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National Institute of Technology Calicut Department of Chemistry

This document provides instructions and questions for an interim online assessment in Physical Chemistry for students of Semester III B. Tech. Chemical Engineering & Engineering Physics. There are 5 questions worth a total of 10 marks related to topics including: [1] Calculating the standard Gibbs free energy change for a chemical reaction given the equilibrium constant; [2] Calculating the cryoscopic constant and freezing point of a solution; [3] Drawing and explaining a labelled tin-lead phase diagram and calculating the eutectic point; [4] Calculating the osmotic pressure of a partially dissociated aqueous solution; and [5] Explaining a three-component phase diagram for the acetic acid-

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49 views1 page

National Institute of Technology Calicut Department of Chemistry

This document provides instructions and questions for an interim online assessment in Physical Chemistry for students of Semester III B. Tech. Chemical Engineering & Engineering Physics. There are 5 questions worth a total of 10 marks related to topics including: [1] Calculating the standard Gibbs free energy change for a chemical reaction given the equilibrium constant; [2] Calculating the cryoscopic constant and freezing point of a solution; [3] Drawing and explaining a labelled tin-lead phase diagram and calculating the eutectic point; [4] Calculating the osmotic pressure of a partially dissociated aqueous solution; and [5] Explaining a three-component phase diagram for the acetic acid-

Uploaded by

Nanditha A
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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National Institute of Technology Calicut

Department of Chemistry
Interim Online Assessment - II
Semester III: B. Tech. Chemical Engineering & Engineering Physics
CY2001D: PHYSICAL CHEMISTRY
Date: 23 November 2020 Time: 4:05 PM-5:00 PM Maximum Marks: 10

Instructions:
a) Answer all questions
b) Write your Name and Registration Number on top of your answer sheet
c) Scan the answer sheet to a single .pdf file and upload by 5.15 PM
*********

1. At 25 °C, Kp for the given reaction is found to be 2.0 x 10-29. Calculate the standard Gibbs
free energy change for the reaction. [2 Marks]

2CO2(g) ⇌ 2CO(g) + O2(g)

2. For D2O, the normal freezing point is 3.82 °C and ΔfusH is 6305 J/mol.

(a) Calculate the cryoscopic constant for D2O.

(b) Find the freezing point of a solution of 0.954 g of CH3COCH3 in 68.40 g of D2O.

[2 Marks]

3. Draw a labelled phase diagram for tin-lead (Sn-Pb) system and explain the curves. How do
you calculate the eutectic point?

[2 Marks]

4. The solute Na2SO4 is 92% dissociated in 1/200 molal aqueous solution at 27 °C. What
would be the osmotic pressure of the solution? [2 Marks]

5. With a phase diagram for three component system, explain the acetic acid-chloroform-
water system at 1 atm. [2 Marks]

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