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Construction Materials Science

Baghdad University/Civil Engineering Dept.
1st stage
Lecture No. 1

Construction material science is the engineering object that involved

with the use of construction materials in constructing buildings in a way
that achieve the strength, economy, safety and durability.
This science also search a new suitable materials to be used in
building construction.

Types of building:
1- Lightweight building: such buildings transfer the load of the building by
its bearing walls to the foundation, these buildings consist usually of one or
two floors.
2- Heavy building: these buildings collect the load to the columns, by the
roofs and beams, and transfer this load to the lower floor till the load
reach the foundation and the soil within its bearing capacity , such buildings
called "skeleton building" .

Main factors to be consider in construction:

1- Design a)architectural design

b) civil desing
c) other design such as sanitary, electric
2- Construction materials to conform the specification
3- Construction work

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Mechanical properties of materials:-

Normal stress :
The application of an external force to a body cause internal resisting force
within the body, whose resultant is equal in magnitude but opposite in
direction to the applied force ,the applied force (N or lb) on a body divided
by its area (mm2 or ft2).
σ =P/A
There are many types of stress occurred in the material such as:
1- Compressive strength
2- Shear stress
3- Tensile stress
 Strength: the ability of the material to stand under external load
 Ultimate strength: maximum ability to bear the load after which the
material failed

Engineering strain:
When a member is subjected to a tensile or compressive stress, it
undergoes a deformation ( A ). Tensile force causes an elongation of the
body, while compressive caues a shortening of the dimension of the body
in the direction of the force. The elongation ( or shortening ) per unit length
is called strain ( € ).

 Volumetric Strain: the change in volume divided by the initial volume.

ε =Δv/v
 linear strain: change in length divided by the initial length.
ε= ΔL/L
The major strains are –elastic strain
-plastic strain

Stress-strain relationship:
After testing the specimen, it is necessary to represent the data in the form
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of stress - strain diagram. The stress is defined as the load divided by the
cross sectional area of the specimen at the start of the test. As the test
proceeds, the actual cross sectional area decreases. The stress based upon
the initial area is not the true stress, but it is generally used. The strain used
is the elongation of a unit length of the test specimen taken over the gauge
length. Typical stress - strain diagram are shown in Fig. below:

 Elasticity: the exposed load should be within specific limit named elastic
limit at which material return to its normal state and above this limit called
residue strength .
 Plasticity: opposite to elasticity, it represent the disability of material to
return to its state after the release of the load.
 Modulus of elasticity: It is a measure of the stiffness of the ductile material.
The slope of the initial straight portion of stress -strain diagram represents
the modulus of elasticity or Young's modulus

E= tan θ = Stress/ strain

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Materials properties

They are the properties related with the material behavior under specific
loading, such properties includes:
1- Reduction of area: As the load on the test material is increased, the
original cross sectional area decrease until it is a minimum at the instant of
fracture. It is usual to express this reduction in area as the ratio of the
change in area to the original specimen cross sectional area expressed as a
percentage.

% reduction in area = {(Ao - Af)/ Ao} * 100

Where - Af- Final cross sectional at the point of failure

Aq- Original cross sectional

2- elongation: Percentage of elongation is the measure of the ability of a

material to undergo deformation without rupture. It is a measure of the
ductility of material.

% Elongation = ( Lf- Lq ) / Lq * 100

Where:
Lf - Final length
Lo - Initial length

3- ductility: Is the property of a material of being deformed by stretching

without recovery of shape upon removed of stretching force. Ductility of
metals is ordinarily determined by measuring the elongation and reduction

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of cross sectional area of a tensile strength test specimen. It is deformation
of material before failure, and after removing the load the material return
to its previous state partly or completely. Ductility means change in length
to the initial length, concrete considered as brittle material with strain of
0.003 which represent the maximum ability of concrete and when strain
exceeds 0.005 the material considered as ductile material and less than it
considered as brittle material.

 4- toughness: The resistance to impact. Toughness is also considered to

mean resistance to fracture when the material is deformed above the
elastic limit. It is a measure of the work required to cause fracture to occur.
Toughness related to ability of material to absorb energy until failure

 5-brittleness: Brittleness: opposite to toughness ductility and give

indication for impact resistance or dynamic strain, the deformation and
failure occurs in brittle materials without graduated deformation and called
sudden failure or sudden breakage, example for brittle materials such as:
concrete, glass, brick, wood and gypsum.
It refers to small resistance to sudden blow. A brittle metal breaks
suddenly without appreciable permanent deformation or warning of
approaching failure.

6- Resilience: Is that property of an elastic body by which energy can be

stored up in the body by loads applied to it and given up in recovering it\s
original shape when the loads are removed.
 7-creep, creep curve: the increase in strain under the effect of steady
stress, the amount of creep depend on time , temperature , material state ,
the amount of load and loading period
We have discussed the mechanical properties of materials on room
temperature. Many structures, particularly these associated with energy
conversion, like turbines, reactors, steam and chemical plant operate at
much higher temperature. As the temperature is raised, materials under
loads continuous deformation with time, i.e. start to creep, the strain
instead of depending only on the stress, now depends on temperature and
time also.
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Creep occurs in three stages:

Stage 1 - Primary creep stage
Consist of a short part during which strain increases rapidly
Stage 2 - Secondary creep stage
Consist of a long period where the rate is much slower and constant
Stage 3 - Tertiary creep stage
At this stage the creep rate increases and the material fractures

8-Fracture : this property occurs under failure of material and give

indication to the beginning of failure at which the material is not
structurally effective.

9-Fatigue: weakening in material to resist periodic loading or long time

loading. Fatigue we have considered so far only the strength of material
under static loading. In many structures, repeated loading is applied, and
when a material fails under a number of repeated loads, each smaller than
the ultimate strength, failure in fatigue is said to take place.
The results of fatigue test are represented by a relationship between stress
and number of cycles to failure

 Stiffness: the ability of material to resist the deformation , this property

related to the stress- strain relationship.
 Hardness: the resistance of material to plastic deformation and to abrasion
, scratch and rust.

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Construction Materials Science

Baghdad University/Civil Engineering Dept.
1st stage
Lecture No. 2
Bonding Materials
Material with adhesive and cohesive properties which make it capable to bond
mineral fragments into a compact whole. This definition embraces a large variety of
cementing materials, among them:
1. Gypsum plaster
2. Lime
3. Cement
1. Gypsum plaster :
Gypsum plaster comprise all that class of plastering and cementing materials
which are obtained by partial or complete dehydration of natural gypsum and to
which contain materials that serve as retarders or hardeners, or that impart greater
plasticity to the product, may not have been added during or after calcinations.

1.1 Raw materials - Gypsum rocks:

Pure gypsum is a hydrous lime sulfate (CaSO4. 2H2O), the composition of which
by weight is:

Lime CaO - 32.6%

Lime sulfate
Sulfur trioxide SO3 - 46.5%
Water H2O - 20.9

- 100 %
Total=

Natural deposit of gypsum are very seldom pure, the lime sulphated being
adulterated with silica, alumina, iron oxide, calcium carbonate and magnesium
carbonate. The total of all impurities varies from a very small amount up to a
maximum of about 6%.
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1.2 Manufacture of gypsum plaster:

1.2.1 Process of manufacture:
There operations are involved in the process of manufacturing plaster. Crushing,
grinding and calcinations. Rock gypsum is crushed to fragments about 25mm in
diameter, which are passed through a finishing mill. The grain gypsum is then
calcined in rotary kilns.
1.2.2 Theory of calcinations:
If pure gypsum is subjected to any temperature above 100 °C, but not exceeding
190 °C, three-fourth of the water of combination originally present is driven off:

100-190 °C
CaSO4.2H20 - ► CaS04 .½H2O + 1 ½ H2O

The resultant product is called plaster of Paris (CaSO4. ½ H2O). Plaster of Paris
readily recombines with water to form gypsum, hardening in a very few minutes:
CaSO4. ½ H2O + 1 ½ H2O- ► CaSO4.2H2O

If the gypsum is calcined at temperature much above 190 °C it losses all its water of
combination, becoming an anhydrous sulfate of lime:

T> 190 °C
CaSO4.2H20 - ► CaSO4 + 2 H2O
1.3 Gypsum products:
1.3.1 Plaster of Paris:
Produced by calcinations of pure gypsum, no foreign materials being added either
during or after calcinations.

1.3.1.1 Uses:
a. It is used as a wall plaster in finish coat.
b. It is used as a mortar for masonry construction.
c. It is used for casting ornamental work.

1.3.1.2 Chemical requirements in accordance with Iraqi standard No. 28/1988:

a. The sum of soluble salts expressed as (Na2O+MgO) not more than 0.25% by
weight of plaster.
b. The percentage of chemically combined water should be between 4-9%.
c. The percentage of impurities not more than 5%.
d. The percentage of SO3 not less than 45%
e. The percentage of CaO not less than 30%.
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1.3.1.3 Physical requirements in accordance with Iraqi standard No. 28/1988:

a. Fineness: The percentage retained on 1.18mm sieve not more than 0%.
b. Setting time should be between 8-25 minute.
c. Mechanical resistance: The diameter impression resulted by a dropping ball not
more than 5mm.
d. Compressive strength: Not less than 5MPa for standard cube 50*50*50mm.
e. Modulus of rupture: Not less than 1.5MPa

1.3.2 Ordinary plaster:

It is a hemi hydrate product (CaSO4. ½ H2O), produced by the calcinations of a
gypsum containing certain natural impurities or by the addition to a calcined pure
gypsum of certain materials which serve to retard the set or render the product more
plastic.
1.3.2.1 Uses:
a. It is used as a wall plaster in first coat.
b. It is used as a mortar for masonry construction.
1.3.2.2 Chemical requirements in accordance with Iraqi standard No. 28/1988:
a. The percentage of SO3 not less than 35%.
b. The percentage of CaO not less than 25%.
c. The sum of soluble salts expressed as (Na20+MgO) not more than 0.25% by
weight of plaster.
d. The percentage of chemically combined water not more than 9%.
e. The percentage of loss of ignition not more than 9%
1.3.2.3 Physical requirements in accordance with Iraqi standard No. 28/1988:
a. Fineness: The percentage retained on 1.18mm sieve not more than 8%.
b. Setting time should be between 8-25 minute.
c. Compressive strength: Not less than 3MPa for standard cube 50*50*50mm.

1.3.3 Technical plaster:

It is produced by mixing two types of plaster: Hemi hydrate product (CaSO4 . ½
H2O) and anhydrous product (CaSO4) with 50% for each.

1.3.3.1 Uses:
a. It is used as a wall plaster in first coat.
b. It is used as a mortar for masonry construction.

1.3.3.2 Chemical requirements in accordance with Iraqi standard No. 28/1988:

a. The percentage of SO3 not less than 50%.
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b. The percentage of CaO not less than 27%.
c. The sum of soluble salts expressed as (Na20+MgO) not more than 0.25% by
weight of plaster.
d. The percentage of chemically combined water not more than 9%.
e. The percentage of loss of ignition not more than 9%

1.3.3.3 Physical requirements in accordance with Iraqi standard No. 28/1988:

a. Fineness: The percentage retained on 1.18mm sieve not more than 5%.
b. Setting time should be between 12-20 minute.
c. Compressive strength: Not less than 6MPa for standard cube 50*50*50mm.
d. Modulus of rupture: Not less than 2MPa
e. Mechanical resistance: The diameter impression resulted by a dropping ball not
more than 5mm.

1.3.4 Anhydrous plaster:

It is produced by the complete dehydration of gypsum, the calcinations being carried
on at temperature exceeding 180 °C. It has low solubility in water compared with
ordinary plaster, thus certain material can be added during the grinding process to
increase its ability to react with water.

1.3.4.1 Uses:
a. As wall plaster in all coats.
b. It is used as a mortar for masonry construction.

1.3.5 Keen cement:

It is anhydrous plaster produced the calcinations, at a red heat or over, of gypsum
to which certain substances, usually (Al2(SO4).2-18H2O ) had been added.

1.3.5.1 Properties:
a. Its set is extremely slow, usually between 1-7 hours.
b. It gains in strength very gradually, but ultimately attains a great degree of hardness
and a strength exceeding that of any ordinary gypsum plaster.
c. Its plasticity is high.
d. Its resistance to water is higher than ordinary plaster.

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1.3.5.2 Uses:
a. It is used as a wall plaster in finishing coat and comers.
b. It is used as a wall plaster in areas exposed to moisture instead of cement and
lime.

1.4 Properties of gypsum plasters:

1.4.1 Setting and hardening:
The term "setting" is meant the initial loss of plasticity, whereas "hardening"
means the subsequent gain in strength and in ability to resist indentation or abrasion.
The setting of plaster of Paris and other gypsum plasters is a process recombination
of the partly or totally dehydrated lime sulfate or gypsum.

1.4.2 Percentage of water in plaster:

The water-plaster ratio is greatly affecting the strength of plaster. The higher the
water plaster ratio, the greater are the plasticity and flow ability of plaster, but when
it exceed the optimum value, part of water remain between paste particles and tends
to pull the particles apart, reducing the cohesion between them and
between the plaster and building units and leading to a reduced strength
and durability.

1.4.3 Condition of setting:

The strength of plaster drops to a large degree when the plaster remains wet for a
long period exceeding 3-days after setting. The reason is due to decomposition of
some of plaster crystals in water, leading to reduced chemical adhesion.

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Construction Materials Science

Baghdad University/Civil Engineering Dept.
2012-2013/1st stage
Lecture No. 3
2. Lime :
2.1 Definition and classification:
2.1.1 Quick lime:
Is the name applied to the commercial form of calcium oxide CaO, obtained by
the calcinations of a stone in which the predominating constituent is calcium
carbonate CaCOs, often replaced, to a greater or less degree by magnesium
carbonate MgCOs, this product being one that will slake on the addition of water.

2.1.2 Hydrated lime:

Is quick lime has been chemically satisfied with water during manufacture.
2.2 Raw materials - Lime stone rocks:
Pure lime stone rocks consist entirely of CaCOs. Pure calcium carbonate consists of
56 parts by weight of CaO to 44 parts of CO2.
Lime stones encountered in practice depart more or less from this theoretical
composition. Part of the lime is almost always replaced by a certain percentage of
magnesia MgO. In addition to magnesia, silica, iron, oxide and alumina are usually
present and too slight extent, sulflir, and alkalies.
The physical character of the lime stone has an effect upon the burning temperature.
A naturally, coarse, porous stone is acted upon by heat much more rapidly than a
dense, finely crystalline stone, and may be burned more rapidly and at a lower
temperature.

2.3 Manufacture of lime - Theory of calcinations:

The burning or calcinations of lime accomplishes three objects:
a. The water in the stone is evaporated.
b. The lime stone is heated to the request temperature for chemical dissociation.
c. The CO2 is driven off as a gas, leaving the oxides of calcium and magnesium.

2.4 Uses of quick lime:

Lime may be used as:
a. Building materials.
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b. Finishing materials.

2.5 Properties of quick lime:

2.5.1 Plasticity:
The term "plasticity" is commonly used to describe the spreading quality of the
material of the material in plastering. If it spreads easily and smoothly, it is plastic,
if it sticks under the trowel, or cracks, and drops behind the trowel, it is non plastic.

2.5.2 Sand- carrying capacity:

Practically all lime used structurally is made up in the form of mortar by the
addition of sand to lime paste for the following reasons:
a. Sand is cheaper than lime.
b. To diminish the great shrinkage which accompanies the setting and hardening of
lime and also to prevent the consequent cracking.
c. To counteract the extreme stickiness' of some high- calcium limes.
It is important that the "sand- carrying capacity" of the lime be properly established.
If too little sand is used, excessive shrinkage will cause a weakening of bond
between the plaster or mortar and the masonry materials or plastered surface. On the
other hand, too much sand produces a non plastic and weak mortar.

2.5.3 Setting time:

The setting of lime and lime mortar is a chemical process involving the evaporation
of the large excess of water used in forming the lime paste, followed by the gradual
replacement of the water of hydroxide by CO2 in the atmosphere, causing the lime
hydrate to revert to the original calcium carbonate.
CaO + H2O - ► Ca(OH)2
Ca(OH)2+ CO2 - ► CaCOs + H2O

2.5.4 Tensile and compressive strength of lime mortars:

The physical properties of lime mortar vary with the:
a. Chemical composition of the lime: Magnesia lime makes it stronger than calcium
limes.
b. Character of the sand: Fine sand makes stronger mortar than coarse sand.
c. The amount of water: Suitable amount of water produces stronger lime mortar.
d. The conditions under which the mortar sets: The humidity and amount of CO2 in
the atmosphere influence the rate of setting of lime drying the air and charging it
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with carbon dioxide, greatly accelerating the setting process.

2.6 H hydrated lime:

2.6.1 Process of manufacture:
Hydrated lime is a dry powder resulting from the hydration, at the place of
manufacture, of ordinary quick lime. Three stages of manufacture characterize the
preparation of hydrated lime:
a. The quick lime is crushed or pulverized to a fairly small size.
b. The crushed materials are thoroughly mixed with a sufficient quantity of water.
c.The slaked lime is, by air separation, screening, or otherwise separated from
lumps of anhydrate lime and impurities, or the entire mass must be finely
pulverized.

2.6.2 Uses:
Hydrated lime may be used as:
a.Building materials.
b.Finishing materials.

2.6.3 Properties:
a. Mortar prepared from hydrated lime is generally inferior to those prepared from
quick lime from the stand point of plasticity and sand - carrying capacity.
b. The strength of hydrated lime mortars, both in tension and in compression, is
somewhat higher than that of the corresponding quick lime mortars.
c. Hydrated lime mortars are more quickly setting than from ordinary quick lime
mortars.

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Construction Materials Science

Baghdad University/Civil Engineering Dept.
1st stage

Lecture No. 4

Classification of bricks according to constituent raw material:

1. Clay bricks
2. Lime - sand bricks
3. Concrete bricks

1. Clay bricks:
1.1 Raw materials:
a. Alumina
Alumina is main constituent of every clay. Loam soil (adhesive soil) forms good clay.
In absencemof sand, pure clay will develop cracks due to shrinkage on drying and
burning. A good clay bricks should contain about 20% of alumina.
b. Silica Free silica (sand), if added to clay in suitable proportion makes hard and
prevents it from warping and shrinkage on drying. Silica, if present in greater proportion,
makes a brick brittle. Silica present in the combined form ( aluminum silicate ) does not
form good bricks, as it will shrink and develop cracks.
Both silica and alumina should be in free form.
c. Lime: This also should be present in small quantities in the brick earth. It should be in
a finely produced condition and it should not be in the form lamps or clods.
Lime prevents shrinkage of raw bricks. It helps fusion of sand at the kiln temperature.
This fused sand will bind the bricks particles fast.
d. Iron oxide: A small quantity of oxide of iron ( 5-6% ) is desirable. It helps the fiision
of sand like lime. It gives red colure to burn bricks. Excess of iron oxide imparts dark
blue or blackish colure to brick, while, alower percentage of iron oxide makes the brick
yellow in colure. Iron oxide makes the bricks hard and strong.
e. Magnesia: A small amount of magnesia helps to decrease the shrinkage of bricks. This
gives a yellow tint to the bricks. But excess of magnesia is not desirable as it tends to
produce the decay of bricks.

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1.2 Composition of good clay brick:

A good clay brick should contain the following:
1. Clay or alumina - AI2O3 - 20%
2. Sand or silica - Si02 - 60%
3- Remaining ingredients, such as:
- Lime
Iron -20%
oxide
Magnea
Manganese
1-3 Harmful ingredients in clay bricks:
a. Excess of lime:
Excess of lime makes the colure of the brick yellow instead of red. Lumps of
limestone remaining in the finished brick are undesirable because, when such a
brick comes in contact with water, lime will begin to slake. During slaking, lime
expands and also generates heat. Due to this, stresses will be produced, which
will result in producing cracks in bricks.
b. Iron pyrites:
These will decompose and oxide the clay during the burning of bricks. After
oxidation a black discoloration will be produced on the bricks, making it look
ugly.
c. Pebbles: The presence of pebbles, girt, gravel etc. will be undesirable because
they prevent the clay from being mixed well. They prevent the manufacture of
smooth and regular, standard bricks. They also spoil the appearance of the bricks.
Pebbles, gravel, grit, etc., should be removed before mixing and pugging of clay
are done.
e. Organic matter:
This includes leaves, twigs. Etc. of plants, roots, grass, bones of animals etc.
These if prevent and burnt along with bricks, produced empty pockets or pores
and will produce porous bricks.
f Alkalis ( MgO , K2O ):
I. It lowers the fiision temperature and molts bricks.
II. Changes the shape of bricks or get twisted.
III. These salts have hygroscopic action; they absorb moisture, present in the
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atmosphere and keep brick damp which is harmful for health and decays the
structure.
MgO + H2O � Mg (OH )2
K2O + H2O � 2 KOH

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g.Salts:
Salts such as sodium sulphate cause efflorescence.
1.4 Manufacture of bricks:
Manufacture of clay bricks involves the following operation:
1.4.1 Preparation of clay:
a. Removal of loose soil:
The top layer of loose disintegrated soil up to about 20 cm depth has to be removed
as this contains a lot of impurities.
b. Digging, spreading and cleaning:
Next, the earth has to be dug up. For small quantity, digging may be done
manually. For large scale work, it may be done by machine.
c. Weathering:
The earth is left to weather for a few weeks, this is necessary to increase the
plasticity of soil and improves its quantity.
d. Blending:
This refers to mixing the clay, after making it loose and adding any required
ingredients to the top of the heap.
e. Tempering:
This is necessary to make the clay fiilly consistent, and fit for molding into raw
bricks, by adding the required amount of water to make it plastic.
1.4.2 Molding:
Molds required for making a brick are made of rectangular blocks slightly
large in size (10% larger than the burnt bricks). It is done to allow for the
shrinkage of the molded brick on drying and burning.
The molding is improved by the following process:
a. Dry press process:
In this method, clay is not made sufficiently plastic, but only small amount of
water is mixed with clay as to form a damp powder. With plunger machines,
this powder is compressed in the mold, in the form of bricks. Such bricks are
directly burned, no drying is needed, but care is to be taken during burning
where the temperature should be raised gradually.
b. Stiff mud process:
In this process the clay is only sufficiently moist to process the required
coherence under moderate pressure, which results in economy of time in
drying and fuel in burning. Such clay is forced to come out of any opening
having dimensions equal to length of bricks, by means of a wire. Hence these
arealso known as wire cut bricks.
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c. Soft mud process:

This process is used where the clay is too wet, there for, it must be dried before
molding. Bricks are molded under pressure in a soft mud brick machine, which
tempers the clay in its pigging chamber,sands or wets the molds, presses the
clay into 4 to 9 molds at a time, strikes off the excess clay, bumps the molds
uniformly and dumps the bricks into a pallet. The pallets of bricks are carried
away to the dryer as fast as made.

1.4.3 Drying:
As wet clay bricks come from different brick machine, they contain from 7-
50% moisture depend on whether dry press stiff mud or soft mud process has
been used moisture in clay may be classified as:
Equilibrium moisture: is that moisture in the material which exerts a vapor
pressure equal to that exerted by the surrounding air of a given temperature
and humidity.
Free moisture: is held strongly in the pore spaces.

ost of the free water is removed in the drying process and the remaining
moisture during the burning process. Mechanical dryer, who permit of
automatic control of temperature, humidity and air velocity, have come into
general use. As the free water of the clay body is removed, the clay particles
tend to coalesce causing shrinkage. The general effect of such shrinkage is to
increase the resistance to moisture flow in the dried layers. If the drying is
carried on too rapidly as by means of hot dry air, the moisture is removed from
the surface of the solid more rapidly than the interior of the solid so that the
surface harden and cracking occur. It is desirable to dry clay with moist air,
reducing the drying rate to the point where diffusion of water to the surface can
keep up with the vaporization at the surface. The average time necessary for
drying clay brick is about 3 days, and the temperature required is from 38 °C
to 149 °C.
1.4.4 Burning:
The burning of clay in a kiln requires an average time of 3 to 4 days. The
process of burning may be divided into the following stages:
a. Water smoking:
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During this period which removes most of the water in the clay under
temperature ranging from 125°C to 175 °C.
b. Dehydration: Dehydration consists of expelling chemically combined water
by breaking down the clay molecules.
It begins at about 425 °C and complete at about 750 °C.

c. Oxidation:
Oxidation begins during the dehydration stage. All combustible matter is
consumed, carbon is eliminated, the fluxing materials are changed to oxides,
and sulfur is removed.
1.5 Classification of clay bricks in accordance with Iraqi standard No. 25 / 1988:
Bricks used in construction works are classified into three grades:
Grade A: Intended for use in building construction and footing subjected to
loads and exposed to sever abrasion by weathering action.
Grade B; Intended for use in building construction subjected to loads and not
exposed to sever abrasion by weathering action, such as exterior walls not
exposed to penetration of water.
Grade C: Intended for use in building construction not subjected to loading
such as interior masonry walls and partitions, not exposed to sever abrasion by
weathering action.
Appearance: A good brick should be rectangular in shape with smooth and
even surfaces. They shall be free from cracks and flows and nodules of free
lime.
Dimensions: A good brick shall have standard dimensions as shown below:

24cm±3%

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Construction Materials Science

Baghdad University/Civil Engineering Dept.
2012-2013/1st stage

Lecture No. 5
1.6 Properties of bricks:
The raw materials and the manner and degree of burning influence the physical
properties greatly and therefore wide ranges in values are to be expected for
each property.
1.6.1 Compressive strength:
The test is carried out in accordance with Iraqi standard No. 24. The brick
placed between two plywood sheets and carefiilly centered between plates of
the compression testing machine. The loadshall be applied at a uniform rate
until failure occurs.

Compressive strength = Load at failure/ Cross sectional area subjected to load

1.6.2 Water absorption:

The absorption of water by brick is often considered to be indicative of its
probable durability. The test also provides a means of checking on the
consistency of the bricks produced by one factory. In this test the specimen shall
21
[Type here] [Type here] [Type here]
be dried to constant weight in a ventilated oven at 110 °C to 115 °C for about 48
hours. Next the specimen shall be completely immersed in clean water for 24
hours. Each specimen shall then be removed, the surface water wiped off with a
damp cloth and the specimen weight.

Water absorption = {( W2-W1)/W1 } *100%

Where W2 - weight of brick after 24 hours in water
Wl- weight of dry brick

1.6.3 Effloresce:
Soluble salts, if present in bricks, will cause effloresce on the surface of bricks.
Effloresce test is carried out in accordance with Iraqi standard No. 24.The test is
very useful for comparing samples of bricks from different sources, such as
when we want to test bricks from several different factories at one time. In this
test take a representative sample of 10 bricks and place them on end in the pan
containing distilled water to a depth of 2.5 cm for 7 days. Allow the bricks to
dry for 3 more days in similar pan not containing water.
The effloresce shall report as:
Nil - No effloresce visible.
Slight- A thin deposit of salts on less than 10% of the area of the brick.
Moderate- A heavier deposit of salts covering between 10-50% of the area of the
brick, but no powdering or flaking of the surface.
Heavy - A heavy deposit of salts covering more than 50% of the area, but no
powdering or flaking of the surface.
Serious - A heavy deposit of salts and some powdering and flaking of the surface.

22
[Type here] [Type here] [Type here]

Water

�2.5 cm

T
Pan

1.7 Compressive strength, water absorption and effloresce according to Iraqi standard No. 25/1988:

Maximum water absorption Minimum compressive strength Effloresce Grade

% N/mm
Average for 10 For one brick Average for 10 For one brick
bricks bricks
20 22 18 16 Slight A
24 26 13 11 Slight B
28 28 9 7 - C

23
[Type here] [Type here] [Type here]
bricks:
2.1 Raw materials:
The raw materials required for manufacture of sand
Const - lime bricks are as follow:
ructi 2.1.1 Sand
on The sand used in sand - lime brick should meet the
Mate physical and chemical requirements of Iraqi CaO +
rials standard No. 572: H2O +
Scien a. Contain not less than 70% silica. SiO2 �
ce b. Well graded between 0.005 - 0.5 mm. Ca0.Si
Baghda c. Free from impurities such as organic matter, rock, O2. H2O
d minerals and soluble salts. "
Univers d. The percentage of clay not more than 10% Toberm
ity/Civi
l
e. Iron compounds not more than 1.5%. orite " "
Engine f Gypsum content not more than 1%. Hydrou
ering g. ( CaO + MgO ) not more than 5%. s
Dept. 2.1.2 Lime: The lime used in sand lime brick should calcium
2012- meet the requirements of Iraqi standard No. 572: silicate
2013/1st a. Activity of lime shall not be less than 83%. "
stage
b. The percentage of lime retaining on 75 |im sieves C
should not be greater than 2%. a
2.1.3 Water: Water used in sand lime brick should be (
fit for drinking. O
2.1.4 Pigment: To make colored sand lime bricks, H
suitable coloring pigment should be added in the )
mixture of sand and lime. The quantity of pigment 2
Lectu varies from o.2 to 3% of the total weight of the brick. +
re 2.2 Mix proportion: The percentage of lime should be C
No. 6 between 9-15% of the weight of sand. O
2 2.3 Manufacture: a. Sand, lime and pigment are taken 2

. in suitable proportions and they are thoroughly mixed �

S with are quired quantity of water. C
a b. The material is then molded in the shape of the a
n bricks under mechanical pressure (150-200 kg/cm). C
d c. Bricks are then placed in closed chamber and O
- subjected to saturated steam pressure of about 8.5-16 s
L kg/cm for 6-12 hours to speed up the interaction +
i between lime and sand. The process is known as H
m autoclaving. 2

e O
24
[Type here] [Type here] [Type here]
e e salt. Hence the trouble of effloresces does not arise. d
r b. If plaster is to be provided on sand lime bricks, the .
T
i quantity of mortar required will be less as bricks h
a are uniform in size and shape. e
l c. These bricks are hard and strong. s
e
s d. These bricks are uniform in colure and texture. b
o e. Sand lime bricks are used for ornamental work. r
f 3. Concrete bricks: i
c
t These bricks are manufactured from a mixture of k
h Portland cement and aggregate for use in brick masonry. s
e Typical aggregate include sand, gravel, crushed stone c
a
s and blast flirnace slag. Mix proportion varies from 1:2:4 n
e to 1:8:16 according to the required bearing capacity. p
b These bricks are often mad hollow for economical r
o
r purposes and to reduce the weight of the brick. The d
i dimensions of the brick are as follow: u
c c
40cm e
k d
20 cm
s w
d i
o
6-35 t
cm h
n v
o a
t r
i
c o
o u
n s
b
t e
a a
i r
i
n3.1 Uses: n
a Concrete bricks are widely used for construction g
n purposes especially in areas where soils are not suitable c
a
y for manufacture of clay bricks and may be used in the p
s construction of bricks panels for light weight structures a
and multistory formed structures. c
o 3.2 Properties of concrete bricks:
i
l a. The using of these bricks save time and effort as brick t
u are light in weight and big in size. y
b b. These bricks give good bonding with plastering
materials used in their construction.
a
l c. These bricks have accurate size and shape. c
c
25
[Type here] [Type here] [Type here]
w e size of openings
e
i
g
h
t L
o e
f c
b t
r u
i r
c e
k N
s o
c
.
a
7
n
b
e
c B
o l
n o
t
c
r
o k
l s
l
e
d I
b n
y t
v r
a o
r d
y u
i Construction Materials Science c
n
Baghdad University /Civil Engineering Dept. t
g
i
t 1st stage
h o

26
[Type here] [Type here] [Type here]
f therefore it should not used before 14 days of B
i production. The block should be clear from cracks or u
n defects that reduce the bearing capacity and durability t
g of the block. The faces of the block should be rough to n
, ensure cohesion between the block and finishing layers. o
b
w
l
Manufacture of blocks:
a
o
d
c
k
a
s Blocks are made from cement and water and the y
w sand will be added gradually, then mix it in the mixer for s
i about 5 minutes to have homogeneous mix, then pour t
l the mix in the moulds. Open the moulds and leave the h
l block for 14 day before use. To check the strength of the i
b block its important to test one sample before use. s
e Blocks used in many applications such as bearing walls
t
l or filling concrete skeletons. All the problems that faces
y
o the block works related to cracking and settlement
p
a when the foundation is weak. The main purpose for
block failure in structure appears when it is exposed to
e
d
water; therefore it should be ensured that construction r
e
joints between blocks should be strong. a
d
r
i
n e
Types of blocks: l
t
h y
e u
 Concrete blocks
s s
t Its dimension (200x300) mm and its height should not e
r less than 100mm (the height less than the length or d
u the height less than 6 times the d
c u
t
There are 3 types of concrete blocks
e
u 1. Solid block: this block does not have pores except t
r two circular holes Ø 10 cm each. This type of block o
e used in bearing walls the modulus of rupture not :
s less than (70 kg /cm3)
27
[Type here] [Type here] [Type here]
n r long time) I
s t
4- Difficulty in extended the sanitary and electric
u o
services. n
l
a i
t c
b
i
 Hollow blocks l
o
o
n c
This block has artificial holes and can be classified in
( k
to:
i :
t
k a) lightweight hollow block: the weight of this block
e l
is light due to the use of aggregate have high ratio
e i
of pores this type is used for special purposes, due
p g
to its high cost, such as (adding loads
s h
t t
h b) Regular hollow blocks: can be classified due to its w
e dimensions, and it will be named according to its e
i thickness to: i
n g
-block 20 (20x20x40)cm=used in external walls or h
n
architectures. t
e
r -block 15(15x20x40)cm= used in external and b
m internal walls l
o o
-block 12(12x20x40)cm=used in partitions
i c
s -block 10(10x20x40)cm= used in partitions k
t -block 4 (4x20x40)cm= used in sliding windows h
u a
r v
e c) Grill blocks: hollow block with different e
f engineering shapes, used for decoration g
o o
28
[Type here] [Type here] [Type here]
e this type used in walls and roofs to reduce weight on -
n columns and foundations its weighted (400-500) S
c kg/m3, also it resist temperature up to 1200Co for 3 a
y hours, but its cost is too expensive. n
6 d
t -
i  Silica blocks: l
m It is Italian blocks produced by white silica sand, its i
e dimension (40x20x70) cm, it is used in arches and m
s decorations and in building furnaces because it can e
m resist high temperature. b
o l
r o
 Glass block:
e c
This block is made of glass with different shapes and
t k
with sizes of (19x19x8)cm and (20x20x7)cm and
h :
quartz white cement paste used in building such
a m
blocks reinforced with steel bars 6mm diameter
n a
anti-rust, the major properties of this blocks are:
t d
h - have fabulous appearance e
e - give beautiful lightening b
c y
o The defects of this block are: m
n i
-heavy weight
c x
r -difficult in building l
e i
t m
e  lime block: e
s Materials used in it are: a
t -lime n
o d
-sand: made of good standard silica sand empty
n s
from impurities and salt
e a
, -water n
29
[Type here] [Type here] [Type here]
2
t nder pressure (10kN/mm ) for about 6-8 hours the -
t resulted block will have three types: m
h o
-1st type: compressive strength not less than 250
e i
kg/cm2
m s
i - 2nd type: compressive strength not less than 150 t
x kg/cm2 u
i -3rd type: compressive strength not less than 75 r
n kg/cm2 e
t r
h e
e  burned clay block: s
m Made by forming mix of clay and water then burned i
o it in special furnace and form the specimens by dry- s
u process or by compressed process and the t
l compressive strength of the block should not be less a
d than120 kg/cm2. n
, t
a i
f  Hourdy blocks t
t The shape of this block is not regular like the other i
e types of blocks, it changed due to its use, also the s
r weight of this block changed due to its use, for t
s example in roofs lighter hourdy blocks use rather h
t than in walls. Density of hourdy blocks between e
e (999-1039) kg/m3 and the crushing strength is p
a between (7.1-9.9) N/mm2 and the compressive e
m strength not less than (30)kg/cm2. r
c f
u e
Advantages and disadvantages of hourdy blocks:
r c
i -hide the structural defects and cover the beams t
n and outstandings s
g -get rid of paints and paste and help to make the re- o
u painting process much better l
30
[Type here] [Type here] [Type here]
U in humid places. B
a
P g
V h
- good thermal and sound insulation d
C a
p - lightweight but strong enough and resist cracking d
r because it is made of high quality PVC U
- multi-purpose uses roofs, walls, in rooms or in n
o i
bathrooms and kitchens, roofs for Balcones and v
p
garages e
e - available in many colours which is steady with r
r s
adequate gloss to give it natural appearance i
t - easy to clean t
i y
/
e C
s i
v
, properties of hourdy block: i
t l
E
h n
e 1- durability: have good durability to wind end g
r environments i
n
e 2- multipurpose uses such as (foundations, retaining e
f walls) e
r
o i
3- maintenance: this block does not need
r n
maintenance except when exposed to water g
e D
i 4- fire resistance: stand about 6 hours against fire e
p
t
5- compressive strength for this block is: t
i .
s -hollow block (7.5-12.5)N/mm2 1
s
p -solid block (7.5-21)N/mm2 t
e s
-hourdy block (3-7)N/mm2
r t
a
f g
e e
c
t
Construction Materials Science
31
[Type here] [Type here] [Type here]
b nner than bricks and have greater tendency to crack  P
s and warp in drying and burning than ordinary bricks o
o and are more liable to breakage. Therefore, great t
f care is needed in their manufacture. They should be o
b dried in the shade, burnt and cooled gradually in r
r specially made kilns. c
i
o
c Types,classifications and uses of tiles: u
k Tiles divided according to their uses in to: n
e
a 1- Roofing tiles 2- flooring tiles t
r r
3-wall tiles 4-drain tiles y
t
h 5-glazed tiles t
, i
1-roofing tiles:
b l
u These tiles should be strong, durable and perfectly e
r leakproof, although they are expensive but they need
s
n less maintenance cost, the main types of roofing tiles
:
t are described below:
t
i  Flat tiles:are rectangular in shape and of variouse h
n dimensions. They are laid in cement or lime mortar. e
k Many types of flat tiles are discussed below: s
i (a)slate tiles: the available size e
l
(60cmx30cmx15mm)and(50cmx25cmx10mm) , t
n
these tiles should be reasonably straight, uniform in i
.
colour, good texture and free from veins, cracks, l
T
i fissures and white patches.the water absorption e
l after 24 hours immersion in cold water should be s
e maximum 21% by weight. a
s (b)burnt clay flat terracing tiles: r
a These tiles should be uniform in shape, size and e
r should be free from irregularities like bends, twists, s
e cracks. The water absorption should not exceed 20% o
t by weight. The compressive strength should not be m
h less than 7.5N/mm2 e
i
32
[Type here] [Type here] [Type here]
d red shape on wooden pattern and burnt in a kiln after 2
e drying.these tiles are semi-circular in section, such -
d tiles used either alone or with flat tiles. These tiles are f
, less liable to be displaced by birds and may used as l
f sole covering to the roof. These tiles are laid on o
i sloped roofs along with the conecave side up and o
r longer end towards the ridge. Then another row of r
s same tiles with convex side up and small end towards i
t the ridge is laid covering the adjoing edges of every n
i pair of tiles below, such tiles commonly used in rural g
n areas. t
t  Allahabad tiles: these tiles are of different shapes. i
o They are generaly laid side by side and joints are l
f covered with half round tile. and they are used for e
l making good and pleasing roofs s
a ,they should not absorb water more than 20% by T
t weight. h
t  Corrugated tiles:these tiles have corrugation and e
i when they are placed in position a side lap of one or s
l two corrugation is formed.placing such tiles on a roof e
e t
give very good appearance of corrugated galvanized
i
t sheets, but they can be easily blown by violent winds.
l
h  Manglore tiles: they are red colour and of double
e
e channeled basel mission manglor pattern, due to its s
n projections they interlock with each other when a
t placed in position, the life of these tiles is about 25 r
o years with 5% replacement per year. e
t  Encaustic tiles: these tiles are employed for f
h decorative purposes and are consist of three layers: l
e 1- The face is a thin coat of pure clay of the required a
r colour t
e 2- The body is of coarse clay a
q 3- The back is formed with thin layer of clay different n
u from the body to prevent warping d
i u
s
33
[Type here] [Type here] [Type here]
a shape.they should give ringing sound when struck B
a
n with each other, and should not absorb water more g
b than 24% by weight . the fracture surface of the tile h
e should be clean, dense and sharp edges, and show d
a
m maximum resistance to impact. Common size of d
a flooring tiles are U
d (15cmx15cmx18mm),(20cmx20cmx20mm)and n
i
e (22.5cmx22.5cmx22mm). v
i e
r
n 3-wall tiles s
a These are similar to the floor tiles except for their i
n design and degree of burning. They are burnt at low
t
y
y temperature, glazed and burnt again at a low /
c temperature, they can be made in different designs C
o and colours and be built to any size.these tiles are
i
v
l used on face work , arches and architectural ceiling. i
o l
u E
r 4-Drain tiles n
g
a Usually are long curved sectiones of various shapes i
n and sizes such as semi-circular or circular . they are n
used for draining waste water and for carrying e
d e
o sewage glazed tiles should be used. r
f i
n
a 5-glazed earthenware tiles g
n Such tiles are of earthenware having top surface D
y e
glazed and underside unglazed so the tile may be p
g adhere properly to the base, these tiles are made in t
e two sizes (14.9cmx14.9cm)and (99mmx99mm), .
o having thickness 5mm,6mm and 7mm,the joint 2
m thickness is 1mm. they should not absorb more than 0
1
e 18% of water , such tiles are used for finishing the 2
t surfaces of walls and floors of water closets, -
r bathrooms, kitchens and hospitals (where cleanliness 2
0
i is important) 1
c 3
a /
1
l Construction Materials Science
34
[Type here] [Type here] [Type here]
Lect. No.9 1
-
Properties of building tiles p
r
-quality : building tiles should be made from good
e
clay of even texture, they should be well burnt and
p
uniform in size and shape and should be free from
a
irregularities such as bends, twists and cracks.
r
-warpage test:in case of flooring tiles warpage should a
not exceed 2% along the edge and (1.5)% along the t
diagonal. In case of terracing tiles should not exceed i
in any direction 1%. o
-characteristics of good tiles: a good tiles should n
posses the following characteristics: o
f
1-should posses uniform colour c
2-should be properly burnt l
a
3-should be free from cracks ,flaws or bends
y
4-should be hard and durable
-
5-should have proper shape and size T
h
6-when placed in position, it should fit well
e
7-its broken surface should exhibit even and compact s
structure e
8-it should give a clear ringing sound when struk with l
light hammer or with another tile. e
c
t
Manufacture of tiles e
The manufacture of common tiles includes: d
1-preparation of clay c
l
2-moulding of tiles
a
3-drying of tiles y
(
4-burning of tiles
b
35
[Type here] [Type here] [Type here]
w impurities such as girt and pebbles.
f
-The clay grind into powder in crushing roller or mills 3
e
and then thoroughly pugged , for making superior -
e
tiles the powdered clay is mixed with large quantity d
t
of water then stirred up well and the mixture is r
b
allowed to settle. The heavier and coarse particles y
e
sink in to the bottom and the finer particles run off i
l
into the lower layer where the matter is allowed to n
o
dry leaving the fine clay ready for mixing this g
w
method is known as plunging process o
b
f
r -to make the tiles hard and impervious a mixture of
t
i ground glass and pottery ware may be added in
i
c required quantity to the clay of tiles
l
k 2-moulding of tiles e
e
Three methods are used for molding the tiles: s
a
r -wooden patterns: the tiles which are not uniform T
t in section throughout their entire length are molded w
h in patterns (made of well seasoned wood).flat cracks o
) of clay are made and when partly dry they are d
i molded, pressed and turned round a wooden a
s pattern to give them the required shape y
m s
-potter's wheel: this method is similar to that a
a
adopted by potter in the manufacture of f
d
earthenware vessels. This method adopted when t
e
tile is of perfectly circular shape, it may have e
f
diameter vary along its length. r
r
e -mechanical method:this method of molding is m
e adopted for tiles having a uniform section througout o
f their length. The pugged clay is prepared by l
r mechanical means through opening of required d
o shape and size. The moulded clay coming out of the i
m opening is received on a platform (wooden or iron) n
a and the tiles are cut off to the required length by g
n means of wire frames. t
y i
36
[Type here] [Type here] [Type here]
l o warping. On the next day they are lifted up when -
e hand hard and the edges , the under surfaces are d
t scraped. They are then placed on edge and left to r
t dry for about 2-days under shade to prevent a
o warping and cracking when they are ready for s
c loading in kiln. t
o i
r c
r 4-burning of tiles r
e The tiles are burnt in a typical kiln known as sialkote e
c kiln, which can accommodate 3000 to 4000 tiles. d
t Such kilns are partly underground and generally u
t provided with a roof.a layer of bricks is laid flat on c
h rows of long narrow flues. The burning is affected t
e by firing wood placed in these flues. The bricks are i
i arranged in such a fashion that open spaces are left o
r in between them. Above the layer of bricks the dried n
r tiles are placed on edge layer by layer, until the kiln o
e is completely loaded with raw tiles. f
g t
u The doorways are then closed with bricks in mud h
l plaster and top is covered with old tiles and ash.the e
a firing of the kiln is started and the fire is kept low till f
r the gases are driven out. The temperature raised i
i gradually till the inner portions of the flues become r
t red hot (at about 800CO), then it slaked for about 6 i
y hours, the temperature raised again till the flues are n
i white hot (about 1300Co) and kept as such for about g
n 3 hours. The tiles is again slaked 6 hours then c
s icreased once more to white hot and kept steady for i
h about 3 to 4 hours.finally the flues are filled with r
a fuel and doorways are closed by brickworks in mud. c
p The kiln is then gradually allowed to cool down. The l
e process of burning the tiles is completed in about 72 e
d hours. f
u "Single firing technology " is a new automatic r
e process achieved the following advantages: o
t m
37
[Type here] [Type here] [Type here]
c production
e \
-improved quality design of the burnt tiles.
d
f
u
e
l
c
o
n
s
u
m
p
t
i
o
n
-
r
e
d
u
c
e
d
t
o
t
a
l
c
o
s
t
o
f
Timber
38
[Type here] [Type here] [Type here]

Lec. No.10
Timber has been one of the primary materials of engineering construction; it is widely used for
structural purpose.
The engineering should have some knowledge of the classification of trees and of their growth
and
structure in orders to understand the flindamentals of the physical and mechanical properties of
timbers.
Classification of trees:
For the engineering purposes, trees are classified according to their mode of growth:
Trees : a. Endogenous
b. Exogenous:
b.l Softwoods
b.2 Hard woods
a. Endogenous trees:
This group is confined largely to tropical semitropical regions. Timber from these trees has very
limited
engineering applications. Example of endogenous tress is:
Palms: because of their long, straight stems are some times locally used as piles.
Bamboo: Is used structurally to a considerable extent.
b. Exogenous trees:
These trees increase in bulk growing outer bark and annual rings are formed in the horizontal
section of
such a tree. Timber which is mostly used for engineering purpose belongs to this category. This
timber
can be divided into two groups:
a. Soft woods: Such as deodar
b. Hard woods: such as oak and teak.
Structure of wood:

/fiik

Cambium

Cross section of an exogenous tree

Cellulose

Cell wall
39
[Type here] [Type here] [Type here]

Cell

Longitudinal section of an exogenous tree

40
[Type here] [Type here] [Type here]

Structural axes of wood:

1. Longitudinal axis: Parallel to the length of the fiber
2. Tangential axis: Perpendicular to the fibers and tangential growth rings.
3. Radial axis: Perpendicular to the fibers and to the growth rings, i.e. parallel to the wood rays
that
radiate from the center of a tree as seen in cross section.

� Longitudinal axis

Moisture of timber:
Freshly cut wood from live trees is said to be in green condition. Green wood contains moisture
in two
general forms:
a. Free moisture: contained in the cell cavities of the walls.
b. Hygroscopic moisture: held in submicroscopic capillaries of the cell walls.
In the green condition, the cell walls of wood are almost saturated but the amount of free water
varies
widely between the species and even between sapwood and heartwood of the same species.
Moisture
content is expressed as a percentage of the oven dry weight of wood.
Fiber Saturation point:
The moisture content at which all free water is removed ( i.e. cell cavities empty ) while the cell
walls
are fiilly saturated. Changes in moisture content below the fiber saturation point are associated
with shrinkage
and swelling, as well as variation in strength and elastic properties and other properties. Fiber
saturation point
in range general between 20 to 32%.
Density and specific gravity:
The specific gravity of wood is its density ( weight per unit volume ) relative to that of water. By
41
[Type here] [Type here] [Type here]
convention, the specific gravity of wood is based on weight of oven dry only per unit volume.
Because of
shrinkage the oven dry in a given piece occupies different volumes, depending on moisture
content of the piece.
Average specific gravities of woods based on oven dry weight and volume range between 0.13 to
1.20 while the
specific gravity of wood substance itself, is about 1.5, regardless of species. Consequently the
specific gravity
of any particular species of wood is a measure of the relative amount of solid substance per unit
volume, e.g.
wood with a specific gravity of a contains V3 solid wood substance, the remainder of its volume
being occupied
by cell cavities, intercellular species and cell wall capillaries.
Seasoning of wood:
As a result of daily and seasonal fiuctuations in relative humidity and temperature, most wood in
service
continually gaining or losing moisture. The most practical means of minimizing trouble some
variations in
moisture content is by seasoning timber prior to its fabrication finished products or used
structurally so the
object of seasoning is to lower the moisture content of the wood a point at which the swelling and
shrinkage is
reduced a minimum for given conditions.

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Seasoning process:
There are two principle methods of seasoning timber:
a. Natural seasoning: This consists of stacking the timber the air, and allowing it to dry naturally,
the
water being expelled gradually and shrinkage occurring informally. This process takes from two
to four years to
complete.
It is necessary to stack the timber with intervals between each so that the air can circulate all
around.
b. Artificial seasoning: Avery large proportion of commercial timber is now dried by the kiln
methods
more particularly in the case of hardwoods. The advantages of kiln drying lie in the rapidity of
the process and
in the possibility of controlling the various factors influencing the correct seasoning results.
The three principle factors concerned in these methods are:
a. The temperature of the process.
b. The moisture.
c. The circulation.
Proper kiln can control the rate and degree of drying, that the tendency during drying to warp and
split is
reduced minimum. Uneven shrinkage may occur when the loss of moisture from the surface is
greater than that
from the interior. This shrinkage can be controlled by supplying moisture inside the kiln which
assists in
keeping the surface soft until the heat has penetrated to the interior, so that warping and cracking
are prevented.
In artificial drying, temperatures of 70 to 82°C are useful employed for a period depending on the
type
of wood.
Shrinkage, warping and checking in drying:
The shrinkage of woods in drying is due to the loss of moisture from the walls of the cells.
Shrinkage
from green to oven dry condition in different species ranges as following:
Volumetric 7 to 21 %
Longitudinal 0.1 to 0.3 %
Radial 2 to 8%
Tangential 4 to 14%
The amount of shrinkage varies in different direction being small longitudinal in the direction of
the
fibers, contractively large radial, and greatest tangentially. The different between tangential and
radial
shrinkage is explained by the fact that bands of dense summerwood are continuous in tangential
direction and
shrink a great deal forcing the loc of springwood along with them. However, in a radial direction
summerwood
bands alternate with bands of less dense springwood, and the total shrinkage is the summation of
shrinks of
summerwood and springwood which is smaller than for all summerwood.

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[Type here] [Type here] [Type here]

Dense summerwood . ,.
Springwood---' A"™'

The warping of lumber is due either to unequal drying different portions or to unequal shrinkage
of
both radial and tangential direction. The warping can be classified into:
a. Bow:
This defect is indicating by the curvature formed in the direction of length of timber as shown in
Fig.:

44
[Type here] [Type here] [Type here]

b. Cup:
This defect is indicating by the curvature formed in the transverse direction of timber as shown in
Fig.:

c. Cup:
When a piece of timber has spirally distorted along its length, it is known as twist:

Checking of timber in drying is a result of the inability of the timber to accommodate strains
consequent upon unequal shrinkage.
Types of checking:
Temporary checking:
A great many small checks occur particularly in the ends of timbers, owing to the more rapid
drying
from the cross section and the consequent extent of shrinkage of the end portion. These checking
are considered
temporary, because they close up and becomes impressible as the inner portion of the timber dries
and shrink.
Permanent checking:
Large checking, caused by the shrinkage of timber in a longitudinal direction along the rings
which is
greater than that along the radius.
Case hardened checking:
Some woods, mostly hardwoods, become case hardened when rapidly dried in the kiln, that is the
outer
port dries and shrinks, and commonly checks, while the interior is still in its original conditions.
The drying of
the interior is thus retarded, but when it does occur great internal strains are set up, resulting in
the formation of
large or numerous radial checks follow the rays. When these checks are comparatively small, but
numerous, the
wood is said to be honeycombed. Case hardening of timber may be avoided by air seasoning
before placing in
the kiln or by admitted steam to the kiln.
Natural defects in timber:
1. Knots: one of the most common defects, they originate in the timber cut from the stem or
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[Type here] [Type here] [Type here]
branches of a tree because of the encasement by the successive annual layers of wood.
Knots can be classified as:
Pin knots - does not exceed 6.5mm.
Small knots - between 6.5-20mm.
Medium knots - between 20-40mm.
Large knots - greater than 40mm.

Large knot Small or medium knot

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Effect of knots:
In structural beams the effect of knots on the bending strength largely depends upon their
location.
Knots in the tension side of a beam near point of maximum stress will have a significant effect on
the maximum
load a beam will sustain, whereas knots on the compression side are somewhat less serious.
Knots in any
position have little effect on shear. Stiffness of beams is not greatly affected by knots.
In long columns, in which stiffness is the controlling factor, knots are not of importance. In short
or
intermediate columns, the reduction in strength caused by knots is approximately proportional to
the size of the
knot, although large knots have a somewhat greater affect than small ones.
Knots increases hardness and strength in compression perpendicular to grain. Knots are harder to
work
and machine than the surrounding wood, may project from the surface when shrinkage occurs,
and are a cause
of twisting.
2. Shakes:
These are cracks which partly or completely separate the fibers of wood. Shakes can be
classified into:
Cup shakes - These are caused by the rupture of tissue in a perpendicular direction as shown in
Fig.
1:

Cup shakes

Fig. 1

Heart shakes - These cracks occur in the center of cross- sectional of tree and they extend from
pith
to sap wood in the direction of modularly rays as shown in Fig. 2. These cracks occur due to
shrinkage of interior part of tree. Heart shakes divide the tree cross sectional into two to four
parts.

Heart shakes

Fig. 2

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[Type here] [Type here] [Type here]

- Ring shakes - When cup shakes cover the entire ring, they are known as radial shakes. Fig. 3.

Star shakes - These are cracks which extend from bark towards the sap wood. They are usually
confined up to the place of sap wood. They are usually formed due to extreme heat or frost. Fig.
4.

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[Type here] [Type here] [Type here]

Radial shakes - These are similar to star shakes, but they are fine, irregular and numerous. They
usually occur when tree exposed to sun for seasoning after being felled down. They run for a
short
distance from bark towards the center. Fig. 5.

Radial shakes

Fig. 5

Wind shakes - If wood is exposed to atmospheric agencies, its exterior surface shrinks. Such a
shrinkage results into cracks as shown in Fig. 6.

Wind shakes

Fig. 6

Mechanical properties of woods:

The intelligent use of wood for any structural purpose requires a general knowledge of the
mechanical
properties of different woods, in order that one selected may conform in its structure qualities to
the
requirements imposed, and in order that a given purpose may be served at a minimum expense.
1. Tensile strength: Timber in construction is practically never subjected to pure tensile stresses
for the
simple reason that the end connections cannot be so devised that they do not involve either shear
along the
grain or compression across the grain.
Failure in tension across the grain involves principally the resistance offered by the thinner -
walled
wood elements to being tern apart longitudinal.
2. Compressive strength: The compressive strength of wood in a direction normal to the grain is
simply
a matter of the resistance offered by the wood elements to being crushed or flattened. The cells
with thinnest
walls collapse first, end the action proceeds gradually.

Compression -l to grain

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[Type here] [Type here] [Type here]

The compressive strength of wood in a direction 11 to the grain depends upon the internal
structure and
the moisture content of the wood and the manner of failure is fixed by these same factors. The
individual fibers
of wood act as so many hallow columns bound firmly together, and failure involves either
buckling or bending
of the individual fibers or bundles of elements.

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[Type here] [Type here] [Type here]

Compression 11 to grain

3. Flexural strength: The flexural strength of timber is determined by the following formula:

i
Sb= 3/2(PL/bh2)

The tensile strength of all timber is greatly an excess of its compressive strength ( about 3 times
as much
the average ), and the latter will usually be the determining factor in limiting the cross- breaking
strength.
(Compressive strength will always be the determining factor, assuming there exist no defects
such as knots or
uneven grain on the tension side of the beam).
4. Stiffness: Stiffness of timber largely upon the same factors as strength. Dense woods are
always
stiffer than open, porous woods, and heavy woods are stiffer than light woods.
Moisture and strength:
All woods gain in strength and in stiffness when thoroughly air seasoning or kiln dried. The
extent of
this effect depend upon the size and type of the timbers dried only by air seasoning, even through
the process is
prolonged for several months or even years, seldom lose sufficient moisture to benefit their
strength to more
than a slight degree. Such timbers, therefore, cannot be safely depended upon to show any greater
strength than
if they where in the original green condition. The explanation of this fact is that a great part of the
moisture
which is first evaporated from wood is water which exists only as " free water " in the cell
cavities, whereas
only variation in the moisture content of the walls of the wood element affects strength in any
way.
The relationship between strength and moisture content can be seen in Fig. below:
51
[Type here] [Type here] [Type here]
Fiber Saturation Point

o
!Z)

o !
Modulus of elasticity Z
)
3
3·o

Compression strength

Moisture content

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[Type here] [Type here] [Type here]
Below Fiber Saturation Point

53
[Type here] [Type here] [Type here]
<—21 Above Fibci
Saturation Point

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[Type here] [Type here] [Type here]

Nanotechnology in materials science

Lec. 12
Nanotechnology is a field that deals with developments in physics and chemistry
sciences where phenomena on atomic and molecular level are used to provide
materials and structures that perform tasks that are not possible using the materials
in their typical form. Nanotechnology can be used for design and construction
processes in many areas since nanotechnology generated products have many
unique characteristics. These include products that are for: Lighter structure;
Stronger structural composites e.g. for bridges etc ; Low maintenance coating ;
Improving pipe joining materials and techniques ; Better properties of
cementitious materials ; Reducing the thermal transfer rate of fire retardant and
insulation ; Increasing the sound absorption of acoustic absorber ; Increasing the
reflectivity of glass. There are large numbers of applications of nanotechnology
in construction engineering. Some of these applications are examined in detail
below. A Concrete is one of the most common and widely used construction
materials.
Understanding, shaping and combining matter at the atomic and molecular scale
is called nanotechnology. Nanotechnology encompasses science, medicine,
engineering, computing and robotics at this scale, called the nanoscale.
Nanotechnology offers the potential for new and faster kinds of computers, more
efficient power sources and life-saving medical treatments. Potential
disadvantages include economic disruption and possible threats to security,
privacy, health and the environment.
Many benefits of nanotechnology depend on the fact that it is possible to tailor
the structures of materials at extremely small scales to achieve specific
properties, thus greatly extending the materials science toolkit. Using
nanotechnology, materials can effectively be made stronger, lighter, more
durable, more reactive, more sieve-like, or better electrical conductors, among
many other traits. Many everyday commercial products are currently on the
market and in daily use that rely on nanoscale materials and processes:

 Nanoscale additives to or surface treatments of fabrics can provide lightweight

ballistic energy deflection in personal body armor, or can help them resist
wrinkling, staining, and bacterial growth.
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[Type here] [Type here] [Type here]
 Clear nanoscale films on eyeglasses, computer and camera displays, windows,
and other surfaces can make them water- and residue-repellent, antireflective,
self-cleaning, resistant to ultraviolet or infrared light, antifog, antimicrobial,
scratch-resistant, or electrically conductive.

 Nanoscale materials are beginning to enable washable, durable “smart fabrics”

equipped with flexible nanoscale sensors and electronics with capabilities for
health monitoring, solar energy capture, and energy harvesting through
movement.

 Lightweighting of cars, trucks, airplanes, boats, and space craft could lead to
significant fuel savings. Nanoscale additives in polymer composite materials are
being used in baseball bats, tennis rackets, bicycles, motorcycle helmets,
automobile parts, luggage, and power tool housings, making them lightweight,
stiff, durable, and resilient. Carbon nanotube sheets are now being produced for
use in next-generation air vehicles. For example, the combination of light weight
and conductivity makes them ideal for applications such as electromagnetic
shielding and thermal management.

High-
resolution image of
a polymer-silicate
nanocomposite.
This material has
improved thermal,
mechanical, and
barrier properties
and can be used in
food and beverage
containers, fuel
storage tanks for
aircraft and
automobiles, and in

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[Type here] [Type here] [Type here]
aerospace
components. (Image
 Nano-engineered
courtesy of NASA.)
materials make superior
household products such as degreasers and stain removers; environmental sensors, air
purifiers, and filters; antibacterial cleansers; and specialized paints and sealing products, such
a self-cleaning house paints that resist dirt and marks.

 Nanoscale materials are also being incorporated into a variety of personal care products to
improve performance. Nanoscale titanium dioxide and zinc oxide have been used for years in
sunscreen to provide protection from the sun while appearing invisible on the skin.

nanomaterials are used in construction

Carbon nanotubes – Expected benefits are mechanical durability and crack

prevention (in cement); enhanced mechanical and thermal properties (in
ceramics); real-time structural health monitoring (NEMS/MEMS); and effective
electron mediation (in solar cells).
Silicon dioxide nanoparticles – Expected benefits are reinforcement in
mechanical strength (in concrete); coolant, light transmission, and fire resistance
(in ceramics); flame-proofing and anti-reflection (in windows).
Titanium dioxide nanoparticles – Expected benefits are rapid hydration,
increased degree of hydration, and self-cleaning (in concrete);
superhydrophilicity, anti-fogging, and fouling-resistance (in windows); non-
utility electricity generation (in solar cells).
Iron oxide nanoparticles – Expected benefits are increased compressive strength
and abrasion-resistant in concrete.
Copper nanoparticles – Expected benefits are weldability, corrosion resistance,
and formability in steel.
Silver nanoparticles – Expected benefits are biocidal activity in coatings and
paints.
Quantum dots – Expected benefits are effective electron mediation in solar cells.
One particular area for nanotechnology in the construction industry is concrete,
specifically research on how to reinforce concrete to improve its mechanical
performance. Nano silica used to strengthen concrete and reduce time cement
takes to harden by increasing its reactivity.

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[Type here] [Type here] [Type here]

Applications in construction

 Cracking is a major concern for many structures. Using microencapsulated

healing agent and a catalytic chemical trigger. When the microcapsules are broken
by a crack, the healing agent is released into the crack and contact with the
catalyst. The polymerization happens and bond the crack faces.
 suitable for application which requires lightweight and rigid designs.
 Its good corrosion and wear resistance can keep life-cycle costs low. Attractive
or wear resistant surfaces can be achieved by various treatments is nanostructure
modified steel, produced. Compared with the conventional steel, it has a
fundamentally different microstructure- a laminated lath structure resembling
“plywood”. This unique structure provides steel with amazing strength (three
times stronger), ductility, toughness, and corrosion resistance.
 Due to high cost, the stainless steel reinforcement in concrete structure is limited
in high risk environments. The nano modified steel could be an alternative
because it has the similar corrosion resistance to that of stainless steel, but at a
much lower cost .
 the coatings incorporating certain nanoparticles or nanolayers have been
developed for certain purpose. It is one of the major applications of
nanotechnology in construction.

- In cement and concrete

• Nano silica and clinker used to increase densification and hence mechanical
properties and durability of cementitious materials.
• Service life can be doubled through the use of nano-additive viscosity enhancers
which reduce diffusion of harmful agents in concrete (patent pending).
• Photocatalytic TiO2 added to concrete to reduce carbon monoxide and NOx
emissions on roadways

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[Type here] [Type here] [Type here]

Carbon Nanotubes
Major use – electronics and composites
• Enhanced strength, stiffness and toughness without added weight
• Improved durability
• Increased functionality
• Reduced flammability

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[Type here] [Type here] [Type here]

Coatings – Inorganic
Self-cleaning glass Nano-TiO2 coated

Nanoadditive Fire Retardants

• Use of nanoadditive fire retardants
• Polymer nanocomposites filled with clay, CNTs, etc., possess improved
flammability resistance while maintaining or improving mechanical properties.
• Reduces heat release rate during fire event by formation of surface char which
insulates underlying material.

Advantages & Disadvantages of Nanotechnology

Manufacturing Advantages

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[Type here] [Type here] [Type here]
Nanotechnology is already making new materials available that could
revolutionize many areas of manufacturing. For example, nanotubes and nano
particles, which are tubes and particles only a few atoms across, and aerogels,
materials composed of very light and strong materials with remarkable insulating
properties, could pave the way for new techniques and superior products. In
addition, robots that are only a few nanometers in length, called nanobots, and
nanofactories could help construct novel materials and objects.
Energy Advantages
Nanotechnology may transform the ways in which we obtain and use energy. In
particular, it's likely that nanotechnology will make solar power more economical
by reducing the cost of constructing solar panels and related equipment. Energy
storage devices will become more efficient as a result. Nanotechnology will also
open up new methods of generating and storing energy.

Medical Advantages
Nanotechnology has the potential to bring major advances in medicine. Nanobots
could be sent into a patient's arteries to clear away blockages. Surgeries could
become much faster and more accurate. Injuries could be repaired cell-by-cell. It
may even become possible to heal genetic conditions by fixing the damaged
genes. Nanotechnology could also be used to refine drug production, tailoring
drugs at a molecular level to make them more effective and reduce side effects.
Environmental Effects
. It is possible, that there will be some negative effects on the environment as
potential new toxins and pollutants may be created by nanotechnology.
Engineering advantages
1. An epoxy containing carbon nanotubes is being used to make windmill blades that
are longer, stronger, and lighter-weight than other blades to increase the amount
of electricity that windmills can generate.
2. it can help detect and clean up environmental contaminants:
-Nanotechnology could help meet the need for affordable, clean drinking water
through rapid, low-cost detection and treatment of impurities in water.
-Engineers have developed a thin film membrane with nanopores for energy-
efficient desalination. This molybdenum disulphide (MoS2) membrane filtered
two to five times more water than current conventional filters.
-Nanoparticles are being developed to clean industrial water pollutants in ground
water through chemical reactions that render the pollutants harmless. This process

61
[Type here] [Type here] [Type here]
would cost less than methods that require pumping the water out of the ground for
treatment.
-Many airplane cabin and other types of air filters are nanotechnology-based
filters that allow “mechanical filtration,” in which the fiber material creates
nanoscale pores that trap particles larger than the size of the pores. The filters also
may contain charcoal layers that remove odors.
-Nanotechnology-enabled sensors and solutions are now able to detect and
identify chemical or biological agents in the air and soil with much higher
sensitivity than ever before.
-Nanoscale sensors and devices may provide cost-effective continuous
monitoring of the structural integrity and performance of bridges, tunnels, rails,
parking structures, and pavements over time.
-Nanostructured ceramic coatings exhibit much greater toughness than
conventional wear-resistant coatings for machine parts. Nanotechnology-enabled
lubricants and engine oils also significantly reduce wear and tear, which can
significantly extend the lifetimes of moving parts in everything from power tools
to industrial machinery.

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