BRASS

MATERIAL SAFETY DATA SHEET

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European Directives

PART I What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED): BRASS
CHEMICAL NAME/CLASS: METAL ALLOY
PRODUCT USE: Printing Operations
MANUFACTURER'S NAME: REVERE GRAPHICS WORLDWIDE
ADDRESS: 5 Boundary Street
Plymouth, MA 02360
EMERGENCY PHONE: (800) 424-9300 (CHEMTREC)
BUSINESS PHONE: (508) 746-1000
DATE OF PREPARATION: January 10, 2003
DATE OF REVISION: September 8, 2004

2. COMPOSITION and INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS # EINECS # % w/w EXPOSURE LIMITS IN AIR
ACGIH OSHA NIOSH OTHER
TLV STEL PEL STEL IDLH
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Lead 7439-92-1 231-100-4 <2 0.05 0.05 (see 29 NE 100 NIOSH REL:
Exposure limits are CFR TWA = < 0.1 (blood Pb <
for lead and 1910.1025) 0.06 mg/100 g whole
inorganic blood)
compounds, as pB DFG MAKs
TWA = 0.1 (inhalable
fraction)
PEAK = 8!MAK 15 min.,
average value, 1-hr
interval
DFG MAK Pregnancy Risk
Classification: B
Carcinogen: EPA-B2,
IARC-2B, TLV-A3
Zinc 7440-66-6 231-175-3 5.0-40.0 5 10 5 NE 500 NIOSH REL:
Exposure limits are TWA = 5
for zinc oxide, DFG MAK (fume):
fume TWA = 0.1 (Respirable
fraction)
PEAK = 1!MAK 15 min.,
average value, 1-hr
interval
Carcinogen: EPA-D (fume)
Copper 7440-50-8 231-159-6 68.0-96. 0.2 NE 0.1 (fume) NE 100 NIOSH RELs:
Exposure limits are (fume) TWA = (fume): 0.1; (dusts
1 (dusts &
for copper fume and & mists): 1
1 (dusts mists)
dust Carcinogen (copper dusts &
& mists)
mists): EPA-D
NE = Not Established See Section 16 for Definitions of Terms Used.
NOTE: All Canadian WHMIS, and European Community required information is included. It is located in appropriate sections based on the ANSI Z400.1-1998
format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the
CPR.

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3. HAZARD IDENTIFICATION
EC LABELING AND CLASSIFICATION: This product does not meet the definition of any hazard class as defined by
the European Community Council Directive 67/548/EEC or subsequent Directives.
EC CLASSIFICATION: Not applicable. EC RISK PHRASES: Not applicable. EC SAFETY PHRASES: Not applicable.

EMERGENCY OVERVIEW: This odorless product is a solid brass alloy plate. Health Hazards: There are no
immediate health hazards associated with this product. If highly heated, fumes from the product may also cause
metal fume fever. Fire Hazards: This product is not flammable. If heated to decomposition this product can produce
irritating vapors and toxic gases (e.g., metal oxides, metal fumes. Reactivity Hazards: This product is not reactive.
Environmental Hazards: Due to the form of this product, it is not expected that damage to the environment can
occur if released. Emergency Considerations: In the event of fire or spill, adequate precautions must be taken for
surrounding materials. Emergency responders must wear personal protective equipment suitable for the situation to
which they are responding.

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
most significant routes of over-exposure for this product are by skin or eye
contact. The following paragraphs describe symptoms of exposure by
route of exposure.
INHALATION: Inhalation is not anticipated to be a significant route of HEALTH HAZARD (BLUE) 0
overexposure to the plates. Inhalation of large amounts of particulates
generated by this product during metal processing operations may be
physically irritating and cause deposits of dust in nasal passages.
Inhalation of dusts and fumes of Copper and Zinc (the main components FLAMMABILITY HAZARD (RED) 0
of this product) can cause metal fume fever. Initial symptoms of metal
fume fever can include a metallic or sweet taste in the mouth, dryness or
irritation of the throat, and coughing. Later symptoms (after 4-48 hours)
can include sweating, shivering, headache, fever, chills, thirstiness, PHYSICAL HAZARD (YELLOW) 0
muscle aches, nausea, vomiting, weakness, and tiredness. Chronic over-
exposure to Copper dust may cause tiredness, stuffiness, diarrhea and
vomiting.
CONTACT WITH SKIN or EYES: Contact of the plate form of this product PROTECTIVE EQUIPMENT
with the skin is not anticipated to be irritating. Contact with the plate form
of this product or metal dust generated during routing can be physically EYES RESPIRATORY HANDS BODY
damaging and irritating to the eye (i.e., foreign object). Rare cases of
allergic contact dermatitis have been reported in people working with
copper dust. See See
SKIN ABSORPTION: Skin absorption is not known to be a significant Section 8 Section 8
route of over-exposure for any component of this product. For Routine Industrial Use and Handling Applications
INGESTION: Ingestion is not anticipated to be a likely route of
occupational exposure for this product. If particulates, generated during See Section 16 for Definition of Ratings
routing operations, are ingested (i.e., through poor hygiene practices),
nausea, vomiting, diarrhea, and abdominal cramps can occur.
INJECTION: Injection of this product is not anticipated to be a significant route of exposure. In the unlikely event that a
splinter of the alloy penetrates the skin, a slow-healing, gaseous bleb may be produced.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure from this product is
very unlikely when used for its designed purpose.
ACUTE: Inhalation of large amounts of particulates generated by this product during metal processing operations may
result in irritation. Inhalation of dusts and fumes of Copper and Zinc (components of this product) can cause metal
fume fever. Contact with the plate form of this product or metal dust generated during routing can be physically
damaging and irritating to the eye (i.e., foreign object).
CHRONIC: Rare cases of allergic contact dermatitis have been reported in people working with copper dust. This product
contains trace amounts of Lead, which is a possible carcinogen and reproductive hazard.
TARGET ORGANS: ACUTE: None under normal circumstances of use and handling. Skin, eyes, and respiratory
system in situations in which fumes or dusts are generated. CHRONIC: Skin (from Photoresist).

PART II What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effect occurs. Remove or cover gross
contamination to avoid exposure to rescuers. Rescuers should be taken for medical attention, if necessary. Take copy of
label and MSDS to health professional with victim.

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4. FIRST-AID MEASURES (Continued)

SKIN EXPOSURE: In the event that skin contact leads to irritation, rinse the area thoroughly with water. The
contaminated individuals must seek medical attention if any adverse effect persists.
EYE EXPOSURE: If particulates generated by this product during metal processing operations enter the eyes, open
victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum
flushing is for 15 minutes. Victim must seek immediate medical attention.
INHALATION: If particulates generated by this product during metal processing operations are inhaled, remove victim
to fresh air. Seek medical attention if adverse effect continues after removal to fresh air.
INGESTION: If particulates generated by this product during metal processing operations are swallowed, CALL
PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not
available, do not induce vomiting. Victim should drink milk, egg whites, or large quantities of water. Never induce
vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Acute or chronic respiratory conditions, skin disorder, central
nervous system conditions, or disorders involving the “Target Organs” (see Section 3, “Hazard Identification”) may be
aggravated by overexposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure .

5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable. NFPA RATING
AUTOIGNITION TEMPERATURE: Not applicable. FLAMMABILITY
FLAMMABLE LIMITS (in air by volume, %): Lower: Not applicable.
Upper: Not applicable.
FIRE EXTINGUISHING MATERIALS: Use fire extinguishing materials 0
appropriate for surrounding fire.
Water Spray: No Carbon Dioxide: Yes 0 0
HEALTH INSTABILITY
Foam: Yes Dry Chemical: Yes
Halon: Yes Other: Any “ABC” Class
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is not
flammable. When involved in a fire, this product may decompose and
produce irritating fumes and toxic gases including copper, lead and zinc
OTHER
oxides, metal fumes.
Explosion Sensitivity to Mechanical Impact: Not sensitive. See Section 16 for
Explosion Sensitivity to Static Discharge: Not sensitive. Definition of Ratings
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters
must wear Self-Contained Breathing Apparatus and full protective equipment. If possible, prevent runoff water from
entering storm drains, bodies of water, or other environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Pick-up plates carefully, avoiding cuts. Place in a suitable container and seal if
appropriate. Dispose of or recycle in accordance with U.S. Federal, State, and local hazardous waste disposal
regulation, those of Canada and its Provinces, and those of EC Member States see Section 13, Disposal
Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after using this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing dusts of this product. If necessary, periodically wipe-down area of product use to prevent accumulation of
dusts. Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this product should be trained to handle it safely.
Avoid breathing particulates generated by this product during metal processing or other operations. Use in a well-
ventilated location. Packages of this product must be properly labeled. No special precautions are necessary when
handling these plates, except to protect the surfaces from mechanical damage. Avoid accumulation of shavings or
powder produced when working with these plates. Store packages in a cool, dry location. Storage in an atmosphere that
is wet, moist, or highly humid may lead to corrosion of this product. Store away from incompatible materials (see Section
10, Stability and Reactivity
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if
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necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures, or the
applicable standards of Canada and its Provinces and EC Member States.

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8. EXPOSURE CONTROLS - PERSONAL PROTECTION

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are
maintained below the limits provided in Section 2 (Composition and Information on Ingredients). Prudent practice is to
ensure eyewash/safety shower stations are available near areas where this product is used.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: The following international exposure limits are currently in
force for some of the components of this product.
COPPER: COPPER (continued): COPPER (continued):
Arab Republic of Egypt: TWA = 0.1 mg/m 3 The Netherlands: MAC-TGG = 1 mg/m3 (dust), United Kingdom: TWA = 0.2 mg/m3, fume, SEP
(fume), JAN 1993 JAN 1993 2000
Australia :TWA = 0.2 mg/m3 (fume), JAN 1993 Norway: TWA = 0.05 mg(Co)/m3, JAN 1999 United Kingdom: TWA = 1 mg/m3, STEL 2
Australia :TWA = 1 mg/m3 (dust), JAN 1993 Norway: TWA = 0.1 mg/m3, fume, JAN 1999 mg/m3, dusts and mists as Cu, SEP 2000
Austria: MAK = 1 mg/m3, JAN 1999 The Philippines: TWA = 1.0 mg/m3 (fume), JAN United Kingdom: TWA = 1 mg(W)/m3, STEL 3
Austria: MAK = 0.1 mg/m3 (fume), JAN 1999 1993 mg(W)/m3, SEP 2000
Belgium: TWA = 0.2 mg/m 3 (fume), JAN 1993 Poland: MAC(TWA) fume = 0.1 mg/m3, In Argentina, Bulgaria, Colombia, Jordan,
Belgium: TWA = 1 mg/m3 (dust), JAN 1993 MAC(STEL) fume 0.3 mg/m3, JAN 1999 Korea, New Zealand, Singapore, Vietnam
Denmark: TWA = 0.1 mg/m3, JAN 1999 Poland: MAC(TWA) MAC(TWA) dust = 1 check ACGIH TLV
Finland: TWA = 0.2 mg/m3 (fume), JAN1 999 mg/m3, MAC(STEL) dust 2 mg/m 3, JAN LEAD:
Finland: TWA = 1 mg/m3 (dust), JAN 1999 1999 Austria: MAK 0.1 mg/m 3, JAN 1999
France: VME (fume) = 0.2 mg/m3, JAN 1999 Russia :STEL = 0.5 ppm (1 mg/m3) (dust), JAN Denmark: TWA = 0.1 mg/m 3, JAN 1999
France: VME (dust) = 1 mg/m3, JAN 1999 1993 Germany: MAK = 0.1 mg/m 3, JAN 1999
France: VME = 1 mg/m3, STEL 2 mg/m3 (dust), Sweden: NGV = 0.2 mg/m3 (resp. dust), JAN Japan: OEL = 0.1 mg/m 3, JAN 1999
JAN 1993 1999 Norway: TWA = 0.05 mg/m 3, JAN 1999
Germany: MAK = 0.1 mg/m3 (fume), JAN 1999 Sweden: NGV = 1 mg/m3 (total dust), JAN 1999 Poland: MAC(TWA) = 0.05 mg/m 3, JAN 1999
Germany: MAK = 1 mg/m3 (dust), JAN 1999 Switzerland: MAK-W = 0.1 mg/m3, KZG-W 0.2 Sweden: TWA = 0.05 mg/m 3 (resp. dust), JAN
Hungary: TWA = 0.2 mg/m3, STEL 0.4 mg/m3 mg/m3 (fume), JAN 1999 1999
(dust), JAN 1993 Switzerland: MAK-W = 1 mg/m3, KZG-W 1 Sweden: TWA = 0.1 mg/m 3 (total dust), JAN 1999
India: TWA = 0.2 mg/m3 (fume), JAN 1993 mg/m3, JAN 1999 Switzerland: MAK-W = 0.1 mg/m 3, JAN 1999
The Netherlands: MAC-TGG = 1 mg/m3 (dust), Thailand: TWA = 0.1 mg/m3 (fume), JAN 1993 ZINC:
JAN 1999 Thailand: TWA = 1 mg/m3, JAN 1993 ARAB Republic of Egypt: TWA = 0.1 mg/m3,
JAN 1993
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying
with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or
standards of EC member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection). Please
reference applicable regulations and standards for relevant details.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in Section 2
(Composition and Information on Ingredients) if applicable. If necessary, use only respiratory protection authorized in
the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards,
Canadian CSA Standard Z94.4-93, the European Standard EN149, or EC member states. Oxygen levels below 19.5%
are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full
facepiece, supplied air respirator with auxiliary self-contained air supply is required under U.S. Federal OSHA’s
Respiratory Protection Standard (1910.134-1998) or the regulations of various U.S. States, Canada, or EC Member
States. Air-purifying respirators with dust/mist/fume filters are recommended if operations may produce dusts from this
product. If use of this product results in the generation of dusts, the following NIOSH Respiratory Equipment
Guidelines may be applicable. The following are NIOSH respiratory protective equipment guidelines for Copper Dust,
Mists and Fume and Lead and are presented as the component of greatest percentage in the plates is Copper and
Lead is the toxic component.
COPPER (DUSTS & MISTS, METAL FUME)
CONCENTRATION RESPIRATORY PROTECTION
Up to 5 mg/m3: Any Dust and Mist Respirator.
Up to 10 mg/m3: Any Dust and Mist Respirator except single-use and quarter-mask respirators, or any Supplied-
Air Respirator (SAR).
Up to 25 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR)
with a dust and mist filter.
Up to 50 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR
with a tight-fitting facepiece and a high-efficiency particulate filter, or Self-Contained Breathing
Apparatus with a full facepiece, or any SAR with a full facepiece.
3
Up to 100 mg/m : Any SAR that has a full facepiece and is operated in a pressure-demand or other positive-
pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in
combination with an auxiliary SCBA operated in pressure-demand or other positive-pressure
mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any
appropriate escape-type, SCBA.

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8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION (continued): NIOSH Respiratory Guidelines (continued):
LEAD
CONCENTRATION RESPIRATORY PROTECTION
3
Up to 0.5 mg/m : Any Air-Purifying Respirator with a high-efficiency particulate filter, or any Supplied-Air
Respirator (SAR).
Up to 1.25 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator with a
high-efficiency particulate filter.
Up to 2.5 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any SAR
that has a tight-fitting facepiece and is operated in a continuous-flow mode, or any PAPR with a
tight-fitting facepiece and a high-efficiency particulate filter, or any Self-contained breathing
apparatus with a full facepiece, or any SAR with a full facepiece.
Up to 50 mg/m 3: Any SAR operated in a pressure-demand or other positive-pressure mode.
3
Up to 100 mg/m : Any SAR that has a full facepiece and is operated in a pressure-demand or other positive-
pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in
combination with an auxiliary SCBA operated in pressure-demand or other positive-pressure
mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any
appropriate escape-type, SCBA.
EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, and the
European Standard EN166.
HAND PROTECTION: Use mechanically-resistant gloves when handling this product. If necessary, refer to U.S. OSHA
29 CFR 1910.138, the appropriate Standards of Canada, or appropriate Standards of the EC.
BODY PROTECTION: Use body protection appropriate for task (e.g. lab coat, overalls). If necessary, refer to
appropriate Standards of Canada. If a hazard of injury to the feet exists due to falling objects, rolling objects, where
objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot
protection, as described in U.S. OSHA 29 CFR 1910.136.

9. PHYSICAL and CHEMICAL PROPERTIES

VAPOR DENSITY (air = 1): Not applicable. EVAPORATION RATE (n-BuAc=1): Not applicable.
SPECIFIC GRAVITY (water = 1): 8.75 MELTING POINT or RANGE: 1880"C (3416"F) [zinc]
SOLUBILITY IN WATER: Insoluble. BOILING POINT: Not applicable.
VAPOR PRESSURE, mm Hg @20"C: Not applicable. pH: Not applicable.
ODOR THRESHOLD (recognition): Not applicable.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable.
APPEARANCE AND COLOR: Flat metal plate.
HOW TO DETECT THIS SUBSTANCE (warning properties): The plate shape is characteristic.

10. STABILITY and REACTIVITY

STABILITY: Stable.
DECOMPOSITION PRODUCTS: Copper, lead and zinc oxides, other metal oxides, metal fumes.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids, strong caustics.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Fire, extremely high temperatures, contact with incompatible materials.

PART IV Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The specific toxicology data available for components greater than 1% in concentration are as
follows.
LEAD: LEAD (continued): LEAD (continued):
TDLo (Oral-Woman) 450 mg/kg/6 years: LDLo (Oral-Human) 155 mg/kg TCLo (Inhalation-Human) 0.011 mg/m 3/26 weeks-
Peripheral Nerve and Sensation: flaccid paralysis LCLo (Inhalation-Human) 271 mg/m 3 intermittent: Brain and Coverings: other
without anesthesia (usually neuromuscular TCLo (Inhalation-Human) 10 µg/m 3: degenerative changes
blockage); Behavioral: hallucinations, distorted Gastrointestinal: gastritis; Liver: other changes TCLo (Inhalation-Man) 0.03 mg/m 3/1 year-
perceptions, muscle weakness TCLo (Inhalation-Human) 9.9 mg/m 3/122 days- intermittent: Endocrine: changes in luteinizing
intermittent: Related to Chronic Data: death hormone; Biochemical: Metabolism (Intermediary):
porphyrin including bile pigments

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11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA (continued):
LEAD (continued): LEAD (continued): LEAD (continued):
TCLo (Inhalation-Man) 0.03 mg/m 3/5 years- TDLo (Oral-Mouse) 6879 mg/kg/5 weeks- LDLo (Oral-Pigeon) 160 mg/kg
intermittent: Endocrine: androgenic continuous: Blood: pigmented or nucleated red Cytogenetic Analysis (Unreported-Human) 50
TCLo (Inhalation-Man) 0.109 mg/m 3/5 years- blood cells, other changes, changes in other cell µg/m 3
intermittent: Reproductive: Paternal Effects: count (unspecified) Cytogenetic Analysis (Inhalation-Rat) 23 µg/m 3/16
spermatogenesis (incl. genetic material, sperm TDLo (Oral-Mouse) 1120 mg/kg: multi-generations: weeks
morphology, motility, and count) Reproductive: Effects on Embryo or Fetus: Cytogenetic Analysis (Oral-Monkey) 42 mg/kg/30
TCLo (Inhalation-Rat) 10 mg/m3/24 hours: female fetotoxicity (except death, e.g., stunted fetus), fetal weeks
1-21 day(s) after conception: Reproductive: death COPPER:
Effects on Embryo or Fetus: fetotoxicity (except TDLo (Oral-Mouse) 6300 mg/kg: female 1-21 LD50 (Intraperitoneal-Mouse) 3500 µg/kg
death, e.g., stunted fetus); Specific Developmental day(s) after conception: Reproductive: Fertility: TDLo (Oral-Human) 120 µg/kg: Gastrointestinal:
Abnormalities: blood and lymphatic systems female fertility index (e.g. # females pregnant per nausea or vomiting
(including spleen and marrow) # sperm positive females; # females pregnant per TDLo (Oral-Rat) 152 mg/kg: female 22 week(s)
TCLo (Inhalation-Rat) 3 mg/m 3/24 hours: female 1- # females mated), pre-implantation mortality (e.g. pre-mating: Reproductive: Effects on Embryo or
21 day(s) after conception: Reproductive: Effects reduction in number of implants per female; total Fetus: fetotoxicity (except death, e.g., stunted
on Newborn: biochemical and metabolic number of implants per corpora lutea) fetus); Specific Developmental Abnormalities:
TCLo (Inhalation-Guinea Pig) 20 mg/m 3/6 hours/30 TDLo (Oral-Mouse) 300 mg/kg: female 1-2 day(s) Central Nervous System
days-intermittent: Immunological Including after conception: Reproductive: Fertility: other TDLo (Oral-Rat) 1520 µg/kg: female 22 week(s)
Allergic: uncharacterized measures of fertility pre-mating: Reproductive: Specific
TCLo (Inhalation-Guinea Pig) 200 µg/m 3/6 hours/26 TDLo (Oral-Mouse) 4800 mg/kg: female 1-16 Developmental Abnormalities: musculoskeletal
weeks-intermittent: Immunological Including day(s) after conception: Reproductive: Effects on system
Allergic: uncharacterized Embryo or Fetus: cytological changes (including TDLo (Oral-Rat) 1210 µg/kg: female 35 week(s)
TDLo (Oral-Rat) 1050 µg/kg/30 weeks-intermittent: somatic cell genetic material) pre-mating: Reproductive: Fertility: pre-
Brain and Coverings: other degenerative changes; TDLo (Oral-Mouse) 4099.2 mg/kg: male 56 day(s) implantation mortality (e.g. reduction in number of
Behavioral: alteration of classical conditioning; pre-mating: Reproductive: Paternal Effects: implants per female; total number of implants per
Nutritional and Gross Metabolic: changes in testes, epididymis, sperm duct, other effects on corpora lutea), post-implantation mortality (e.g.
metals, not otherwise specified male dead and/or resorbed implants per total number of
TDLo (Oral-Rat) 790 mg/kg: multi-generations: TDLo (Oral-Mammal-domestic) 662 mg/kg: female implants)
Reproductive: Effects on Embryo or Fetus: 1-21 week(s) after conception: Reproductive: TDLo (Oral-Rabbit) 3 gm/kg/60 days-continuous:
fetotoxicity (except death, e.g., stunted fetus), fetal Effects on Newborn: behavioral Cardiac: other changes; Liver: hepatitis
death TDLo (Oral-Mammal-domestic) 814 mg/kg: female (hepatocellular necrosis), zonal; Related to
TDLo (Oral-Rat) 1140 mg/kg: female 14 day(s) 5 week(s) pre-mating female 1-21 week(s) after Chronic Data: death
pre-mating-21 day(s) post-birth: Reproductive: conception: Reproductive: Effects on Newborn: TDLo (Intravenous-Rabbit) 75 mg/kg/2 days-
Effects on Newborn: behavioral behavioral intermittent: Liver :other changes; Related to
TDLo (Oral-Rat) 520 mg/kg: female 7-22 day(s) TDLo (Oral-Mammal-species unspecified) 2118 Chronic Data: death
after conception lactating female 10 day(s) post- mg/kg: lactating female 15 day(s) post-birth: TDLo (Intrapleural-Rat) 100 mg/kg: Tumorigenic:
birth: Reproductive: Effects on Newborn: Reproductive: Effects on Embryo or Fetus: equivocal tumorigenic agent by RTECS criteria;
biochemical and metabolic fetotoxicity (except death, e.g., stunted fetus), fetal Lungs, Thorax, or Respiration: fibrosis, focal
TDLo (Oral-Rat) 1100 mg/kg: female 1-22 day(s) death (pneumoconiosis), tumors
after conception: Reproductive: Specific TDLo (Oral-Non-mammalian species) 582 LDLo (Subcutaneous-Rabbit) 375 mg/kg: Liver:
Developmental Abnormalities: blood and mg/kg/30 days-continuous: Endocrine: hepatitis (hepatocellular necrosis), zonal; Liver:
lymphatic systems (including spleen and androgenic, estrogenic; Related to Chronic Data: other changes; Kidney, Ureter, Bladder: other
marrow); Effects on Newborn: growth statistics changes in ovarian weight changes
(e.g.%, reduced weight gain) TDLo (Unreported-Rat) 0.012 mg/kg/10 days- TDLo (Intrauterine-Rat) 250 µg/kg: female 1 day(s)
TDLo (Oral-Rat) 93.6 mg/kg/30 days-continuous: intermittent: Reproductive: Paternal Effects: pre-mating: Reproductive: Maternal Effects:
Kidney, Ureter, Bladder: other changes; Blood: spermatogenesis (incl. genetic material, sperm uterus, cervix, vagina; Fertility: female fertility
other changes; Biochemical: Enzyme inhibition, morphology, motility, and count), testes, index (e.g. # females pregnant per # sperm
induction, or change in blood or tissue levels: epididymis, sperm duct positive females; # females pregnant per #
other Enzymes TDLo (Unreported-Rat) 0.012 mg/kg/10 days- females mated)
TDLo (Oral-Mouse) 4099.2 mg/kg/8 weeks- intermittent: Endocrine: effect on menstrual cycle; ZINC:
intermittent: Endocrine: changes in endocrine Reproductive: Maternal Effects: ovaries, fallopian Standard Draize Test (Skin-Human) 300 µg/3days-
weight (unspecified) tubes intermittent: Mild
TDLo (Oral-Mouse) 10,248 mg/kg/20 weeks- TDLo (Unreported-Horse, Donkey) 120 TCLo (Inhalation-Human) 124 mg/m 3/50 minutes:
intermittent: Endocrine: other changes; mg/kg/days-intermittent: Peripheral Nerve and Lungs, Thorax, or Respiration: cough, dyspnea;
Biochemical: Enzyme inhibition, induction, or Sensation - flaccid paralysis without anesthesia Skin and Appendages: sweating
change in blood or tissue levels: other Enzymes (usually neuromuscular blockage); Lungs, LDLo (Oral-Duck) 388 mg/kg: Autonomic Nervous
Thorax, or Respiration: respiratory depression; System: other (direct) para-sympathomimetic;
Related to Chronic Data: death Behavioral: ataxia; Blood: changes in leukocyte
LDLo (Intraperitoneal-Rat) 1 gm/kg (WBC) count
SUSPECTED CANCER AGENT: The components of this product are listed by agencies tracking the carcinogenic
potential of chemical compounds, as follows:
COPPER: EPA-D (Not Classifiable as to Human Carcinogenicity)
LEAD: ACGIH-TLV-A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans); EPA-B2 (Probable Human Carcinogen-Sufficient Evidence from
Animal Studies; Inadequate Evidence or no Data from Epidemiologic Studies); IARC-2B (Possibly Carcinogenic to Humans); MAK-3B (Substances for Which in
vitro tests or Animal Studies Have Yielded Evidence of Carcinogenic Effects that is Not Sufficient for Classification of the Substance in One of the Other
Categories. Further Studies are Required Before a Final Classification Can Be Made.)
ZINC: EPA-D (Not Classifiable as to Human Carcinogenicity)
The other components of this product are not found on the following lists: FEDERAL, OSHA Z LIST, NTP, IARC and
CAL/OSHA and therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies.

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11. TOXICOLOGICAL INFORMATION (Continued)
IRRITANCY OF PRODUCT: Fumes or dusts from this product may be irritating to contaminated skin, eyes and
respiratory system.
SENSITIZATION TO THE PRODUCT: Repeated contact with the Photoresist may result in skin sensitization reaction
(e.g. dermatitis, skin rash) in susceptible individuals. Rare cases of allergic contact dermatitis have been reported in
people working with copper dust.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and
their components on the human reproductive system.
Mutagenicity: Lead is considered mutagenic, based on positive results obtained in tests using somatic and germ
cells of animals exposed by relevant routes of exposure. Several studies have reported positive results
(chromosomal aberrations) in the white blood cells of workers with low to moderate inorganic Lead exposure. Other
studies have shown no increase in chromosomal aberrations in workers with similar exposures.
Embryotoxicity: Inorganic Lead exposure during pregnancy has historically been associated with significant harmful
effects on pregnancy, including increased miscarriages and stillbirths. Many of these historical reports involved
exposure to very high levels of Lead, as well as other environmental, social and lifestyle characteristics which may
have caused or contributed to the observed effects. Lead exposure which has not also caused significant toxicity in
the mother has not been clearly associated with teratogenic or embryotoxic effects. Several non-occupational
studies indicate that low to moderate exposure to Lead during pregnancy and in early childhood, can produce
harmful effects on neuro-behavioral development and IQ, a measure of intelligence. Reduced birth weight and
shorter pregnancy may also be related to low level lead exposure. However, this literature is inconsistent and no
firm conclusions can be drawn. There is no relevant animal information available for elemental Lead.
Teratogenicity: Components of this product are not reported to cause teratogenic effects in humans. Studies on
test animals exposed to relatively high doses of the Copper and Lead components of this product indicate adverse
teratogenic effects.
Reproductive Toxicity: Significant harmful effects have been reported in the male reproductive system following low
to moderate Lead exposures. Harmful effects on the female reproductive system have not been clearly
demonstrated following low to moderate inorganic Lead exposure. Harmful reproductive effects have been reported
in both men and women following high level exposures. Studies on test animals exposed to relatively high doses of
the Copper component of this product indicate adverse reproductive effects.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will
propagate through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within
the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines.
A reproductive toxin is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: There are Biological Exposure Indices (BEIs) determined for the Lead component
of this product, as follows.
CHEMICAL DETERMINANT SAMPLING TIME BEI
LEAD
! Lead in blood ! Not critical ! 30 µg/100 mL

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL STABILITY: The components of this product are metals and resins and are expected to persist in
the environment for an extended period of time. The components will react with water and air to form a variety of metal
oxide compounds. The following environmental data are available for the components of this product.
COPPER:
Terrestrial Fate: The fate of Copper with respect to its leachability in purely organic spruce forest soils was studied. Appreciable mobilization of
Copper occurred only with prolonged leaching at pH 2.8. Therefore, it does not appear likely that acidic rainfall will result in significant mobilization
of Copper from organic soils unless the pH of rainfall decreases to < 3. Estimated that approx 50% of Copper in the top few centimeters of these
soils was organically bound, approx 18% was in the hydroxy carbonate form, approx 7% was in the adsorbed state, approximately 11% was
bound by other anions and 6% was irreversibly adsorbed. Only 3% of the Copper was extractable with water at pH 4.5; hence only 3% was
mobile at this pH. In urbanized areas the effects of land clearing, profile disruption and increased acid rainfall may increase copper mobilization in
these soils.
LEAD: Insoluble in water. Biological Half-Life for lead in bones of humans is 10 years. Lead was absorbed (by fresh water filed crab) through the gills, and
distributed to the haenolymph to hepatopancrease, muscle, and exoskeleton. Lead bioaccumlated over the course of the study showed a high degree of organ
specificity.
ZINC: Insoluble in water. Biological Half-Life for humans 162-500 days. The Bioconcentration Factor in edible portions of Crassostrea virgina, adult oyster) is
16,700 (total zinc).
EFFECT OF MATERIAL ON PLANTS or ANIMALS: The metal components of this product occur naturally in the.
Under normal circumstances, this product is not expected to cause adverse effects on plant or animal life.

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12. ECOLOGICAL INFORMATION (Continued)
EFFECT OF CHEMICAL ON AQUATIC LIFE: Under normal circumstances, this product is not expected to cause
adverse effects on aquatic life. Low chronic aquatic limits indicate a high chronic hazard, it may be concentrated to toxic
levels in food chain. The following aquatic toxicity data are available for the components:
COPPER: ZINC: Zinc poisoning causes inflamed gills in fish. Laboratory studies of
LC50(fathead minnows) = 0.14 ppm in hard water Atlantic salmon, rainbow trout, carp, and goldfish have shown avoidance
LC50(bluegill) = 0.02 ppm in soft water reactions by these fish to zinc in water. The sensitivity of fish to zinc varies
LC50(brook trout) = 0.09 ppm in soft water with species, age, and the condition of fish, as well as they characteristics of
LEAD: the water. Some acclimatization to the presence of zinc is possible, and
LC50 (Japanese quail) =, males, females, 14 days old, oral (5-day ad libitum in survivors from batches of fish exposed to dissolved zinc are less
diet) = 5,000 ppm. At 1,000, 2236, and 5000 ppm onset of toxic symptoms susceptible to additional toxic concentrations than fish not previously
began at 7 days and remissed at 11-12 days exposed. It has also been observed that the effects of zinc poisoning may
Concentration for fresh and salt water fish, o,1 not become apparent immediately, so that fish removed from zinc-
Lobster die with 20 days when kept in lead-lined tanks. contaminated to zinc-free water (after 4-6 hour exposure) may die within 48
LC50 (brook tout) = 0.13 ppm hours.
LC50 (rainbow trout) = 0.43 ppm

13. DISPOSAL CONSIDERATIONS

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State,
and local regulations, or those of Canada and its Provinces. This product, if unaltered by use, may be disposed of by
treatment at a permitted facility or as advised by your local solid waste regulatory authority.
EPA WASTE NUMBER: Waste of this product should be analyzed for Toxicity Characteristic Leaching Procedure
chemicals, as follows: D008 (Lead), Regulated Level: 5.0 mg/L.
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Not Regulated
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable
UN IDENTIFICATION NUMBER: Not Applicable
PACKING GROUP: Not Applicable
DOT LABEL(S) REQUIRED: Not Applicable
EMERGENCY RESPONSE GUIDE NUMBER: Not Applicable
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: Not applicable.
MARINE POLLUTANT: No component of this product is designated as a marine pollutant by the Department of
Transportation (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not
considered as Dangerous Goods.
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is not considered
as dangerous goods, per rules of IATA.
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is not considered as
dangerous goods, per rules of the International Maritime Organization.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This product is not considered by the Economic Commission for Europe to be dangerous goods.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements
of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Copper (fume or dust) No No Yes
Lead No No Yes
Zinc (fume or dust) No No Yes
U.S. SARA THRESHOLD PLANNING QUANTITY: Not applicable.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Copper = 5000 lb (2270); Lead = 10 lb (4.54 kg).; Zinc = 1,000 lb (454
kg); (for metal particles under 100 micrometers in diameter).
U.S. TSCA INVENTORY STATUS: All components of this product are on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: If necessary for large-scale operations in which excessive airborne dusts are
generated, refer to the OSHA Lead Standard (29 CFR 1910.1025).

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15. REGULATORY INFORMATION (Continued)
ADDITIONAL U.S. REGULATIONS (continued):
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The Lead component
of this product is on the California Proposition 65 Lists. Toluene is present in the photoresist. Toluene is listed on the
California Proposition 65 Lists. WARNING: This product contains a chemical known to the State of California to cause
cancer, birth defects or other reproductive harm.
LABELING: CAUTION! PARTICULATES GENERATED FROM THIS PRODUCT MAY CAUSE SKIN AND EYE
IRRITATION. PROLONGED SKIN CONTACT WITH DUSTS MAY CAUSE ALLERGIC SKIN REACTIONS. Do not get
particulates on skin or in eyes. Avoid prolonged skin contact. Avoid breathing dust or particulates generated by this
product. Wear gloves and goggles, as appropriate. FIRST-AID: In case of contact, immediately flush skin or eyes with
plenty of water if irritation occurs. If dusts are inhaled, remove to fresh air. If particulates are ingested, do not induce
vomiting. Get medical attention if any adverse effect occurs. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or
“alcohol” foam. IN CASE OF SPILL: Pick-up or sweep-up product. Place in a suitable container and seal. Consult
Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS: CLASS D2B: Materials Causing Other Toxic Effects (for
Photoresist Layer)

EUROPEAN ECONOMIC COMMUNITY INFORMATION:

EUROPEAN ECONOMIC COMMUNITY INFORMATION FOR PRODUCT:
EC LABELING AND CLASSIFICATION: This product does not meet the definition of any hazard class as defined by
the European Economic Community Guidelines.
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOLS: Not applicable.
EUROPEAN ECONOMIC COMMUNITY INFORMATION FOR CONSTITUENTS: The following information is available for
primary constituents in the components of this product.
Copper:
An official classification for this substance has not been published in Commission Directives 93/72/EEC or 94/69EC.
Lead:
An official classification for this substance has not been published in Commission Directives 93/72/EEC or 94/69EC.
Zinc:
NOTE: This constituent is present as part of a solid metal alloy. The information provided below pertains to Zinc in powder form
only.
EC CLASSIFICATION: Highly Flammable [F; R10]
EC RISK PHRASES: Flammable. Contact with water liberates extremely flammable gases. [R: 10!15]
EC SAFETY PHRASES : Keep out of the reach of children. (This safety phrase can be omitted from the label when the substance
or preparation is sold for industrial use only). Keep container tightly closed and dry. In case of fire, use appropriate fire
extinguishing media. [S: (2-) *7/8!43]

16. OTHER INFORMATION

PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
619/670-0609
DATE OF PRINTING: January 13, 2005
Although the information set forth herein is presented in good faith and believed to be correct as of the date of issuance, it has been furnished by our suppliers;
consequently, Revere Graphic Products, Inc. makes no representations or warranties, express or implied, with respect to information herein presented. The information
set forth herein is supplied upon the condition that the persons receiving same will make their own determination as to suitability for their purposes prior to use and relates
only to the specific product described and not to such product in combination with any other product. In no event will Revere Graphic Products, Inc. be responsible for
damages of any nature resulting from the use of or reliance upon this information.

DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies EXPOSURE LIMITS IN AIR (continued):
each constituent. NE: Not Established. When no exposure guidelines are established, an entry of
EXPOSURE LIMITS IN AIR: NE is made for reference.
CEILING LEVEL: The concentration that shall not be exceeded during any part NIC: Notice of Intended Change.
of the working exposure. NIOSH CEILING: The exposure that shall not be exceeded during any part of the
LOQ: Limit of Quantitation. workday. If instantaneous monitoring is not feasible, the ceiling shall be
MAK: Federal Republic of Germany Maximum Concentration Values in the assumed as a 15-minute TWA exposure (unless otherwise specified) that shall
workplace. not be exceeded at any time during a workday.

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DEFINITIONS OF TERMS (Continued)
EXPOSURE LIMITS IN AIR (continued): HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
NIOSH RELs: NIOSH’s Recommended Exposure Limits. RATINGS (continued):
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits. FLAMMABILITY HAZARD (continued)
This exposure value means exactly the same as a TLV, except that it is 1 (continued): Including: Materials that will burn in air when exposed to a
enforceable by OSHA. temperature of 815.5"C (1500"F) for a period of 5 minutes or less; Liquids, solids
PEL-Permissible Exposure Limit (continued): The OSHA Permissible and semisolids having a flash point at or above 93.3"C [200"F] (e.g. OSHA Class
Exposure Limits are based in the 1989 PELs and the June, 1993 Air IIIB, or; Most ordinary combustible materials [e.g. wood, paper, etc.]; 2
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the (Moderate Hazard-Materials that must be moderately heated or exposed to
current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 relatively high ambient temperatures before ignition can occur. Materials in this
PEL,” is placed next to the PEL that was vacated by Court Order. degree would not, under normal conditions, form hazardous atmospheres in air,
SKIN: Used when a there is a danger of cutaneous absorption. but under high ambient temperatures or moderate heating may release vapor in
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15- sufficient quantities to produce hazardous atmospheres in air, Including: Liquids
minute time-weighted average (TWA) exposure that should not be exceeded at having a flash-point at or above 37.8"C [100"F] Solid materials in the form of
any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL- course dusts that may burn rapidly but that generally do not form explosive
TWA or REL-TWA. atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly
TLV-Threshold Limit Value: An airborne concentration of a substance that and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that
represents conditions under which it is generally believed that nearly all workers readily give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that
may be repeatedly exposed without adverse effect. The duration must be can be ignited under almost all ambient temperature conditions. Materials in this
considered, including the 8-hour. degree produce hazardous atmospheres with air under almost all ambient
TWA-Time Weighted Average: Time Weighted Average exposure temperatures, or, unaffected by ambient temperature, are readily ignited under
concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday almost all conditions, including: Liquids having a flash point below 22.8"C [73"F]
and a 40-hr workweek.IDLH-Immediately Dangerous to Life and Health: and having a boiling point at or above 38"C [100"F] and below 37.8"C [100"F]
This level represents a concentration from which one can escape within 30- [e.g. OSHA Class IB and IC]; Materials that on account of their physical form or
minutes without suffering escape-preventing or permanent injury. environmental conditions can form explosive mixtures with air and are readily
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable
RATINGS: This rating system was developed by the National Paint and liquids]; Materials that burn extremely rapidly, usually by reason of self-
Coating Association and has been adopted by industry to identify the degree of contained oxygen [e.g. dry nitrocellulose and many organic peroxides]);4 (Severe
chemical hazards. Hazard-Materials that will rapidly or completely vaporize at atmospheric
HEALTH HAZARD: pressure and normal ambient temperature or that are readily dispersed in air,
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not and which will burn readily, including: Flammable gases; Flammable cryogenic
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”. Eye materials; Any liquid or gaseous material that is liquid while under pressure and
Irritation: Essentially non-irritating, or minimal effects which clear in < 24 hours has a flash point below 22.8"C [73"F] and a boiling point below 37.8"C [100"F]
[e.g. mechanical irritation]. Draize = “0”. Oral Toxicity LD50 Rat: < 5000 mg/kg. [e.g. OSHA Class IA; Material that ignite spontaneously when exposed to air at a
Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation Toxicity 4-hrs temperature of 54.4"C [130"F] or below [e.g. pyrophoric]).
LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury may occur; PHYSICAL HAZARD:
slightly or mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye 0 (Water Reactivity: Materials that do not react with water. Organic Peroxides:
Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: > 500-5000 mg/kg. Materials that are normally stable, even under fire conditions and will not react
Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg. Inhalation Toxicity with water. Explosives: Substances that are Non-Explosive. Unstable
LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard: Temporary or transitory Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No “0”
injury may occur. Skin Irritation: Moderately irritating; primary irritant; rating allowed. Unstable Reactives: Substances that will not polymerize,
sensitizer. PII or Draize > 0, < 5. Eye Irritation: Moderately to severely irritating decompose, condense or self-react.); 1 (Water Reactivity: Materials that change
and/or corrosive; reversible corneal opacity; corneal involvement or irritation or decompose upon exposure to moisture. Organic Peroxides: Materials that
clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50-500 are normally stable, but can become unstable at high temperatures and
mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation pressures. These materials may react with water, but will not release energy.
Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 2 (Moderate Hazard: Temporary or Explosives: Division 1.5 & 1.6 substances that are very insensitive explosives or
transitory injury may occur. Skin Irritation: Moderately irritating; primary that do not have a mass explosion hazard. Compressed Gases: Pressure
irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation: Moderately to severely below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging Group
irritating and/or corrosive; reversible corneal opacity; corneal involvement or III; Solids: any material that in either concentration tested, exhibits a mean
irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50- burning time less than or equal to the mean burning time of a 3:7 potassium
500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation bromate/cellulose mixture and the criteria for Packing Group I and II are not met.
Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3 (Serious Hazard: Major injury likely Liquids: any material that exhibits a mean pressure rise time less than or equal
unless prompt action is taken and medical treatment is given; high level of to the pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the
toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may criteria for Packing Group I and II are not met. Unstable Reactives: Substances
destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize > 5-8 that may decompose, condense or self-react, but only under conditions of high
with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of temperature and/or pressure and have little or no potential to cause significant
ocular tissue; corneal involvement or irritation persisting for more than 21 days. heat generation or explosive hazard. Substances that readily undergo hazardous
Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 polymerization in the absence of inhibitors.); 2 (Water Reactivity: Materials that
mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity may react violently with water. Organic Peroxides: Materials that, in
LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or themselves, are normally unstable and will readily undergo violent chemical
permanent damage may result from single or repeated exposure. Skin Irritation: change, but will not detonate. These materials may also react violently with
Not appropriate. Do not rate as a “4”, based on skin irritation alone. Eye water. Explosives: Division 1.4 – Explosive substances where the explosive
Irritation: Not appropriate. Do not rate as a “4”, based on eye irritation alone. effect are largely confined to the package and no projection of fragments of
Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 20 appreciable size or range are expected. An external fire must not cause virtually
mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L). instantaneous explosion of almost the entire contents of the package.
Compressed Gases: Pressurized and meet OSHA definition but < 514.7 psi
FLAMMABILITY HAZARD:
absolute at 21.1"C (70"F) [500 psig]. Pyrophorics: No Rating. Oxidizers:
0 (Minimal Hazard-Materials that will not burn in air when exposure to a Packing Group II Solids: any material that, either in concentration tested, exhibits
temperature of 815.5"C [1500"F] for a period of 5 minutes.); 1 (Slight Hazard-
a mean burning time of less than or equal to the mean burning time of a 2:3
Materials that must be pre-heated before ignition can occur. Material require
potassium bromate/cellulose mixture and the criteria for Packing Group I are not
considerable pre-heating, under all ambient temperature conditions before
met
ignition and combustion can occur,

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DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
RATINGS (continued): RATINGS (continued):
PHYSICAL HAZARD (continued): INSTABILITY HAZARD: 0 Materials that in themselves are normally
3 (continued): . Liquids: any material that exhibits a mean pressure rise time stable, even under fire conditions. 1 Materials that in themselves are
less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution normally stable, but that can become unstable at elevated temperatures
(40%)/cellulose mixture and the criteria for Packing Group I are not met. and pressures. 2 Materials that readily undergo violent chemical change
Unstable Reactives: Substances that may polymerize, decompose, condense, at elevated temperatures and pressures. 3 Materials that in themselves
or self-react at ambient temperature and/or pressure, but have a low potential for are capable of detonation or explosive decomposition or explosive
significant heat generation or explosion. Substances that readily form peroxides reaction, but that require a strong initiating source or that must be heated
upon exposure to air or oxygen at room temperature); 3 (Water Reactivity: under confinement before initiation. 4 Materials that in themselves are
Materials that may form explosive reactions with water. Organic Peroxides: readily capable of detonation or explosive decomposition or explosive
Materials that are capable of detonation or explosive reaction, but require a reaction at normal temperatures and pressures.
strong initiating source, or must be heated under confinement before initiation; or FLAMMABILITY LIMITS IN AIR: Much of the information related to fire
materials that react explosively with water. Explosives: Division 1.2 – Explosive and explosion is derived from the National Fire Protection Association (NFPA).
substances that have a fire hazard and either a minor blast hazard or a minor Flash Point - Minimum temperature at which a liquid gives off sufficient vapors
projection hazard or both, but do not have a mass explosion hazard. to form an ignitable mixture with air. Autoignition Temperature: The minimum
Compressed Gases: Pressure > 514.7 psi absolute at 21.1"C (70"F) [500 psig]. temperature required to initiate combustion in air with no other source of ignition.
Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any material that, LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in
in either concentration tested, exhibits a mean burning time less than the mean the presence of an ignition source. UEL - the highest percent of vapor in air, by
burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids: Any volume, that will explode or ignite in the presence of an ignition source.
material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or TOXICOLOGICAL INFORMATION:
which exhibits a mean pressure rise time less than the pressure rise time of a Human and Animal Toxicology: Possible health hazards as derived from
1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances human data, animal studies, or from the results of studies with similar
that may polymerize, decompose, condense or self-react at ambient compounds are presented. Definitions of some terms used in this section are:
temperature and/or pressure and have a moderate potential to cause significant LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals;
heat generation or explosion.); 4 (Water Reactivity: Materials that react LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals;
explosively with water without requiring heat or confinement. Organic ppm concentration expressed in parts of material per million parts of air or
Peroxides: Materials that are readily capable of detonation or explosive water; mg/m3 concentration expressed in weight of substance per volume of air;
decomposition at normal temperature and pressures. Explosives: Division 1.1 mg/kg quantity of material, by weight, administered to a test subject, based on
& 1.2-explosive substances that have a mass explosion hazard or have a their body weight in kg. Other measures of toxicity include TDLo, the lowest
projection hazard. A mass explosion is one that affects almost the entire load dose to cause a symptom and TCLo the lowest concentration to cause a
instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose
definition of Flammability “4”. Oxidizers: No “4” rating. Unstable Reactives: (or concentration) to cause lethal or toxic effects. Cancer Information: The
Substances that may polymerize, decompose, condense or self-react at ambient sources are: IARC - the International Agency for Research on Cancer; NTP -
temperature and/or pressure and have a high potential to cause significant heat the National Toxicology Program, RTECS - the Registry of Toxic Effects of
generation or explosion.). Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD on a scale of decreasing potential to cause human cancer with rankings from 1 to
RATINGS: 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH
HEALTH HAZARD: 0 (material that on exposure under fire conditions would Biological Exposure Indices, represent the levels of determinants which are most
offer no hazard beyond that of ordinary combustible materials); 1 (materials that likely to be observed in specimens collected from a healthy worker who has
on exposure under fire conditions could cause irritation or minor residual injury); been exposed to chemicals to the same extent as a worker with inhalation
2 (materials that on intense or continued exposure under fire conditions could exposure to the TLV.
cause temporary incapacitation or possible residual injury); 3 (materials that can ECOLOGICAL INFORMATION:
on short exposure could cause serious temporary or residual injury); 4 EC is the effect concentration in water. BCF = Bioconcentration Factor, which is
(materials that under very short exposure could cause death or major residual used to determine if a substance will concentrate in lifeforms which consume
injury). contaminated plant or animal matter. TLm = median threshold limit; Coefficient
FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire of Oil/Water Distribution is represented by log Kow or log K oc and is used
conditions, including intrinsically noncombustible materials such as to assess a substance’s behavior in the environment.
concrete, stone, and sand. 1 Materials that must be preheated before REGULATORY INFORMATION:
ignition can occur. Materials in this degree require considerable U.S. and CANADA:
preheating, under all ambient temperature conditions, before ignition and This section explains the impact of various laws and regulations on the material.
combustion can occur 2 Materials that must be moderately heated or ACGIH: American Conference of Governmental Industrial Hygienists, a
exposed to relatively high ambient temperatures before ignition can occur. professional association which establishes exposure limits. EPA is the U.S.
Materials in this degree would not under normal conditions form Environmental Protection Agency. NIOSH is the National Institute of
hazardous atmospheres with air, but under high ambient temperatures or Occupational Safety and Health, which is the research arm of the U.S.
under moderate heating could release vapor in sufficient quantities to Occupational Safety and Health Administration (OSHA). WHMIS is the
produce hazardous atmospheres with air. 3 Liquids and solids that can Canadian Workplace Hazardous Materials Information System. DOT and TC
be ignited under almost all ambient temperature conditions. Materials in are the U.S. Department of Transportation and the Transport Canada,
this degree produce hazardous atmospheres with air under almost all respectively. Superfund Amendments and Reauthorization Act (SARA); the
ambient temperatures or, though unaffected by ambient temperatures, are Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S.
readily ignited under almost all conditions. 4 Materials that will rapidly or Toxic Substance Control Act (TSCA); Marine Pollutant status according to the
completely vaporize at atmospheric pressure and normal ambient DOT; the Comprehensive Environmental Response, Compensation, and
temperature or that are readily dispersed in air and will burn readily. Liability Act (CERCLA or Superfund); and various state regulations. This
section also includes information on the precautionary warnings which appear on
the material’s package label. OSHA - U.S. Occupational Safety and Health
Administration.

BRASS MSDS
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