CHEMI

CALENGI
NEERI
NGREVI
EW:CALCULATI
ONS1
1. Cr yst allizat ionoccur si nasol ut i
ont hati s a) dr ybul b c) dewpoi nt
a) unsat ur ated c) super sat ur ated b) wetbul b d) equi libri
um t emper atur e
b) sat ur at ed d) atanyconcent ration 22. In some r eact ion oper ation,by passi ng some amountoft he
2. I ti st he f ract ion ofa st ream t hati s by passed f r
om f urt
her react ant spr ev entwast efulpr ocessi ng.Todet ermi net heamount
processi ngi nor dert obesubj ectedt oanear lieruni tprocess oft heby pass, itisessent ial thatamat erialbal ancebet aken
a) By passr at io c) Pr oduct–Feedr ati
o a)insi det her eact or c)atov er allout put&i nputmat erials
b) Feed–Pr oductr at io d) noanswer b)att hef eed d)ar oundapoi ntwher emi xingoccur s
3. I ndi st i
llat ion,component swi thahi gherboi lingpoi ntar ei nthe 23. Thisi sast eady–st atet emper atur e,reachedbyasmal lamount
ov erheadpr oduct ofl iqui dev apor at i
ngi nt oal ar geamountofunsat uratedv apor–
a)t rue b)f alse c)noanswer gasmi xt ure
4. Av er ydi lut esol utioni spr epar edbydi ssol v i
ng' x1' mol eofsol ut e a)sat ur at iont emper atur e c)wetbul bt emper at ure
i
n' x2'mol e of a sol vent .The mol ef ract ion of sol utei s b)dr ybul bt emper at ur e d)dewpoi nttemper at ure
appr oxi mat elyequal to 24. Ani ndi cat i
onoft hemoi stur econt entofambi entai risi ts
a)x1/ x2 b)x2/ x1 c)1–( x1/x2) d)1/ x2 a)Dr ybul b b)Wetbul b c)Ambi ent d)Dewpoi nt
5. Ani deal gascanbel i
qui f i
ed, because 25. Cry st allizat i
onofasol ut ef rom asol utioncanbeaccompl i
shedby
a) i tsmol ecul arsi zei sv erysmal l anyoft hef ollowi ngexcept
b) i tscr i
t i
cal temper at ur ei smor et han0° C a) ev apor ationofsol ventatsat ur ati
onpoi nt
c) f or cesoper at i
v ebet weeni t
smol ecul esar enegl igible b) adi abat i
cev apor ation
d) i tget ssol i
di fieddi rect l
ywi thoutbecomi ngl iqui d c) cool i
ng
6. Ther at eofmat erial_ _ ___ ____ _iszer oi ncaseofast eadyst at e d) sal tingout
sy stem. 26. Whatdoesequi libr ium moi stur econt entmeans
a) Pr oduct ion c) React ion a) Moi stur econt entatwhi chdr y i
ngr atei sconst ant
b) I nput d) Accumul at i
on b) Moi stur econt entatwhi chdr y i
ngr atei snegl igible
7. Themat er ial, whi chr emai nsunchangedi nt hepr ocess c) Moi stur econt entatt heboundar yofCRPandFRP
a) t i
er eact ant c) excessr eact ant d) Fr eemoi st ur econt ent
b) pr oducty ield d) l i
mi ti
ngr eactant 27. Separ at ion ofmi xt uresbased on di fferencesi nv olat il
i
tiesby
8. Thebasi sofal l massbal ancecal culations uti
lizi ng v apor and l iqui d phases at essent iallyt he same
a) l awofmassact ion temper at ur eandpr essur ef ort hecoexi sti
ngzones
b) l imi tingr eact ant a)Gasabsor ption c)Di sti
llation
c) t emper at ur eandpr essur econdi tions b)Ev apor ation d)Scr eeni ng
d) l awofconser vat i
onofmass 28. Theeaseordi fficul tyofsepar atingcomponent sbydi still
ationis
9. CaCO3cont ains_ __ __ ___ __per centofCabywei ght . deter mi nedby
a)12 b)40 c)48 d)96 a) Rel at i
v ev ol atility c) Vaporpr essur e
10. Pr ocesscondi tionsar echangi ngwi tht ime b) Vi scosi ty d) Rel ativesol ubi lity
a) st eady–st ate c) bat ch 29. Thesear emat er ialswhi chdonotdi rectl
ypar ticipat ei nt heact ual
b) unst eady–st at e d) cont inuous processbutt heydonotcomeoutaspar toft hepr oduct .
11. Inl i
qui dext ract i
on, thet r ansf erofsol utebet weent woi mmi scible a)pr emi um mat er ials c)auxi li
ar ymat erials
l
iqui dsi spossi blewhent her ei sadi ff
er encei n b)anci ll
ar ymat er ials d)pr imar ymat erials
a)SG b)mass c)temp d)sol ubil
ity 30. Af lowdi agr am whi chgi vesi nf ormat i
onont hedi rect ionoff l
owof
12. Incr easi ngt het emper at ur eofanaqueoussol ut i
onwi llcause mat er i
al sf oranequi pmentorpr ocess,t hecomposi t
ionsoft he
decr easei ni t s streamsandpr ocessv ar iabl esi nv olved
a)mol al ity b)mol ef ract ion c)wei ght% d)mol arity a)schemat icdi agr am c)pr ocessf l
owchar t
13. Sol ut i
onswhi chdi st il
l wi thoutchangei ncomposi t i
onar ecal led b)qual itat i
v ef l
owdi agr am d)quant itativef lowdi agram
a) i deal c) sat ur ated 31. Desor ptioni sanot hert er mf or
b) super sat ur at ed d) azeot ropi c a)dephl egmat ion c)flashdi stil
lat i
on
14. Amet aloxi dei sr educedbyheat i
ngi tinast r
eam ofhy drogen. b)st r ippi ng d)rect i
ficati
on
Af tercompl et er educt ion, itisf oundt hat3. 15gm oft heoxi dehas
yielded1. 05gm oft hemet al.Itmaybei nf erredt hatt he 32. Theboi lingpoi ntismeasur ed
a) at omi cwei ghtoft hemet al i
s4 a)abov et hesur faceoft hel iquid
b) equi val entwei ghtoft hemet al i
s4 b)int heboi li
ngl iqui di t self
c) at omi cwei ghtoft hemet al i
s2 c)int her ecei v i
ngf lask
d) equi val entwei ghtoft hemet al i
s8 d)wit hat her momet erext ernal tothedi stil
lationappar atus
15. Allmassi schar gedt ot hepr ocessandnot hingi swi thdr awnunt i
l 33. Inthisr eact ion,t her eact i
ngsubst ancesi nsteadofpr oceeding
theoper at ioni scompl et e alongonepat ht oy ieldagi vensetofpr oduct s,alsof oll
owoneor
a) st eady–st ate c) bat ch mor eot herpat hst ogi v edi f
fer entpr oduct s
b) unst eady–st at e d) cont inuous a)consecut iver eact ions c)par allelreactions
16. Pr ocesswher einasol utei sr emov edf rom al i
qui dbybr ingingt he b)rev ersibler eact ions d)chai nr eactions
l
iqui di ntocont actwi thani ner tgas. 34. Hotai rfact ort hatcoul di ncreasedr yingr at e
a) gasabsor pt i
on c) gasdesor pt ion a)lowt emper at ur e c)highhumi dit
y
b) l iqui dext ract ion d) ev apor at i
on b)lowv eloci ty d)lowhumi dity
17. Bat chpr ocessesar eal sost eady–st atepr ocesses 35. _________ ___i sast ageoper ationwher ecomponent sofasol i
d
a) t rue b) f alse c) noanswer phasecanbesepar at edbysel ecti
velydi ssolv i
ngt hesol ublepar
t
18. Equal massesofCH4andH2ar emi xedi nanempt ycont ainer .The ofthesol idwi thanappr opriat esolvent .
par tialpr essur eofhy dr ogeni nt hiscont ainerexpr essedast he a)adsor ption c)equi li
brium st age
fract ionoft ot al pr essur ei s b)electr odi al
y sis d)leachi ng
a)1/ 9 b)½ c)5/ 9 d)8/ 9 36. Balancest hatdescr ibeswhathappensbet weent woi nstantsof
19. Theoper at ionwher et hemechani sm oft ransf eri sequi mol ar ti
me
count er cur rentdi ffusi on a) Di ffer ential balance c) Bat ch
a) Gasabsor pt ion c) Di still
at ion b) I ntegr al bal ance d) Cont inuous
b) Dr ying d) Humi dificat i
on 37. Ther atiooft hedi ff er enceoft her eact anti nputt opr ocessand
20. Rat io oft he mol es ofdesi red pr oductt ot he mol es oft he reactantout putf r
om t hepr ocess,andt her eact anti nputt othe
undesi redpr oductorby -product process.
a) Degr eesofcompl etion c) Sel ectivit
y a)single- passconv er sion c)t wo- passconv ersion
b) Ov er al lconv er sion d) Yi eld b)ov erall conv er si
on d)t otal conv ersion
21. Ref er st ot het emper at ureatwhi chv aporpr essur ei sequalt othe 38. The act ualgas- vapor mi xt uret emper at ure whi ch coul d be
par tial pr essur eofv apor measur edwi that her momet erwhi chi snotf it
tedwi t hawi ck.
 CHEMI
CALENGI
NEERI
NGREVI
EW:CALCULATI
ONS1
a)Wetbul bt emper at ure c)Dr ybul bt emper atur e minut
es,
ther
ateofdrai
ningi
nL/min
b)At mospher i
ct emper at ur e d)Dewpoi nt a)400 b)800 c)32000 d)6400
39. Expr essi onf orr adi oact iv edecay
a)N=NOekt b)N=NOe-kt c)NO=Nekt d)NO=Ne-kt
40. Forbal ancesonat omi cspeci es,whi choft hef ol
lowi ngmat erial
balancei sappl ied?
a) i nput=out put
b) i nput+gener at i
on=out put
c) i nput+gener at i
on=out put+consumpt i
on
d) i nput=out put+consumpt ion
41. Thespeci est ransf erredt ot hel i
qui dphasear er efer
redt oas
solut esor_ ___
a) Adsor bat e c) Adsor bent
b) Absor bat e d) Absor bent
42. Thef ormat ionofsol idpar ticleswi t
hi nahomogeneousphase
a) Cr yst allizat ion c) Di sti
ll
at i
on
b) Dr yi
ng: Car rierGas d) Gasabsor pt i
on
43. Theoper at i
onofr emov ingt heabsor bedsol ut ef rom t hesolvent
a)St rippi ng b)Leachi ng c)Ext ractiond)Adsor pt
ion 52. Inabat chprocess,10000poundsof20%solut
ionofacetonein
44. Itinv ol vest her ev er set r ansf erwher ebywat erv apori str
ansferred waterisdist
il
led.Waterresi
duecontai
ns50l
bacetone,whil
ethe
from t hev aporst atet ot hel iqui dst ate. dist
il
lat
econt ai
ns10% wat er
. Whati st
hetotalweightofthe
a) Humi di f
icat ion c) Absor ption dist
il
lat
e
b) Dehumi di ficat ion d) Cr ystalli
zat ion a)6584 b)1950 c)2167 d)2222
45. Ter mf orat wo- phasemi xtureofmot herliquorandcr yst
als
a)sl ur ry b)mai nl iquor c)magma d)
bagasse
46. Ther at i
ooft heamountofmoi sturecur rent l
yi nt heai randt he
maxi mum moi stur et heai rcoul dhol dbef or econdensat i
on.
a) Rel at i
v ehumi dity c) Humi dit y
b) Per centhumi di ty d) Humi dv olume
47. Bal ancest hati ndi cat ewhati shappeni nginasy stem atani nstant
i
nt ime.
a)Di fferent ial bal ance c) Bat ch
b)I nt egr al bal ance d) Cont inuous
48. Expr essi onf orbact erial growt h
kt -kt
c)NO=Ne d)NO=Ne-kt
kt
a)N=NOe b)N=NOe
49. Awel lknowr eact iont ogener at ehy drogenf rom st eam i stheso
calledwat ergasshi ftr eact i
on:
CO +H2O CO2+H2.
Ifthegaseousf eedt ot her eact orconsi stsof30mol esCO,12
mol esCO2 and35mol esofst eam perhourat8000C.Whi le18
mol esofH2ar epr oducedperhour ,thel i
mi tingr eact antis
53. Humi dai
ratt emper
ature6000Fandat ot
alpressur eof1atm
a)CO b)st eam c)CO2 d)H2 3
passedthroughahumi di
fi
eratt herateof1000f t /mi
n.Ifthe
part
ialpr
essureofwatervaporinairisreducedf r
om 45mm Hg
to10mm Hg.Howmanypoundsofwat erisremov edperhour
?
a)1.09 b)82.
6 c)76.3 d)65.2

50. Int he precedi

ng probl
em,t
he degree ofcomplet
ion oft
he
reactioni
s
a)0. 10 b)0.60 c)0.45 d)0.
80

51. Atanki
sbei
ngdr
ainedt
hroughaholeatthebot
tom.Thev olume
r
emaini
ngi
nthet
ankatagiventimeisdefi
nedbytheequati
on:V
2
=5(100– t
),whereV i
si nli
tersandti nminutes. Af
ter20
 CHEMI
CALENGI
NEERI
NGREVI
EW:CALCULATI
ONS1

56. Topr epar

easol uti
onof50% sul furi
cacid,adi
lutewasteaci
d
contai
ning28.0% sul
furi
cacidisf or
ti
fi
edwi t
hapurchasedaci
d
contai
ning 96.
0% sulfur
ic aci
d. How manyki lograms oft
he
purchasedacidmustbeboughtf ora100kgofdil
uteacid
a)45 b)55 c)65 d)75

54. Woodistobedriedfrom 40%to25%moi

stur
e.What%oft
he
feedwoodi
sthewaterevaporat
ed?
a)80 b)20 c)25 d)60

57. Howmanypoundsofcal cium f l

uorider ockisneededt opr oduce
3000l bsofa60% HFperdayi fthey iel
di s90% andt her ock
contains95%cal cium f luori
de?
55. Themol ef
racti
onofsoluteenter
ingagasabsorberi
s0.25.I
fthe a)4105. 2 b)3694. 7c)3510. 0 d)3900. 0
percentagerecover
yi s75%,thenthemolefract
ionofthesol
ute 58. A solutioncont aining20% w/ w sal tisf et oanev aporatort o
atexitgasstream i
s concent ratet he sal tt o 85%.I ft he wat err emov ed f r
om t he
a)0.0833 b)0.0625 c)0.0769 d)0.1875 processi s800l b/hr,det erminet heamountofpr oductpr oduced
andthef eedrat e.
a) P=256. 86l bs; F=1056. 86lbs
b) P=246. 15l bs; F=1046. 15lbs
c) P=236. 86l bs; F=1076. 86lbs
d) Noneoft heabov e
59. Aslurryoff l
akedsoy beanswei ghing100kgcont ains75kgi nerts
soli
dsand25kgsol utionwi th10%oi land90%bywei ghtsol vent
hexane.Thi ssl urryi scont actedwi th100kgpur ehexanei na
si
nglest agesot hatt hev alueofr etenti
onf ortheout letunder f
low
i
s1. 5kgofi nsol ublesol i
dperkgsol venti ntheadher ingsolution.
Whati st hecomposi tionofunder fl
owl eav i
ngt heext racti
onst age
i
n%bywei ghtoi l?
a)1.5 b)2. 3 c)0.3 d)0. 8
60. Coali smi xedwi thwat ert oform asl ur r
yf ort ransportati
onby
pi
pelines.I f2t ons/ hrofcoalar emi xedwi thwat ert ogiveasl urry
containing50% coalbywei ght,fi
ndt hemass( tons/hr)ofwat er
added.
a) 4 b) 2 c)6 d) 3. 5
61. Asat uratedsol ut i
oncont ai
ning1500kgofpot assium chl or
ideat
360Ki scool edi nanopent ankt o290K.i fthespeci fi
cgr avit
yof
 CHEMI
CALENGI
NEERI
NGREVI
EW:CALCULATI
ONS1
thesol ut ioni s1. 2,t hesol ubi li
tyofpot assi um chl or i
deper100 b) P=836.
15lbs;F=10046.
15l
bs
partsofwat eri s53. 55at360Kand34. 5at290K,cal culatet he c) P=486.
12lbs;F=11260.
76l
bs
amountofcr yst alsobt ained assumi ng t hatl ossofwat erby d) Noneoftheabove
evapor at i
oni snegl igibl e.
a)4301kg b)966kg c)534kg d)1500kg
62. Achemi stat tempt st opr epar esomev erypur ecr yst alsofbor ax,
Na2B4O7• 10H2O, bydi ssol v i
ng100gofNa2B4O7i n200gofboi l
ing
wat er . He t hen car ef ully cool s t he sol ut ion unt il some
Na2B4O7• 10H2O cr y stal lizesout .Cal culat et hegr am ofcr ystals
recov er edper100gofi nitialsol ution,i ft her esi dualsol ut i
onat
55°Caf tert hecr yst alsar er emov edcont ains12. 4%Na2B4O7
a)51. 84 b)100 c)156. 37 d)noanswer
63. A lacquerpl antmustdel i
ver1000 l b ofan 8% ni trocel l
ulose
solut i
on.Theyhav ei n st ocka5. 5% sol ut ion.How much dr y
nitr
ocel l
ul osemustbedi ssol v edi nt hesol utiont of i
lltheor der ?
a)58. 4kg b)2000g c)35. 6l bs d)none
64. Inthepr oduct ionofadr ughav i
ngamol ecul arwei ghtof192,t he
exitst r
eam f rom t her eact orf l
owsatar at eof10. 5L/ mi n.The
drugconcent rat ioni s41. 2%( i
nwat er )
,andt hespeci ficgr avityof
the sol ut i
on i s 1. 024.Cal cul atet he f l
ow r at e oft he dr ug i n
kgmol /mi n.
a)1. 265 b)0. 023 c)0. 562 d)none
65. Inbiol ogi cal sy stems, enzy mesar eusedt oaccel er at et her atesof
certai nbi ol ogi calr eact ions.Gl ucoamy lasei sanenzy met hatai ds
i
nt heconv ersi onofst ar cht ogl ucose.Exper imentshowst hat1
μg molofgl ucoamy lasei na4% st archsol ut ionr esul tsi na
product ionr ateofgl ucoseof0. 6μgmol mL-1-
- mi n-1.Det ermi net he
product ion r at e ofgl ucose f ort hi s sy stem i nt he uni ts of
3
l
bmol /(
f t -day ).
a)0. 0539b)0. 1256 c)0. 6892 d)noanswer
66. Themol arcomposi tionofagasi s10%H2,10%O2,30%CO2 and
ther esti swat er .If50%oft hewat ercondenses,whati st hef inal
mol eper centoft heH2i nt hegasonadr ybasi s?
a) 50 b) 70 c) 25 d) 20
67. Nitri
c aci d( HNO3)t hati s used i ndust rial l
yf ora v ariety of
react ionscanbepr oducedbyt her eact ionofammoni awi t
hdr y
airt oy iel dni tricaci dandwat er .Thepr oductgasf rom such
react orhast hef ollowi ngcomposi ti
on( onawat erf reebasi s):
0.8% NH3,9. 5% HNO3,3. 8% O2 and 85. 9% N2.Det er minet he
percentconv er sionofammoni a.
a)92. 2% b)97. 6% c)99. 8% d)noanswer
68. Whati st hev ol umeofar i
gidt ankt hatcont ai ns15kgofwat erat
95°C,i f10kgoft hi swat eri sl iqui d?Speci ficv ol umeof l i
qui d
wat eri s0. 001040m3/ kgandofv apori s1. 982m3/ kg.
3 3 3
a)8. 56m b)9. 93m c)7. 67m d)noanswer
69. Apr essur egaugei sat tachedandf ixedt oadel iv erypump.The
gauger eads75. 49kPa.I ftheat mospher ici sassumedas10. 8
met er s ofwat er ,det er mi ne t he absol ut e pr essur e ofwat er
pumped.
a)1at m b)6589KPa c)18. 48mH2O d)76. 5KPa
70. Howmuchdoes30l bm obj ectwei ghont hemoon?Gmoon i s5. 47
fts2,
/ expr essansweri nl bm
a)4. 8 b)5. 1 c)5. 9 d)i t’st hesame
71. Asol utionofspeci ficgr av ity1i s35%bywei ghtAandt her estis
B.ift hespeci ficgr av ityofAi s0. 7, whati st hespeci fi
cgr av i
tyof
B?
a)1. 16 b)1. 5 c)1. 71 d)1. 8
72. Youar easkedwhatsi zeofcont ai ner st ouset oshi p1000l bsof
cottonseedoi l( SG=0. 926) .Whatwoul dbet hemi nimum si zeof
drum expr essedi ngal lons?
a)85. 6 b)103. 9 c)129. 5 d)254. 2
73. Robi nheat st hewat ert o70oC.Hewai tsf or10mi n.How much
woul dbet het emper at ur ei fk=0. 056permi nandsur roundi ng
temper at ur eis27oC.
0 0 0 0
a)41. 56C b)41. 96C c)51. 56C d)51. 96C
74. Ar adi oact ivemat erialwasor i
ginal lywei ghed10gr amsandaf ter
6mont hs,onl y1. 7gr amsr emai ns.Whati st hehal f-
lifeoft he
radioact ivemat erial?
a) 1. 3473mont hs c) 2. 3473mont hs
b) 0. 3473mont hs d) 3. 3473mont hs
75. Asl udgecomi ngf rom t hesecondar ysedi ment at i
ont anki sfedt o
adr y ert obedewat er ed.I f9500l b/ hrofwat eri sr emov edf r
om
thesl udge,i ti sf oundt hatt hesl udgewat ercont entf rom 92%
w/ wi schar gedt o10%.Cal culat et hesl udgef eedr ateandt he
amountofdr ysol idspr oduced.
a) P=926. 83l bs; F=10426. 83l bs