SAFETY DATA SHEET

according to GB/T 16483 and GB/T 17519

KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

1. PRODUCT AND COMPANY IDENTIFICATION

Product code : 05732255

Chemical nature : butadiene/acrylonitrile copolymer, carboxylated

Polymer
Manufacturer or supplier's details
Supplier : 阿朗新科高性能弹性体（常州）有限公司
中国江苏省常州市新北区黄海路 318 号 213127, 中华人民共和
国
Telephone : +8651988021199

Telefax : +8651988021255

Emergency telephone number : +86 532 83889090

Supplier : ARLANXEO High Performance

Elastomers (Changzhou) Co., Ltd.
No. 318, Huanghai Road, Xinbei District
Changzhou, Jiangsu Province, 213127, P.R, People's Republic
of China
Telephone : +8651988021199

Telefax : +8651988021255

Emergency telephone : +86 532 83889090

Recommended use of the chemical and restrictions on use

Recommended use : crude product for the production of technical rubber articles

2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance : rubber bales
Colour : yellow
Odour : slight, aromatic
Causes mild skin irritation. Causes serious eye irritation.

GHS Classification
The polymer is not hazardous in the form in which it is placed on the market as long as the haz-
ardous component is included in the polymer matrix.
GHS label elements
The polymer is not hazardous in the form in which it is placed on the market as long as the haz-
ardous component is included in the polymer matrix.
Physical and chemical hazards
Not classified based on available information.
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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Health hazards
Causes mild skin irritation. Causes serious eye irritation.
Environmental hazards
Not classified based on available information.
Other hazards which do not result in classification
None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : butadiene/acrylonitrile copolymer, carboxylated

Polymer
Hazardous components
Chemical name CAS-No. Concentration (% w/w)
Benzenesulfonic acid, C10-13-alkyl derivs., so- 68411-30-3 >= 1 -< 2.5
dium salts
There are no additional ingredients present which, within the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment
and hence require reporting in this section.

4. FIRST AID MEASURES

General advice : Keep warm and in a quiet place.

If inhaled : If inhaled, remove to fresh air.

Get medical attention if symptoms occur.

In case of skin contact : Wash off with soap and water.

Get medical attention if symptoms occur.

In case of eye contact : Flush eyes with water as a precaution.

Get medical attention if symptoms appear.

If swallowed : Get medical attention if symptoms appear.

Most important symptoms : No information available.

and effects, both acute and None known.
delayed Causes mild skin irritation.
Causes serious eye irritation.

Notes to physician : Treat symptomatically.

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray

Foam
Dry chemical
Carbon dioxide (CO2)
Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Unsuitable extinguishing : None known.

media

Specific hazards during fire- : Toxic and irritating gases/fumes may be given off during burn-
fighting ing or thermal decomposition.

Hazardous combustion prod- : Carbon dioxide (CO2)

ucts Carbon monoxide
Nitrogen oxides (NOx)

Specific extinguishing meth- : Promptly isolate the scene by removing all persons from the
ods vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without
suitable training.

Special protective equipment : Fire-fighters should wear appropriate protective equipment

for firefighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer-
gency procedures

Environmental precautions : Should not be released into the environment.

Methods and materials for : Vacuum or sweep up material and place in a designated, la-
containment and cleaning up belled waste container.
Dispose of wastes in an approved waste disposal facility.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed.

Avoidance of contact : No specific data.

Storage
Conditions for safe storage : Keep away from direct sunlight or strong incandescent light.

Store in original container.

Keep containers tightly closed in a cool, well-ventilated place.
Store away from incompatible materials (see section 10) and
food and drink.
Keep away from direct sunlight or strong incandescent light.

Recommended storage tem- : < 35 °C

perature
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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : If user operations generate dust, fumes or mist, use ventila-
tion to keep exposure to airborne contaminants below the
exposure limit.

Personal protective equipment

Respiratory protection : In case of dust formation particle filter.

Filter type : P1 filter

Eye/face protection : Safety glasses with side-shields

Skin and body protection : Wear suitable protective clothing.

Hand protection

Remarks : Wear suitable gloves.

Protective measures : Wear suitable protective equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period.
Ensure that eyewash stations and safety showers are close
to the workstation location.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : rubber bales

Colour : yellow

Odour : slight, aromatic

Odour Threshold : No data available

pH : No data available

Melting point/freezing point : No data available

Boiling point/boiling range : No data available

Flash point : Not applicable

> 250 °C
Method: closed cup

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit : No data available

Vapour pressure : No data available

Relative vapour density : No data available

Relative density : No data available

Density : 0.99 g/cm³ (20 °C)

Solubility(ies)
Water solubility : insoluble

insoluble

Partition coefficient: n- : No data available

octanol/water

Ignition temperature : > 200 °C

Decomposition temperature : > 200 °C

Viscosity : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Molecular weight : No data available

10. STABILITY AND REACTIVITY

Reactivity : No specific test data related to reactivity available for this

product or its ingredients.

Chemical stability : This product is stable.

Possibility of hazardous reac- : None known.

tions

Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : No specific data.

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Hazardous decomposition products

Thermal decomposition : Caused by smouldering and incomplete combustion toxic
fumes mainly consisting of CO and CO2 may be developed.
Degradation products of the polymers and their additives may
also be formed.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method

Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Acute oral toxicity : LD50 (Rat, male and female): 1,220 mg/kg
Method: OECD Test Guideline 401

Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg
Method: OECD Test Guideline 402
GLP: yes
Remarks: Extrapolation according to Regulation (EC) No.
440/2008

Skin corrosion/irritation
Causes mild skin irritation.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Species: Rabbit
Method: OECD Test Guideline 404
Result: Irritating to skin.

Serious eye damage/eye irritation

Causes serious eye irritation.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Species: Rabbit
Result: Risk of serious damage to eyes.
Method: OECD Test Guideline 405

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
Not classified based on available information.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Exposure routes: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: Did not cause sensitisation on laboratory animals.

Germ cell mutagenicity

Not classified based on available information.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Genotoxicity in vitro : Test Type: Ames test
Test system: Bacteria
Metabolic activation: with and without metabolic activation
Result: negative

Genotoxicity in vivo : Test Type: Cytogenetic assay

Species: Mouse
Application Route: Oral
Result: negative

Carcinogenicity
Not classified based on available information.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Species: Rat
Application Route: Oral
Exposure time: 2 Years
Result: negative

Reproductive toxicity
Not classified based on available information.
Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Effects on foetal develop- : Species: Rat, female
ment Application Route: Oral
Dose: 600 milligram per kilogram
Duration of Single Treatment: 15 d
Remarks: No known significant effects or critical hazards.
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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

STOT - single exposure

Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity

Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Species: Rat, male and female
NOAEL: 50 mg/kg
Application Route: Oral
Exposure time: 84 d
Remarks: Subchronic toxicity

Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks: Under the recommended processing conditions small amounts of emitted substance
(e.g. residual monomers, residual solvents, decomposition products) may be discharged.
According to our experience and information the product has no harmful effects on health if
properly handled.
The substance(s) listed in Chapter 3 is/are encapsulated in this preparation in a polymer and
is/are therefore not bioavailable.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 1.67 mg/l
Exposure time: 96 h
Method: OPPTS 850.1075

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.9 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
GLP: yes
Remarks: Fresh water

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 10 - 100

mg/l
Exposure time: 72 h

NOEC (Chlorella vulgaris (Fresh water algae)): 3.1 mg/l

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Exposure time: 15 d

Toxicity to fish (Chronic tox- : NOEC (Lepomis macrochirus (Bluegill sunfish)): 1 mg/l
icity) Exposure time: 28 d
Method: OECD Test Guideline 204
GLP: no
Remarks: Fresh water

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 1.18 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Method: OECD Test Guideline 211
GLP: no
Remarks: Fresh water

Persistence and degradability

Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Biodegradability : aerobic
Inoculum: activated sludge
Concentration: 34.3 mg/l
Result: Readily biodegradable.
Biodegradation: 83 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
GLP: yes

Bioaccumulative potential

Components:

Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts:

Partition coefficient: n- : log Pow: 1.4
octanol/water Method: OECD Test Guideline 123

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : The product is practically insoluble in water. In view of its con-
mation sistency and insolubility in water, no ecological problems are
to be expected if the product is properly handled. This product
is not readily biodegradable.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Empty containers retain product residue; observe all precau-

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

tions for product.

Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

14. TRANSPORT INFORMATION

National Regulations

China-DG GB 6944/12668
Not regulated as a dangerous good

Transportation Notes:
- Appropriate & sufficient fire-fighting facilities and spill emergency handling apparatus should be
equipped with the transport vehicles.
In case of products with explosive, flammable, self-reactive, pyrophoric, self-heating and oxidiz-
ing properties:
- Tank cars used in transport should be equipped with a grounding chain; a porous separator
plate may be provided in the tank car to reduce static electricity shocks.
- The exhaust pipes of vehicles used for shipping this product must be equipped with fire retard-
ant devices. The use of mechanical equipment or tools prone to sparking is prohibited.
- Protect against exposure to sun, rain and high temperatures during transit; in summer,
transport should ideally be in the morning or evening.
- Keep away from fire, heat and high temperature zones during stopovers.
- When transporting over public roads, select routes compliant with regulations and do not stop
over in residential or densely populated areas.

International Regulations

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

Hazard statements : Not dangerous cargo.

Keep separated from foodstuffs.

15. REGULATORY INFORMATION

National regulatory information

Further information : 1. Regulations of the Safety Administration of Dangerous

Chemicals
2. Rules for classification and labeling of chemicals
(30000.2~29)
3. Lists of dangerous goods （GB12268）
4. Safety Data Sheet for Chemical Products -Content and

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SAFETY DATA SHEET
according to GB/T 16483 and GB/T 17519
KRYNAC X 740

Version Revision Date: SDS Number: Date of last issue: -

1.0 2019/02/01 103000003997 Country / Language: CN / 6N

Order of Sections （GB/T16483）

5. Classification and Code of Dangerous Goods（GB6944）
6. List of hazardous waste
7. Catalogue of hazardous chemicals
8. Occupational exposure limits for hazardous agents in the
workplace Part 1: Chemical hazardous agents (GBZ 2.1）

16. OTHER INFORMATION

Full text of other abbreviations

ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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