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Analytical Lab Exp. 2 PDF

This experiment involves titrating an unknown HCl solution against a Na2CO3 solution to determine the molarity of HCl. Then, titrating the standardized HCl solution against a NaOH solution to determine the molarity of NaOH. Key steps include standardizing the HCl solution, titrating the HCl against NaOH, and calculating the molarities. Minor errors like using a slightly different NaOH volume, a wet flask, or failing to fully rinse the burette could impact the calculated molarity. Using too much indicator solution rather than drops could also alter the concentrations being titrated.

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74 views5 pages

Analytical Lab Exp. 2 PDF

This experiment involves titrating an unknown HCl solution against a Na2CO3 solution to determine the molarity of HCl. Then, titrating the standardized HCl solution against a NaOH solution to determine the molarity of NaOH. Key steps include standardizing the HCl solution, titrating the HCl against NaOH, and calculating the molarities. Minor errors like using a slightly different NaOH volume, a wet flask, or failing to fully rinse the burette could impact the calculated molarity. Using too much indicator solution rather than drops could also alter the concentrations being titrated.

Uploaded by

aktham hijazeen
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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University Name: Balqa Applied University , Salt

Science college

Chemistry department

Experiment (1) : Neutralization Titration


(Acid-Base reaction).

Name : Abdallah Barakat Albalawneh


Osama Amjad Alanaty
Lina Mohammed Ahmad

Lecturer : Dr- Reham Abu shmeis

Time : 2-5 (Thursday)


Objective
The mean goal of this experiment is to know the
concentration of unknown solution by using titration
method.

Introduction to this experiment


 Titration is method to detect the concentration of
unknown solution by adding a standard solution from
a burette to the analyte until the reaction between the
two is complete.

 In titration it’s very important to determine the


equivalence point, because when we reach the
equivalence point the amount of titrant is equal the
amount of analyte.

 Unfortunately, we cannot determine the equivalence


point experimentally, so it’s more convenient to
determine the End point by adding an indicator and
observe the physical change like change in color
(appear or disappear).

 In this experiment we will do acid-base titration


“neutralization”.
Acid + Base Salt + Water

 This experiment is divided into two part :


1. The first is standardization of HCl against Na2CO3.
2. The second is standardization of NaOH against HCl.
Data
Calculations

A) standardization of HCl against Na2CO3.

2HCl + Na2CO3 2NaCl + H2CO3.

n.mNa2CO2 = mass . = 0.1325 g * 1 mole .= 1.204*10-3 mole Na2CO3.


M.mass 105.988 g

MHCl = 1.204*10-3 mole Na2CO3 * 2 mole HCl * 1 . * 1 ml .


1 mole Na2CO3 2.5 ml 10-3 L

MHCl = 0.963 M.

B) standardization of NaOH against HCl.

HCl + NaOH NaCl + H2O .

n.mNaOH = 0.963 mole HCl * 1 mole NaOH * 8.65 ml * 10-3 L


1 L 1 mole HCl 1 ml

= 8.336*10-3 mole NaOH .

MNaOH = 8.336*10-3 mole NaOH * 1 . * 1 ml .


10 ml 10-3 L

MNaOH = 0.833 M .
Questions
What is the effect of the following on the calculated M of
NaOH. Why ?

1) If you use “ 12 ml " NaOH instead 10 ml .


Solution:
The molarity decrease because the volume of NaOH increase.
M = n.mole . M = 8.336 = 0.964 M.
Volume 12

2) If the flask of titration was not dry .


Solution:
No effect, because water is media for reaction and has Ph equal
7 (neutral), so it has no effect on the Ph or reaction.

3) If the burette was not rinsed with HCl and was not dry .
Solution:
This step isn’t just a sacred ceremony or a special chemistry
ritual by rinsing the burette, you make sure that the
concentration of the solution inside will be exactly what you
expect it to be. Rinsing with solution actually serves a simple
but very practical purpose.

4) If you use “5 ml” of indicator instead of 5 drops .


Solution:
Phenolphthalein is slightly acidic. It does affect titration because
if you add to much, then it will alter the concentration of
whichever solution you are adding it in. If you added it to the
acid, it will cause that the acid to be more acidic than you may
have calculated.

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