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    Long Activity 5 - Che 408

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    imPERFECTme09
    1. The document provides 14 chemistry problems involving calculations of heat effects and concentrations for solutions of LiCl, HCl, and H2SO4 in water. The problems require determining heat effects, concentrations, temperatures, and amounts of substances involved in various mixing and reaction processes. 2. The problems cover topics like heat effects of mixing or dissolving salts in water, determining concentrations of solutions formed by mixing other solutions, and calculating heat transfer and steam requirements for evaporating acid solutions. 3. The final answers for each problem are to be rounded to 3 decimal places.

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    Long Activity 5 - Che 408

    Uploaded by

    imPERFECTme09
    697 views2 pages
    1. The document provides 14 chemistry problems involving calculations of heat effects and concentrations for solutions of LiCl, HCl, and H2SO4 in water. The problems require determining heat effects, concentrations, temperatures, and amounts of substances involved in various mixing and reaction processes. 2. The problems cover topics like heat effects of mixing or dissolving salts in water, determining concentrations of solutions formed by mixing other solutions, and calculating heat transfer and steam requirements for evaporating acid solutions. 3. The final answers for each problem are to be rounded to 3 decimal places.

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    Activity 5

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    1. The document provides 14 chemistry problems involving calculations of heat effects and concentrations for solutions of LiCl, HCl, and H2SO4 in water. The problems require determining heat effects, concentrations, temperatures, and amounts of substances involved in various mixing and reaction processes. 2. The problems cover topics like heat effects of mixing or dissolving salts in water, determining concentrations of solutions formed by mixing other solutions, and calculating heat transfer and steam requirements for evaporating acid solutions. 3. The final answers for each problem are to be rounded to 3 decimal places.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    697 views2 pages

    Long Activity 5 - Che 408

    Uploaded by

    imPERFECTme09
    1. The document provides 14 chemistry problems involving calculations of heat effects and concentrations for solutions of LiCl, HCl, and H2SO4 in water. The problems require determining heat effects, concentrations, temperatures, and amounts of substances involved in various mixing and reaction processes. 2. The problems cover topics like heat effects of mixing or dissolving salts in water, determining concentrations of solutions formed by mixing other solutions, and calculating heat transfer and steam requirements for evaporating acid solutions. 3. The final answers for each problem are to be rounded to 3 decimal places.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    LONG ACTIVITY 5 - CHE 408

    DIRECTION: Solve the following problems. Round off your final answer to 3
    decimal places.

    1. If a liquid solution of HCl in water, containing 1 mol of HCl and 4.5 mol of H2O,
    absorbs an additional 1 mol of HCl(g) at a constant temperature of 25°C, what is the heat
    effect?

    2. What is the heat effect when 20 kg of LiCl(s) is added to 125 kg of an aqueous solution
    containing 10-wt-% LiCl in an isothermal process at 25°C?

    3. An LiCl/H2O solution at 25°C is made by adiabatically mixing cool water at 10°C


    with a 20-mol-% LiCl/H2O solution at 25°C. What is the composition of the solution
    formed?

    4. A 20-mol-% LiCl/H2O solution at 25°C is made by mixing a 25-mol-% LiCl/H2O


    solution at 25°C with chilled water at 5°C. What is the heat effect in joules per mole of
    final solution?

    5. A liquid solution of LiCl in water at 25°C contains 1 mol of LiCl and 7 mol of water. If
    1 mol of LiCl 3H2O(s) is dissolved isothermally in this solution, what is the heat effect?

    6. What is the heat effect when 75 kg of H2SO4 is mixed with 175 kg of an aqueous
    solution containing 25-wt-% H2SO4 in an isothermal process at 300 K?

    7. For a 50-wt-% aqueous solution of H2SO4 at 350 K, what is the excess enthalpy HE in
    kJ·kg−1?

    8. A single-effect evaporator concentrates a 20-wt-% aqueous solution of H2SO4 to 70-


    wt-%. The feed rate is 15 kg·s−1, and the feed temperature is 300 K. The evaporator is
    maintained at an absolute pressure of 10 kPa, at which pressure the boiling point of 70-
    wt-% H2SO4 is 102°C. What is the heat-transfer rate in the evaporator?
    9. What is the heat effect when sufficient SO3(l) at 25°C is reacted with H2O at 25°C to
    give a 50-wt-% H2SO4 solution at 60°C?

    10. A mass of 70 kg of 15-wt-% solution of H2SO4 in water at 70°C is mixed at


    atmospheric pressure with 110 kg of 80-wt-% H2SO4 at 38°C. During the process heat in
    the amount of 20,000 kJ is transferred from the system. Determine the temperature of
    the product solution.

    11. An insulated tank, open to the atmosphere, contains 750 kg of 40-wt-% sulfuric acid
    at 290 K. It is heated to 350 K by injection of saturated steam at 1 bar, which fully
    condenses in the process. How much steam is required, and what is the final
    concentration of H2SO4 in the tank?

    12. Saturated steam at 3 bar is throttled to 1 bar and mixed adiabatically with (and
    condensed by) 45-wt-% sulfuric acid at 300 K in a flow process that raises the
    temperature of the acid to 350 K. How much steam is required for each pound mass of
    entering acid, and what is the concentration of the hot acid?

    13. For a 35-wt-% aqueous solution of H2SO4 at 300 K, what is the heat of mixing ΔH in
    kJ·kg−1?

    14. If pure liquid H2SO4 at 300 K is added adiabatically to pure liquid water at 300 K to
    form a 40-wt-% solution, what is the final temperature of the solution?

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