Part I

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-0.0
INDO GULF FERTILISERS LTD
ISSUE NO. 03 DATE 01.12.03
TITLE : DISTRIBUTION & INDEX REV. NO. 00 DATE 01.12.03
PAGE 01 OF 05
DISTRIBUTION LIST
All controlled copies of WORK INSTRUCTION are approved, controlled and distributed to the
following personnel by Dy. Gen. Manager (TQM & EC) :
S.NO. DESINGNATION COPY NO.
01. DGM (TQM&EC) 1
02 SHIFT IN-CHARGE ( CENTRAL HALL) 2
03. M.R. 3
04. AUDITOR'S COPY 4
PREPARED BY SIGNATURE DESIGNATION Dy. Manager

APPROVED BY SIGNATURE DESIGNATION DGM(TQM&EC)
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WORK INSTRUCTION
Q&EC Q&EC-W-0.0
PAGE 02 OF 05
INDEX
Doc. No. Topic No. of Page
Q&EC-W-0.0 Distribution & Index 5

Q&EC-W-1.0 pH 2
Q&EC-W-1.1 Turbidity 2
Q&EC-W-1.2 Conductivity 2
Q&EC-W-1.3 T.D.S 2
Q&EC-W-1.4 T.S.S 2
Q&EC-W-1.5 Phenolphthalein Alkalinity 1
Q&EC-W-1.6 Total Alkalinity 1
Q&EC-W-1.7 Total Hardness 2
Q&EC-W-1.8 Calcium Hardness 2
Q&EC-W-1.9 Magnesium Hardness 1
Q&EC-W-1.10 Equivalent Mineral Acidity (EMA) 1
Q&EC-W-1.11 Chloride 4
Q&EC-W-1.12 Sodium and Potassium 2
Q&EC-W-1.13 Ammonia 2
Q&EC-W-1.14 Silica 3
Q&EC-W-1.15 Hydrazine 1
Q&EC-W-1.16 Iron Estimation 1
Q&EC-W-1.17 Free chlorine 1
Q&EC-W-1.18 O-phosphate 2
Q&EC-W-1.19 Total Phosphate 2
Q&EC-W-1.20 Measurement of Zinc 2
Q&EC-W-1.21 2
Q&EC-W-1.22 Measurement of Zinc(By Turbidity method) 2
Q&EC-W-1.23 H2S Analysis 2
Q&EC-W-1.24 T.Alk, KHCO3 in G.V Solution 1
Q&EC-W-1.25 Vanadium in G.V Solution 2
Q&EC-W-1.26 Iron in G.V Solution 2
Q&EC-W-1.27 Water & Oil in liquid ammonia 2
Q&EC-W-1.28 Gas Analysis 5
Q&EC-W-1.29 Condensate Analysis 1
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-0.0
PAGE 03 OF 05
INDEX
Q&EC-W-1.30 Glycine & DEA in G.V Solution 3

Q&EC-W-1.31 Ammonia in Urea process samples 2
Q&EC-W-1.32 CO2 & Oxygen by Orsat Method 2
Q&EC-W-1.33 Urea in Urea process Analysis 1
Q&EC-W-1.34 Oil analysis 1
Q&EC-W-1.35 CO2 analysis in Urea Process samples 2
Q&EC-W-1.36 Urea in P-18 1
Q&EC-W-1.37 Dew point By U-Tube 3
Q&EC-W-1.38 Dew point By Instrument. 1
Q&EC-W-2.0 Biuret in Urea Prills. 1
Q&EC-W-2.1 Total Nitrogen in Urea Prill 2
Q&EC-W-2.2 Particle size of Urea prills. 1
Q&EC-W-2.3 Moisture in urea prill 3
Q&EC-W-2.4 Moisture in urea prill ( By oven dry method). 1
Q&EC-W-3.0 Bag analysis 1
Q&EC-W-3.1 Bag Testing ( Sampling) 2
Q&EC-W-3.2 Bag Testing (Inspection) 4
Q&EC-W-3.3 Strength testing 3
Q&EC-W-3.4 Bitumen and lamination 2
Q&EC-W-3.5 Lamination ( Liner) 1
Q&EC-W-3.6 Alkali test for color 1
Q&EC-W-3.7 Stitching thread 1
Q&EC-W-4.0 Glycine 4
Q&EC-W-4.1 Sulphuric acid 2
Q&EC-W-4.2 Vanadium Penta Oxide 3
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-0.0
PAGE 04 OF 05
INDEX
Q&EC-W-4.3 Potassium carbonate 6
Q&EC-W-4.4 Hydrated lime 3
Q&EC-W-4.5 Hydrochloric acid 2
Q&EC-W-4.6 Titrimetric method of Non-ferric Alum 2
Q&EC-W-4.7 Non- Ferric Alum( Gravimetric) 3
Q&EC-W-4.8 Caustic soda lye 2
Q&EC-W-4.9 Tri sodium phosphate 5
Q&EC-W-4.10 Activated carbon 5
Q&EC-W-4.11 Sodiun sulphite 4
Q&EC-W-4.12 Hydrazine hydrate 2
Q&EC-W-4.13 Resin 4
Q&EC-W-4.14 Poly Propylene thread 1
Q&EC-W-4.15 Di-Ethanol amine 4
Q&EC-W-5.0 Reference for analytical procedures 1
Q&EC-W-5.1 Calibration of Gas chromatograph 4
Q&EC-W-5.2 Calibration of Spectrophotometer 3
Q&EC-W-5.3 Calibration of conductivity meter 1
Q&EC-W-5.4 Calibration of Electronic balance 1
Q&EC-W-5.5 Calibration of AAS 1
Q&EC-W-5.6 Calibration of pH meter 2
Q&EC-W-5.7 Calibration of Oxygen meter 1
Q&EC-W-5.8 Calibration of PCO 1
Q&EC-W-5.9 Calibration of Tensile Machine 1
Q&EC-W-5.10 Calibration of Gas Flow meter 1

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-0.0
PAGE 05 OF 05
INDEX
Q&EC-W-5.11 Standardisation of KF Titrator 2
Q&EC-W-5.12 Standardisation of Nephelometer 1
Q&EC-W-5.13 Calibration of Dew point meter 2
Q&EC-W-5.14 Calibration of Wet and Dry Bulb Thermometer 1
Q&EC-W-5.15 Standardisation of 1 N HCl 1
Q&EC-W-5.16 Standardisation of 1N NaOH 1
Q&EC-W-5.17 Standardisation of 0.028 N AgNO3 1
Q&EC-W-5.18 Standardisation of 0.02 N EDTA 1
Q&EC-W-5.19 Standardisation of 0.1 N FAS 1
Q&EC-W-5.20 Standardisation of 0.02N H2SO4 1
Q&EC-W-5.21 Standardisation of 0.1 HYPO 1
Q&EC-W-5.22 Standardisation of Mercuric Nitrate 1
Q&EC-W-5.23 Standardisation of Versine - 100 1
Q&EC-W-6.0 Total Viable count ( TVC) 2
Q&EC-W-6.1 Sulphate reducing Bacteria ) SRB) 2
Q&EC-W-7.0 Sampling 3
Q&EC-W-7.1 Sampling schedule of Ammonia Plant 2
Q&EC-W-7.2 Sampling schedule of Urea Plant 1
Q&EC-W-7.3 Sampling schedule of PP&U Plant 1
Q&EC-F-01 Calibration report of spectrophotometer 1
Q&EC-F-02 Calibration report of Instrument other than 1
spectrophotometer

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.0

TITLE : pH REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PURPOSE
To outline the analytical procedure for measurement of pH.
2 SCOPE
Cooling water, Boiler water, Raw water, DM water and effluent water.
3 REFERENCE
IS-3025: 1964, Instrument instruction manuals.
4 DEFINITION &ABBREVIATIONS
pH is the negative logarithm of Hydrogen ion concentration.

pH = - Log 10 (H+) = Log 10 1/(H+)
pH + pOH = 14
5 WORK INSTRUCTION
Respons-
S.NO. ACTIVITY Ref.Doc./ Related Doc.
ibility (QMS/EMS/
Rec.
OHSMS)
5.1 Instrument / Reagent required. Analyst QMS
EMS
5.1.1 pH Meter
5.1.2 4 pH BUFFER SOLUTION :- Dissolve one tablet of 4 pH
Buffer in 100 ml of DM water.
5.1.3 7 pH BUFFER SOLUTION :- Dissolve one tablet of 7 pH
5.1.4 9.2 pH BUFFER SOLUTION :- Dissolve one tablet of 9.2 pH
5.2 PROCEDURE
5.2.1 ON" the instrument & warm up for at least 30 mins.
SIGNATURE DESIGNATION Dy.Manager
SIGNATURE DESIGNATION DGM(TQM&EC)
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.0
TITLE : pH REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
2 Then calibrate the pH meter as per procedure Q&EC-W-5.6.

3 Wash the electrode with D.M. Water & wipe off the electrode
with tissue paper.
4 Dip the pH electrode in the test solution & shake.
4 Set meter to appropriate range of pH, wait for reading to stabilise.
5 Record reading.
NOTE :-
1 pH electrode should be filled with saturated solution of KCl.
2 After every measurement, pH electrode should be kept in raw
water.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.1

TITLE : TURBIDITY REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PURPOSE
To outline the analytical procedure for measurement of turbidity.
2 SCOPE
Cooling water, Raw water, Soft water and any water.
3 REFERENCE
Instrument instruction manual.
The turbidity is based on a measurement of the light scattering, the characteristics (Tyndal effect)
of the particulate matter in the sample. Determination of the turbidity is accomplished by
measuring the intensity of scattered light at 90 degree to the incident beam is called Nephelometry
while the measurement of intensity of light passing through the solution is called turbiditymetry.
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 Turbidity Meter ( Systronics)
5.1.2 STANDARD TURBIDITY SOLUTION ( 4000 PPM) :-
Dissolve 5 gram of analytical grade hydrazine sulphate in 400 ml
of distilled water. Dissolved 50 gram pure hexamethylene tetra
amine in 400 ml of distilled water. Add both the above solution
in 1.0 litre volumetric flask and make upto the mark with DM
water. It gives the turbidity of the solution 4000 ppm.
5.2 PROCEDURE
5.2.1 Set the "zero" reading on the scale in required range by using
DM water.
5.2.2 Standardise by using appropriate standard and range.
5.2.3 Fill the sample in the cell & placed it in the path of incident light.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.1
TITLE : TURBIDITY REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.2.4 Record the scale reading & calculate the turbidity using the
appropriate range factor.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.2

TITLE : CONDUCTIVITY REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PURPOSE
To outline the analytical procedure for the measurement of conductivity.

2 SCOPE
Cooling water, Boiler water, Raw water, DM water and any water.
3 REFERENCE
Instrument instruction manual.
4 DEFINITION & ABBREBIATIONS
Specific conductance is the conductance at a specified temperature across a column of a liquid 1

cm2 in area 1 cm long and is expressed in Mho/cm.
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1 Instrument / Reagent required. Analyst QMS/EMS
5.1.1 Conductivity meter & conductivity cell
5.2 PROCEDURE
5.2.1 Wash the electrode with DM water.
5.2.2 'Take the sample in a clean beaker and insert the conductivity cell
in it
5.2.3 Now fix the appropriate range.
5.2.4 Select the SET/CAL/READ switch to "SET" and adjust the
"SET 100" control to read "100" on the DPM.
5.2.5 Turn the RANGE switch to extreme clockwise position before dipping
the cell into any unknown conductivity solution.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.2
TITLE : CONDUCTIVITY REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.2.6 Select the SET/CAL/READ switch to "READ" position to read

the Sp. Conductance of the test solution on DPM.
5.3 CALCULATION
CONDUCTIVITY IN MICRO MHO/CM =

6
Scale reading x cell constant x range value x 10
NOTE: Keep the cell in D.M.Water when not in use.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.3

TITLE : TOTAL DISSOLVED SOLIDS. REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
The TDS is determined by evaporations of known quantity of water and weighing the residue.
2 SCOPE :-
Raw water, Cooling water, Drinking water, Effluent water, and any water samples.
3 REFERENCE
IS: 3025 -1964
4 DEFINITION & ABBREBIATIONS

TDS - Total dissolved solid
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 Measuring cylinder, glass beaker, water bath, dessicator, Mettler

balance ( AE - 100/ AE-200).
5.2 PROCEDURE
5.2.1 Take a clean and dry glass beaker. Keep it in a desiccators for
half an hour. Weight the beaker & record. Take 100 ml sample &
pass it through whatman 41 filter paper into the pre-weighed
beaker. Keep the beaker on hot plate and take out when 10-20
ml sample left in the beaker . Place the beaker on water bath and
evaporate to dryness. Wipe water drops outside of the beaker.
Keep the beaker into the desiccators. Weight it as soon as beaker
achieve the room temperature. Repeat drying and weighing till
the weight of the beaker is constant.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.3
TITLE : TOTAL DISSOLVED SOLIDS. REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
S.NO. ACTIVITY Respons- Ref.Doc./ Related Doc.

ibility Rec. (QMS/EMS/
OHSMS)
5.2.2 CALCALUTION :-
TDS in ppm = W x 106 / V
where, W = Weight in gm. of residue obtained,

V= volume of the sample taken.
Note= If oil is present in the sample, remove it from residue by
filtering first with ethanol followed by carbon tetrachloride
before drying at 105oC.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.4

TITLE : TOTAL SUSPENDED SOILD ( T.S.S.) REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
The TSS is determined by filtration of known volume of water and weigh the residue.
2 SCOPE :-
Raw water, Cooling water, Drinking water, Effluent water, and any water samples.
3 REFERENCE
IS: 3025 -1964
4 DEFINITION & ABBREVIATIONS

TSS --Total Suspended Solid
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 Measuring cylinder, glass beaker, water bath, dessicator, Mettler

balance ( AE - 100/ AE-200).
5.2 PROCEDURE
5.2.1 Take 1 piece whatman No. 42 filter paper . Keep it in a
dessicator for half an hour. Weigh the filter paper (W1). Filter
500 ml sample through this filter paper by using gentle suction.
Wash with distilled water and put it in oven at 103 -105 oC for 2-
3 hrs. After drying, put it in dessicator for 1/2 hr and weigh the
filter paper ( W2).

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.4
TITLE : TOTAL SUSPENDED SOILD ( T.S.S.) REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.2.2 CALCULATION :- Analyst

QMS/EMS
TSS in ppm = (W2-W1) x 106
V
Where,
W1 = Initial weight of filter paper.
W2 = Final weight of filter paper after filtration.
V = Volume of the sample taken.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.5

TITLE : PHENOLPHTHALEIN ALKALINITY REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
Acid-alkali based titration
2 SCOPE :-
Cooling water, Raw water, Drinking water and any type of clear water samples.
3 REFERENCES :-
IS: 3025 -1964
4 DIFFINITION & ABBREBIATION :-

5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1 Reagent required. Analyst QMS/EMS

i) Sulphuric acid solution (0.02 N) :-
Take 40 ml of 1N sulphuric acid and dilute upto 2000 ml with
ii) Phenolphthalein Indicator :-
Dissolve 0.1 gm of Phenolphthalein in 60 ml of rectified spirit
and dilute with DM water to 100 ml.
5.2 PROCEDURE :-
Take adequate volume of the sample in a 250 ml philips beaker.
Add 2-3 drops of phenolphthalein indicator and titrate with 0.02
N Sulphuric acid solution till the color changes from pink to
colourless. Note the burette reading ( BR) at the end point.
5.2.2 CALCULATION :-
3
P.Alk as CaCO3 in ppm = BR x N x F x 50 x 10
Sample volume
Where, F = Factor for H2SO4.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.6

TITLE : TOTAL ALKALINITY REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
Acid-alkali based titration
2 SCOPE :-
Cooling water, Raw water, Drinking water and any type of clear water samples.
3 REFERENCES :-
IS: 3025 -1964

5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1 Instruments/Reagent required. Analyst QMS/EMS
Measuring cylinder, class - A burette & pipette, beaker ( Philips -
made)
5.1.1 Sulphuric acid solution (0.02 N) :-

Take 40 ml of 1N sulphuric acid and dilute upto 2000 ml with
DM water. Standardised against Sodium carbonate standard.
5.1.2 Mixed Indicator :-
Dissolve 0.5 gram Bromocresol green and 0.75 gram Methyl red
in 1 litre methanol.
5.2 PROCEDURE :-
Take adiquate volume of the sample in a 250 ml philips beaker. Add
2-3 drops of Mix indicator. Shake well. Titrate with 0.02 N Sulpuric
acid solution untill the colour changes from green to red. Note the
burette Reading (B.R.) at the end point.
5.3 CACULATION :-
3
P.Alk as CaCO3 in ppm = BR x N x F x 50 x 10
Sample volume
Where, F = Factor for H2SO4.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.7

TITLE : TOTAL HARDNESS REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
Complexometric titration with sodium salt of Ethylene Diamine tetra acetate ( EDTA).
2 SCOPE :-
Cooling water, Raw water, Drinking water and any type of water samples.
3 REFERENCES :-
IS-3025
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Measuring cylinder, class A Burette & Pipette and beaker (philips
5.1.1 BUFFER SOLUTION :-
Dissolve 67.5 gram ammonium chloride in 570 ml of ammonium
hydroxide( Sp. gr. 0.92) and dilute to 950 ml with DM water.
Dissolve 0.616 gram Magnesium sulphate ( MgSO4.7H2O) and
0.93 gram of disodium ethylene diamine tetra acetate in 50 ml.of
5.1.2 E.D.T.A SOLUTION (0.02 N) :-
Dissolve 4 gram of disodium ethylene diamine tetra acetate
dihydrate in about 600 ml of DM water. Add 0.86 gram of
NaOH and 0.10 gram of Magnesium chloride ( MgCl2 .6H
make up to 800ml. Standardise against standard calcium chloride
solution ( 1ml =1mg calcium carbonate).
5.1.3 ERIOCHROME BLACK T :-
Dissolve 0.5 gram Eriochrome black T in 100 ml triethanol amine.
5.2 PROCEDURE :-
Take adequate volume of the sample in 250 ml philips beaker.
Add 2 ml buffer solution and mix well. Add 4-5 drops of
Eriochrome black T indicator. Shake well and titrate with 0.02 N
EDTA solution untill colour changes from red to blue. Note the
burette reading (BR) at the end point.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.7
TITLE : TOTAL HARDNESS REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02

OHSMS)
5.3 CALCULATION : Analyst QMS

T. Hardness as CaCO3 ppm.= B.R.x N x Fx 50 x 1000/ V
F - Factor of EDTA
V- Volume of sample taken for titration.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.8

TITLE : CALCIUM HARDNESS REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
Complexometric titration with sodium salt of Ethylene Diamine tetra acetate ( EDTA).
2 SCOPE :-
Cooling water, Raw water, Drinking water and any type of water samples.
3 REFERENCES :-
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

Measuring cylinder, class A Burette & Pipette and beaker (philips
REAGENTS :-
5.1.1 SODIUM HYDROXIDE SOLUTION :-
Dissolve 80 grams sodium hydroxide 500 ml DM water.
5.1.2 E.D.T.A. Solution (0.02 N) :-

Please refer Procedure of Total Hardness
5.1.3 Calcon indicator
5.2 PROCEDURE :-
Take adequate volume of the sample in 250 ml Philips beaker.
Add 2 ml of NaOH solution and mix well. Add 4-5 drops of
calcon indicator. Shake well. Titrate with 0.02 N EDTA
solution until color changes from pink to orchid purple. Note the
burette reading ( B.R.) at the end point.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.8
TITLE : CALCIUM HARDNESS REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.3 CALCULATION :-
Ca-Hardness as CaCO3 ppm = B.R.x N x Factor x 50 x 103
Sample volume
(F= Factor of EDTA)

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.9

TITLE : MAGNESIUM HARDNESS REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
MAGNESIUM HARDNESS
MAGNESIUM HARDNESS = TOATL HARDNESS - CALCIUM HARDNESS

as CaC03 ppm. as CaC03 ppm. as CaC03 ppm.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.10

TITLE : EQUIVALENT MINERAL ACIDITY (E.M.A.) REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
Acid base titration.
2 SCOPE :-
3 REFERENCES :-
5 WORK INSTRUCTION
Respons-
ibility QMS/EMS
Rec.
5.1 Instruments/Reagent required. Analyst QMS

Glass column filled with cation resin, measuring cylinder, Philips
beaker and burette ( class A)
5.1.1 MIXED INDICATOR :-
Dissolve 0.2 gram Bromocresol green and 0.1 gram Methyl red
in 100 ml of methanol.
5.1.2 0.02 N NaOH :-
Weight 2 gram of NaOH dissolve it 1 litre DM water.
Standardise it against potassium hydrogen phthalate.
5.1.3 2N HCl :-Dissolve 363 ml conc. Hydrochloric acid in 1500 ml of
DM water. Make up it 2000 ml with DM water.
5.2 PROCEDURE :-
Take 50 ml of cation resin in a glass column. Back wash the resin
with DM water. Drain the DM water upto the resin surface. Pass
250 ml 2 N HCl at the rate of 3 to 5 ml/min. Rinse the column
with DM water till the effluent pH is achieved near 7.0. Pass
100ml sample at the rate of 3 to 5 ml/min. and throw it.
Again pass 100 ml sample at the rate of 3 to 5 ml/min and
collect it in 250 ml philips beaker. Add 2-3 drops of mixed or
Methyl orange indicator. Titrate it with 0.02 N NaOH.At the
end point colour changes from red to green.
5.3 CALCUTIATION :-
E.M. A as CaCO3 ppm = B.R x N x F x 50 x 1000
ml of sample
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.11

TITLE : CHLORIDE REV. NO. 00 DATE 01.12.03
PAGE 01 OF 04
1 PRINCIPLE :-
Water adjusted to pH 8.30 is titrated with silver nitrate solution in the presence of potassium
chromate indicator. The end point is indicated by persistance of brick red colour of silver
chromate.
2 SCOPE :-
Cooling water, raw water, drinking water, effluent water and any clear water.
3 REFERENCES :-
ASTM (vol-11.01) D-512 page 329
5 WORK INSTRUCTION
OHSMS)
5.1 Instruments/Reagents required. Analyst QMS/EMS

Class A burette and pipette, measuring cylinder, philips beaker.
REAGENTS :-
5.1.1 Potassium Chromate Indicator Solution :-
Dissolve 50 gram of potassium chromate in 100 ml of water and
add silver nitrate untill a slight red precipitate is produced. Allow
the solution to stand, protected from light for at least 24 hrs then
filter the solution to remove the precipitates and dilute to one
5.1.2 Silver Nitrate Standard Solution :-
Disslove 4.791 gm. of silver nitrate in DM water and dilute to
one litre. Standardise the solution using sodium chloride
standard solution of 1 ml = 1 mg of chloride.
5.1.3 Sodium Chloride Standard Solution ( 1ml = 1 mg of chloride) :-
Dissolve 1.649 gram of GR grade sodium chloride previously
dried at 600 oC for one hour, in water and dilute to one litre.
5.2 PROCEDURE :-

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.11
PAGE 02 OF 04
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Take adequate amount of sample in a philips beaker. Adjust the

pH to pH 8.3 by using 0.02N Sulphuric acid or 0.02N Sodium
Hydroxide solution. Add approximately 1.0 ml of potassium
chromate indicator solution and mix well.
Titrate the solution by 0.028 N silver Nitrate solution dropwise
untill a brick red ( or pink) colour persists through out the
5.3 CALCULATION :-
Choride ppm as Cl- = BR x 0.028 x 35.5 x F x 1000

Volume of sample

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.11
PAGE 03 h 04
1 PRINCIPLE :-
When chloride ion is titrated with mercuric ion, the reaction is essentially stoichiometric, since
slightly dissociated mercuric chloride is produced. The end point may be detected with diphenyl
carbazone, which forms a blue violet complex with mercuric ion.
SCOPE :-
Cooling water, raw water, drinking water, effluent water and any clear water samples.
3 REFERENCES :-
ASTM (vol-11.01) D-512 page 329
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

Class A burette and pipette, measuring cylinder, philips beaker.
REAGENTS :-
5.1.1 Mercuric Nitrate ( 0.001N) :-Dissolve 0.171 gram of Mercuric
nitrate in 25 ml water acidified with 0.25 ml of concentrated
nitric acid. Dilute the solution to one litre. Standardise it using
standard chloride solution.
5.1.2 Diphenyl Carbazone Indicator Solution :- Disslove 0.5 gram

of crystalline diphenyl carbazone & 0.05 gram of bromophenol
blue powder in 75 ml of ethyl alcohol & for sharp end point,a
crystal of xylene cyanol FF of 5 mg can be added in the indicator
5.1.3Nitric Acid ( 3 + 997) :- Mix 3 volumes of concentrated Nitric

acid with 997 volume of water.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.11
PAGE 04 OF 04
Respons- Related Doc.
S.NO. ACTIVITY Ref.Doc./
ibility (QMS/EMS/
Rec.
OHSMS)
5.2 PROCEDURE Analyst QMS
Take adequate volume of sample in 250 ml philips beaker. Add

5-10 drops of mix indicator solution and shake well. If a blue
violet or red color developed, add nitric acid drop wise until
colour changes to greenish yellow. Add 1 ml acid in excess then
titrate against 0.001 N mercuric nitrate solution until a blue -
violet colour persists through out the sample.
5.3 CALCULATION :-
Chloride as Cl- ppm. = BR x 0.001 x 35.5 x F x 1000

Volume of sample.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.12

TITLE : SODIUM AND POTASSIUM REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
When a solution containing salts of sodium and potassium is sprayed as a fine mist into a non-
luminous flame which becomes coloured according to the characteristics emission of the metal. A
very narrow band of wavelength corresponding to the element being analysed is selected by a light
filter and allowed to fall on a photo detector whose output is the measure of concentration of the
element.
2 SCOPE :-
Raw water, drinking water, DM water, and any clear water.
3 REFERENCES :-
Is 2488 (P:5) 1976- page-9
4 DEFINITION & ABBREBIATION :-
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Flame Photometer
REAGENTS :-
5.1.1 (1) SODIUM 1000 PPM :-
Dissolve 2.5418 grams of sodium chloride ( Previously dried) in
one litre of DM water.
5.1.2 (2) POTASSIUM 1000 PPM :-
Dissolve1.91 gms of Potassium chloride ( Previously dried) in
one litre of DM water.
5.2 PROCEDURE :-
Aspirate the DM water and adjust the digital to read out "0"
reading. Then aspirate standard sodium / potassium solution of
appropriate range and adjust the digital read out to 100. Now
aspirate the sample and note the reading.
5.3 CALCULATION
Sodium or Potassium = Scale reading x scale conversion factor
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.12
TITLE : SODIUM AND POTASSIUM REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.4 PRECAUTION
5.4.1 Change the LPG tube after six months.

5.4.2 Use match box or flame type igniter for igniting the flame in the Flame Photometer.
5.4.3 Ensure the sample should be transparent.
5.4.4 First we turn off the gas supply of LPG cylinder before switching of the instrument.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.13

TITLE : AMMONIA REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
Ammonium ion react with nessler reagent and form pale yellow colour .
2 SCOPE :-
Effluent water, ammonia process condensate, urea process condensate and any clear water
sample.
3 REFERENCES :-
ASTM (vol-11.01) D-1426 page 258
4 DEFINITION & ABBREVIATION :- Nil
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

Spectrophotometer ( Hitachi 200-20) or Spectronic - 20 , Class
A pipette and Burette.
5.1.1 NESSLER'S REAGENTS :-
Take Vol. flask of 2 lit capacity & dissolve 35 gram Potassium
Iodide in 100 ml distilled water in the flask.
Make saturated solution of mercuric chloride & add it in
Potassium Iodide solution and shake till permanent brown
precipitate appear. Add few drops in excess. Now add 120
grams of Sodium hydroxide,dissolve and make it upto 1 litre
with Ammonia free distilled water. Keep it over night and decant
the clear solution in Reagent bottle.
5.1.2 SODIUM POTASSIUM TARTRATE :-

Dissolve 32 grams KOH and 20 gram sodium potassium tartrate
and make upto one litre.
5.2 PROCEDURE :-

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.13
TITLE : AMMONIA REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Take 2 ml 50% alkaline tartrate in 50 ml volumetric flask. Add Analyst QMS/EMS

suitable amount of sample containing (0.01 to 0.05 mg of
ammonia) in 50 ml volumetric flask. Make upto the volume with
ammonia free water. Add 1 ml. Nessler's reagents, shake well
and wait for 10 minutes. Take the absorbance at 425 nm
wavelength in 10 mm cuvette cell. Run a blank with ammonia
free water using all the reagents.
5.3 CALCULATION :-
Ammonia mg./ lit. = mg of Ammonia x 1000

Vol. of sample
mg of Ammonia = Absorbance x Factor for ammonia.
5.4 PRECAUTION
5.4.1 Use vacuumpet for sampling of ammonical water and for reagents.
5.4.2 During sampling of ammonical water, stand towards the
upstream of the air flow.
5.4.3 Use safety measures before taking the sample.
5.4.4 Use the identified sample bottle and changed after six month.
5.4.5 Ensure that sample should not contain turbidity before taking absorbance.
5.4.6Use potable water for blank as well as makeup purposes in case
of D.M water is contaminated.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.14

TITLE : SILICA ANALYSIS BY AMINO/ F.A.S METHOD REV. NO. 00 DATE 01.12.03
PAGE 01 OF 03
AMINO METHOD
1 PRINCIPLE :- Colorimetric estimation.
It is based on the reaction of soluble silica with molybdate ion to form a greenish yellow complex
which in turns is converted to blue complex by reducing with 1-amino 2-Napthol 4-sulphonic acid.
2 SCOPE :-
Raw water, cooling water, DM water, feed water, boiler water and any other clear water.
3 REFERENCES :-
ASTM (vol-11.01) D-859 page 487
4 DEFINITION & ABBREVIATION :- NIL
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Spectrophotometer , Hitachi 200 - 20 or Spectronic - 20. Class -
A Burette & pipette.
5.1.1 AMMONIUM MOLYBDATE SOLUTION :-
100 gram Ammonium Molybdate, dissolve in hot silica free
water, make up to 1 litre and filter if necessary. Store in a PVC
5.1.2 OXALIC ACID SOLUTION :-
100 gram oxalic acid dissolve in 500 ml warm silica free water,
make up to 1 litre and filter if necessary. Store in PVC bottle.
5.1.3 HYDROCHLORIC ACID SOLUTION :-

Prepare 1:1 Hydrochloric acid solution in silica free water. Store
in PVC bottle.
5.1.4AMINO SOLUTION:-
Dissolve 0.5 gram 1-amino 2-Napthol, 4-sulphonic acid in 50 ml
solution containing 1 gram of sodium sulphite. After dissolving,
add the solution to 100 ml of a solution containing 30 gram
sodium meta bisulphite, make up to 400 ml and store in dark
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.14
PAGE 02 OF 03
5.2 PROCEDURE :-
Take an adequate amount of sample containing 0.005 to 0.025
mg of silica in a 100 ml plastic beaker. Make up to 50 ml with
silica free water. Add 1 ml of Hydrochloric acid solution , shake
carefully . Add 2 ml of ammonium Molybdate solution., mix well
& wait for 5 minutes. Add 2ml oxalic acid solution,mix well, add
2 ml amino solution and mix well. Wait for 10 min. Take
absorbance on Spectrophotometer at 815 nm wavelength in 10
mm cuvett cell. Run a blank with silica free water using all the
reagents.
5.3 CALCULATION :-
Silica ( Mg/liter) = Mg of silica x 1000 / sample volume
Mg of silica = Factor x absorbance for silica.
5.4 PRECAUTIONS
5.4.1 Analysis should be done in fume hood and checked the fume
hood before starting the analysis.
5.4.2 Clean the spectrophotometer and sample beakers after use.

F.A.S METHOD
1 PRINCIPLE :- Colorimetric estimation.
It is based on the reaction of soluble silica with molybdate ion to form a greenish yellow complex
which in turns is converted to blue complex by reducing with Ferrous ammonium sulphate.
2 SCOPE :-
Raw water, cooling water, DM water, feed water, boiler water and any other clear water.
3 REFERENCES :-
ASTM (vol-11.01) D-859 page 487
4 DEFINITION & ABBREVIATION :- NIL
5 WORK INSTRUCTION
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.14
PAGE 03 OF 03
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 AMMONIUM MOLYBDATE SOLUTION :-
50 gram Ammonium Molybdate, dissolve in hot silica free water,
make up to 1 litre and filter if necessary. Store in a PVC bottle.
5.1.2 OXALIC ACID SOLUTION :-
80 gram oxalic acid dissolve in 500 ml warm silica free water,
make up to 1 litre and filter if necessary. Store in PVC bottle.
5.1.3 SULPHURIC ACID SOLUTION :-
Prepare 5 % Sulphuric acid solution in silica free water. Store in
PVC bottle.
5.1.4 F.A.S SOLUTION:-
Dissolve 12 gram F.A.S (A.R. grade) in 1000 ml D.M. water
containing 12 % sulphuric acid and store in dark plastic bottle.
5.2 Procedure:-
Take an adequate amount of sample containing 0.005 to 0.025 mg of silica in a 100 ml plastic
beaker. Make up to 50 ml with silica free water. Add 1 ml of Sulphuric acid solution , shake
carefully . Add 1 ml of ammonium Molybdate solution., mix well & wait for 5 minutes. Add 1ml
oxalic acid solution,mix well, add ml F.A.S solution and mix well. Wait for 10 min. Take
absorbance on Spectrophotometer at 815 nm wavelength in 50 mm cuvett cell. Run a blank with
silica free water using all the reagents.
5.3 CALCULATION :-
Silica ( Mg/liter) = Mg of silica x 1000 / sample volume
Mg of silica = Factor x absorbance for silica.
5.4 PRECAUTIONS
5.4.1 Analysis should be done in fume hood and on the fume hood
before starting the analysis.
5.4.2 Clean the spectrophotometer and sample beakers before and after use.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.15

TITLE : HYDRAZINE REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
It is based on the reaction of Hydrazine with Paradimethyl-aminobenzaldehyde to from yellow
colour complex in acidic medium.(Condensation reaction)
2 SCOPE :-
Boiler feed water and any clear water.
3 REFERENCES :-
ASTM (vol-11.01) D-1385 page 385
4 DIFFINITION & ABBREBIATION :- NIL
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 REAGENTS :-
1. HYDROCHLORIC ACID (1:9) :-
Mix 1 volume of Conc. HCl acid with 9 volume of DM water.
2. P.D.M.A.B. SOLUTION :-
Dissolve 4.0 gram of P-dimethylamino Benzaldehyde in 200ml of
Methyl alcohol and 20 ml of hydrochloric acid. Store in dark
bottle & avoid it from direct sunlight.
5.2 PROCEDURE :-
Take the 5 ml (1:9) Hydrochloric acid solution in a 50 ml
volumetric flask. Add suitable amount of sample (containing
0.002 mg to 0.02 mg of hydrazine). Add 5 ml PDMAB solution.
Make up to 50 ml with DM water and shake it. Wait for 10
minutes. Take the absorbance at 458 nm wavelength using 10
mm cuvette cell. Run a blank with DM water using all the
5.3 CALCULATION:-
Hydrazine( mg/litre) = mg of Hydrazine x 1000 / sample volume
Mg of Hydrazine = Absorbance x factor for hydrazine.
NOTE: Addition of sample in HCl (1:9) should be done rapidly
after opening the cover of bottle.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.16

TITLE : IRON ESTIMATION REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
Method is of T.Iron in the form of Ferrous,it is based on the reaction of Iron with with 1-10
Phenanthroline to form orange - red color complex.
2 SCOPE :-
Raw water, cooling water, G.V. Solution, boiler water and any clear water.
3 REFERENCES :-
Std. method for water and waste water, America
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
5.1.1 BUFFER SOLUTION :
Dssolve 200 grams Ammonium Acetate in 600 ml of DM water.
Add 250 ml of glacial acetic acid, dilute to 1000 ml with DM
water and mix.
5.1.2 HYDROXYL AMINE HYDROCHLORIDE SOLUTION :-
Dissolve 10 gram of Hydroxyl amine hydrochloride in 50 ml
DM water and dilute to 100 ml with DM water.
5.1.3 1-10 PHENANTHROLINE SOLUTION :-
Dissolve 0.10 gram of above in 100 ml of Methanol.
5.2 PROCEDURE
Take suitable amount of sample ( containing 0.01 mg to 0.5 mg or Iron) in a 150 ml beaker. Add
5 ml 1:1 HCl evaporate on hot plate up to dryness,add accurately 1 ml. 1:1 HCl to dissolve
sample. Add 25 ml D.M. water and 10 ml buffer solution shake well. Add 2 ml hydroxyl amine
hydrochloride solution add 2 ml 1-10 phenanthroline solution shake well.Make up to 100 ml with
DM water, shake well wait for 10 minutes. Take absorbance at 515 nm wavelength in 10 mm
cuvett cell.
5.3 CALCULATION :- Iron mg / liter = mg. Iron x 1000
Sample volume
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.17

TITLE : FREE CHLORINE REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
It forms coloured complex with chlorotex.
2 SCOPE :-
Drinking water, cooling water, and any clear water.
3 REFERENCES :-
Method supplied by vendor
4 DEFINITION & ABBREVIATION :-
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Graduated cylinder, Class A pipette.
5.2 PROCEDURE
Pipette 5 ml chlorotex reagents and transfer to 100 ml cylinder.
In another cylinder, measure 50 ml sample & pour this into the
first cylinder. Mix well with the glass stirring rod. Allow to
stand for exactly one minute, compare the color produced with
the table given below :-
OBSERVATION AND CONCLUSIONS :-
COLOR RESIDUAL CHLORINE PPM
(A) White & Milky with a blue. None
(B) Fainty Pink & slightly milky 0.1
(C) Pink 0.2
(D) Red 0.5
(E) Purple 0.6
(F) Blue 1.0
NOTE :- 1) Direct sunlight should be avoided when comparing the colours.
2) It is essential that the volume of chlorotex reagents and water to be accurately measured, and
that the water to be added to the reagent and not vice-versa.
3)Dilute the sample if the blue colour developed.
4)If sharp smell of free chlorine persists in the sample chlorotex will not give colour .For such
cases estimation shall be done by titrimetric.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.18

TITLE : ORTHO PHOSPHATE REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
It is based on the reaction of soluble phosphate with Molybdate ion to form greenish yellow
complex which in turn in converted to a blue complex by reduction with Amino solution.
2 SCOPE :- Cooling water.
3 REFERENCE IS-2488(P-4) 1974
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

5.1.1 Spectrophotometer (Hitachi 200-20 or Spectronic - 20 ) Class A EMS
pipette.
5.1.2 Ammonium Molybdate
Dissolve 48 gms of Amm. Molybdate in about 800 ml DM water & add
2.5 ml Amm. Hydroxide ( Sp.Gr. 0.90). Dilute it to 1 lit with DM water.
5.1.3 Sulphuric Acid ( 37% V/V)

Add 370 ml conc. Sulphuric acid in 600 ml DM water by slow addition
& continuous shaking under cooled water. Finally make up to 1000 ml
with DM water.
5.1.4 Amino Solution
Dissolve in 2000ml of DM Water the following Chemicals in given order
Sodium Sulphite - 37 gms
1-Amino 2-Napthol 4-Sulphonic acid 1 gm
Sodium Metabisulphite 62 gms
Store the solution in amber bottle & keep in cool place.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.18
TITLE : ORTHO PHOSPHATE REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.2 PROCEDURE :-
Take a suitable amount of sample ( containing 0.1 mg to 0.8 mg
of phosphate) in a 100 ml Vol.fask. Add 5 ml. sulphuric acid
solution. Add 5 ml ammonium molybdate solution mix well
.After 5 minutes add 5 ml amino solution & make up to 100 ml
with DM water . Wait for 10 minutes. Take absorbance at 650
nm wavelength using 10 mm cuvette cell. Run a blank with DM
water using all the reagents.
CALCULATION :-
ORTHO PHOSPHATE in ppm = mg of phosphate x 1000
Sample Vol.
mg. Of phosphate = Factor x absorbance
Precaution:
1 Check the Absorbance of the solution exactly after 10 min.

2 Drain the test solution immediately after measurement in the sink.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.19

TITLE : TOTAL PHOSPHATE REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
It is based on the reaction of soluble phosphate with Molybdate ion to form greenish yellow
complex which in turn in converted to a blue complex by reduction with Amino solution.
2 SCOPE :- Cooling water.
3 REFERENCE IS-2488(P-4) 1974
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

5.1.1 Spectrophotometer (Hitachi 200-20 or Spectronic - 20 ) Class A EMS
pipette.
5.1.2 Ammonium Molybdate

Dissolve 48 gms of Amm. Molybdate in about 800 ml DM water & add
2.5 ml Amm. Hydroxide ( Sp.Gr. 0.90). Dilute it to 1 lit with DM water.
5.1.3 Sulphuric Acid ( 37% V/V)

Add 370 ml conc. Sulphuric acid in 600 ml DM water by slow addition
& continuous shaking under cooled water.Finally make up to 1000 ml
with DM water.
5.1.4 Amino Solution

Dissolve in 2000ml of DM Water the following Chemicals in given order
Sodium Sulphite - 37 gms
1-Amino 2-Napthol 4-Sulphonic acid 1 gm
Sodium Metabisulphite 62 gms
Store the solution in amber bottle & keep in cool place.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.19
TITLE : TOTAL PHOSPHATE REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.2 PROCEDURE :-
Take a suitable amount of sample ( containing 0.1 mg to 0.8 mg
of phosphate) in a 500 ml conical flask. Add 0.5 gram potassium
per sulphate or ammonium per sulphate salt. Add 2 ml sulphuric
acid ( 37% v/v). Add 150 ml DM water digest on hot plat up to
25 ml of total volume and cool it. Add 2-3 drops of
phenolphthalein indicator. Neutralise the solution with 4 N
sodium hydroxide solution. Add 5 ml. sulphuric acid solution.
Add 5 ml ammonium molybdate solution mix well. After 5
mintues add 5 ml amino solution & make up to 100 ml with DM
water . Wait for 10 minutes. Take absorbance at 650 nm
wavelength using 10 mm cuvette cell. Run a blank with DM
water using all the reagents.
CALCULATION :-
TOTAL PHOSPHATE in ppm = mg of phosphate x 1000
Sample Vol.
mg. Of phosphate = Factor x absorbance
Organophosphate = Total phosphate - Orthophosphate.
Precaution:
1 Check the Absorbance of the solution exactly after 10 min.

2 Drain the test solution immediately after measurement in the sink.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.20

TITLE : MEASUREMENT OF ZINC REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
ZINC ANALYSIS IN COOLING WATER (By Atomic absorption spectrophotometer)
1 PRINCIPLE:-
Zeeman effect:- When a magnetic field of an appropriate intensity is applied to the atomic vapour
produced in the automizer,the primary line split in to three component, ii(dm=0) and $+- (dm=+-
1) by the zeeman effect. These components 2nd and $+- are linearly polarized light beams parallel
with and vertical to the magnetic field respectively. In the normal zeeman effect, the wave length
of 2nd lines does not shift Therefore, only 2nd lines matches the emission line from the hollow
cathode lamp and the $+- lines are shifted from the emission line.That is :-
i) The resonance emission line (p-ii) of the polarized component is absorbed by the 2nd line of the
atomic vapour.
ii) Since the $+- lines have been shifted, the sensitivity of atomic absorption for the resonance
emission line (p+-) is decreased.
2 SCOPE:-
Cooling water and other clear water samples.
3 REFERENCE
Instrument manual
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
Atomic absorption spectrophotometer (Hitachi Z-8000)
5.2 PROCEDURE:-
On the instrument as per training manual vol.II set its condition
as per condition list provided in the instrument for zinc. Insert
the sample sucker tube in DM water and press start . If reading
of water does not come zero , then press zero. Now insert the
sample sucker tube in standard solution and press start. Note
down its reading (say X).Then insert the sample tube in sample
(To be analysed) and press start, note down the reading (say Y).
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.20
TITLE : ZINC ANALYSIS REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.3 CALCULATION:-
PPM of Zinc = Y x PPM of std. Solution / X
NOTE:
1 Before ignition, the fuel / Oxidant switch must be in stop position prior to opening the gas cylinder
valve.
2 After measurement turn the fuel / oxidant switch to stop and close the main valve of gas cylinder.
3 Before ignition the fuel,open the tap water valve and close after the measurement.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.22

TITLE : ZINC ANALYSIS ( Turbidity method) REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
ZINC ANALYSIS IN COOLING WATER (By Turbidity Method)

1 PRINCIPLE:-
Zinc reacts with potassium Ferro cyanide in acidic medium to yield zincferrocyanide white ppts.
Which is converted by excess of reagent in to less soluble Zinc potassium Ferro cyanide.
REACTION:-
2ZnSO4 +K4[Fe(CN)6]------- Zn2[Fe(CN)6+2K2SO4
3Zn 2 [Fe(CN)6]+K4[Fe(CN)6]-------2Zn3K2[Fe(CN)6]
2 SCOPE:-
Cooling water and other clear water samples.
3 REFERENCE
ASTM ( Vol- 11.01) D-1691 page 535 / IG Method
4 DEFINITION &ABBREVIATIONS Nil
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)
6 N-H2SO4
10% Hydroxyl amine hydrochloride solution
5% Potassium ferro cyanide solution
Zinc standard (5ppm)
Nephlo turbidity meter
5.2 PROCEDURE:-
Take 4 Nos. of 250 ml conical flask A, B, C & D.
In flask A take 50 ml DM water and 5 ml 6N H2SO4 then add 10
ml Hydroxyl amine HCl and 2 ml Potassium Ferro cyanide.
In flask B take 50 ml sample and 5 ml 6N H2SO4 then add 10
ml Hydroxyl amine Hydrochloride.
In flask C take 50 ml sample and 5 ml 6N H2SO4 then add 10
ml Hydroxyl amine hydrochloride and 2 ml Potassium ferro
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.22
TITLE : ZINC ANALYSIS ( Turbidity method) REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
In flask D take 50 ml of 5 ppm Zn std.and 5 ml 6N H2SO4 then add

10 ml hydroxyl amine hydrochloride and 2 ml Potassium ferro
c anide
Wait for 10 minutes for developing the turbidity.
Now set Scale reading "0" by the solution of flask A and there
after 100 by the solution of flask D.
Now check the turbidity of B and C flask's solution.
5.3 CALCULATION :
ppm of Zinc = Scale reading for solution C - Scale reading for
solution B / 20

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.23

TITLE : H2S ANALYSIS REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
It is based on the reaction of hydrogen sulphite with paradimethyl aniline sulphate in presence of
ferric chloride to form blue color complex.
2 SCOPE :-
Natural Gas at R-202 outlet & R-201 inlet.
3 REFERENCE ASTM ( Vol-11.02) D-2913-87 Page 76
5 WORK INSTRUCTION
Respons-
ibility (QMS/EMS/
Rec.
OHSMS)

Spectrophotometer ( Hitachi 20-200 or Spectronic 20). Class-A
pipette, volumetric flask - 100 ml, Gas bubbler ( 250 ml) & Gas
flow meter.
5.1.1 ZINC ACETATE (2%) : Dissolve 20 gram zinc acetate in 600
ml DM water and add 20 ml glacial acetic acid. Make up 1000
ml with DM water.
5.1.2 PARADIMETHYL ANILINE SULPHATE :- Dissolve 0.15
gram of paradimethylaniline sulphate in a mixture of 100 ml
sulphuric acid and 50 ml water.
5.1.3 FERRIC CHLORIDE SOLUTION :-Dissolve 2.70 gram of
ferric chloride in 50 ml conc. Hydrochloric acid and dilute to 100
ml with DM water.
5.2 PROCEDURE :-
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.23
TITLE : H2S ANALYSIS REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
Take 50 ml 2% zinc acetate in 250 ml bubbler, pass sufficient

amount of sample ( approx. 500 litre for R-202 O/L sample and
approx. 30 lit. for R-201 I/L sample). Add slowly 5 ml of
paradimethyl aniline sulphate. Add slowly 1 ml of ferric chloride
and make up 100 ml with 2% zinc acetate solution. Allow the
solution to stand for 20 minutes for color development. Similarly
a blank is prepared using 50 ml of 2% zinc accetate and all other
reagents. Measure color intensity at 740 nm wavelengh.
5.3 CALCULATION :-
Hydrogen sulphite in ppm = Absorbance x F x 22.4 x 1000
34 x lit of gas at NTP

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.24

TITLE : T.Alkalinity, KHCO3 in G.V. Solution REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PRINCIPLE :-
Acid base titration
2 SCOPE :- G.V Solution
3 REFERENCE G.V analytical procedures

4 DEFINITION &ABBREVIATIONS GV - Gimmaro Vetrocoke
5 WORK INSTRUCTION
Respons-
OHSMS)
I) 1N Hydrochloric acid
ii) Phenolphthalein indicator.
iii) Mixed indicator for total alkalinity.
5.2 PROCEDURE :-
Take 2 grams of sample in 250 ml conical flask. Add 25 ml DM
water & 6-8 drops of phenolphthalein indicator. Titrate the
above solution with 1 N HCl and note the burette reading at the
end point, colour change pink to clourless ( pH 8.3). Now add 6-
8 drops of mixed indicator in same solution and titrate further
with 1N hydrochloric acid. At the end point color change from
green to red (pH 4.3). Let burette reading at phenolphthalein end
point is P ml and burette reading at mixed indicator end point is
M ml ( total ml of acid consumed).
5.3 CALCULATION :-
T-alk as K2CO3 % by wt = BR (M)xN x Fx 69.10
10x sample weight
Bicarbonate as K2CO3 % by wt. = (M-2P) x N x F x 69.10
10 x sample weight
CO2 loading = Conc. Bicarbonate as Potassium carbonate
Total alkalinity as Potassium carbonate.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.25

TITLE : Vanadium in G.V Solution. REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
DETERMINATION OF TOTAL VANADIUM
VANADIUM { V+5} AND VANADIUM { V+4)
1 PRINCIPLE :-
The method is based on the oxidation with KMnO4 of the reduced forms of Vanadium and on the
following reduction of V+5 to V+4 by F.A.S Solution.
2 SCOPE :- Vanadium analysis in G.V solution.
3 REFERENCE G.V analytical procedures
4 DEFINITION & ABBREVIATIONS Nil
5 WORK INSTRUCTION
Respons-
OHSMS)
A Total Vanadium
Philips beaker, Class - A burette & pipette, Mettler balance ( AE-
200/PM-200).
5.1.1 0.1 N Potassium permagnate solution :- Dissolve 3.16 gram of

potassium permagnet in 1000 ml of distilled water.
5.1.2 Ferrous ammonium sulphate 0.1 N:- Dissolve 39.2 gram ferrous
ammonium sulphate in 800 ml DM water and add 40 ml conc.
H2SO4. Make up to 1000 ml with DM water.
5.1.3 Conc. Ortho phosphate acid.
5.1.4 Sulphuric acid ( 1:4)
5.1.5 Sodium diphenyl amine sulphonate Indicator - 0.2 %.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.25
TITLE : Vanadium in G.V Solution. REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
5.2 PROCEDURE
Take about 5 gram of sample in 250 ml Philips beaker add 20 ml
1:4 sulphuric acid, add 5 ml ortho phosphoric acid. Add 30 ml
0.1N potassium permagnet or untill a pink color is obtained. Add
2.0 ml in excess,put the above solution on hot plate and heat the
solution at 70-80 oC for two minutes, cool the solution and
ensure that slightly pink colour of KMnO4 is persisting then
titrate the above solution with 0.1 N ferrous ammonium sulphate
upto colorless to neutralise the excess KMnO4. Then add 4-5
drops sodium diphenyl amine sulphonate indicator and titrate
with 0.1 N ferrous ammonium sulphate up to the end point,color
change from blue violet to green.
Record the burette reading of FAS from at colourless to green

colour end point.
5.3 CALCULATION
T.V. As V2O5 % by wt. = BR x 0.1 x F x 91
10 x Sample weight
B Pentavalent & Tetravalent Vanadium
5.1 Instrument / Reagent required.
5.2 PROCEDURE
Take about 10 grams of sample in 250 ml philips beaker, add 20
ml 1:4 sulphuric acid. Add 5 ml orthophosphoric acid , add 4-5
drops sodium diphenyl amine sulphonate, titrate the above
solution against 0.1 N ferrous ammonium sulphate at the end
point, color change from blue violet to green.
5.3 CALCULATION :-
Vanadium V+5 As V2O5 % by wt. = BR x 0.1 x F x 91
10x sample weight
V+4 (%) = T.V.(%) - V+5(%)
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.26

TITLE : Iron in G.V Solution REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PRINCIPLE :-
Colorimetric analysis. It is based on the reaction of Iron with 1-10 Phenanthrolien in acidic
medium to form complex of brick red color.
2 SCOPE :- G.V.Sample.
3 REFERENCE IG Method
5 WORK INSTRUCTION
Respons-
OHSMS)

Conc. HNO3, Pot. Persulphate & other reagents as given in
DOC. NO.Q &EC - W- 1.16.
5.2 PROCEDURE :-
Take 10 gram sample in a beaker, add 2 gram potassium
persulphate . Add 1 ml HNO3 then add 80 ml DM water, digest
the solution on the hot plate and reduce the volume upto 20-30
ml. Cool the solution and dilute to 100 ml by DM water in the
volumetric flask. Then take 10 ml from the aliquate in 100 ml
volumetric flask, add 5 ml 1:1 HCl, add 20 ml Buffer solution
shake well. Add 10 ml Hydroxyl amine hydrochloride solution
and 2 ml 1-10 Phenanthrolein solution shake well. Make up 100
ml with DM water, shake well wait for 10 minutes, take the
absorbance at 515 nm wavelength using 10mm curette cell.
5.3 CALCULATION:-
Iron mg/litre = mg of Iron x 1000
wt of sample
mg of Iron = Factor x absorbance.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.26
TITLE : Iron by AAS REV. NO. 00 DATE 01.12.03
PAGE 02 OF 02
Alternate Method
Respons-
OHSMS)

Atomic absorption spectrophotometer, HCl ( 1:1) & Vol. flask (
100ml).
5.2 PROCEDURE :- Take 10 gram sample in 100 ml beaker, add

10 ml 1:1(HCl) shake it and boil for 1 min on hot plate, cool the
solution & transfer it in 100 ml vol. Flask. Make up to the mark
with DM water. Now check the conc. on AAS using suitable
standard of Fe ( Ref. DOC NO. Q&EC-C-05 for operation &
calibration of AAS)
5.3 CALCULATION:-
Total Fe in ppm = Std. Conc.x sample reading x 100

std. Reading x sample wt.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.27

TITLE : WATER & OIL IN LIQUID AMMONIA REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
1 PURPOSE
Evaporation method.
2 SCOPE All grade of anhydrous ammonia.
3 REFERENCE FCO-1985 PAGE 97 TO 102
5 WORK INSTRUCTION
Respons-
OHSMS)

2000 ml round bottom flask, water bath, funnel, stand and
clamp, glass beaker 100 ml
5.2 PROCEDURE :-
Step-I FOR WATER CONTENTS :-
Thoroughly clean and dry a 2000ml round bottom flask using
acetone. Mark the flask well at the 2000 ml level ( equivalent to
1400 gram liquid ammonia ) clamp the flask on stand. Purge the
sample line well. Take the flask to the sample point and collect
the sample upto the mark with liquid ammonia. Immerse the
flask in a continuous flowing cold water bath and allow the
ammonia to evaporate slowly. When the evaporation is
completed, remove the flask from the stand and remove the
final traces of ammonia with a gentle stream of air dry from
outside of the flask. Measure the residue volume ( X).
Place the flask in a oven at 105 oC -+ 50 oC for 15 minutes to
remove traces of moisture blow out with a gentle stream of air
and allow to cool. Using 10 ml carbon tetrachloride, rinse down
the walls of the flask and swirl to dissolve the oil. Filter the
carbon tetrachloride through whattman No.41 collect the filtrate
into previously weighed glass beaker of 50 ml.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.27
TITLE : WATER & OIL IN LIQUID AMMONIA REV. NO. 00 DATE 01.12.03
PAGE 01 OF 02
Respons-
OHSMS)
Step-II FOR OIL CONTENT :-
Repeat the washing of the flask two or more times with 10 ml
portions or carbon tetrachloride, filter through the filter paper
whattman No. 41 and collect into the same beaker. Evaporate
the combined extracts to dryness on a water bath. Finally dry in
an air oven at 105oC +/- 5oC for 15 minutes. Allow the beaker to
cool in a desiccator. Weight the beaker.
CALCULATION :-
FOR STEP - 01
% of H2O weight = ml. Of residue x 0.890 x 0.872 x 100
ml of sample x 0.682
Where,
0.890 = density of residue at room temperature.
0.684 = decimal equivalent of water content of the residue
contents 31.6 % of ammonia.
0.872 = evaporation factor
0.682 = density anhydrous ammonia at the boiling point at
atmospheric pressure.
or, % H2O by weight = ml of residue in step -1 x 77.8
2000
FOR STEP - 02.
ppm oil = weight different of beaker x 106 x 0.872
2000 x 0.682
where,
0.872 = evaporation factor
0.682 = density of liquid at its boiling point at atmospheric
pressure.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.28

TITLE : GAS ANALYSIS REV. NO. 00 DATE 01.12.03
PAGE 01 OF 05
1 PURPOSE
The gas chromatography is the most useful technique for the separation and estimation of different
components of the gas mixture. The component of the gas mixture are distributed between two
phases ( stationary and mobile phase) depending upon the partition coefficient of the various
components. The mobile phase which passes through the stationary phase, elutes the separated
components one by one. The components in the mobile phase are detected by a detector block and
recorded by a recorder in terms of the variables of the components.
2 SCOPE :-
Gas samples from ammonia plant, urea plant, air and any other gas samples.
3 REFERENCE :- IG method
5 WORK INSTRUCTION
Respons-
OHSMS)
Gas chromatograph ( shimadzu 8A/9A/14B), chromatopack, EMS
CBM-102, bladders, flow meter - silica gel tube.
Generally, we are using Argon and Hydrogen as carrier gases.
The carrier gas flow 46 ml / minutes is adjusted with the help of
a flow meter.
Before the gas sample enters in the absorption columns, it passes
through a column packed with silica gel in order to absorb
moisture of the gas sample. Before injection the gas sample it is
ensured that the knob should be in the fill position. After one
minutes the sample is injected in the carrier gas stream. The
component of the gas mixture are then separated due to the
different absorptive behavior and the peaks are recorded by the
detector of a (MV) recorder after the specific retention time or
by data processor.

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.28
PAGE 02 OF 05
For the analysis of N2, Ar, CO, CH4, CO2 - the carrier gas
Hydrogen is used in TCD column. The different parameters are
used as given below :-
5.2 Instrument / Reagent required.

Carrier Gas = Hydrogen
Carrier Gas flow = 45 ml/min.
Column temperature = 60oC
TCD temperature o
= 90 C
Chart speed = 05 mm/min.
TCD current = 90
mA
5.3 CALCULATION :-
% N2 in converter ( inlet & outlet )

(100 - %NH3) X Height x Width x Sensitivity x 100xF
100 average area of the air peaks.
%N2 ( other than converter ) =
Height x Width x Sensitivity x 100xF
average area of the air peaks.
% CO =
Height x Width x Sensitivity x 100 x Factor
% CH4 =
Height x Width x Sensitivity x 100 x Factor
%H2 = Balance.
NOTE Sensitivity is chosen according to the percentage of the different components in the gas mixture.
For the determination of the Hydrogen content in the gas mixture, Argon is used as a carrier gas.
SIGNATURE DESIGNATION Dy. Manager

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.28
PAGE 03 OF 05
STANDARD OPERATING PROCEDURE
Check carrier gas for TCD/FID and H2 & air for FID
Power 'ON' to the GC,CBM102 & Computer with monitor, to get link O.K.
Switch "ON' the desired detector (TCD/FID)
Switch ON heater button.'ON' the Methaniser button.
Double click on Class GC- 10
Configuration is already feeded & stored.The setting is as under-
Click Configuration
WS
System No. 1 Yes

System No. 2 No
DP1 GC-1
GC system 1 GC list- 14 BPTF

GC -14B
Channel 1Auto save method - NO Click Customize
Line select -1 Inj port- DRI
Temp. Unit- INJ
Detector
Detector 1 ( for FID)
Detector 4 ( for TCD)
Temp Unit - DET
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.28
PAGE 04 OF 05
Data Directory : Default Setting

Ext. Temp Unit - 1 Aux. 3
2
3 None
4
O.K.
Analysis of a gas sample
Analysis of a gas sample can be done if calibration has already been done.
Double click on Real Time Analysis
Method File
Load ( Load desired File ) on which analysis is to be done

Presently two files have made.
1- METHANE .MET ( FOR R-311 O/L)
2- CO2 . MET( FOR B-304 O/L)
GC SETUP
See all parameters
Temp.
Column Oven
Inj Port
Detector
Aux.3 (TCD)* *In FID operation Aux. 3 (TCD) will be 250C as made
in method file already.
SYSTEM ON ( if any change has done in temp. setting. Then SET before
system On.
In case of FID Ignite Flame with lighter by pressing IGNITE button by lowering
air pressure.
SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.28
PAGE 05 OF 05
Go to monitor & see that all the temperatures are maintained. Instrument is showing
ready signal on monitor. INSTRUMENT IS NOW READY FOR ANALYSIS.
SAMPLE LOGIN
Operator Name : Your Name Vial: 1

Sample Name : Sample Amount ( For TCD Air Area)
DATA FILE :Sample Name (For FID 100 as Default Value)
Type : Unknown
IS amount, Inj Volume& Dilution factor are 1 as default value.
Report On/Off as per requirement.
DISPLAY select-
CH -1
CH - Monitor Out line
PEAK REPORT
Set BASE LINE/ LEVEL approaching to zero then FEED THE SAMPLE using CBM start/
stop button on desired channel.( Channel 1 for G.C. 14B & Channel 2 for G.C. 8A)
After completion of analysis the result will display on monitor

SECTION DOCUMENT
WORK INSTRUCTION
Q&EC Q&EC-W-1.29

TITLE : CONDENSATE ANALYSIS. REV. NO. 00 DATE 01.12.03
PAGE 01 OF 01
1 PURPOSE
For the analysis of following condensate i.e.. Deaerator outlet / B-201BD / E-501 BD / B-201-SS
/ E-501-SS.
2 SCOPE Process water
3 REFERENCE
pH refer DOC. No Q&EC-W-1.0
CONDUCTIVITY refer DOC. No Q&EC-W-1.2
SILICA refer DOC. No Q&EC-W-1.14
PHOSPHATE refer DOC. No Q&EC-W-1.18
Hydrazine Refer DOC. No. Q&EC-W-1.15
5 WORK INSTRUCTION
Respons-
OHSMS)
5.1 Analysis shall be carried out as per referred procedures. Analyst QMS


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SECTION DOCUMENT

S.NO. DESINGNATION COPY NO.

01. DGM (TQM&EC) 1

02 SHIFT IN-CHARGE ( CENTRAL HALL) 2

04. AUDITOR'S COPY 4

PREPARED BY SIGNATURE DESIGNATION Dy. Manager

Q&EC-W-0.0 Distribution & Index 5

Q&EC-W-1.30 Glycine & DEA in G.V Solution 3

PREPARED BY SIGNATURE DESIGNATION Dy. Manager

PREPARED BY SIGNATURE DESIGNATION Dy. Manager

INDO GULF FERTILISERS LTD

To outline the analytical procedure for measurement of pH.

IS-3025: 1964, Instrument instruction manuals.

pH is the negative logarithm of Hydrogen ion concentration.

2 Then calibrate the pH meter as per procedure Q&EC-W-5.6.

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

To outline the analytical procedure for the measurement of conductivity.

Instrument instruction manual.

4 DEFINITION & ABBREBIATIONS

Specific conductance is the conductance at a specified temperature across a column of a liquid 1

5.1.1 Conductivity meter & conductivity cell

SIGNATURE DESIGNATION Dy.Manager

5.2.6 Select the SET/CAL/READ switch to "READ" position to read

CONDUCTIVITY IN MICRO MHO/CM =

NOTE: Keep the cell in D.M.Water when not in use.

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

4 DEFINITION & ABBREBIATIONS

5.1 Instrument / Reagent required. Analyst QMS/EMS

5.1.1 Measuring cylinder, glass beaker, water bath, dessicator, Mettler

S.NO. ACTIVITY Respons- Ref.Doc./ Related Doc.

where, W = Weight in gm. of residue obtained,

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

4 DEFINITION & ABBREVIATIONS

5.1 Instrument / Reagent required. Analyst QMS/EMS

5.1.1 Measuring cylinder, glass beaker, water bath, dessicator, Mettler

SIGNATURE DESIGNATION Dy.Manager

5.2.2 CALCULATION :- Analyst

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

4 DIFFINITION & ABBREBIATION :-

5.1 Reagent required. Analyst QMS/EMS

INDO GULF FERTILISERS LTD

4 DIFFINITION & ABBREBIATION :-

5.1.1 Sulphuric acid solution (0.02 N) :-

INDO GULF FERTILISERS LTD

S.NO. ACTIVITY Respons- Ref.Doc./ Related Doc.

5.3 CALCULATION : Analyst QMS

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD

4 DIFFINITION & ABBREBIATION :-

5.1 Instruments/Reagent required. Analyst QMS/EMS

5.1.2 E.D.T.A. Solution (0.02 N) :-

SIGNATURE DESIGNATION Dy.Manager

INDO GULF FERTILISERS LTD