Revised Procedural Manual On Hazardous Waste Management (Revised DAO 04-36) I CONTENTS Chapter Page PDF
Revised Procedural Manual On Hazardous Waste Management (Revised DAO 04-36) I CONTENTS Chapter Page PDF
Revised Procedural Manual On Hazardous Waste Management (Revised DAO 04-36) I CONTENTS Chapter Page PDF
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CONTENTS
Chapter Page
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Revised Procedural Manual on Hazardous Waste Management
(Revised DAO 04-36)
Appendices
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FOREWORD
This Revised Procedural Manual seeks to collate and streamline the existing
rules and regulations on the regulation of Hazardous Wastes. Its main
objectives are to:
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Regulations of Republic Act 6969
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Unless otherwise specified, the following terms shall have the meaning
provided for in this Procedural Manual:
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initiating necessary response activities to minimize the impacts of the
hazardous materials spill or release to the environment
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m. “Flammable Liquids” are any liquid having a flash point below 37.8oC,
except any mixture having components with flash points of 37.8oC or
higher, the total of which make up 99 percent or more of the total
volume of the mixture
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s. “Ignitable Liquid” is any liquid with a flash point of not more than
60oC, closed-cup test or 65.6oC, open cup test
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Infectious Substances Affecting Humans, and Etiologic Agent.
y. “Infectious Waste” is a type of biomedical or health care waste
suspected to contain pathogens (bacteria, viruses, parasites or fungi)
in sufficient concentration or quantity to cause disease in susceptible
hosts
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hh.“Poisonous Substances” are materials other than gas that are known
to be so toxic to humans as to afford a hazard to health during
transportation, or which in the absence of adequate data on human
toxicity is presumed to be toxic to humans because it falls within any
one of the following categories:
• Oral Toxicity. A liquid with an LD50 for acute oral toxicity of
not more than 500 mg/kg or a solid with an LD50 for acute
oral toxicity of not more than 200 mg/kg
• Dermal Toxicity. A material with an LD50 for acute dermal
toxicity of not more than 1,000 mg/kg
• Inhalation Toxicity: A dust or mist with an LC50 for acute
toxicity on inhalation of not more than 10 mg/L
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ww.“Special Wastes” Special wastes shall refer to household hazardous
wastes such as paints, thinners, household batteries, lead-acid
batteries, spray canisters and the like. These include wastes from
residential and commercial sources that comprise of bulky wastes,
consumer electronics, white goods, yard wastes that are collected
separately, batteries, oil, and tires. These wastes are usually handled
separately from other residential and commercial wastes.
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concentration > 5 mg/L based on
analysis of an extract
Lead compounds Includes all wastes with a total Pb D406
concentration > 1 mg/L based on
analysis of an extract
Mercury and mercury Includes all wastes with a total Hg D407
compounds concentration > 0.1 mg/L based on
analysis of an extract. These also
includes organomercury compounds.
Refer to CCO.
Fluoride and its Includes all wastes with a total F D408
compounds concentration > 100 mg/L based on
analysis of an extract
E: Reactive Chemical Wastes
Oxidizing agents Includes all wastes that are known to E501
contain oxidizing agents in concentration
that cause the waste to exhibit any of the
following properties:
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chemicals detonation
subject to aorstrong
explosive reaction
initiating when
source or
when heated under confinement, or 2)
capable of detonation or explosive
decomposition at a temperature of 20oC
and Pressure of 1 atm.
Highly reactive Includes all other wastes that exhibit any E599
chemicals of the properties described for D501,
D502, and D503.
F: Inks/Dyes/Pigments/Paint/ Resins/Latex/Adhesives/Organic Sludge
Solvent based Includes all solvent based wastes that F602
also meet one or more of the sub-
categories
Inorganic pigments Includes all wastewater treatment sludge F603
from the production of inorganic
pigments
Ink formulation Includes all solvent washings and sludge, F610
caustic washings and sludge or
wastewater and sludge from cleaning of
tubs and equipment used in the
formulation of ink from pigments, driers,
soaps, and stabilizers containing
Chromium and Lead.
G: Waste Organic Solvent
Halogenated organic Includes the ff. spent halogenated G703
solvents solvents:
Tetrachloroethylene, trichlororethylene,
methylene chloride, 1,1,1,
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categories listed
chemicals M504inand
theM505, andChemical
Priority the
List.
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Description
Household waste such as garbage under RA 9003
Industrial and commercial wastewaters which are disposed of on-site
through the sewerage system
Industrial and commercial solid wastes which do not contain hazardous
wastes as identified in Table 2.1
Materials from building demolition except asbestos
Septic tank effluents and associated sullage wastewaters
Untreated spoils from mining, quarrying and excavation works but not
materials in the nature of tailings, commercially treated materials and mine
facility consumables
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In general, waste generators are classified into large and small depending on
the volume and type of waste generated as prescribed in Table 3.1.
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quantity generators. Table 3.2 summarizes the compliance requirements for
large and small quantity generators.
b. Register online and disclose to the Department the type and quantity
of waste generated, submit all the required documentary
requirements, and pay the prescribed fee to the EMB Regional Office
having jurisdiction over the waste generator
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Compliance Requirements
Large quantity
Yes Full time Quarterly Yes 1 year Yes Yes
generators
Small quantity
Yes Part-time Annual Yes 3 years Yes Yes
generators
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Draft: Not for quotation or distribution
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d. Implement proper waste management from the time the wastes are
generated until they are rendered non-hazardous by complying to the
Hazardous Waste Storage and Transport Requirements (Chapters 6
and 7 of this Procedural Manual)
Top management of waste generator shall designate a full-time PCO that will
be responsible for the day-to-day management of wastes generated in the
facility. The designated PCO shall have the appropriate competency to
manage wastes, be in the form of education, experience, and/or training.
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management requirements:
1. Waste Storage Requirements
Waste generator shall comply with the storage and handling requirements
as specified in Chapter 6 of this Procedural Manual
2. Pre-Transport Requirements
Waste generator whose wastes are transported outside its premises shall
comply with the packaging and labeling requirements appropriate to the
wastes being transported. In addition, waste generator shall prepare a spill
response plan specific to the wastes being transported. The spill
response plan includes the following instructions to the waste transporter in
the event of an accident:
Waste generator shall give a copy of the spill response plan to the
designated waste transporter and ensure that waste transporter personnel
understood the plan. Moreover, waste generator shall ensure that the
designated waste transporter has the necessary spill response equipment as
indicated in the spill response plan prepared for the wastes being
transported.
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Before wastes are transported, waste generators shall ensure that the risk of
untoward incident during transport is minimized through the following pre-
transport requirements.
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Waste generator must ensure that their personnel working directly with
hazardous wastes are properly trained in accordance with Chapter 9 of this
Procedural Manual.
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If the applicant meets the requirements, the EMB shall issue DENR
Transporter Accreditation I.D. Number and automatically include the
applicant in the Hazardous Waste Transporter Register within the
Hazardous Waste Manifest System. The applicant will likewise receive
USERNAME and PASSWORD that will be used in accessing the Online
Hazardous Waste Manifest System.
b. Ensure that its duly authorized driver keeps the following in the
vehicle at all times during transport:
▪ Printed and duly signed Hazardous Waste Manifest
Acknowledgement Letter from EMB Regional Office
▪ Emergency response plan specific to the wastes being
transported
▪ Emergency response equipment such as pigs, booms, fire
extinguishers, oversized drums for holding defective
drums, personal protective equipment (PPE), etc.
▪ Communication equipment
▪ Approved route from waste generator to TSD facility
clearly indicating the plan to avoid densely populated
areas, watershed or catchments areas, and other
environmentally sensitive areas
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e. Not have any exposed spark producing metal inside, which could
come in contact with wastes that have explosive properties
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▪ Fittings
▪ Bolts
▪ Nuts
▪ Closures
▪ Fastening systems
▪ Pressure relief devices
▪ Thermal protection systems
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These information must be marked on each side and each end of the
vehicle.
Waste transport vehicles must have a secured and designated facility for
parking when not in use. At a minimum, the facility must include:
a. Bund wall to protect any accidental spills from going down the
drain;
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One month before the expiration date of the DENR Transporter I.D.
Number, an email notification will be sent by EMB reminding the waste
transporter to renew accreditation. The waste transporter must complete
online renewal accreditation requirement within the period; otherwise,
the waste transporter will be automatically deleted from the Hazardous
Waste Transporter Register in the Hazardous Waste Manifest System.
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permitted by the Department.
Category Description
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Category Description
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F Facilities that
generated store hazardous
or produced from thewastes, which were not
facility.
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The EMB will conduct inspection at the facility and may require other
data/information in addition to those listed above as part of the review
process.
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The applicant shall likewise be issued an official TSD Permit. The Permit
may either be:
The maximum validity of TSD Permit is one (1) year and this may be
revoked if any requirement is not complied with.
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Existing TSD facility shall within 10 days from the issuance of this
regulation update their registration online. Failure to do so will mean
delisting in the Online Hazardous Waste Manifest System.
One month before the renewal date of the TSD Facility Permit, the TSD
facility shall receive computer generated notification for renewal. The
TSD facility shall then update the registration information and submit
the required documents together with the receipt of payment.
A TSD facility may apply for amendment of a TSD Facility Permit to the
EMB Central Office when it wishes to change any of the following:
a. Waste types that the TSD facility will accept without changes in
treatment process
The TSD facility shall notify the EMB Central Office through the Online
Hazardous Waste Registration System and clearly disclose the intent of
the request for amending the TSD Permit. The EMB Central Office
(through the System Administrator) shall in turn provide access to the
TSD facility for updating the TSD facility’s Accreditation Record. In this
manner, the TSD facility has to go through the same Accreditation
Process (Appendix 1).
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The TSD facility shall reject the waste load if any of the waste acceptance
requirements is in question or not in place. Interim storage at the TSD
facility (that is, storage until the issue is resolved) is not permitted. If
such cases occur, the TSD facility shall immediately inform the EMB
Central Office and the EMB Regional Offices that have the jurisdiction
over the waste generator, transporter, and TSD facility.
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This chapter prescribes the rules and regulations governing proper waste
storage and labeling that must be complied by waste generators,
transporters, and TSD facilities.
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The maximum waste accumulation time is one (1) year, except for wastes
that have no existing infrastructure for proper treatment and disposal.
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Type Content
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6.2 LABELING REQUIREMENTS
a. Minimum size of the label is 20cm x 30cm or readable from five (5)
meters away from the vehicle;
b. Color of the label is yellow for background and black for letters
conspicuously marked in paint or other permanent form of
marking;
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HAZARDOUS WASTE
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The label shall be attached to the side of the vessel, container, or tank. If
the vessel, container, or tank is used repeatedly, the label can be a plate
and hung on the side of the vessel, container, or tank that stores the
wastes. In case of a containment building, all types of wastes contained
in the building should be included in the plate.
• Class 1 – Explosives
• Class 2 – Gases
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• Class 6 – Poisons
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The placard shall be attached to the side of the vessel, container, or tank.
If the vessel, container, or tank is used repeatedly, the placard can be a
plate and hung on the side of the vessel, container, or tank that stores
the wastes. In case of a containment building, all types of hazardous
wastes contained in the building should be included in the plate.
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hazardous wastes shall be required to be:
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d. Used vessel, container, and tank is cleaned before being reused for
storing wastes incompatible with that previously stored
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Waste generator wanting to have its wastes treated shall initiate the Online
Hazardous Waste Manifest System. The waste generator shall log into the
system using the USERNAME and PASSWORD provided for during the
registration process.
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The waste generator shall fill in the necessary information required for in the
system. Once the manifest form is submitted, the waste generator shall
automatically received email notification requiring payment for the manifest
system.
Using the print out notification, the waste generator shall proceed to the
EMB Regional Office to pay the corresponding fees. The Official Receipt (OR)
number is an important requirement before the EMB Regional Office process
the manifest system.
The waste generator shall input the OR number into the manifest system.
The EMB Regional Office shall then evaluate the waste generator Manifest
Application.
Once approved, the EMB Regional Office shall send Notice of Acceptance to
the waste generator as well as to the waste transporter indicated in the
Manifest Application.
Upon receiving the Notice of Acceptance, the waste transporter shall log into
the system using the USERNAME and PASSWORD provided during the
accreditation process. The waste transporter shall fill in the required
information and submit online.
The EMB Regional Office shall then evaluate the Transporter Manifest Form
and, upon approval, issue the Hazardous Waste Manifest Acknowledgement
Letter, which authorizes the waste transporter to pick up and transport
wastes from the waste generator to the TSD facility indicated in the Manifest
Form. The waste transporter is required to have the original copy of the
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Within two (2) days upon receipt of the Notice of Acceptance as well as
receipt of the wastes, the TSD facility shall log into the system using the
USERNAME and PASSWORD provided during the accreditation process.
The TSD facility shall fill in the required information and submit online,
clearly specifying the exact date the wastes are received from the waste
transporter indicated in the Manifest Form.
Within 30 days from receipt of the wastes, the TSD facility shall fill in the
required portion in the Manifest Form, and issue the Certificate of
Treatment (COT).
The EMB Regional Office shall then evaluate the Treater Manifest Form and,
upon approval, issue Acceptance Letter and close-out the Manifest Form.
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a. Type of emergencies
b. Scenario
d. Response Organization
f. Evacuation route
i. Response equipment
k. Decontamination process
The Response Plans shall also include process for recovery and clean-up.
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The Training and Awareness Plan shall include training of personnel on the
implementation of the Contingency Program. In addition, it shall include
specific trainings for the members of the Emergency Response Organization.
In cases where actual chemical releases occur and the Contingency Program
has been activated, the organization shall notify EMB within 24 hours of
initiating the Contingency Program. It shall record all response activities
and submit the corresponding Incident Report to EMB.
The organization shall update their Contingency Program and submit the
same to EMB when any of the following occurs:
Absence of the above, the organization shall review the Contingency Program
every three (3) years and submit the same to EMB.
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All waste generators, transporters, and TSD facilities shall train their
personnel and staff on the following:
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▪▪ Proper
Labeling and Placarding
storage
▪ Public participation and risk communication,
▪ Site investigation and remediation,
▪ Siting of waste management facilities
▪ Waste minimization/Cleaner Production
▪ Treatment and disposal technologies
▪ Healthcare waste management
b. Contingency Plan
▪ Types of potential emergencies arising from wastes handling,
storage, and/or treatment and disposal
▪ Emergency preparedness and response including response to
fire, explosion, spill, loss of electricity, evacuation, natural
catastrophes, civil disturbance, war, and other cases of force
majeure.
▪ Health and safety plans
▪ Personnel protective equipment,
▪ Decontamination procedures,
▪ Incident command systems,
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10.1 LEGAL FRAMEWORK
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c. Physical characteristics
d. Chemical characteristics
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Table 10.1 Schedule of Recyclable Materials Containing Hazardous Substances that may be Imported Subject
to the Corresponding Limiting Conditions
1. Scrap Metals a. Scrap and waste containing precious metals All materials under this category should not
and their alloys of: contain radioactive materials such as Cesium
(Cs), Cobalt (Co), Americium (Am), Strontium
- Gold (Sr), lanthanide, actinide and others as
- Platinum (which include iridium, osmium, determined by PNRI.
palladium, rhodium and ruthenium)
- Silver
b. Metal sludges containing precious metals and The alloys or metals do not contain mercury and
all associated metals its compounds.
- Cast iron
- Stainless steels
- Other alloy steels
- Tinned iron or steel
- Tunnings, shavings, chips, milling waste,
fillings, trimmings and stampings
- Scraping
- Used iron and steel nails
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2. Solid Plastic a. Waste parings and scrap of plastics No importation of heterogenous and unsorted
Materials b. polymerized or co-polymerized plastic materials shall be
c. Resins of condensation products allowed.
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4. Used Oil a. Spent oil such as waste oil or oil residues No importation of tanker sludge shall be
allowed; Spent oil shall have no traces of
polychlorinated biphenyls (PCBs)
5. Fly-ash a. Coal-Fired Power Plant Fly-Ash 1. Coal-fired power plant fly-ash containing
Annex I substances in the concentrations
sufficient to exhibit Anne III characteristics
(note the related entry on Basel Convention list
B B205) shall not be allowed for importation.
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The EMB shall, upon receipt of the registration application, determine the
completeness of the submission and coordinate with the concerned Regional
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Office to inspect the recycling/receiving facility. Upon determination that
the applicant has the capability to recycle the imported material in an
environmentally acceptable manner, the EMB shall consider the importer as
“registered”.
The registered importer may proceed with the importation by submitting the
required import applications to the DENR.
The EMB shall process the application by comparing the submission (Form
R-2) against the registered information (R-1). Once the examination is
completed, an IC covering that particular shipment shall be issued to the
importer stipulating the conditions for the importation.
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The procedural flow for the processing of the applications for recyclable
material importation appears as Annex 3.
a. Designate a PCO
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e. Make recyclable materials containing hazardous substances
accompanied by the movement document as provided for in this
Chapter from the point at which a transboundary movement
commences to the point of disposal
g. Require exporter from the country of origin to notify the EMB as per
Basel Convention Notification Form through the Competent Authority
of the exporting countries.
The DENR reserves the right to require the testing and sampling of the
imported recyclable materials at the expense of the importer. Refusal of the
importer to the subject testing and sampling shall result in the immediate
suspension of the Importation Clearance. Testing of imported materials
shall be done by the DENR through its EMB laboratory and/or any of its
duly recognized laboratories.
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b. Designate a PCO
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cover cost for re-import or other measures that may be needed
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12.0 MONITORING
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The EMB Central Office shall serve as the oversight agency and shall resolve
all cases of non-compliance with transport manifest requirements and
appropriate treatment and disposal procedures. It shall also monitor the
importation/exportation of recyclable materials containing hazardous
substances in the country.
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The following shall be prescribed fees for the various activities related to
Hazardous Waste Management.
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Appendix 2
Hazardous Waste Manifest System Process Flow
w/ Incomplete
EMB RO1 Evaluates Requirements EMB RO1 Emails the HW
the Generator Generator Requesting for
Manifest Application Additional Requirements
w/ Complete
Requirements
w/ Incomplete
EMB RO1 Evaluates Requirements EMB RO1 Emails Transporter
the Transporter Requesting for Additional
Manifest Form Requirements
w/ Complete
Requirements
EMB RO1Accepts the Application and Transporter Completes
Issues HW Manifest Acknowledgement Requirements and Submits to
Letter EMB RO1
w/ Incomplete
Transporter Picks-Up the Wastes from EMB RO2 Evaluates Requirements EMB RO2 Emails Treater
the Transporter and Brings it to the the Treater Manifest Requesting for Additional
Treater Form Requirements
w/ Complete
Requirements
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