MUGAS, Audrey A Assuming Raoult's law to apply to the system n-pentane(1)/n-heptane(2)

10.3 (a) What are the values of x1 and y1 at t = 55°C and 𝑃= 1/2 ( 〖𝑃∗〗 _1+ 〖𝑃∗〗 _2 )? For these
conditions plot the fraction of system that is vapor V vs. overall composition 𝑧_1.
(b) For t = 55°C and 𝑧_1=0.5, plot P, 𝑥_(1,) and 𝑦_1 vs. V.

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑡+𝐶)

A B C
P* t
n-pentane 13.7667 2451.88 232.014 55 185.6718
n-heptane 13.8622 2910.26 216.432 55 23.11137
P 104.3916
𝑃_𝑇=𝑥_1 〖𝑃∗〗 _1 + 𝑥_2 〖𝑃∗〗 𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇
𝑥_1=(𝑃_𝑇−
_2 𝑧_1 =𝑥_1 𝐿 + 𝑉=(𝑧_1−𝑥_1 )/(𝑦_1−𝑥_1 )
𝑥_1 + 𝑥_2=1 〖𝑃∗〗 _2 )/ 𝑦_1 𝑉
𝐿 + 𝑉=1
( 〖〖𝑃∗〗 _
x1 y1 1z1−𝑃∗ 〗 _2V )
0.5 0.889304 0.5 0
0.5 0.889304 0.6 0.256868
0.5 0.889304 0.7 0.513737
0.5 0.889304 0.8 0.770605
0.5 0.889304 0.889304 1

V-z1
1.2

0.8
Axis Title

0.6

0.4

0.2

0
0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95
Axis Title
)
_1+ 〖𝑃∗〗 _2 )? For these
tion 𝑧_1.

)/(𝑦_1−𝑥_1 )
 MUGAS, Audrey A Assuming Raoult's law to apply to the system n-pentane(1)/n-heptane(2)
10.3 (a) What are the values of x1 and y1 at t = 55°C and 𝑃= 1/2 ( 〖𝑃∗〗 _1+ 〖𝑃∗〗 _2 )? For these
conditions plot the fraction of system that is vapor V vs. overall composition 𝑧_1.
(b) For t = 55°C and 𝑧_1=0.5, plot P, 𝑥_(1,) and 𝑦_1 vs. V.

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑡+𝐶)

A B C t P*
n-pentane 13.7667 2451.88 232.014 55 185.6718
n-heptane 13.8622 2910.26 216.432 55 23.11137
P 104.3916
𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇
𝑥_1=(𝑦_𝑛 𝑃 )/ 𝑧_1 =𝑥_1 𝐿 + 𝑥_1 =(𝑧_1−𝑦_1 𝑉 )/(1−𝑉)
( 〖〖𝑃∗〗 _ 𝑦_1𝐿𝑉+ 𝑉=1
1 〗_ )
(𝑦_1 𝑃 )/( 〖〖𝑃∗〗 _1 〗 _ )=(𝑧_1−𝑦_1𝑉
𝑃=( 〖𝑃∗〗)/(1−𝑉)
_1 )/𝑦_1 ((𝑧_1−𝑦_1 𝑉 )/(1−𝑉)) P-V
120
x1 y1 z1 V P
0.5 0.889304 0.5 0 104.3916 100
0.5 0.889304 0.5 0.1 95.36047
80
0.5 0.889304 0.5 0.2 84.07155

P (kPa)
0.5 0.889304 0.5 0.3 69.55722 60
0.5 0.889304 0.5 0.4 50.20479
40
0.5 0.889304 0.5 0.5 23.11137
20
𝑧_1 =𝑥_1 𝐿 + 𝑧_1 =𝑥_1 (1−𝑉) + (𝑥_1 〖𝑃
0
𝑦_1 𝑉 ∗〗 _1 )/𝑃_𝑇 𝑉 0 0.1 0.2 0.3 0
𝐿 + 𝑉=1
𝑥_1 =𝑧_1/((1−𝑉) "+ " ( 〖𝑃∗〗 _1 )/𝑃_𝑇 𝑉)
𝑦_1=(𝑥_1 〖𝑃∗〗 _1 )/𝑃_𝑇
V

z1 p*1 P V x1 y1
0.5 185.6718 104.3916 0 0.5 0.889304 mol fractio
1
0.5 185.6718 104.3916 0.1 0.463882 0.825064
0.5 185.6718 104.3916 0.2 0.43263 0.76948 0.9
0.5 185.6718 104.3916 0.3 0.405323 0.720912 0.8
0.5 185.6718 104.3916 0.4 0.381259 0.678111
0.7
0.5 185.6718 104.3916 0.5 0.359892 0.640108
0.5 185.6718 104.3916 0.6 0.340793 0.606138 0.6
mol fraction

0.5 185.6718 104.3916 0.7 0.323619 0.575592 0.5

0.5 185.6718 104.3916 0.8 0.308093 0.547977 0.4
0.5 185.6718 104.3916 0.9 0.293988 0.52289
0.3
0.5 185.6718 104.3916 1 0.281119 0.5
0.2

0.1

0
0 0.2 0.4 0.
V
0.2

0.1

0
0 0.2 0.4 0.
V
)
_1+ 〖𝑃∗〗 _2 )? For these
tion 𝑧_1.

P-V

0.2 0.3 0.4 0.5 0.6

V

mol fraction vs V
x1-
V
y1-
V

0.2 0.4 0.6 0.8 1 1.2

V
0.2 0.4 0.6 0.8 1 1.2
V