1

TAMIL NADU PUBLIC SERVICE

COMMISSION
Advertisement No.485
Notification No: 28/2017 Dated :24.11.2017
Applications are invited only through online mode upto 20.12.2017 for Direct Recruitment to the
following posts:-

It is mandatory for the applicants to register their basic particulars through One Time online
Registration system on payment of Rs.150/- (Rupees One Hundred and Fifty only) towards
registration fee and then should apply online for this recruitment. (The One Time Registration will
be valid for 5 years from the date of registration. Thereafter, the registration should be renewed by
paying the prescribed fee.)

Sl. Name of the Post Name of the Number of Scale of pay

No. and Code No. Service and vacancies
Code No.
1. Junior Analyst in the Drugs
Tamil Nadu Medical Rs.9,300-34,800/-
Testing Laboratory
Subordinate Service 14 (PB2) + 4,600/- G.P
2015 – 2016, 2016 - 2017
(Code No.049) Pre-revised
(Code No. 2006)
2. Junior Chemist in Industries
and Commerce Department Rs.9,300-34,800/-
6
2013 – 2014, 2015 - 2016 Tamil Nadu (PB2) + 4,400/- G.P
(Code No. 1914) Industries Pre-revised
3. Chemist in Industries and Subordinate Service
Commerce Department (Code No. 044) Rs.9,300-34,800/-
3 (PB2) + 5,100/-G.P
2015 - 2016
(Code No. 1913) Pre-revised
4. Archaeological Chemist in Tamil Nadu General Rs.15,600-39,100/-
Archaeology Department Subordinate Service 1 (PB2) + 5,400/-G.P
2015 – 2016 (Code No.1844) (Code No.036) Pre-revised

2. DISTRIBUTION OF VACANCIES
SC(A) (PSTM)
MBC/DC(W)
MBC/DC(G)
GT (PSTM)

Name of the Post Total

BC (G)
GT (G)

SC (G)
BC(W)
GT(W)

SC(W)

Junior Analyst 3 1 1 2 1 3 - 1 1 1 14
Junior Chemist 1 - 1 1 1 - 1 1 - - 6
Chemist 1 - - - 1 - 1 - - - 3
Archaeological
1 - - - - - - - - - 1
Chemist

Abbreviation:- GT- General Turn - G- General, W - Women; PSTM - Persons Studied in Tamil Medium;
BC - Backward Class (Other than Muslim); MBC/DC - Most Backward Class / Denotified Community;
SC – Scheduled Caste; SC (A) – Scheduled caste (Arunthathiyar)
 2

3. IMPORTANT DATES AND TIME

Date of Notification 24.11.2017
Last date for submission of application 20.12.2017
Last date for payment of Fee through Bank
22.12.2017
(State Bank of India or Indian Bank)

Date of Written Examination

Paper – I (Subject Paper) (Degree Standard) 17.02.2018 FN 10.00 A.M. to 01.00 P.M
Paper – II (General Studies) 17.02.2018 AN 02.30 P.M. to 04.30 P.M
Paper – I (Subject Paper) (PG Degree Standard) 18.02.2018 FN 10.00 A.M. to 01.00 P.M

4. FEES
a) Registration Fee

For One Time Registration (Revised with effect from 01.03.2017 vide Rs.150/-
G.O.(Ms).No.32, Personnel and Administrative Reforms Department,
dated 01.03.2017)

Note
Applicants who have already registered in one time Registration system
paying Rs.50/- before 01.03.2017 and those who have registered for
One-Time Registration on or after 01.03.2017 by paying Rs.150/- are
exempted from paying the registration fee for this recruitment

b) Examination Fee
Note
Rs.150/-
The Examination fee should be paid at the time of submitting the online
application for this recruitment if they are not eligible for the fee
concession noted below :-

EXAMINATION FEE CONCESSION

Category Concession Condition
(i) Scheduled Castes /
Scheduled Caste --
Full Exemption
(Arunthathiyars),
Scheduled Tribes.
(ii) Differently Abled (i) For Differently Abled persons,
Persons, Destitute the disability should be not
Widow of all less than 40%.
communities. Full Exemption (ii) For DWs, the DW certificate
should have been obtained
from the RDO / Sub Collector/
Assistant Collector
(iii) Most Backward Those who have not availed Should not have availed three free
Class / Denotified three free chances so far in the chances in the previous
Communities, previous recruitments may avail recruitments.
Backward Classes exemption from payment of
(Other than Muslim) examination fee.
Backward Class
(Muslim).
 3

(iv) Ex-Servicemen Those who have not availed two (i) Should not have availed two
free chances so far in the free chances in the previous
previous recruitments may avail recruitments.
exemption from payment of (ii) Fee concession will not apply
examination fee. to those who have already
been recruited to any class or
service or category.

Note
(i) The three / two free chances referred to above are not for EACH POST but for ANY THREE /
TWO APPLICATIONS ONLY. The claim for exemption from payment of examination fee
made in any application which is rejected / admitted or withdrawn will be counted as a free
chance availed.
(ii) Failure to pay the prescribed fee along with the application in-time will be liable for rejection of
application.
(iii) The number of free chances availed by the applicant means the total number of free chances
hitherto availed by the applicant in his / her earlier application submitted to the Commission for
any post / recruitment.
(iv) If the examination fee concession claimed in the applications is found to exceed the
admissible limits as announced above, the application will be rejected at any stage of
selection. The number of free chances availed by the applicants will be counted from the
previous applications submitted through One Time Registration and / or submitted directly
without One-Time Registration i.e., before One Time Registration was made as mandatory.

5. MODE OF PAYMENT OF EXAMINATION FEE

 Examination fee Rs.150/- (Rupees One Hundred and Fifty only) is payable online through
Net banking / Credit card / Debit card or it can be paid offline at SBI / Indian Bank within 2
days from the date of submission of online application, by choosing the option in the online
application.
 Applicants have to register their basic particulars through One Time Registration which is
mandatory on payment of Rs.150/- (Rupees One Hundred and Fifty only) towards
registration fee and then should apply online for this recruitment. The One Time Registration will
be valid for 5 years from the Date of Registration. Thereafter, the registration should be
renewed by paying the prescribed fee. Applicants who have already registered in One Time
Registration system on payment of Rs.50/- before 01.03.2017 and those who have registered
for One Time Registration on or after 01.03.2017 by paying Rs.150/- towards One Time
Registration are exempted from paying the registration fee for this recruitment.
 Applicants have also to pay the service charges applicable to the State Bank of India /
Indian Bank.
 Applicants can avail exemption from paying examination fees as per eligibility criteria.
 Offline mode of payment in the form of Demand Draft / Postal Order etc., will not be
accepted and the applications forwarded with such modes of payment will be summarily
rejected.
 Those who have registered in the One Time Registration system, and paid the registration fee
of Rs.150/- and received the registration ID need not pay the Registration fee i.e., Rs.150/- and
it is enough to pay the examination fee alone.
 Applicants who have made One Time Registration must pay the prescribed examination fee
for this recruitment unless fee exemption is claimed. (One Time Registration is only to
avail exemption for Registration fee for a period of 5 years from the date of registration and it
will not be considered as prescribed examination fee for this recruitment).

(For further details regarding the Examination fee concession, refer para 2 (13 – 23) of
“Instructions to Applicants”).
 4

6. QUALIFICATIONS
(A) AGE (as on 01.07.2017)

Name of the post Category of Applicants Maximum Age

Junior Analyst / SCs, SC(A)s, STs, MBCs/DCs, BCs, BCMs and No Maximum
DWs of all Castes Age limit
Junior Chemist /
Chemist /
Archaeological 30 Years
“Others” [i.e. Applicants not belonging to SCs, (Should not have
Chemist SC(A)s, STs, MBCs/DCs, BCs and BCMs]
completed)

Age Concession

(i) No Maximum age limit for the applicants who belong to SCs, SC(A)s, STs,
MBCs/DCs, BCs, BCMs and DWs of all castes.

(ii) For Differently Abled Persons

(a) No maximum age limit for the applicants who belong to SCs, SC(A)s, STs,
MBCs/DCs, BCs and BCMs.

(b) ‘Others i.e. the applicants not belonging to the Categories mentioned in (a) above
are eligible for age concession upto 10 years over and above the maximum age
limit prescribed above.

(iii) For Ex-Servicemen

(a) No maximum age limit for the Applicants who belong to SCs, SC(A)s, STs,
MBCs/DCs, BCs and BCMs.

(b) The maximum age limit is 48 years for “others” (i.e.) Applicants not belonging to
any of the above said categories.

(c) The above mentioned age concession will not apply to those Applicants who
have already been recruited to any class or service or category.
Note

(i) “Others” [i.e., Applicants not belonging to SCs, SC(A)s, STs, MBCs/DCs, BCs and BCMs]
who have put in 5 years and more of service in the State / Central Government are not
eligible to apply even if they are within the age limit.

(ii) Instructions given with regard to maximum age limit under para 5 of the 'Instructions to
Applicants' will apply to this recruitment.
 5

(B) EDUCATIONAL QUALIFICATION AND EXPERIENCE: [as on 24.11.2017 (i.e. the date of
notification)]
Applicants should possess the following or its equivalent qualification:-

Name of the post Educational Qualification

A Degree in Pharmacy Experience in the analysis of drugs for a
or period of not less than one year.
A Degree in Chemistry
or Experience in the analysis of drugs for a
A Degree in Pharmaceutical period of not less than two years.
Chemistry
JUNIOR ANALYST
or
Candidates who possess Post
Graduate Experience in the analysis of drugs for a
Degree in Chemistry with period of not less than one year.
Analytical Chemistry as a
special subject.

Must possess a first or Second Class Post Graduate Degree in any

Branch of Chemistry of any university or institution recognized by the
UGC.
(OR)
Associateship Diploma of the Institution of Chemists (India).

Note
Other things being equal, preference shall be given to a candidate who
JUNIOR CHEMIST possesses a post graduate degree in Analytical Chemistry or to a candidate
who possesses practical experience for a period of not less than one year in
any recognized research or Analytical or Metallurgical Laboratory.
Explanation
i. “Recognised Research Laboratory” means laboratory recognised by the
Ministry of Science and Technology of the Government of India.

ii. “Recognised analytical or Metallurgical Laboratory” means a Laboratory,

which is engaged in Testing and Analytical and issues Test Certificate.

(1) A First or Second Class Degree in M.Sc., in Chemistry

OR
Chemical Technology
OR
CHEMIST Industrial Chemistry
OR
Associateship Diploma of the Institution of Chemists (India).
and
(2) Experience in research in pure or applied chemistry or Analytical
Chemistry for a period of not less than 2 years.

ARCHAEOLOGICAL
Must have obtained M.Sc., (Chemistry) degree.
CHEMIST
 6

Note
(i) The qualification prescribed for this post should have been obtained by passing the required
qualification in the order of studies viz. 10th + HSC / Diploma or its equivalent +U.G. degree +
P.G. degree as stipulated in Section 25 of Tamil Nadu Government Servants (Conditions of
Service) Act 2016. The results of examination should have been declared on or before the
date of Notification.

(ii) Applicants claiming equivalence of qualification to the prescribed qualification should upload
and submit evidence for equivalence of qualification in the form of G.O. issued prior to the
date of this notification when called for, failing which, their application will be summarily
rejected. The G.Os issued regarding equivalence of prescribed qualification after the date of
this notification will not be accepted. A list of Equivalence of qualification in the related subject
is available in Annexure - I.

(iii) The applicants should upload or submit experience certificate as provided in Annexure - II to this
notification when called for.

(Refer para 10 of the ‘Instructions to Applicants’)

C. CERTIFICATE OF PHYSICAL FITNESS

Applicants selected for appointment to the above said posts will be required to produce a
certificate of physical fitness in the form prescribed below before his/her appointment.

Form of Certificate of Physical

Name of the Post Standard of Vision Prescribed
Fitness

Form prescribed for Other than

Junior Analyst Standard – III or Better
Executive and Ministerial Posts.

Form prescribed for Executive

Junior Chemist Standard – III or Better
Posts.

Standard – III or Better Form prescribed for Executive

Chemist
Posts.

Archaeological Standard – III or Better Form prescribed for Executive

Chemist Posts.

The Applicants with defective vision should produce eye fitness certificate from qualified eye
specialist. Colour Blindness or Night blindness will be a disqualification.

D. KNOWLEDGE IN TAMIL

Applicants should possess adequate knowledge in Tamil on the date of this Notification.
(For details refer para 11 of the Commission’s ‘Instructions to Applicants’)
 7

7. CONCESSIONS
(i) Concessions in the matter of age and / or fees allowed to SCs, SC(A)s, STs, MBCs/DCs,
BCs, BCMs, Destitute Widows, Differently Abled Persons, Ex-servicemen, other categories
of persons etc., are given in para 12 to 14 of the 'Instructions to Applicants'.

(ii) Persons claiming concession referred to above have to produce evidence for such claim
when called for otherwise their application will be liable for rejection.
Note
In all cases, an Ex-Serviceman once recruited to a post in any class or service or category,
cannot claim the concession of being called an Ex-Serviceman for his further recruitment.
(Proviso to Section 3(1) (vii) of Tamil Nadu Government Servants (Conditions of Service) Act
2016)

8. SCHEME OF EXAMINATION OBJECTIVE TYPE (OMR METHOD) AND ORAL TEST:-

For the Post of Junior Analyst

Minimum Qualifying
Marks for Selection
Subject Maximum
Duration SCs, SC(A)s, STs,
Marks
MBCs/DCs, BCs and BCMs Others

i. Paper - I

Degree Standard (200 Questions) 3 Hours 300

Pharmacy(Code No.246)
Pharmaceutical Chemistry
(Code No.245)
*Chemistry(Code No.243)

ii. Paper - II GENERAL STUDIES 2 Hours 200 171 228

(100 Questions) (Code No-003)

General Studies (Degree

Standard) – 75 Questions and
Aptitude and Mental Ability (SSLC
Standard) – 25 Questions.
iii. Interview and Record 70
Total 570

* For those who have studied PG Degree in Chemistry with Analytical Chemistry as a Special
**Subject.
 8

For the Posts of Junior Chemist, Chemist and Archaeological Chemist

Minimum Qualifying
Marks for selection
Maximum
Subject Duration
Marks SCs, SC(A)s,
STs, MBCs / DCs, Others
BCs and BCMs

i. PAPER I 3 hours 300

(P.G. Degree Standard) (200
Questions)
* Chemistry (Code No: 244)
Chemical Technology(Code No: 290)

ii. PAPER II GENERAL STUDIES

2 hours 200 171 228
(100 Questions) (Code No-003)

General Studies (Degree

Standard) – 75 Questions and
Aptitude and Mental Ability (SSLC
Standard) – 25 Questions
70
iii. Interview and Records
Total 570

*For those who have studied M.Sc.,Chemistry, M.Sc.,Industrial Chemistry and

Associateship Diploma of the Institution of Chemists.
Note
(i) The Question Paper in the subjects Pharmacy, Pharmaceutical Chemistry and Chemical
Technology will be set in English only. The Question Paper in the subjects Chemistry and
Paper - II will be set both in English and in Tamil.
(ii) Refer para 22 of “Instructions to Applicants” in regard to instructions to be followed while
appearing for competitive examinations conducted by the Commission.
(iii) The Syllabus for Examination is furnished in the Annexure - III of this notification.
(iv) Candidates should choose and specify in the application, only the prescribed subject in
which they have obtained the educational qualification for appearing to the examination.
9. CENTRE FOR EXAMINATION
Examination will be held in following centres: -
Sl. No Name of the Centre CODE
1 Chennai 0100
2 Coimbatore 0200
3 Madurai 1000
4. Tiruchirapalli 2500
5. Tirunelveli 2600
Note

(i) Applicants will be required to appear for the Written Examination /

Certificate Verification / Oral Test at their own expenses.
 9

(ii) The Commission reserves the right to increase/decrease the number of Examination
Centre and to re-allot the Applicants.
10. SELECTION PROCEDURE
Selection will be made in two successive stages i.e., (i) Written Examination and (ii) Oral Test
in the form of an interview. Final selection will be made on the basis of total marks obtained by
the candidates at the Written Examination and Oral Test taken together subject to the rule of
reservation of appointments. Appearance in both the papers of the Written Examination and
Oral Test is compulsory. A candidate who has not appeared in any one of the papers in
Written Examination or Oral Test will not be considered for selection, even if he/she secures
qualifying marks in the Written Examination or Oral Test.

(For further details Refer paragraph 23 (b) of Instructions to Applicants).

11. NO OBJECTION CERTIFICATE / INFORMATION TO THE EMPLOYER

No Objection Certificate obtained from appropriate authority shall be produced at the time of
Certificate Verification, failing which, the application will be rejected.
For details refer para 15 (g) of Commission’s ‘Instructions to Applicants’. - Any violation of this
instruction will be liable for / end in rejection of application and forfeit his/her candidature.

12. GENERAL INFORMATION

A. The rule of reservation of appointments is applicable to this recruitment except for the post of
Archaeological Chemist. The distribution of vacancies will be as per rule in force.

B. In G.O.Ms.No.145, Personnel and Administrative Reforms(S) Department, dated 30.09.2010 and

G.O.Ms.No.40, Personnel and Administrative Reforms(S) Department, dated 30.04.2014, the
Government have issued orders to fill up 20% of vacancies in direct recruitment on preferential
basis to Persons who studied the prescribed qualification in Tamil Medium. The 20% reservation of
vacancies on preferential allotment to Persons Studied in Tamil Medium (PSTM) will apply for this
recruitment. Applicants claiming PSTM preference must produce certificate issued by Head of
Institution as proof as per the specimen contained in the “Instructions to Applicants” for having
studied the prescribed qualification in Tamil Medium. (Having written the examination in Tamil
language alone will not qualify for claiming this preference). If the Applicants with PSTM certificate
are not available for selection for appointment against reserved turn such turn shall be filled up by
other eligible Applicants but belonging to the respective communal category. The PSTM certificate,
in prescribed format / proforma available in the Commission’s website at ‘www.tnpsc.gov.in’ shall be
obtained from the Head of the Institution and shall be produced / uploaded when called for. (For
further details refer Instructions to Applicants) However, no reserved turn to PSTM candidate arises
for the posts of Junior Chemist, Chemist and Archaeological Chemist.
C. The number of vacancies advertised is only approximate and is liable to modification with
reference to vacancy position at any time including reduction before finalization of selection.
D. The selection for appointment to the above said posts are purely provisional subject to final
Orders on pending Writ Petitions, if any, filed at Madras High Court and Madurai Bench of
Madras High Court.
E. As per the Section 26 and 27(c) of Tamil Nadu Government Servants (Conditions of Service)
Act, 2016, reservation of appointment to Destitute Widows and Ex-Serviceman respectively
will not apply to this recruitment.

F. If the posts are identified as suitable for Differently Abled persons of any category, the
reservation of 4% for Differently Abled persons as per G.O.Ms. No. 21, Welfare of Differently
Abled Persons (DAP3.2) Department, dated 30.05.2017 will be made applicable. Hence, the
Differently Abled persons may apply to this recruitment. Their application will be accepted
subject to the orders to be issued by the Government.
 10

G. The Differently Abled persons should submit copy of Differently Abled Certificate specifying the
nature of physical handicap and the degree of disability when called for by the Tamil Nadu
Public Service Commission.

H. If no qualified and suitable women applicants are available for selection against the vacancies
reserved for them, those vacancies will be filled by male applicants belonging to the respective
communal categories.

I. Even after filling up of the vacancies reserved for SC Arunthathiyars on preferential basis, if
more number of qualified Arunthathiyars are available, they shall be entitled to compete with
the Scheduled Castes other than Arunthathiyars in the inter-se merit among them and if any
post reserved for Arunthathiyars remain unfilled for want of adequate number of qualified
Applicants, it shall be filled up by Scheduled Castes other than Arunthathiyars. However, no
required turn to SC(A) candidates arises except for the post of Junior Analyst.

J. Evidence for claims made in the online application should be uploaded / submitted in time when
called for the documents. Any subsequent claim made thereafter on submission of online
application will not be entertained. Failure to submit the documents within the stipulated time
limit will entail rejection of the Application.

K. Correct and True information regarding arrest, convictions / debarment / disqualification by any
recruiting agency, criminal or any disciplinary proceedings initiated / pending or finalized,
participation in agitation or any Political Organization, candidature in election for
Parliament/State Legislature/Local Bodies etc., if any, should also be furnished to the
Commission at the time of application i.e., the details thereof, originals of the Judgement, order
or G.O dropping further action in Departmental proceedings or any document that may prove
the suitability of such Applicants for a Government appointment in such cases must be
produced at the stage / time of Certificate Verification without fail.

L. Incomplete applications and applications containing wrong claims or incorrect

particulars relating to category of reservation / other basic qualification / eligibility wise
/ age / communal categories / educational qualification / physical qualification and other
basic eligibility criteria will be liable for rejection.

M. One Time Registration is not an application for any Post / Recruitment. Though the
details / particulars were furnished in the One Time Registration by the applicants,
the details/particulars furnished in the online application submitted for this recruitment
alone will be taken into consideration. Tamil Nadu Public Service Commission will not
be responsible for any consequences arising out of furnishing of incorrect and
incomplete details in the application or omission to provide the required details in the
application for this recruitment.

13. OTHER IMPORTANT INSTRUCTIONS

a) Applicants should ensure their eligibility for examination: The applicants applying for
the examination should go through all instructions carefully and ensure that they fulfil all
eligibility conditions for admission to examination. Their admission to all stages of the
examination will be purely provisional subject to satisfaction of the eligibility
conditions. Mere issue of memo of admission to the applicant will not imply that his/her
candidature has been fully cleared by the Commission.

b) The Hall Tickets for eligible applicants will be made available in the Commission’s
Website www.tnpsc.gov.in or www.tnpscexams.net or www.tnpscexams.in for
downloading the same by applicants. No Hall Tickets will be sent by post. So, the
applicants should watch TNPSC website before the scheduled date of examination. The
Applicants must comply with each and every instruction given in the Hall Ticket.
 11

c) Communication to Applicants
Individual communication regarding the date and time of certificate verification, oral
test and counselling will not be sent to the applicants by post. The details will be
made available on the Commission’s website. Applicants will be informed of the
above fact only through SMS and e-mail.

d) Grievance Redressal Cell for guidance of applicants: In case of any guidance /

information / clarification of their applications, candidature etc., applicants can contact
Tamil Nadu Public Service Commission’s Office in person or over Telephone No.044-
25332833 / 25332855 or the Commission’s Office Toll-Free No.1800 425 1002 on all
working days from 10.00 a.m. to 05.45 p.m.

e) Mobile Phones and other Articles Banned:

i. Applicants are not allowed to bring Cellular Phone, Watches and Ring with Inbuilt
Memory Notes etc., or any other Electronic device and Non Electronic devices such
as P&G Design Data Book, Books, Notes, Hand Bags and Recording Device either as
separate piece or part of something used by the applicants such as Watch or Ring etc.,
to the examination hall / room on the date of examination.
ii. If they are found to be in possession of any such thing or instrument, they will not be
allowed to write the examination further, besides invalidation of answer paper and / or
debarment. If it is considered necessary, they will be subjected to thorough physical
search including frisking on the spot. (For further details refer ‘Instructions to Applicants’).
iii. Applicants must not bring into the Examination Hall any article such as books, notes,
loose sheets, electronic or any other type of calculators, mathematical and drawing
instruments, Log Tables, stencils of maps, slide rules, Text Books, rough sheets etc.,
except the permitted writing material (i.e. pen). No colour pen or Pencil must be used.
iv. Applicants are advised in their own interest not to bring any of the banned items including
Mobile Phones to the venue of the examination, as arrangements for safekeeping cannot
be assured.

f) Unless specific instruction is given, applicants are not required to submit along with their
application any certificates in support of their claims regarding age, educational
qualifications, practising / service, physical qualification, community certificates and certificates
regarding their physical disability etc., which should be submitted when called for by the Tamil
Nadu Public Service Commission. The applicants applying for the examination should ensure
that they fulfil all the eligibility conditions for admission to the Examination. Their admission at
all the stages of examination for which they are admitted by the Commission viz. Preliminary
Examination, Main Written Examination and Oral Test will be purely provisional, subject to their
satisfying the prescribed eligibility conditions. If on verification at any time before or after
Preliminary Examination, Main Written Examination, Certificate Verification and Oral Test, it is
found that they do not fulfil any of the eligibility conditions, their candidature for the recruitment
will be liable for rejection / cancellation by the Commission. (For further details refer Instructions
to Applicants).
g) If any of their claims is found to be incorrect, it will lead to rejection of their candidature and
suitable penal action including debarment.

h) Unfair means strictly prohibited: No applicants shall copy from the papers of any other
candidate or permit his papers to be copied or give or attempt to give or obtain or attempt to
obtain irregular assistance of any description. (For further details refer Instructions to
Applicants).
 12

i) Conduct in Examination Hall: No applicant should misbehave in any manner or create a

disorderly scene in the Examination Hall or harass the staff employed by the Commission for
the conduct of the examination. Any such misconduct will be severely viewed and penalised.
(For further details refer Instructions to Applicants).

j) For violation of “ Instructions to Applicants” in any manner, suitable penalty will be

imposed as per the Instructions to Applicants or as deemed fit by the Commission.

14. HOW TO APPLY

1. Applicants should apply only through online mode in the Commission’s Websites
www.tnpsc.gov.in / www.tnpscexams.net / www.tnpscexams.in.

2. One Time Registration (OTR) and applicant Dashboard are mandatory before applying for any
post. Applicant should register only once in the One Time Registration by paying Rs.150/- as
Registration fee. Successfully registered One Time Registration is valid for 5 years from the
date of Registration. All the applications should be submitted using the One Time Registration
ID and password registered by the applicant.

3. For applying in One Time Registration, the applicants should have scanned image of their
photograph, certificate wherever insisted and signature in CD/DVD/Pen Drive to upload the
photo, certificate and signature.
4. Applicants who have already registered in One Time Registration on or before 29.09.2015 shall
use their existing user ID and Password to create applicant Dashboard in the new One Time
Registration system. No applicant is permitted to create more than one registration ID in One
Time Registration.

5. Applicants should enter the Unique ID and password to view the already available information
and update them.

6. One Time Registration is not an application for any post. It is just a collection of information
from the applicants and giving a separate dashboard to each applicant to facilitate them to
maintain their own profile. Applicant who wishes to apply for any post shall click “Apply” against
the post Notified in the Commission’s Website and use the same USER ID and PASSWORD
given for ONE TIME REGISTRATION.

7. Applicants should select the name of the post or service for which they wish to apply.

8. Applicants are required to upload their photograph and signature as per the specifications
given in the Guidelines for Scanning and Upload of Photograph and Signature.

9. An Online application uploaded without the photograph, specified documents and signature will
be rejected.
10. All the particulars mentioned in the online application including name of the Candidate, Post
applied, educational qualifications, Communal Category, Date of Birth, Address, Email ID,
Centre of Examination etc. will be considered as final and no modifications will be allowed after
the last date specified for applying online. Since certain fields are firm and fixed and cannot be
edited, applicants are requested to fill in the online application form with the utmost care and
caution as no correspondence regarding change of details will be entertained.
11. Print Option

a) After submitting the application, applicants can print / save their application in PDF format.
b) On entering user ID and password, applicants can download their application and print, if
required.
 13

c) Need not send the printout of the online application or any other supporting documents to
the Commission. The certificates will be verified only when the applicants come up for next
stage of selection.

12. One Time Registration will not be considered as an application for any post.

15. UPLOAD OF DOCUMENTS

Applicants should upload or submit the Certificate of Experience referred to the said posts in
paragraph 6(B) of the Notification as provided in Annexure – II when called for. If, the required
certificate is not uploaded or submitted by the applicant when called for at any point of time by the
Commission his/her application will not be considered for the above posts.

16. LAST DATE FOR SUBMITTING APPLICATION

The Online Application can be submitted upto 20.12.2017 till 11.59 p.m., after which the link will
be disabled.

(For detailed information applicants may refer Commission’s ‘Instructions to Applicants’ at the
Commission’s website www.tnpsc.gov.in )

Secretary
 14

DISCLAIMER

“The Government orders relating to Equivalence of qualification have been

hosted in the Tamil Nadu Public Service Commission website. However,
the applicants while applying for the examination should furnish the details
of equivalence of qualification declared in the form of Government order
issued prior to the date of this notification if any, which are not mentioned in
Annexure-I to the notification and produce the same when called for by
Tamil Nadu Public Service Commission, failing which their application will
be rejected. The Government Orders issued regarding equivalence of
prescribed qualification after the date of this notification will not be
accepted.”

Secretary
 15

ANNEXURE- I

(NOTIFICATION NO: 28/2017, DATED 24.11.2017)

Equivalence of relevant
G.O. No.
Qualifications

M.Sc., (Chemistry 5 years Integrated Course) G.O.Ms.No.75, Personnel and

offered by Annamalai University is considered Administrative Reforms (M)
eligible wherever B.Sc, Chemistry is prescribed. Department, dated 30.06.2011.

M.Sc., (Applied Chemistry) awarded by G.O.Ms.No.133, Personnel and

Gandhigram University is equivalent to M.Sc., Administrative Reforms (M)
(Chemistry). Department, dated 28.07.1999.

M.Sc., (Applied Chemistry) awarded by Anna G.O.Ms.No.164, Personnel and

University is equivalent to M.Sc., (Chemistry). Administrative Reforms (M)
Department, dated 21.08.2000.
M.Sc., Analytical Chemistry awarded by University
of Madras as equivalent to M.Sc.,(Chemistry).
G.O.Ms.No.165, School
M.Sc., (Organic Chemistry), M.Sc.,(In-organic Education (M2) Department,
Chemistry) and M.Sc., (Physical Chemistry) dated 04.07.2012.
awarded by Annamalai University as equivalent to
M.Sc., (Chemistry).

M.Sc., Industrial Chemistry awarded by G.O.Ms.No.24, Higher Education

Bharathidasan University and Alagappa University (K2) Department, dated
is equivalent to M.Sc., Chemistry. 13.02.2013.
 16

ANNEXURE-II
EXPERIENCE CERTIFICATE

1. Name and Address of the Institution / Organisation

:
2. Whether the said Institution / Organisation is a
recognized one? :

3. Registration Number of Institution / Organisation if

any :

4. Name of the Employee and Date of Birth

:
5. Qualification possessed by the Employee on the
Date of Joining Service in the above said Institution
:
/ Organisation

6. Designation and period of Experience of the

:
Employee

7. Nature of the Work/Duty performed by the

Employee (To be mentioned in brief) :

8. Whether the Employee possesses experience as : Yes / No

laid in para 6(B) of the notification for the Post of
....................
(relevant post may mentioned)

9. Whether Attendance Register / Attendance Rolls / Yes / No

Pay Register and other records /available for this
Employee :

10. Certificate from the Institution / Organisation The above said employee
: having experience in this
Institution / Organisation as
stated above. The above
particulars furnished by us are
correct

Office Seal:

Date:

Place: Signature.

Name & Designation of

the issuing Authority.
Note:

Institution / Organisation which issues the certificate is cautioned that issuing of any certificate
containing false details will lead to legal / penal action on them.
 17

ANNEXURE – III
TAMIL NADU PUBLIC SERVICE COMMISSION
(JUNIOR ANALYST) – MAIN WRITTEN EXAMINATION
PAPER – I PHARMACY (DEGREE STANDARD) OBJECTIVE TYPE
CODE NO.246
UNIT- I

a) The physical, physico-chemical and engineering principles governing design,

layout and operation of plants for the process employed in pharmaceutical
industry.
b) Unit operations: size reduction, size separation, mixing, compression, filtration,
centrifugation, extraction, evaporation, drying, distillation, crystallization.
c) Industrial Hazards and Safety Precautions: Mechanical, Chemical, Electrical,
Fire and Dust hazards, Industrial dermatitis, Accident records
d) Containers, closures and packaging materials
e) Preformulation Studies
f) Pharmaceutical excipients: Antioxidants, preservatives, Colouring, Flavouring
and Sweetening agents, Solvents.
g) Facts related with formulation:- Physical properties, particle size. Crystal from,
flow cohesiveness. Solubility. Chemical properties, Hydrolysis.Oxidation
racemization, enzymatic decompositions.
h) pH determination, application, buffer equation, buffer capacity,buffered isotonic
solutions; Micrometrics: Particle size determinations, derived properties of
powders; Interfacial phenomenon : HLB values surfactants, factors influencing
interfacial phenomenon, Critical micellar concentration, Electrical properties at
interface; Coarse dispersions: Suspensions and emulsions, Theories of
emulsification, multiple emulsions.
i) Pharmaceutical calculations: Calculations of doses, alcohol dilutions, proof spirit,
isotonic solutions.
j) Nuclear Pharmacy- Introduction to Radiopharmaceuticals, radioactive half-life,
units of radioactivity. Production of radiopharmaceuticals, methods of isotopic
tagging, preparation of radioisotopes in laboratory using radiation dosimetry and
radioisotope generators. Permissible radiation dose level, radiation hazards, their
prevention and specifications for radioactive laboratory.
k) Good Manufacturing Practice
 18

l) Quality control, of the following formulations: Semisolids, Solid dosage forms,

Liquid dosage forms, Parenteral and ophthalmic preparations

m) New Drug Delivery Systems- Aerosols, Ocusert, Transdermal Drug Delivery

Systems, Osmotic Drug Delivery Systems, Targeted Drug Delivery Systems,
Prolonged Drug Delivery Systems

n) Cosmetics- Dentifrices, Lipsticks, Face powders, shampoos, depilatories and

Manicure preparations

UNIT- II

a) Blood Products and Plasma Substitutes: Collection, processing and storage

of whole human blood, concentrated human RBCs, dried human plasma, human
fibrinogen, human thrombin, human normal immunoglobulin, human fibrin foam,
plasma substitutes, ideal requirements of PVP, dextran, etc. Control of blood
products as per IP.

b) Basics of pharmacokinetic studies and their importance

c) Pharmaceutical Biotechnology- General principles of immunology, immunological
techniques used in pharmacy; Sterilization of different pharmaceutical dosage
forms; Sterility Testing; Methods of preparation of official sera and vaccines;
Microbiological assays of antibiotics and vitamins of the pharmacopeia;
Disinfectants- Classification, Mechanism and uses of disinfectants in brief.
Factors affecting disinfection and methods of disinfectant evaluation.
d) Immunologicals: Preparation and quality control of products representing
various categories like
Toxoids – Diphtheria and Tetanus,
Live Bacterial Vaccines – BCG
Killed Bacterial Vaccines – Cholera, DPT.
Viral Vaccines – Polio, Rabies and small pox
Antitoxins – Diphtheria

UNIT - III

a) Chemistry of Alkaloids, Vitamins, Flavanoids, Glycosides, steroids, terpenes,

vitamins and hormones.
 19

b) Catalytic hydrogenation, dehydrogenation, metal hydride reduction. Reduction

with hydrazine and its derivatives, Birch reduction, Clemenson’s reduction,
Meerwin – Ponndrof reduction, oxidation with periodic acid, lead tetra acetate,
mercuric acetate and selenium oxide. Beckmann rearrangement, Schmidt
rearrangement and Darzen’s reaction.

UNIT - IV

Synthesis, properties, test for purity, storage of the following categories of drugs -
Analgesics and Antipyretics, Anti-inflammatory, Hypnotics and sedatives, Anti
convulsants, Anti-psychotics, Anti-histamines, Sympathomimetics, Adrenergic
antagonists, Cholinomimetics and anti-cholinergic, Local Anaethetics, Anti-
hypertensives, Anti-anginal, Sulphonamides,antibiotics, Anti-TB, Anti-Viral, Anti-
Fungal, Antimalarials, Anti-Neoplastics,

UNIT- V

a) Principles and Pharmacopeial Assay Procedures involving Non-aqueous

Titration, Oxidation-Reduction, Diazotization, complexometric methods,
electrometric titration, gravimetric analysis

b) Polarimetry and refractometry, and gasometric analysis of oils, fats and waxes
c) Chromatography- TLC, Column, Paper, GC, Ion exchange, HPLC, HPTLC, Gel
electrophoresis,
d) Theory, principle, instruments and applications of colorimetry, UV- Visible
Spectrometry, Fluorimetry, Nephalometry, Turbidometry, IR, Mass, NMR, RIA.

UNIT- VI

a. General Pharmacology:- Routes of adminstration, Absorption, distribution,

Biotransformation and Extretion of drugs, Bioavailability and bio equivalence,
Factors affecting bioavaliability, Mechanism of action of drugs at receptor level,
adverse drug reaction;

b. Drugs acting on Central Nervous system: Analgesics, Nonsteroidal anti inflammatory

drugs, Sedatives and Hypnotic, Anti convulsants and Antipsychotic drugs. Drugs
used in parkinsonism.
 20

c. Drugs acting on Autonomic Nervous system: Drugs which influence the working of
autonomic nervous system, Adrencrgic drugs (or) sympathominitic drugs, Adrenergic
blocking drugs, Cholinergic drugs and cholinergic blocking drugs, Drugs acting on
autonomic ganglia.
d. Drug acting on cardiovasular system: cardiac glycosides, Anti hypertensive, anti-
arrhythmic and anti anginal drugs.
e. Diuretics & anti diuretics

UNIT- VII

a. Drugs acting on GIT

b. Insulin and oral anti diabetic drugs, Thyroid and anti-thyroidal drugs, oral
contraceptives. Hormone replacement therapy, drugs acting on uterus.

c. Antihistaminic drugs and Drugs used in Migraine

d. Chemotherapy- sulphonamides penicillins, cephalosporins, quinolones,
Tetracyclines, Aminoglycosides, Chemotherapy of Tuberculosis, leprosy, malaria,
cancer , Ameobiasis, Helminthiasis.
e. Toxicology- Systematic & local treatment of poisoning and their treatment.

UNIT- VIII

a. General principles of cultivation and collection of drugs from wild & cultivated
sources, their merits and demerits, factors affecting cultivation, adulterants and their
detection
b. Plant growth regulators
c. Source, synonym, cultivation, collection, preparation for market, diagnostic
characters (both macroscopical and microscopical). Constituents, substitutents,
adulterants and uses of Cinnamon, Cinchona, Senna, digitalis, Clove, Saffron,
Pyrethrum. Cochineal, Ergot, opium, Aloe, Acacia, Tragacanth, Benzoin, Ginseng,
Brahmi, Dioscorea, Cascara, Gelatin, umbelliforous fruits, spirulina, nuxvomica,
ginseng, belladonna, taxol , vinca.
d. Principle and application plant tissue culture.
e. Basics of fermentation technology & production of Antibiotics, Vitamins.
 21

UNIT- IX
a. Biosynthetic pathways of Tropane alkaloids, Cholesterol, amino acids.
b. WHO Guidelines for herbal medicines

UNIT- X

a. Drugs and Cosmetics Act 1940 and Rules 1945

b. Pharmacy Act 1948

 22

ANNEXURE – III
TAMIL NADU PUBLIC SERVICE COMMISSION
(JUNIOR ANALYST) – MAIN WRITTEN EXAMINATION
PAPER – I PHARMACEUTICAL CHEMISTRY (DEGREE STANDARD)
Code No.245
UNIT I

1) Atomic structure and valency, Radioactivity, Radio isotopes and Pharmaceutical

applications of Radio Pharmaceuticals, hazards and precautions.
2) Sources of impurities in Pharmaceutical substances; Limit test as per I.P;
Fundamentals of volumetric Analysis.
3) A systematic study of inorganic compounds for their preparation, assay and use
which includes Gastrointestinal agents, Topical agents and Dental products.

UNIT II

1) Assay, test for purity of sodium, calcium, iron, aluminium and ammonium
compounds. Major intracellular and extra cellular electrolytes.

2) Preparation and use of Chemical reagents and Volumetric Solutions as per

Pharmacopia in Pharmaceutical Analysis.

3) Theory of Co-ordination Compounds with special reference to application in

Pharmaceutical Analysis via EDTA, Dimercaprol, Pencillamine.

UNIT III

1) Physiochemical properties of gases, liquids and solids. Density, Surface tension,

Viscosity and physical properties.

2) Osmosis, osmotic pressure, vapour pressure, Raoult's law, Ostwalds dilution law,
Molecular weight determination by osmotic pressure.

3) Non- aqueous and complexometric titrations, analysis of fats, oils and waxes.
Importance of quality control, Different types of titrations, Gasometric analysis and
determination of Nitrogen.

UNIT IV

1) Gases in liquids, liquids in liquids, partially miscible, completely miscible and

completely immiscible liquids.
2) Thermochemistry: Heat of reaction, heat of solution, heat of formation and heat of
neutralization and Hess law.
3) Stereo chemistry, optical isomerism, Geometrical isomerism.

4) Theory of Polarimetry, Refractometry and catalyst.

 23

UNIT V
1) Electronic configuration and electron displacement effects, chemical bonds and
polarity.
2) Chemistry and medicinal uses of cardiac glycosides and vitamins.
3) Synthetic utility of acetoacetic ester, Grignard reagent and Diazonium
compounds.
UNIT VI
1) Aromaticity,concept of resonance, Nucleophilic, Electrophilic substitution
reaction, Elimination reactions in aliphatic and aromatic compounds.
2) Anti-infective agents comprising of Anti-fungal agents, synthetic antibacterial
agents, anti-tubercular Agents, and Anthelmintics agents.
UNIT VII

Chemical structure, Synthesis, assay and therapeutic uses of organic synthetic drugs
like, Antidepressants, General anesthetics, Sedatives and hypnotics, Narcotic
analgesics, Anti -histaminics, Antimalarials., Sulphonamides, Drugs acting on CVS.

UNIT VIII
1) Structural elucidation of natural products - General methods.

2) Structure, chemistry, methods of estimation, and uses of Alkaloids, Carbohydrates,

and Proteins.

3) Chemistry of steroids and natural hormones, currently used steroidal drugs.

UNIT IX
1) Study of separations and determination involving TLC, HPTLC, and column
chromatography.
2) Colorimetry, UV and Visible Spectrophotometry, Spectrofluorimetry-Theory, Principle,
Instrumentation and working.
3) Theory and principles of separation techniques involving Ultra centrifugation, HPLC
and Gel filtration.

UNIT X
1) Conductometry, Potentiometry and Amperometric titrations, Basic concepts and
application in pharmaceutical analysis.
2) Radio Immuno Assay and Electrophoresis.
3) Theory, Principle and application of NMR, MS, IR spectroscopy.
 24

ANNEXURE – III
TAMIL NADU PUBLIC SERVICE COMMISSION
(JUNIOR ANALYST) – MAIN WRITTEN EXAMINATION
PAPER – I CHEMISTRY (DEGREE STANDARD) OBJECTIVE TYPE
CODE NO.243
UNIT - I
PHYSICAL CHEMISTRY:-
a) Gas law and Kinetic Theory:- Ideal gas equation - Deviation from ideal behaviour -
vander waals equation for real gases - Molecular velocities - the Maxwell's distribution of
molecular velocities –heat capacity and viscosity of gases.

b) Solid State:- Crystal systems - Bravaislattice - Unit Cell - Miller Indices - Symmetry
elements in crystals - Bragg's equation - Radius ratio's and packing in crystals –
Determination of crystal structures by Braggs method – structure of Nacl, Kcl, Zns and
spinals.

c) Thermodynamics:- Intensive and extensive variables - First law of thermodynamics –

CP and CV relation - Hess's law of constant heat summation - Kirchoff's equation -
Second law of thermodynamics - Carnot theorem - entropy and probability, Joule
Thomson effect -Free energy and Chemical equilibrium - Temperature and pressure
dependence and - Gibb's and Helmholtz functions – Heterogeneous equilibrium and
Le – Chatlier principle.

UNIT - II
d) Chemical Kinetics:- Rate laws - rate constant - order and molecularity of reactions I,
II, III, and Zero order reaction Arrhenius theory - collision theory and Transition state
theory - catalysis.
e) Electro-Chemistry:- Types of reversible electrodes - Nernst equation - reference
electrode and standard hydrogen electrode - computation of cell e.m.f. calculations of
thermodynamic quantities of cell reactions (DG, DH, DS and K) - Over potential and
hydrogen over voltage - Arrhenius theory - Debye 'Huckel equation - Kohliraush's law -
Ostwald's dilution law - Determination of PH and Pka of acids by potentiometric methods.
UNIT - III
f) Chemical spectroscopy:- Elementary ideas of microwave, infrared, Raman, uv, NMR,
ESR and Mass spectroscopy.
 25

g) Pharmaceutical chemistry: Terminology pharmacology, pharmacotheraies,

toxicology, chemotherapy, classification, and nomenclature of drugs, sources of drugs,
assay of drugs by biological, chemical and immunological methods, physiological
effects of functional groups of drugs different types of drugs like analgesics, antibiotics,
antiseptics, disinfectants, anesthetics, antidepressants, antipsychotic etc.

UNIT - IV
h) Colloids and surface Chemistry:- Classification – preparation, purification - properties
- Tyndall effect- Gels - Emulsions Absorption - Langmuir isotherms - Heterogeneous
catalysis.

i) Physical properties and Chemical constitution:- Surface tension - parachor and its
application to structural problems – Dipole moment - applications of dipolemoment
measurements to structural studies of simple inorganic and organic molecules -
magnetic properties of matter, diamagnetism, paramagnetism, ferromagnetism and anti-
ferromagnetism - Applications to structural problems.

UNIT - V

INORGANIC CHEMISTRY:-

j) Periodic classification:- Classification based on electronic configuration - periodic

properties - atomic and ionic radii, ionisation potential, electron affinity and
electronegativity- various scales - trend along periods and groups.

k) Chemical bond:- Lattice energy - VSEPR Theory and its applications - partial ionic
character from electronegativity - Fajan's Rules.

l) Compounds of Boron:- Electron deficient nature of boron compounds - preparation

and properties of halides and nitrates of boron - diborane – Borazine, silicones and
structures of silicates

UNIT - VI

LANTHANIDES AND ACTINIDES:-

m) Ocurrence Electronic configuration oxidation state, magnetic properties and

complexation behaviour - comparison of lanthanides and actinides, lanthanide
contraction and their position in the periodic table.
 n) Fertilisers:- Ammonium nitrate, ammonium phosphate, Superphosphate and
Diammonium Phosphate, NPK fertilisers.

o) Nuclear Chemistry:- Radio activity – detection and measurement – half life period -
Nuclear stability, - n/p ratio - isotopes, isobars and isotones Nuclear reactions
Spallation - Nuclear fission and fusion – stellar energy uses of nuclear energy -
nuclear power projects in India - applications of tracers in industry, medicine,
agriculture.

UNIT - VII
p) Co-ordination Chemistry:- Redo Nomenclature - theories of co-ordination
compounds - Werner, valence bond, crystal field and ligand field theories - Effective
atomic number - isomerism - Metal Carbonyls of iron and Nickel.

q) Analytical Chemistry:- i) Principles of volumetric analysis - different types of

titrations gravimetric analysis - separation and purification techniques.

UNIT - VIII
ORGANIC CHEMISTRY:-
r) Types of reactions:- Nucleophilic, electrophilic, free radicals, addition and
elimination reactions.
s) Electron displacement effects:- Inductive, inductometric, electromeric, mesomeric,
resonance, hyperconjugation and steric effects.

UNIT - IX
t) Nature of Bonding:- Hybridisation (Sp, Sp2 & Sp3) and Geometry of molecule -
cleavage of bonds - homolytic and heterolytic fission of carbon – carbon bonds -
Reaction intermediates - free radicals, carbocations and carbonions - their stability.

u) Stereo Chemistry:- Optical isomerism and Geometrical isomerism - chirality -

optical isomerism of lactic and tartaric acid - Racemisation - Resolution - Asymmetric
synthesis - walden inversion - cis and trans isomerism of maleic and fumeric acids -
R-S-Notations - conformational analysis of cyclohexane - applications of ORD and CD
Techniques.
 27

UNIT - X

v) Dyes:- Classification and Properties of dyes – methyl orange, cangored, malachite

green, fluorenscein and indigo.

w) Carbon hydrates:- Classification and reactions - Glucose, Fructose, Sucrose and

lactose- structure of glucose and fructose.
x) Aromatic Substitution:- Mechanism of nitration, Halogenation, sulphoration and Friedel
Crafts reaction - Orientation effects - nucleophilic substitution - Benzyne mechanism.
 28

ANNEXURE – III
TAMIL NADU PUBLIC SERVICE COMMISSION
(JUNIOR CHEMIST – CHEMIST – ARCHAEOLOGICAL CHEMIST) – MAIN WRITTEN EXAMINATION
PAPER – I CHEMISTRY (POST GRADUATE DEGREE) OBJECTIVE TYPE

Code No.244
UNIT- I

Reaction Kinetics:-

Rate laws - rates constant for first, second, third and zero order reaction - Half life
period - Arrehenius theory - collission theory - Absolute reaction rate theory - ionic
reaction - salt effect - catalysis – Laws of photo chemistry, quantum efficiency - photo
physical processes of electronic excited molecules. Green Chemistry – reactions and
reagents

Chemical Equilibrium:-
partial molar quantities, gibbs - Duhem equation, Equilibrium constant - temperature
dependence of equilibrium constant - phase rule and its applications to two and three
components systems.

UNIT- II

Solid State:-

crystal systems - designation of crystal faces, lattice structure and unit cell - law of
rational indices - Bragg's law and x rays diffractrion by crystals - schottky and Frenkel
defects - Electrical properties - Insulators and semiconductors - band theory of solids-
Superconductors – nano materials preparations and properties.

Electrochemistry:-

Types of Reversible electrodes - Nearnst equation - calculation of thermo dynamic

quantities of cell reactions - overpotential and hydrogen over voltage - Determination of
pka of acids by potentiometric methods - Kohlarash's law - ostwald's dilution law -
Debye - Huckel onsager equation for Strong electrolytes - (no derivation required) -
Primary and Secondary fuelcells - corrosion and prevention – drycells and storage
batteries
 29

UNIT- III
Structure and Bonding:-
Electronic configuration of atoms, Term symbols and periodic properties o f elements,
Ionic radii, ionisation potential electron affinity, electronegativity, concept of
Hybridization, molecular orbitals and electronic configuration of homonuclear and heter
nuclear diatomic molecules, shapes of polyatomic molecules VSEPR theory,

symmetry elements and point groups for simple molecules, Bond lengths, Bond angles,
bond order and bond energies Types of chemical bond (weak and strong) inter
molecular forces, structure of simple and covalent bonds – covalent character in ionic
bond and partial ionic character – lattice energy.

Acids and Bases:-

Bronsted and Lewis acids and bases - pH and pKa acid - base concept in non -
aqueous media – HSAB concept - Buffer Solutions. Redox Reactions:- Oxidation
numbers, Redox potential, Electro chemical series – application of EMF measurements
- Redox indicators.

Chemistry of Non - transition elements:-

General characteristics, structure and reaction of simple compounds - boranes -

silicates Oxoacids of N,P,S and halagens - xenoncompounds - inter halegens,
Pseudehalides and noble gas compounds – metal clusters – S,N ring and chain
compounds - inorganic Polymers such as silicones, Borazines and phosphonitrilic
compounds.

IUPAC Nomenclature of simple organic and Inorganic compounds.

UNIT - IV

Organic reaction mechanism:-

General methods (Kinetic and non Kinetic) of study of reaction mechanisms Methods
of determining reaction mechanism. – isotopic labelling SN1, SN2 mechanisms -
addition substitution, elimination and rearrangements -free radical mechanism - aromatic
substitution - and stability of reactive intermediate (Carbocations, Carbanion's free
radicals, nitrates and benzynes) - Polar effects - Hammett's equation and it
modification.
 30

Chemistry of important organic reaction:-

Aldol condensation - Claisen condensation - perkin reactions - cannizaro reaction -
Fridel craft reaction - Favorski reaction - Strok enamine reaction - Michael addition -
Baeyer - villigner reaction - Chichibabin reaction - Asymmetric synthesis pericyclic
reactions - classification and examples - woodward and Hoffmann rules. - use of OsO4,
NBS, diborane, NaBH4, LiAlH4 in organic Synthosise.

UNIT- V

Quantum Chemistry:-

Planck's quantum theory wave - particle duality, uncertainty principle, operators and
commutation relations, postulates of quantum mechanics, schrodinger wave equation,
particle in one dimensional box and three dimensional box - harmonic oscillator, rigid
rotator and hydrogen atom, angular momentum, spin - orbit coupling.

Classical thermodynamics and elements of statistical thermodynamics:-

First law of thermodynamics:- heat capacity - isothermal adiabatic processes - Thermo

chemical laws - Kircheff's equation second law of thermodynamics, entropy, in
reversible and irreversible processes - Gibe's free energy and Helmholtz free energy -
Third law of thermodynamics

UNIT VI
Spectroscopy:-
Rotational spectra of diatomic molecules - Isotopic substitution and retational constants
- vibrations spectra of linear symmetric, linear asymmetric and bent triatomic molecules
- electronic spectra - selection rules - nuclear magnetic resonance
- chemical shifts - spin - spin coupling - election spin resonance and hyperfine splitting
theoretical principles of mass spectroscopy. Application's of UV, IR, NMR, ESR and
mass spectroscopy for structural elucidation of organic compounds, inorganic
complexes and free radicals.

UNIT - VII
Chemistry of Co-ordination Compounds:-
structural aspects, isomorism - octahedral and tetrahedral, crystal - splitting of orbitals
- CFSE - magnetism and colour of transition metal ions - charge transfer spectra -
crystal field theory and ligand field theory – MO theory complexes of pi acceptor ligands
- stereochemistry of inorganic co-ordination compounds – ORD and CD Techniques.
 31

Chemistry of lanthanides and actinides:-

Electronic configuration - occurrence and Separation techniques -oxidation states,

colour - magnetic and spectroscopic properties – lanthanide contraction , use of
lanthanide compounds as shift reagents.

UNIT - VIII
Organemetallic compounds and bio inorganic chemistry:-
Metal carbonyls, Metal nitrosyls, metal alkyl, alkenes and arene compounds - organo
metallic compounds in catalysis - Chemistry of porphyrins - chlorophyll homeglobin,
myoglobin, ferrodexin, rubredoxin, and cytochromes, copper proteins, enzymes, zinc
enzymes, toxicity of metals and the effect of excess and deficient levels, metal
complexes in therapy

UNIT- IX
Stereo chemistry:-
Elements of symmetry - optical and goemetric isomerism E. Z and R.S notation's -
Conformational analysis of simple cyclic and acyclic systems - Effects of conformation
on reactivity in acyclic compounds and cyclohexanes.

Carbohydrates:-

Classification - configuration and general reactions of monosacharides - Chemistry of

glucose, fructose, Surcose and Maltose, Important compounds in chemistry - Dyes -
aze, triphenylmethane, and phthalein groups - indige - alizarin vitamins, hormones -
antibiotics - proteins. Polymers: Preperation and uses of polythylene, poly butylene
PVC, Nylon - Ziegler - Natta catalysts -

UNIT - X
Instrumental methods of analysis:-
Adsorption, partition chromatography - Gas chromatography - HPLC - Solvent
extraction and ion turlaexchange methods - atomic absorption spectroscopy -
Eletroanalytical techniques voltammetry, cyclic voltammetry, polarogaphy,
amperonmetry, Coulometry and conductometry, ion - Selective elctrodes- TGA, DTA,
DSC and ICPU. Analysis of industrial products such as ores and Minerals, Coal, Water,
Soaps & Detergents, Metals & Alloys, Manures & fertilizer, cement, Aggregate, Bricks,
petroleum products, food & products, plastics.
 32

ANNEXURE – III
TAMIL NADU PUBLIC SERVICE COMMISSION
(CHEMIST) – MAIN WRITTEN EXAMINATION
PAPER – I CHEMICAL TECHNOLOGY (PG DEGREE STANDARD)

CODE NO: 290

UNIT- I PROCESS CALCULATIONS AND THERMODYNAMICS
Properties of liquids, solids and gases - Gas laws - Material and Energy balance, Material
balance involving recycle by-pass and purge

Thermodynamics functions - Chemical and Phase Equilibrium - Laws of

Thermodynamics - Ideal and non-ideal gases and solutions, fugacity, correlation of activity
coefficient, partial molal properties.

UNIT- II FLUID MECHANICS AND MECHANICAL OPERATIONS

Newtonian and non-Newtonian fluids, compressible and non - compressible fluids, flow
through pipeline systems, flow in closed ducts, packed beds and fluidized bed.
Continuity and conservation equations. Macroscopic energy balance, Bernoulli equation
and its applications, Dimensional analysis, flow meters, pumps and compressors.

Size reduction and size separation; laws of size reduction, Gravity settling, hindered
settling sedimentation; centrifuges and cyclones; thickening and classification, filtration;
mixing and agitation; thickening, elutriation, conveying of solids.

UNIT - III REACTION ENGINEERING, HEAT AND MASS TRANSFER

Rate equation, elementary and non-elementary reactions, theories of reaction rate and
Prediction; Design equation for constant and variable volume batch reactors.

Non-isothermal homogeneous reactor systems, adiabatic reactors, rates of heat

exchanges for different reactors, The residence time distribution, basic models for non-
ideal flow; conversion in non-ideal reactors.

Fourier’s law of heat conduction, convection and radiation, Heat transfer with phase
change, heat exchangers, evaporation, Heat transfer in extended surfaces, Dimensional
analysis in heat transfer, heat transfer coefficient for flow through a pipe, flow past flat
plate, flow through packed beds. Radiative heat transfer – Black body radiation,
Emissivity, Stefan - Boltzman law, Plank’s law, radiation between surfaces.
 33

Diffusion, Theories of mass transfer, Analogy, inter-phase mass transfer. Distillation,

absorption, leaching, liquid-liquid extraction, crystallization, adsorption, drying,
humidification, de-humidification.

UNIT - IV PROCESS CONTROL AND INSTRUMENTAL METHODS OF ANALYSIS

Laplace transformation, application to solve ODEs. Dynamics of process elements, open

loop and closed loop systems, principles of pneumatic and electronic controllers,
Instrumentation: Sensors for Pressure, Flow, Temperature, Control values, Computer
Control of Processes, Analysis of control systems. Micro processer –based control.

Spectroscopic analysis: Absorption spectroscopy, emission spectroscopy, mass

spectroscopy, x-ray diffraction, color measurement by spectrometers, Gas analysis by
thermal conductivity Moisture (humidity analysis) pH measurements, Chromatography -
H.P.L.C.

UNIT – V CHEMICAL PROCESSES

Nitration, Sulphonation and Sulfation, Hydrogenation, Halogenation & Oxidation, Kinetics

and mechanism, the derivative reactions, Industrial applications, Raw material and
manufacture of Soda ash, Sodium bicarbonate, Chlorine and Causticsoda, Bleaching
powder, Calcium Hypochlorite; Sodium Hypochlorite; Sodium chloride or common salt,
sodium sulfate, sodium bisulfate, or Nitercake, Sodium Bisulfite; Sodium Sulfite, Sodium
Hydrosulfite; Sodium sulfide, Sodium Hydrosulfide, Sodium Thiosulfate; Sodium Nitrite;
Sodium Silicates; Sodium peroxide, Sodium perborate; Sodium amide; Sodium cyanide
and Ferri cyanide.

Industrial alcohols, Beer, Wine, Butyl alcohol. Raw Materials, Manufacture of phosphoric
acid, nitric acid, Sulfuric acid and HCL & the occurrence, Purification of all acids.

Occurrences of oils, fats and waxes, classification, chemical composition, Extraction and
refining oils and fats. Manufacture of edible oil.

Surfactant : Concept of surface activity, Hydrophilic-lypophilic balance; Mechanism of

detergency. Classification of surfactants; Biodegradation of surfactant; application of
surfactants.
 34

Soap and Detergent: Soap, detergent, Glycerine: spentlye, synthetic glycerine

manufacture and their applications

Origin, Occurrence, exploration and classification of crude oils, Hydrocarbon, composition

of petroleum and petroleum products (liquid and gas); Refining of crude oil, Catalytic
cracking, thermal cracking; reforming. Chemical conversions, Extraction of Aromatics.

UNIT - VI PULPAND PAPER, AGROCHEMICALS AND FERTILIZERS

Classification and manufacture of Insecticides and pesticides, Plant derivatives, Pyrethrin,

Nicotine, Rotenone, attractants and repellents, Fumigants, Nematacides, Acaricides,
Fungicides, Industrial Biocides, Plant growth regulators, Herbicides.

Raw material for fertilizers; Synthesis of ammonia, Ammonium nitrate, ammonium sulfate,
Ammonium Phosphates; Urea, Super phosphates, Mixed fertilizers, organic fertilizers.

Raw material for pulp, manufacture of pulp and paper. Hydrolysis of wood, Wood
extractives. Cellulose; Hemi cellulose, lignin and associated materials. composition of cell
walls. Physical and Chemical properties of cellulose and derivatives.

UNIT- VII PHARMACEUTICALS, POLYMERS, PLASTICS AND RUBBERS

Types of polymers, Thermoplastics and thermosetting plastics, Polymerization Types.

Degradation of polymers through thermal, mechanical and chemical methods. Raw
materials for polymers and resins. Chemistry of Natural resins and polymers such as lace,
rosin, cellulose, rubber, proteins, fossil resins, etc. Preparation and applications of
phenolics, amino resins, polyesters, polyamides, epoxides, polyurethanes, vinyls. Raw
materials, manufacturing processes of plastics.

Composites: Raw materials, Comparison of different materials with composite; advantages

and disadvantages of Natural rubber, synthetic rubber, rubber compounding, rubber
fabrication; latex compound, rubber derivatives.

Alkylations, Carboxylation and Acetylation; Condensation and Cyclization; Dehydration;

Halogenation; Oxidation; Sulfonation; Amination; Complex Chemical Conversions.
Fermentation and Life processing for antibiotics, Biologicals, Harmones and Vitamins,
Biologicals, Steroids Hormones; Isolates from Plants and Animals.
 35

UNIT - VIII COAL CHEMICALS AND INDUSTRIAL CARBON AND EXPLOSIVES

The destructive distillation of coal; Coking of coal; Distillation of coal tar; coal to Chemicals.
Methods of manufacture and applications of Lampblack; carbon black; activated carbon;
Natural graphite; Manufactured graphite and carbon; Industrial diamonds.

Nuclear reactions: uranium and Thorium fission; Uranium as an energy source; nuclear
fuels and processing. Types, Characteristics & Uses of explosive, Industrial Explosives.

UNIT - IX CERAMIC, GLASS, CEMENT AND LIME

Basic raw Materials; Chemical conversions, Including Basic Ceramic Chemistry; White
wares: Structural Clay products; Refractories; Specialized Ceramic products: Vitreous
Enamel; Kiln, Composition, manufacture of specialty glasses.

Portland cement: Raw materials & Manufacture of Portland cements; Setting and
Hardening of cement; Manufacture and use of Lime and Gypsum.

UNIT - X FOOD AND FOOD BY- PRODUCTS

Classification and structure of carbohydrates, Physical and chemical properties of sugar,

starch, pectin substances, gum and other polysaccharide, Functional properties of
carbohydrates in foods, Definition and classification of lipids, chemistry of fatty acids and
glycerides.

Functional properties of lipids in foods, structure and chemistry of amino acids, peptides
and proteins, Source and distribution of proteins, Isolation, identification and purity of
proteins.

Texture of fruits and vegetables, Plant pigments, Effects of cooking on texture and
composition of fruits and vegetables Animal proteins, Structure and chemical composition
of muscles .Composition of milk, Physical and chemical properties of milk proteins and
effects, chemistry of milk products like cheese, cream, butter, ghee, etc.
 36

ANNEXURE - III
TAMIL NADU PUBLIC SERVICE COMMISSION
(MAIN WRITTEN EXAMINATION)
PAPER - II GENERAL STUDIES (DEGREE / PG DEGREE STANDARD)
OBJECTIVE TYPE

UNIT – I GENERAL SCIENCE

Physics - Universe - General Scientific laws - Scientific instruments - Inventions and

discoveries - National scientific laboratories - Science glossary - Mechanics and properties
of matter - Physical quantities, standards and units - Force, motion and energy - electricity
and Magnetism - Electronics & communications - Heat, light and sound - Atomic and
nuclear physics - Solid State Physics-Spectroscopy – Geophysics - Astronomy and space
science.

Chemistry - Elements and Compounds - Acids, bases and salts - Oxidation and reduction
– Chemistry of ores and metals - Carbon, nitrogen and their compounds -Fertilizers,
pesticides, insecticides - Biochemistry and biotechnology –Electrochemistry - Polymers
and plastics
Botany - Main Concepts of life science-The cell-basic unit of life-Classification of living
organism - Nutrition and dietetics-Respiration - Excretion of metabolic waste-Bio-
communication
Zoology - Blood and blood circulation-Endocrine system-Reproductive system-Genetics
the science of heredity-Environment, ecology, health and hygiene, Bio- diversity and its
conservation-Human diseases, prevention and remedies-Communicable diseases and
non- communicable diseases-Alcoholism and drug abuse-Animals, plants and human life-

UNIT – II CURRENT EVENTS

History - Latest diary of events – National - National symbols -Profile of States-Defence,

national security and terrorism - World organizations-pacts and summits-Eminent persons
& places in news-Sports & games - Books & authors - Awards & honours - Cultural
panorama - Latest historical events - India and its neighbours - Latest terminology-
Appointments - who is who?

Political Science - India’s foreign policy - Latest court verdicts – public opinion - Problems
in conduct of public elections- Political parties and political system in India- Public
awareness & General administration- Role of Voluntary organizations & Govt.,- Welfare
oriented govt. schemes, their utility.
 37

Geography - Geographical landmarks-Policy on environment and ecology.

Economics - Current socio-economic problems-New economic policy & govt. sector.
Science - Latest inventions on science & technology - Latest discoveries in Health
Science - Mass media & communication.

UNIT – III GEOGRAPHY

Earth and Universe - Solar system - Atmosphere hydrosphere, lithosphere -Monsoon,

rainfall, weather and climate - Water resources - rivers in India - Soil, minerals & natural
resources-Natural vegetation - Forest & wildlife-Agricultural pattern, livestock & fisheries -
Transport & communication - Social geography – population-density and distribution-
Natural calamities – disaster management-Climate change - impact and consequences -
Mitigation measures - Pollution Control.

UNIT – IV HISTORY AND CULTURE OF INDIA

Pre-historic events - Indus valley civilization-Vedic, Aryan and Sangam age - Maurya
dynasty - Buddhism and Jainism - Guptas, Delhi Sultans, Mughals and Marathas - Age of
Vijayanagaram and the bahmanis - South Indian history - Culture and Heritage of Tamil
people - Advent of European invasion - Expansion and consolidation of British rule-Effect
of British rule on socio-economic factors - Social reforms and religious movements - India
since independence - Characteristics of Indian culture - Unity in diversity – race, colour,
language, custom - India-as secular state - Organizations for fine arts, dance, drama,
music-Growth of rationalist, Dravidian movement in TN-Political parties and populist
schemes – Prominent personalities in the various spheres – Arts, Science, literature and
Philosophy – Mother Teresa, Swami Vivekananda, Pandit Ravishankar ,
M.S.Subbulakshmi, Rukmani Arundel and J.Krishnamoorthy etc.

UNIT – V INDIAN POLITY

Constitution of India - Preamble to the constitution - Salient features of constitution -

Union, State and territory - Citizenship-rights amend duties - Fundamental rights -
Fundamental duties - Human rights charter - Union legislature – Parliament - State
executive - State Legislature – assembly - Status of Jammu & Kashmir - Local
government – panchayat raj – Tamil Nadu - Judiciary in India – Rule of law/Due process of
law - Indian federalism – center – state relations - Emergency provisions - Civil services in
India - Administrative challenges in a welfare state - Complexities of district administration
- Elections - Election Commission Union and State - Official language and Schedule-VIII -
 38

Amendments to constitution - Schedules to constitution-Administrative reforms & tribunals-

Corruption in public life - Anti-corruption measures – Central Vigilance Commission, lok-
adalats, Ombudsman, Comptroller and Auditor General of India. - Right to information -
Central and State Commission - Empowerment of women- Voluntary organizations and
public grievances redressal - Consumer protection forms.

UNIT – VI INDIAN ECONOMY

Nature of Indian economy - Five-year plan models-an assessment - Land reforms &
agriculture - Application of science in agriculture -Industrial growth - Capital formation and
investment - Role of public sector & disinvestment - Development of infrastructure-
National income - Public finance & fiscal policy - Price policy & public distribution -
Banking, money & monetary policy - Role of Foreign Direct Investment (FDI) – WTO -
globalization & privatization - Rural welfare oriented programmes - Social sector problems
– population, education, health, employment, poverty -
HRD – sustainable economic growth- Economic trends in Tamil Nadu - Energy Different
sources and development - Finance Commission - Planning Commission - National
Development Council.

UNIT – VII INDIAN NATIONAL MOVEMENT

National renaissance- Early uprising against British rule-1857 Revolt- Indian National
Congress - Emergence of national leaders- Gandhi, Nehru, Tagore, Netaji -Growth of
militant movements -Different modes of agitations-Era of different Acts & Pacts-World war
& final phase struggle - Communalism led to partition- Role of Tamil Nadu in freedom
struggle - Rajaji, VOC, Periyar, Bharathiar & Others - Birth of political parties /political
system in India since independence.

UNIT – VIII APTITUDE & MENTAL ABILITY TESTS

Conversion of information to data - Collection, compilation and presentation of data -

Tables, graphs, diagrams - Parametric representation of data-Analytical interpretation of
data - Simplification – Percentage - Highest Common Factor (HCF) - Lowest Common
Multiple (LCM) - Ratio and Proportion - Simple interest - Compound interest - Area-
Volume - Time and Work - Behavioral ability - Basic terms, Communications in information
technology - Application of Information and Communication Technology (ICT) - Decision
making and problem solving.
Logical Reasoning - Puzzles – Dice - Visual Reasoning - Alpha numeric Reasoning-
Number Series - Logical Number/Alphabetical/Diagrammatic Sequences.