KRISHNA MURTHY IIT ACADEMY

SOLUTIONS –IIT-JEE – UNIT – 1 PAPER -1 – 18-01-2011:

CHEMISTRY – SOLUTIONS :

1. Ans. : D
Area of closed cycle
Efficiency of cycle = × 100
Area under the curve
1
× (1500 − 1000) × (250 − 150)
= 2 × 100
1
× (1500 − 1000) × (250 − 150) + (1500 − 1000) × (150 − 0)
2
1
× 500 ×100
= 2 × 100
1
× 500 × 100 + 500 × 150
2
500 × 50 × 100
=
500 × 50 + 500 × 150
= 25.

2. Ans. : C
POH = 10; [OH–] = 10–10 M.
10−10
Number of moles of OH– ion in 1mL of solution = = 10–13.
1000
Number of ions of OH– will be : 6023 × 1023 × 10–13 = 6.023 × 1010.

3. Ans. : D
The reaction is :N 2 O 4 (g)  2NO 2 (g);
20
n = 2 and α = = 0.2.
100
D = 4.6, initial vapour density; d = vapour density at equilibrium
D−d
α=
(n − 1)d
46 − d
0.2 =
(2 − 1)d
d = 38.3.

4. Ans. : D
Mn3+ oxidizes H 2 O to O 2 because the standard reduction potential of (Mn3+ + e– →
Mn2+;
E0 = +15 V) is greater than that of (O 2 + 4H+ + 4e– → 2H 2 O; E0 = +1.23 V).

5. Ans. : C
Al3+ > Ba2+ > Na+
Decreasing coagulating power for blood, which is a negative colloid.

6. Ans. : A
1
Number of Ca2+ ions = 8 × =1
8
Number of Tin+ ions = 1
1
Number of O2– ions = 6 × = 3.
2
Simples formula of mineral = CaTiO 3 .
Let oxidation state of Ti is x.
∴ +2 + x – 6 = 0
x = +4

7. Ans. : A
At low pressure, (V – b) ≈ V
  a 
 P + 2 V = RT
 V 
a
PV + = RT
V
a
PV = RT −
V
PV a
= 1− .
RT VRT

8. Ans. : B
T1 n13 Z 2 2 23 22 32
= × = × = .
T2 Z12 n23 12 33 27

9. Ans. : ABC
For H 2 and He, Z > 1.

11. Ans. : BCD

[OH − ]1 α1 Kb1
Relative strength of two bases = = = .
[OH − ]2 α 2 Kb2

12. Ans. : BCD

13-15 Ans. : B, C, D
Sol. 13.O 3 (g)  O 2 (g) + [O] (fast) …. (i)
O 3 + [O] → 2O 2 (slow) …. (ii)
Rate = k′ [O 3 ][O] ….. (iii)
[O 2 ][O]
From (i), k=
[O3 ]
[O ]
[O] = k 3
[O 2 ]
[O3 ]
From (iii) Rate = k′[O 3 ] k
[O 2 ]
= k[O3 ]2 [O 2 ]−1 .
14 Step 1 : NO + Br 2  NOBr 2 (fast)
Step 2 : NOBr 2 + NO → 2NOBr (slow)
Rate = k′[NOBr 2 ][NO] …. (i)
[NOBr2 ]
From step 1, K=
[NO][Br2 ]
[NOBr 2 ] = K[NO][Br 2 ] …. (ii)
From (i) and (ii), Rate = k′K[NO][Br 2 ][NO]
= k[NO]2 [Br 2 ]
Order = 2 + 1 = 3
15. Slowest step is rate determining.
Thus, Rate = k[A 2 ] and order = 1.

16-18 Ans. : B, A, A.
Sol.16 ∆Go = ∆Ho – T∆So
ΔH o − ΔG o (−285.6) − (−237.4)
∆So = =
T 298
= –0.16kJK-1
= –160JK-1.
17. Cell potential of fuel cells does not depend on the concentration of ions present in
electrolyte solution.
18. E ocell = E ocathode − E anode
o

123 = 0.40 – x
x = –0.83 V.

20. Ans. : A – PRS, B – QR, C – QR, D – QR.

MATHEMATICS :– SOLUTIONS :

21. Ans. : B
Image of A about y = x, y = –2x are A 1 and A 2 which lies on BC
 11 2  A(1, 2)
A 1 ≡ (2, 1), A 2 ≡  − , 
 5 5
Equation of BC is x – 7y + 5 = 0 y = – 2x (0, 0) y=x
5 5 1 I
r = ID = = = r
1 + 49 5 2 2 B
D
C
A2 A1

22. Ans. : D
The given circles are (x – 1)2 + y2 = 4 and (x – 1)2 + y2 = 16
B
The points (a + 1, 3 a) lie on the line x = a + 1, y = 3 a. A CA = 2
i.e., y = 3 (x – 1) [eliminating a] 60o CB = 4
O C(1, 0)

23. Ans. : B
−2 p 1 −2 p
y= x+ ; m=
1 − p2 1 − p2 1 − p2
4 p2
⇒ m2 = ⇒ m2 = (4 + m2)p2
1− p 2

m2
⇒p ⇒2

4 + m2
1 4 + m2
y = mx + ⇒ y = mx +CA = 2
mo
60
2 4
1−
4 + m2
1
⇒ y \ mx + 1 + m 2
4
x2 y 2
Which touches the ellipse + =
1
1/ 4 1
1 3
Whose eccentricity e = 1 − =
4 4

24. Ans. : C
The equation of the normal at (a sec θ, b tan θ) to the given hyperbola is
ax cos θ + by cot θ = (a2 + b2)
This meets the transverse axis i.e. x-axis at G.
 a 2 + b2 
So, the coordinates of G are  sec θ, 0 
 a 
 
The coordinates of the vertices A and A′ are A (a, 0) and A′ (–a, 0) respectively
 a 2 + b2  a 2 + b2 
∴ AG A′G =  −a + sec θ  a + sec θ 
 a  a 
  
= (–a +ae2 sec θ) (a + ae2 sec θ)
= a2(e4 sec2 θ – 1)

25. Ans. : B
Let the equation to the rectangular hyperbola be x2 – y2 = a2 …. (i)
As the asymptotes of this are the axes of the other and vice versa, hence the equation of
the other hyperbola may be written as xy = c2 …. (ii)
Let (i) and (ii) meet at some point whose coordinates are (a sec α, a tan α)
Then the tangent at the point (a sec α, a tan α) to (i) is x – y sin α = a cos α … (iii)
2c 2
and the tangent at the point (a sec α, a tan α) to (ii) is y + x sin α = cos α …. (iv)
a
 Clearly, the slopes of the tangents given by (iv) and (iii) are respectively – sin α and
1
, so their product = – 1. Hence the tangents are at right angle.
sin α

26. Ans. : C
x2 y 2
Given ellipse is + = 1 …. (i)
16 4
Equation of a circle centered at (1, 0) can be written as (x – 1)2 + y2 = r2 ….(ii)
The abscissae of the intersection points of the circle and the ellipse is given by the
16 − x 2
equation : (x – 1)2 + = r2.
4

(1, 0) (4, 0)

i.e., 4(x2 – 2x + 1) + 16 – x2 = 4 r2
i.e., 3x2 – 8x + 20 – 4r2 = 0
If the circle lies inside the ellipse, then the roots of the above equation must be imaginary
or equal
i.e. D ≤ 0 i.e. 64 + 12(4r2 – 20) ≤ 0
11
⇒r=≤ .
3
11 11
Hence, greatest value of r = and the equation of required circle is (x – 1)2 + y2 =
3 3
2 2
i.e. 3(x + y ) – 16x – 8 = 0.

27. Ans. : A
 c
Equation of normal at any point  ct ,  is ct4 – xt3 + ty – c = 0
 t
⇒ slope of normal = t 2

Let P be (h, k) ⇒ ct4 – ht3 + tk – c = 0

h
⇒ ∑ ti = and ∑ ti t j = 0
c
∑ ti 2 = ( ∑ ti )
2
⇒
⇒ h2 = c2λ
⇒ required locus is x2 = λc2.

28. Ans. : D
Equations of tangents at two points having eccentric angles θ 1 and θ 2 are
x y
cos θ1 + sin θ1 =1 ….. (1)
a b
x y
cos θ2 + sin θ2 = 1 ….. (2)
a b
The point of intersection of (1) and (2) is
  θ1 + θ2   θ1 + θ2  
 a cos  2  b sin  2  
  ,  .
θ − θ
 cos  1 2  cos  1 2   θ − θ
     
  2   2  
It is given that θ 1 + θ 2 = 2k = constant
∴ point of intersection A(x 1 , y1 ) is
a cos k b sin k
x1 = , y1 =
 θ −θ   θ −θ 
cos  1 2  cos  1 2 
 2   2 
x a
⇒ 1 = cot k
y1 b
x a a θ +θ 
∴ Required locus= is =cot k cot  1 2  which is a straight line.
y b b  2 

29. Ans. : BC
 x2 y2
The given ellipse 2
+ 2 2
=
1 has eccentricity e = 1 − b 2
a a b
Thus if P(h, k) be the ends of the latus rectum of the ellipse then we have
a 2b 2
h = ± a e = ±a 1 − b 2 , k = ± = ±a b2
a
h2 h
Eliminating b from equation (i) and (ii), we have 1 − 2 = ± i.e. h2 ± ak = a2.
a a
Hence, equation of the required lotus is x ± ay = a .
2 2

30. Ans. : BCD

 1
Let (x i , yi ) =  ti ,  i = 1, 2, 3, 4
 ti 
 1
Any points on the rectangular heperbola xy = 1 is  t ,  which lies on the circle.
 t
1
x2 + y2 = 1 if t 2 + 2 = 1 ⇒ t4 – t2 + 1 = 0.
t
The roots of the equation are t 1 , t 2 , t 3 , t 4 ,
where t 1 + t 2 + t 3 + t 4 = 0 ⇒ x 1 + x 2 + x 3 + x 4 = 0
∑ t1t2 = –1, ∑ t1t2t3 = 0
t 1 t 2 t 3 t 4 = 1 ⇒ x 1 x 2 x 3 x 4 = y1 y2 y3 y4 = 1

and y1 + y2 + y3 + y4 = + + + =
1 1 1 1 ∑ t1t2t3 = 0
t1 t2 t3 t4 t1t2t3t4

31. Ans. : AB
Suppose the chords l 1 x + m 1 y = 1 and l 2 x + m 2 y =1 cut the ellipse at P and Q and R and
S respectively, such that the normals to ellipse at P, Q, R and S pass through T(h, k). Let
a 2 x b2 y
(α, β) be one of the points P, Q, R or S. Then equation of normal at (α, β) is −
α β
2 2
=a –b .
a 2h b2k
it passes through T(h, k). Therefore − = a2 – b2.
α β
a 2h b2k
∴ locus of (α, β) is − = a2 – b2.
x y
⇒ a hy – b kx = (a – b )xy
2 2 2 2
….. (1)
The equation of the curve passing through the intersection of the ellipse and one of the
chord l 1 x + m 1 y = 1 or l 1 x + m 2 y = 1 is
 x2 y 2 
 2 + 2 − 1 + λ(l 1 x + m 1 y – 1)(l 2 x + m 2 y – 1) = 0 …. (2)
 a b 
(1) and (2) both represents the same curve
1 1
∴ 2 + λl1l2 = 0 2 + λm1m2 = 0 and – 1 + λ = 0.
a b
1 1
⇒ 2 + l1l2 = 0, 2 + m1m2 = 0
a b
1 1
⇒ l1 l2 = − 2 , m1 m2 = − 2 .
a b

32. Ans. : BC
Clearly the vertices of the squares will lie on the director circle, i.e. on x2 + y2 = 4 + 3 and
hence the area of the square is 2(4 + 3) = 14. Only one such square is possible.

For 33-35
Incident beam have equation λx – y + 2(1 + λ) = 0
⇒ λ(x + 2) + (–y + 2) = 0
⇒ the rays are coming from (–2, 2). Reflected beam follow the equation
µx – y + 2(1 – µ) = 0
⇒ µ(x – 2) + (–y + 2) = 0
⇒ the rays converge at (2, 2)
So, the foci of the ellipse are S 1 (2, 2) and S 2 (–2, 2). The centre is C(0, 2). Further the
given circle must be auxiliary circle. So its radius = 3 = semi-major axis (a)
33. Ans. : C
2
S 1 S 2 = 4 = 2al. Thus e = .
3
34. Ans. : B
The triangle has largest area if the point of incidence coincedes with an end of major axis.
∴ Largest area = bac = a 1 − e 2 ae
4
= 3 1− ×2 = 2 5 .
9
35. Ans. : D
Since for every position of the point P on the ellipse PS 1 + PS 2 = constant (=2a = 6). So,
no such point exists.

36. Ans. : A
37. Ans. : C
38. Ans. : B

36. Equation of tangent in parametric form

x −1 y −1
= = ±3 2
−1/ 2 1/ 2
⇒A ≡ (4, –2), B ≡ (–2, 4)
−2
Equation of asymptotes (OA and OB) are y + 2 = ( x − 4) ⇒ 2y + 4 + x – 4 = 0
4
2y + x = 0
4
and y – 4 = ( x + 2) ⇒ y – 4 = –2x – 4
−2
2x + y = 0
(2x + y) (x + 2y) = 0 ⇒ 2x2 + 2y2 + 5xy = 0
1
37. mQA = − , mQB = −2
2
−1/ 2 + 2 3
∴ tan θ = =
1+1 4
3 3
sin θ = ⇒ θ = sin-1 .
5 5
38. Equation of the hyperbola is 2x2 + 2y2 + 5xy + λ = 0.
It passes through (1, 1)
So, 2 + 2 + 5 λ = 0 ⇒ λ = –9.
 7
Hyperbola 2x2 + 2y2 + 5xy = 9 so, the tangent at  −1,  is
 2
7 x.7 / 2 + (−1)
2x (–1) + 2y   + 5 = 9.
2 2
3x + 2y = 4.

39. Ans. : A – Q, B – S, C – R, D – P
(A) Equation of normal is y = –tx + 2at + at3.
2
It intersect the curve again at point Q(t 1 ) on the parabola such that t1 =−t − .
t
2
Again slope of OP is = m OP .
t
2
Alos, slope is OQ is = m OQ .
t1
4
Since m OP . m OQ = –1 = ⇒ tt 1 = –4.
tt1
 2
t  −t −  = – 4 ⇒ t2 = 2.
 t
(B) The points are P(1, 2), Q(4, 4), R(16, 8).
1 2 1
1
Now at(∆PQR) = 4 4 1 = 6 sq. unit.
2
16 8 1
(C) Equation of normal from any point P(am2, –2m) is y = mx – 2am – am3.
  11 1 
It passes through  , 
 4 4
⇒ 4m + 8m – 11m + 1 = 0
3

⇒ 4m3 + 3m + 1 = 0
Now, f(m) = 4m3 – 3m
⇒ f′(m) = 12m2 – 3 = 0
⇒ m = ± ½.
1  1
Since f   f  −  < 0 so, 3 normals are possible.
2  2
2
(D) Since, normal at P(t 1 ) if meets the curve again at (t 2 ), then t 2 = –t 1 – .
t1
Such, that here normal at P(1) meets the curve again at Q(t).
1
⇒t=–1– = –3.
2

40. Ans. : A – R, B – Q, C – PT, D – QS.

(A) Origin is the circumcentre
⇒ circle is x2 + y2 = 1
⇒ θ = π/4.
(B) A tangent to x2 + y2 = 1 is y = mx ± 1 + m 2
2m ± 1 + m 2
It touches (x – 2)2y2 = 4 if = 2.
1 + m2
1
⇒m=± .
3
1 2 1 2
The common tangents are y = x+ and y = x– which intersect at (–2, 0).
3 3 3 3
(C) Common chord of the given circles is (x2 + y2 – 8) – [(x – a)2 + y2 – 8] = 0.
⇒ 2x – a = 0
⇒ 2x/a = 1
Homogenising x2 + y2 – 8 = 0
2
 2x 
⇒ x + y – 8   = 0.
2 2

 a 
It represents perpendicular lines
32
⇒ 1− 2 +1 = 0
a
⇒ a2 = 16 ⇒ a = ± 4.
(D) (4, k) must lie on the director circle of the given circle which is x2 + y2 = 20. Thus
16 + k2 = 20 ⇒ k = ±2.

PHYSICS : 41 – 60 – SOLUTIONS :

41. N = mg + 2mg cos 60

3
F(2r sin 60) = mr2 α
2
3 F
f+ F =mrα ∴ f = N = 2mg
2 2 3
1
µ≥ .
2 3

F F
42. N = Mg + f =
2 2
f
Static friction µ s ≥ for any value if F.
N
F
∴ f = always.
2

3 2
43. mg sin θ – 3 f = Ma f=
(2r ) mr α
2
 g sin θ 4g
a= 2r α a= = .
9m 11
1+
8M

1 2
44. m(V1 − V2 =
) mv − D
2
GM GM 5GM
V1 = − , V2 = − v=
6R R 3R

2r 2 (1 − cos θ)
45. vav =
rθ v0
v0 v0
θ
θ
2sin  
=  
vav 2
vin = v0 ∴
vin θ

46. U=
k
1
2
(
m(2r 2 ) + 2mr 2 ω= )2
2mr 2ω2

=
v0 2r ω U k = mv0 2 .

l  ml 2 ml 2 ml 2  3v0 3 ×10
47. mv0 sin 30 =  + + ω ω= =
4  16 12 16  5l 1
5 
2
= 12 rad/s

48. mv0 R e = mvR

1 Gmme 1 Gmme 7GM e
mv0 2 − = mv 2 − v0 =
2 Re 2 r 4 Re
Solving r = 7R e ∴ height = 6R e

v0 ( u cos α ) + ( u sin α − gt )
2 2
49. =
Work done by gravity from O to Q = 0
Instantaneous power at the top of the trajectory = 0.

50. =
aB a0 sec θ − g tan θ > 0
∴ a0 > g sin θ

51. Vertical acceleration = 0

At t = 0, ac = 0 at = r α F=mrα
ω2 = 2α(2π) a =r α 1 + 16

52. Work done by gravity = U g1 − U g 2

= 10 m g r – 2 m g r
=8mgr
mv 2
N + mg = = 16 mg N = 15 mg
r
mv′2
At N′ = = 18 mg
r

53, 54, 55 : V 1 = velocity of the rod, V 2 = velocity of the particle

ω = angular velocity fo the rod
lω
v1 = mV 0 = 2mV 1 + mV 2
2
 2ml 2 
  ω + mV2 x = mV 0 x
 3 
xω − v2 1 2l 3V (1 + e)
= solving x = , ω = 0
v0 2 3 5l
 v0 (2 − 3e)
v2 =
5

56, 57, 58 : x = R sec θ, x′ = R sec θ tan . ω0 .

Rω0 2 (1 + sin 2 θ)
x′′ = = 14Rω0 2 at θ = 60o
cos θ3

20
N cos θ = Mx″ N = MRω0 2 (at θ = 30o)
9

59. 2v 3 – v 1 = v 0 cos 30
v 2 = v 0 sin 30 V2
v1 + v3 1 V1
=
v0 cos 30 2
V2
v0 v
Solving v 1 = 0, v 2 = v3 = 3 0
2 4
2 2
v 3v 5v 2
U KA = 0 U KB = 0 U K system = 0
8 16 16
2
3v
Energy dissipated = 0
16

60. a P = acceleration of the plank

aP
=Rα
2
maP α
f1 + f1′ =
2
f1′
3 
f1 (2r ) =  mr 2  α
2 
3 F
f1 = maP aP =
8 9m
M+
8
maP
Force on plank = Ma P , force on A =
2
Friction force on plank = 3f 1 .

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