D - ECR FILE - CERTIFICATE H&M 2014 - Revised - BASF - MSDS - Helizarin Binder ET ECO

Safety data sheet
Page: 1/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 25.03.2014 Version: 2.4
Product: Helizarin® Binder ET ECO
(ID no. 52618811/SDS_TEX_EU/EN)
Date of print 27.03.2014
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Helizarin® Binder ET ECO

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: auxiliary / finishing agent for the textile industry
1.3. Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Textile Chemicals
Telephone: +49 621 60-58197

E-mail address: [email protected]
1.4. Emergency telephone number
International emergency number:

Telephone: +49 180 2273-112
SECTION 2: Hazards Identification
2.1. Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP]
No need for classification according to GHS criteria for this product.
According to Directive 67/548/EEC or 1999/45/EC

Page: 2/12
Possible Hazards:
No particular hazards known.
2.2. Label elements
Globally Harmonized System, EU (GHS)
The product does not require a hazard warning label in accordance with GHS criteria.
According to Directive 67/548/EEC or 1999/45/EC
EEC Directives
The product does not require a hazard warning label in accordance with EC Directives.
2.3. Other hazards
According to Regulation (EC) No 1272/2008 [CLP]
High risk of slipping due to leakage/spillage of product.
SECTION 3: Composition/Information on Ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Chemical nature
polyacrylate, anionic surfactants, in water
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
2,2'-oxybisethanol; diethylene glycol

Content (W/W): 1 % - 2 % Acute Tox. 4 (oral)
CAS Number: 111-46-6 STOT RE (Kidney) 2
EC-Number: 203-872-2 H302, H373
REACH registration number: 01-
2119457857-21
INDEX-Number: 603-140-00-6
Hazardous ingredients
according to Directive 1999/45/EC
Page: 3/12
2,2'-oxybisethanol; diethylene glycol

Content (W/W): 1 % - 2 %
EC-Number: 203-872-2
REACH registration number: 01-2119457857-21
INDEX-Number: 603-140-00-6
Hazard symbol(s): Xn
R-phrase(s): 22
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth and then drink plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
Further important symptoms and effects are so far not known.
Hazards: No hazard is expected under intended use and appropriate handling.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam
Page: 4/12
5.2. Special hazards arising from the substance or mixture
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
5.3. Advice for fire-fighters

Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.
SECTION 6: Accidental Release Measures

High risk of slipping due to leakage/spillage of product.
6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective clothing.
6.2. Environmental precautions

Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. After long storage, slight
quantities of carbon monoxide may be formed. To our best knowledge, the occupational exposure
limit (OEL) is not exceeded during use. Entering of tanks must only be performed after intensive
cleaning and when it is ensured that residual vapours have been removed. Consideration of national
laws and international standards for confined space entry should be taken in to account. In case of
doubt, the concentration of Carbon monoxide must be determined.
Protection against fire and explosion:

No special precautions necessary.
7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep container tightly closed and in a cool place.
Storage stability:
Storage temperature: 0 - 40 °C
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Protect from temperatures below: 0 °C
Protect from temperatures above: 40 °C
7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters
Components with occupational exposure limits
630-08-0: carbon monoxide
8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for
solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is recommended.
SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Form: liquid
Colour: slightly milky, cloudy
Odour: product specific
Page: 6/12
Odour threshold:
No applicable information available.
pH value: 7-9
(20 °C)
(measured with the undiluted
substance)
solidification temperature: approx. 0 °C
Boiling range: approx. 100 °C
Flash point: > 100 °C (DIN 51758)
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.
Flammability: not self-igniting
Lower explosion limit: 1.8 %(V) (air)
(20 °C)
Information applies to the solvent.
Upper explosion limit: 12.2 %(V) (air)
(20 °C)
Information applies to the solvent.
Ignition temperature: > 200 °C (DIN 51794)
Vapour pressure: 150 mbar
(50 °C)
Density: 1.03 g/cm3
(20 °C)
Solubility in water: dispersible
Partitioning coefficient n-octanol/water (log Kow):
Study scientifically not justified.
Self ignition: not self-igniting
Thermal decomposition: No decomposition if used as directed.

Viscosity, dynamic:
not determined
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
9.2. Other information
Self heating ability: It is not a substance capable of

spontaneous heating.
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Page: 7/12
Corrosion to metals: No corrosive effect on metal.
10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions

No hazardous reactions when stored and handled according to instructions.
10.4. Conditions to avoid

Temperature:
Avoid heat.
10.5. Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
10.6. Hazardous decomposition products
Hazardous decomposition products:

carbon monoxide
The mentioned substances/groups of substances may be released after prolonged storage.
SECTION 11: Toxicological Information

11.1. Information on toxicological effects
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 5,000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (Draize test)
Serious eye damage/irritation rabbit: non-irritant (Draize test)
Respiratory/Skin sensitization
Assessment of sensitization:
Based on the ingredients, there is no suspicion of a skin-sensitizing potential.
Germ cell mutagenicity
Assessment of mutagenicity:
Based on the ingredients, there is no suspicion of a mutagenic effect.
Page: 8/12
Carcinogenicity
Assessment of carcinogenicity:
The whole of the information assessable provides no indication of a carcinogenic effect.
Reproductive toxicity
Assessment of reproduction toxicity:

Based on the ingredients, there is no suspicion of a toxic effect on reproduction.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:

Based on our experience and the information available, no adverse health effects are expected if
handled as recommended with suitable precautions for designated uses. The product has not been
tested. The statement has been derived from the properties of the individual components.
Aspiration hazard
No aspiration hazard expected.
Other relevant toxicity information
The statement was derived from products of similar composition.
SECTION 12: Ecological Information

12.1. Toxicity
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Leuciscus idus
Microorganisms/Effect on activated sludge:

> 1,000 mg/l (DEV-L2)
Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations.
12.2. Persistence and degradability
Assessment biodegradation and elimination (H2O):

The product can be virtually eliminated from water by abiotic processes e.g. adsorption onto
activated sludge.
Elimination information:
> 70 % DOC reduction (OECD 303A; ISO 11733; 92/69 EEC,V, C.10) Easily eliminated from water.
12.3. Bioaccumulative potential
Assessment bioaccumulation potential:

Significant accumulation in organisms is not to be expected.
Page: 9/12
Discharge into the environment must be avoided.
12.4. Mobility in soil
Assessment transport between environmental compartments:

No data available.
12.5. Results of PBT and vPvB assessment
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria.
12.6. Other adverse effects
The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.
12.7. Additional information
Sum parameter
Chemical oxygen demand (COD): 860 mg/g
Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.
Other ecotoxicological advice:

Do not release untreated into natural waters. The product has not been tested. The statement has
been derived from the properties of the individual components.
SECTION 13: Disposal Considerations
13.1. Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
Observe national and local legal requirements.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Page: 10/12
SECTION 14: Transport Information
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
RID
user
Inland waterway transport

ADN
user
Transport in inland Not evaluated
waterway vessel:
Sea transport
IMDG
Page: 11/12
user
Air transport
IATA/ICAO
user
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.
14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.
14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.
14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
Page: 12/12
SECTION 15: Regulatory Information
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.2. Chemical Safety Assessment
Chemical Safety Assessment not yet performed due to registration timelines
SECTION 16: Other Information
Assessment of the hazard classes according to UN GHS criteria (most recent version):
Information on intended use: This product is of industrial quality and unless otherwise specified or
agreed intended exclusively for industrial use. This includes the mentioned and recommended
usage. Any other intended applications should be discussed with the manufacturer. In particular this
concerns the application for products that are the object of special standards and regulations.
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xn Harmful.
22 Harmful if swallowed.
Acute Tox. Acute toxicity
STOT RE Specific target organ toxicity — repeated exposure
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

SECTION 1: Identification of the substance/mixture and of the

Helizarin® Binder ET ECO

1.3. Details of the supplier of the safety data sheet

Telephone: +49 621 60-58197

1.4. Emergency telephone number

International emergency number:

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

No need for classification according to GHS criteria for this product.

According to Directive 67/548/EEC or 1999/45/EC

2.2. Label elements

Globally Harmonized System, EU (GHS)

According to Directive 67/548/EEC or 1999/45/EC

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

High risk of slipping due to leakage/spillage of product.

SECTION 3: Composition/Information on Ingredients

polyacrylate, anionic surfactants, in water

Hazardous ingredients (GHS)

2,2'-oxybisethanol; diethylene glycol

2,2'-oxybisethanol; diethylene glycol

SECTION 4: First-Aid Measures

On contact with eyes:

Further important symptoms and effects are so far not known.

Hazards: No hazard is expected under intended use and appropriate handling.

SECTION 5: Fire-Fighting Measures

5.3. Advice for fire-fighters

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and Storage

Protection against fire and explosion:

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

SECTION 8: Exposure Controls/Personal Protection

Components with occupational exposure limits

630-08-0: carbon monoxide

8.2. Exposure controls

General safety and hygiene measures

SECTION 9: Physical and Chemical Properties

Thermal decomposition: No decomposition if used as directed.

9.2. Other information

Self heating ability: It is not a substance capable of

SECTION 10: Stability and Reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

Hazardous decomposition products:

SECTION 11: Toxicological Information

Serious eye damage/irritation rabbit: non-irritant (Draize test)

Germ cell mutagenicity

Assessment of reproduction toxicity:

Assessment of repeated dose toxicity: