materials by the design
engineers, they selected corrosion-resistant, martensitic, 17-4PH stainless
steel for the rollers at Oahe Dam.
12
27. Another advantage obtained by selecting 17-4PH for the roller
material was that the width of the individual rollers could be reduced more
than 25 percent, permitting the use of a narrower track. This overall
decrease in roller size allowed a more corrosion-resistant, higher strength
stainless steel (compared to Type 410) to be used without an increase in cost,
28. The 17-4PH rollers and their associated Type 304 stainless steel
links and pins and 15-7PH Mo stainless steel retaining rings have been in
service, both totally immersed and alternately immersed in the Missouri River
since their original installation (1962), without corrosion problems. Similar
experience has been reported for the roller assemblies on the tractor-type
gates at Gavins Point Dam on the Missouri River.
29. Some districts are considering using round link chain and pocket
wheels for tainter gate hoists. These may fulfill the required design and
cost criteria better than roller chain. If suitability is proven, round link
ch^in will be used exclusively on dams on the Mississippi River during major
rehabilitation, in the interest of standardization of gate operating
machinery.
30. The second case study involved an indepth study of the Corps of
Engineers* experience with gate seals for 40 dams on the Monongahela, Ohio,
Mississippi, Columbia, and Illinois Rivers. Information from this study is
significant because it can be useful in selecting the best materials and
design options for dam gate seals.
13
However, if a tighter seal is required, it may be necessary to use a rubber
seal attached to the skinplate.
32. Examination of the gate seals for the dams included in the study
revealed that the guidelines of EM 1110-2-2702 have, in general, been followed
with reasonably good performance. The only exception is at Emsworth Dam on
the Ohio River wherewood was used for seals on the vertical lift gates between
1934 and 1936. Theywere replaced with rectangular neoprene seals during
the major rehabilitation of the dam between 1981 and 1986. Reportedly,
personnel at Emsworth Dam do not like rubber seals on the gates because they
tend to "bind" and subsequently overload the gate motors. The rubber seals
were found to bind in the vertical travel, primarily because the seals are set
for the "gate closed" gauge, which over the years has widened due to wear and
corrosion, while the gauge of the pier track above the gate closed position is
narrower. Rubber seals exhibit a great deal of friction, especially in the
drv condition, undereven nominal pressure. The problem has been addressed
and the solution consists in realigning the lower portion of the pier gate
wheels and seal gauge, and providing a relief for the rubber seals above the
gate closed elevation. This opinion, however, is not completely shared by
personnel at the other dams contacted. For example, nylon-reinforced seals
have been used on roller gates for as long as 46 years without the need for
replacement (at Dam No. 4 on the Mississippi River). Only about 100 ft of
rubber or neoprene J-seals have been replaced on the 15 tainter gates at Dam
No. 24 on the Mississippi River during the past 25 years.
14
(2) Type 304 stainless steel plates for the contacting seal
surfaces in the piers.
(3) Type 304 stainless steel bolts and washers with NITRONIC 60
nuts for attachment of the J-seals (to minimize galling or wear and to
facilitate removal and loosening of the bolts for field adjustment of the
seals).
(2) Type 304 stainless steel plates for the spillway and sills for
those gates where water leakage can be tolerated.
15
PART V: MATERIALS SELECTION
16
WW-V-051 Cancelled
WW-V-054 Cancelled
17
Bulkhead & Tainter Gate Components
18
Bulkhead & Tainter Gate Components (Continued)
Wire Rope Adjusting Bolts ASTM A564, Grade XM25 Stainless Steel
• Armeo 17-4PH Stainless Steel
• Carpenter Custom 450 Stainless Steel
19
Bulkhead & Tainter Gate Components (Continued)
20
Miter Gate Components
Pintle Socket Grease Lines • ASTM A312, Type 304 Stainless Steel Pipe
• ASTM A269, Type 316 Stainless Steel Tube
High Pressure Neoprene Hose
^Annealed.
**Brinell Hardness of 390 to 410.
21
Miter Gate Components (Continued)
Mitering Device Guide Rollers ASTM A148, Grade 80-40 Cast Steel**
22
Miter Gate Components (Continued)
23
Miter Gate Machinery
Sector Arm Support Wheel ASTM A564, Grade XM-25 Stainless Steel
• Armco 17-4PH Stainless Steel
• Carpenter Custom 450 Stainless Steel
24
Miter Gate Machinery (Continued)
Key for Hydraulic Cylinders ASTM A575 and A576, Type 1040 Steel
25
Miter Gate Machinery (Continued)
26
Tainter-Valve Components
1
Skin Plate ASTM A36 Steel
• Type 304 Stainless Steel Clad for
Downstream Face
J-Seals Neoprene**
Natural Rubber*
27
Tainter-Valve Components
28
Emergency-Gate Machinery
29
Emergency-Gate Machinery (Continued)
30
Segmental Valve Machinery
31
Segmental Valve Machinery (Continued)
Piston Rod Connecting Casting ASTM A27, Grade 60-30 Cast Steel
32
Emergency Dam (Wicket Type) Components
33
Gears
34
Shafts
Bull Gear and Drum Shaft ASTM A668, Class C Steel Forgings
35
Pins
Hinge Pin for Valve Machinery ASTM A564, Type XM-25 Stainless Steel
• Armeo 17-4PH Stainless Steel
• Carpenter Custom 450 Stainless Steel
36
Steel Reinforcements for Concrete
37
Hydroelectric Plant Components
Interior Wicket Gate Grease Pipe ASTM A53, Grade E and S Steel pipe
Scroll Case Vinyl Coated Carbon Steel
Powerhouse Pipe/Tube
38
Hydroelectric Plant Components (Continued)
C i r c u l a t i n g W a t e r for A i r
C o n d i t i o n i n g , up to 125 psi g A S T M A 5 3 G a l v a n i z e d St e e l Pipe for Lines
U p to 2 . 5 - I n c h e s (Threaded)
A S T M A 5 3 B l a c k Steel Pipe for L i n e s 2.5-
Inches and Larger (Welded)
Pressure Sewage, u p to
100 p s i g A S T M A 5 3 B l a c k Steel S c h e d u l e 80 P i p e
Where Exposed
WW-P - 4 0 1 Cast Iron Pipe W h e r e
Underground
G o v e r n o r , L u b e Oil, C i r c u i t
Bre a k e r , a n d T r a n s f o r m e r
Oil U p to 150 p s i g WW-T-799, Type K Copper Tube
Hydroelectric Plant Components (Continued)
40
Pi sheries
Fish-Handling Equipment
(Spawning) • ASTM A276, Type 304 Stainless Steel
41
Traveling Fish Screens
*With stainless steel isolated from structural steel using Oilon Pv80.
42
Miscellaneous Components
Floating Mooring Bitts Posts ASTM A106, Grade B Schedule 160 Steel
Pipe
Rollers for Floating Mooring Bitts • ASTM A416, Type 410 Stainless Steel
• Carpenter 450 Stainless Steel
• Armeo 17-4PH Stainless Steel
Shafts for Floating Mooring Bitts ASTM A176, Type 410 Stainless Steel
Carpenter 450 Stainless Steel
Armeo 17-4PH Stainless Steel
♦Lubricated.
**Vinyl coated.
43
Miscellaneous Components (Continued)
44
Miscellaneous Components (Continued)
45
PART VI: CONCLUSIONS
39. While stainless steels are viable options for many lock, dam, and
hydroelectric plant applications, no single stainless steel available exhibits
the desired mechanical properties and corrosion resistance for all applica
tions'. Alloys must be carefully selected and specified for a particular
application, and the components must be properly designed and fabricated.
General guidelines for selection of materials for specific components are
provided in Part V.
46
Table 1
47
Table 2
48
TabLe 3
Impact
Alloy Form Condition UTS 0.2% YS % E % RA Hard. Strength
(ksi ) (ksi) (ft-lbs)
10% CD 120 91 51 68 Rc 24 -
(Continued) (Sheet 1 of 3)
49
Table 3 (Continued)
Impact
Alloy Form Condi tion UTS 0.2Z YS X E X RÀ Hard. Strength
(ksi) (ksi ) (ft-lbs)
CUSTOM
450 Bar SA 141 118 13 50 Rc 28 Charpy 95
50
Table 3 (Continued)
Impact
Alloy Form Condition UTS 0.2% YS Z E % RA Hard. Strength
(ksi) (ksi) (ft-lbs)
*
TH1050 170 140 6 25 Rc 38
+Charpy keyhole notch; all other Charpy impact data are for V-notch.
(Sheet 3 of 3)
N All of the above are more cavitation resistant than cast iron or
S ral steel.
51
Table 4
*) *)
Stainless Steel/Condition** Ep» Volt c , amp/cm ip , amp/cm Etp, Volt
Type 304, Annealed + 10% CW -0.347 4.28 IO'4 3.27 X IO’6 +0.89
52
Table 5
Type 304/Annealed
+ 10% CW -0.328 0.246
Custom 450/Aged at
1150°F -0.362 0.212
53
Table 6
17-4PH/Condition A 2.2 X 10 ^
*See Table 3 for condition abbreviations. All samples exposed to aerated 0.5M sodium
chloride solution at ambient temperature.
54
Table 7
55
Table 8
Type 3 0 3 ^ 4 9 2 2 3 3 50+
Type 316§ 2 42 3 2 2 2 38
17-4PH§§ 3 2 2 2 2 2 50+
Nickel Alloy Steels Data Book. 1965. The International Nickel Company, Inc.
Schumacher, W. J. 1977. "Wear and Galling Can Knock Out Equipment," Chemical
Engineering, Reprint, May 9, 1977.
Segan, E. G., et al. 1982 (March). "Wrought Stainless Steel Fasteners for
Civil Works Applications," U.S. Army Construction Engineering Research
Laboratory Technical Report M-306.
Working Data: Carpenter Stainless and Heat Resisting Steels. 1965. Carpenter
Technology Corporation).
57
POINT OF CONTACT Dr. Ashok Kumar