Chemistry 101

SECOND Exam (131)

Name:________________________________ Date: 16/12/2013

Student no. ____________________________ Section:______

Useful Information: Gas Constant R= 0.08206 L.atm/K.mol, Specific heat of H2O=4.18 J/g. C

H1 He2
1.000 4
3 4 5 6 7 8 9
Li Be B C N O F Ne10
6.941 9.012 10.81 12.01 14.01 16 19 20.18
11 12 13 14 15 16 17
Na Mg Al Si P S Cl Ar18
22.99 24.31 26.98 28.09 30.97 32.06 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr36
39.10 40.08 44.96 47.9 50.94 51.99 54.94 55.85 58.93 58.71 63.54 65.37 69.72 72.59 74.92 78.96 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe54
85.47 87.62 88.91 91.22 92.91 95.94 99.91 101.1 102.91 106.4 107.87 112.4 114.8 118.69 121.75 127.6 126.9 131.3
55 56 57-71 72 73 74 75 76 77 78 79 80 81 82 83 84 85
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn86
132.9 137.3 * 178.5 180.9 183.85 186.2 190.2 192.2 195.1 196.97 200.6 204.37 207.2 208.98 210 210 222

Write the best fit answer of the following questions in this table:

Q8 Q7 Q6 Q5 Q4 Q3 Q2 Q1

Total (13) Q14 Q13 Q12 Q11 Q10 Q9

1) Consider the following Unbalanced equations:
(1) NH3 + NO2  N2 + H2O
(2) HNO3 + S  NO + SO2 + H2O

Nitrogewn is acting as:

a) Oxidizing agent in both equations.
b) Reducing agent in both equations.
c) Reducing agent in equation (1) and oxidizing agent in equation (2).
d) Reducing agent in equation (2) and oxidizing agent in equation (1).

2) An experiment calls for 0.0353 g of potassium hydroxide, KOH. How many milliliters of
(0.0176 M) KOH are required:
a) 35.8 mL b) 0.0358 mL c) 120.6 mL d) 71.6 mL

3) Complete and balance the following molecular reaction then write the IONIC and the
NET IONIC equations:
CH3COOH(aq) + Ca(OH)2(aq) ……………………………………………………….
Ionic:.................................................................................................................................
Net Ionic:………………………………………………………………………………..

4) Hydrochloric acid (75.0 mL of 0.25 M) is added to 225.0 mL of 0.0550 M Ba(OH)2

solution. What is the concentration of HCl or Ba(OH)2 left in this solution:
a) 0.02 M b) 0.00938 M c) 0.01 M d) 0.005 M

5) A sample of methane gas, CH4, has the volume of 35.5 mL. This sample was produced at
31 ºC and 753 torr. What is the volume of this sample at STP?

a) 31.6 mL b) 0.032 mL c) 2.4 x 104 mL d) 39.2 mL

6) A certain volume of concentrated H2SO4 (18 M) was diluted by adding 100 mL of water
to give a solution of 7.0 M H2SO4. The final volume of the solution will be:
a) 200.30 mL b) 63.64 mL c) 36.80 mL d) 163.64 mL
7) Air bags in cars are inflate by nitrogen gas, N2(g), which is generated according to the
following equation:

6 NaN3(s) + Fe2O3(s )  9 N2(g) + 3 Na2O(s) + 2 Fe(s)

How many grames of sodium azide, NaN3 would be required to provide 75.0 L of
Nitrogen gas, N2, at 25 ºC and 748 mmHg:
a) 130.9 g b) 3.0 g c) 292.0 g d) 14.3 g

8) Calculate H for the reaction:

C2H4(g) + H2(g)  C2H6(g)
Given the following reactions and their respective enthalpy changes:
H/kJ
C2H4(g) + 3 O2(g)  2 H2O (l) + 2 CO2(g) - 1411
C2H6(g) + 7 /2 O2(g)  3 H2O (l) + 2 CO2(g) - 1560
H2(g) + 1/2 O2(g)  H2O (l) - 286
a) 3257 kJ b) 435 kJ c) - 435 kJ d) - 137 kJ

9) A 48.90 mL sample of 0.2040 M acid was reacted with an excess Na2CO3 to form 125.0
mL CO2 at 722 mmHg and 17 ºC. If the acid is HCl or H2SO4, WHICH IS IT? SHOW
YOUR CALCULATIONS:
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………

10) The pressure of oxygen gas, O2, which exist in 200 mL flask was 2.7 mmHg at 15 ºC. If
0.56 mg helium gas, He, was added to the flask, calculate the partial pressure of oxygen
in this mixture:
a) 0.353 % b) 0.42 % c) 1.99 % d) 0.00043 %

11) What will be the final temperature of a mixture made from 25.0 g of a liquid at 15 ºC,
45.0 g of the same liquid at 50 ºC, and 15.0 g of this liquid at 37.0 ºC:
a) 37.41 ºC b) 37.50 ºC c) 93.75 ºC d) 109.23 ºC
12) Given the following thermochemical equation:
C6H6(l) + 15/2 O2(g) → 6 CO2(g) + 3 H2O(l) Ho = -3271 kJ
If the heat of formation Hof of CO2(g) and H2O(l) are -394 kJ/mol and -286 kJ/mol
respectively. The heat of formation Hof of C6H6(l) is:

a) -320 kJ/mol b) 49 kJ/mol c) -78 kJ/mol d) 173 kJ/mol

13) Calculate the wave length, λ (nm), for the radiation emitted when an electron transferred
from fourth energy level to the first energy level:
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………

14) Molybdenum, Mo, is one of the transition elements which has the atomic number of 42:

A. Write the electron configuration of Mo…………………………………….......

…………………………………………………………………………………..

B. Determine the number of unpaired electrons…………………………………...

C. Determine the number of valence shell electrons………………………….........

D. What are the four quantum numbers of the valance shell electron(s)…………..

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-GOOD LUCK-