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Revision Date: 25/03/2015
Print Date: 14/07/15
Product Information
ZAKOL
Acidic Toilet Cleaner/Descaler
Removes limescale, staining and bacteria
Long lasting, fresh fragrance
Powerful and fast-acting
USES
A powerful acidic toilet cleaner designed to descale, deodorise and disinfect.
The thick, blue, pine fragranced formula clings to the toilet bowl and deodorises by removing scale and
killing bacteria, attacking scale and organics even below the waterline.
NB. Not suitable for use on stainless steel.
Ideal for use to remove severe scale and staining from toilets and urinals, Zakol can also be used to
remove algae and slime from walls, patios and paths.
DIRECTIONS
To clean ceramic W.C. bowls and urinals: Apply ZAKOL undiluted to the surface and allow
5 minutes contact time. Agitate heavily stained areas with a toilet brush and then flush
the toilet or urinal.
Use biocides safely. Always read the label and product information before use.
Available Sizes
1L
5L
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Revision Date: 25/03/2015
Print Date: 14/07/15
SAFETY DATA SHEET
ZAKOL
1. IDENTIFICATION OF THE PREPARATION AND COMPANY
Product Name: ZAKOL
Product Code: 501
Company name: Hugh Crane (Cleaning Equipment) Ltd
South Walsham Road, Acle
Norwich NR13 3ES
Telephone: 01493 750072 Fax 01493 751854
Emergency tel: NHS Direct:0845 4647, NHS24:0845 242424, ROI:018092166
Relevant Identified Uses Of The Substance Or Mixture And Uses Advised Against
Use of substance / mixture: PC35: Washing and cleaning products (including solvent based products).
2. HAZARDS IDENTIFICATION
Classification Of The Substance Or Mixture
Classification under CLP: Aquatic Chronic 3: H412;
Skin Corr. 1A: H314
Most important adverse effects: Causes severe skin burns and eye damage. Harmful to aquatic life with long lasting effects.
Label elements:
Hazard statements: H314: Causes severe skin burns and eye damage.
H412: Harmful to aquatic life with long lasting effects.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion
Precautionary statements: P102 Keep out of reach of children.
P282 Wear eye protection.
P280 Wear protective gloves.
P260 Do not breathe fumes.
P301+330+331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P315 Get immediate medical attention.
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P332+313 If skin irritation occurs: Get medical attention.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists: Get medical attention.
P362 Take off contaminated clothing.
Other hazards
PBT: This product is not identified as a PBT/vPvB substance.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient EINECS CAS PBT / WEL CLP Classification Percent
HYDROCHLORIC ACID 231-595-7 - - Skin Corr. 1B: H314 1-10%
STOT SE 3; H335
BIS(2-HYDROXYETHYL)OLEYLAMINE 246-807-3 235301-17-9 - Acute Tox. 4: H302; Skin 1-10%
Corr. 1B: H314;
Aquatic Chronic 1: H410;
Aquatic Acute H400
CETYL TRIMETHYL AMMONIUM 203-928-6 112-02-7 - Acute Tox. 3: H311; <1%
CHLORIDE Skin Corr. 1C: H314;
Eye Dam. 1: H318;
Aquatic Acute 1:H400;
Acute Tox. 4: H302;
Aquatic Chronic : H410
4. FIRST AID MEASURES
Description of First Aid Measures
Skin Contact: Wash immediately with plenty of soap and water.
Eye Contact: Bathe eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Do not induce vomiting. Wash out mouth with water. If conscious, give half a litre of water
to drink immediately. Transfer to hospital as soon as possible.
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Revision Date: 25/03/2015
Print Date: 14/07/15
Inhalation: Remove casualty from exposure ensuring ones own safety whilst doing so. If conscious,
ensure the casualty sits or lies down. If unconscious and breathing is OK place in the
recovery position. Transfer to hospital as soon as possible.
Most Important Symptoms and Effects, Both Acute And Delayed
Skin Contact: There may be irritation and redness at the site of contact.
Eye Contact: There may be irritation and pain.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed/Immediate Effects: Immediate effects can be expected after short term exposure.
Indication of Any immediate Medical Attention and Special Treatment Needed
Immediate/Special Treatment: Eye bathing equipment should be available on the premises.
5. FIRE FIGHTING MEASURES
Extinguishing Media: Water.
Exposure Hazard: In combustion emits toxic fumes of hydrogen chloride/phosgene.
Protect of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
Personal Protection: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side
up to prevent the escape of liquid.
Environmental Precautions: Do not discharge into drains or rivers.
Clean-up Procedures: Transfer to a suitable container.
Reference to Other Sections: Refer to section 8 of SDS.
7. HANDLING AND STORAGE
Precautions for Safe Handling:
Storage Conditions: Store in cool, well-ventilated area. Keep container tightly closed.
Suitable Packaging: Polyethylene.
Specific End Uses: No data available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Hazardous Ingredients
Ingredient State Workplace Exposure Limits Respirable Dust
8 Hour TWA 15 Min STEL 8 Hour TWA 15 Min STEL
HYDROCHLORIC ACIDF 100% UK 1 ppm; 2mg/m3 5 ppm ; 8mg/m3 - -
DNEL/PNEC: No data available.
Exposure Controls
Engineering Measures: Ensure there is sufficient ventilation of the area.
Respiratory Protection: Respiratory protection not required. Gas/vapour filter, type E: sulphur dioxide and other
acid gases (EN141).
Hand Protection: Gloves (acid resistant).
Eye protection: Safety glasses with side-shields
Skin Protection: Acid resistant protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State: Liquid
Colour: Blue
Odour: Pleasant
Evaporation Rate: Moderate.
Oxidising: Non-oxidising (by EC criteria).
Solubility in water: Soluble.
Viscosity: Viscous.
Boiling Point/Range ºC: 100
Melting Point/Range ºC: 0
Flammability limits %: lower: Not applicable.
upper: Not applicable.
Flash point °C: Not applicable.
Part.coeff. n-octanol/water: Not applicable.
Autoflammability °C: Not applicable.
Vapour pressure: Not applicable.
Relative Density: 1.04
pH: 1.2
VOC G/L: 0
Other Information: No data available.
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Revision Date: 25/03/2015
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10. STABILITY AND REACTIVITY
Reactivity: Stable under recommended transport or storage conditions.
Chemical Stability: Stable under normal conditions.
Hazardous Reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Conditions to Avoid:
Materials to avoid:
Hazardous Decomp. Products: In combustion emits toxic fumes of hydrogen chloride/phosgene.
11. TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Hazardous Ingredient Hazard
BIS(2-HYDROXYETHYL)OLEYLAMINE ORAL RAT LD50 300-2000 mg/kg
Relevant Hazards for Substance
Hazard Route Basis
Skin corrosion / irritation DRM Hazardous : Calculated
Serious eye damage / irritation OPT Hazardous : Calculated
Symptoms / Routes Of Exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and pain.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
12. ECOLOGICAL INFORMATION
Toxicity
Hazardous Ingredient Toxicity
BIS(2-HYDROXYETHYL)OLEYLAMINE Algae 72H ErC50 >0.01 – 0.11 mg/l
Fish 96H LC50 >0.1 – 1 mg/l
Daphnia 48H EC50 >0.1 – 1 mg/l
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Mobility: Soluble in water.
PBT Identification: This product is not identified as a PBT substance.
Other Adverse Effects:
13. DISPOSAL CONSIDERATIONS
Disposal of Packaging: Dispose of as normal industrial waste
NB: The users attention is drawn to the possible existence of regional or national regulations.
14. TRANSPORT INFORMATION
Transport Class: This product does not require a classification for transport.
15. REGULATORY INFORMATION
Chemical Safety Assessment: A chemical safety assessment has not been carried out for the substance or the mixture by
the supplier.
16. OTHER INFORMATION
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EC) No
1272/2008
This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
SDS Revision Date: 25th March 2015
Risk phrases used in s.2&3: H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage
resulting from handling or from contact with the above product.
End of Safety Data Sheet.
