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    Tutorial 1 Ans

    Uploaded by

    harsh jetani
    This document provides answers to tutorial questions about chemistry concepts. It includes: 1) A calculation to determine the mass of zinc phosphate that will precipitate from a reaction between sodium phosphate and zinc chloride solutions. The mass is 0.386 g. 2) Calculations to find the final concentrations of zinc ions (0.0444 M) and sodium ions (0.133 M) after the above reaction. 3) Answers identifying the systematic name or molecular formula for several compounds as requested. 4) Identifying element C (with 15 protons and 17 neutrons) and element Ge as exhibiting semi-metallic behavior. 5) A calculation showing there are 4 iron atoms in each

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    Tutorial 1 Ans

    Uploaded by

    harsh jetani
    14 views3 pages
    This document provides answers to tutorial questions about chemistry concepts. It includes: 1) A calculation to determine the mass of zinc phosphate that will precipitate from a reaction between sodium phosphate and zinc chloride solutions. The mass is 0.386 g. 2) Calculations to find the final concentrations of zinc ions (0.0444 M) and sodium ions (0.133 M) after the above reaction. 3) Answers identifying the systematic name or molecular formula for several compounds as requested. 4) Identifying element C (with 15 protons and 17 neutrons) and element Ge as exhibiting semi-metallic behavior. 5) A calculation showing there are 4 iron atoms in each

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    This document provides answers to tutorial questions about chemistry concepts. It includes: 1) A calculation to determine the mass of zinc phosphate that will precipitate from a reaction between sodium phosphate and zinc chloride solutions. The mass is 0.386 g. 2) Calculations to find the final concentrations of zinc ions (0.0444 M) and sodium ions (0.133 M) after the above reaction. 3) Answers identifying the systematic name or molecular formula for several compounds as requested. 4) Identifying element C (with 15 protons and 17 neutrons) and element Ge as exhibiting semi-metallic behavior. 5) A calculation showing there are 4 iron atoms in each

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    14 views3 pages

    Tutorial 1 Ans

    Uploaded by

    harsh jetani
    This document provides answers to tutorial questions about chemistry concepts. It includes: 1) A calculation to determine the mass of zinc phosphate that will precipitate from a reaction between sodium phosphate and zinc chloride solutions. The mass is 0.386 g. 2) Calculations to find the final concentrations of zinc ions (0.0444 M) and sodium ions (0.133 M) after the above reaction. 3) Answers identifying the systematic name or molecular formula for several compounds as requested. 4) Identifying element C (with 15 protons and 17 neutrons) and element Ge as exhibiting semi-metallic behavior. 5) A calculation showing there are 4 iron atoms in each

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    Tutorial 1 - answers

    Marks
    • If 20.0 mL of a 0.100 M solution of sodium phosphate is mixed with 25.0 mL of a 6
    0.200 M solution of zinc chloride, what mass of zinc phosphate will precipitate from
    the reaction?

    Steps: 1) Write equation for the reaction; 2) Determine amount (in moles) of starting
    materials present; 3) Determine which of the starting materials is limiting; 4) Based on
    the limiting reagent, determine the amount (in moles) of product obtained; 5) Use molar
    mass of product to determine mass of product obtained.

    1. 3Zn2+ (aq) + 2PO4 3-(aq) → Zn3(PO4)2(s)

    2. 25.0 mL of a 0.200 M solution of ZnCl2 contains:


    n(Zn2+) = concentration × volume = (0.200 mol L-1) × (25.0 × 10-3 L)
    = 0.00500 mol

    20.0 mL of a 0.100 solution of Na3PO4 contains:


    n(PO43-) = (0.100 mol L-1) × (20.0 × 10-3 L) = 0.00200 mol

    3. Determine which reagent is limiting: if Zn2+ is limiting it would react with


    (2/3)0.00500 = 0.00333 mol of phosphate – the amount of phosphate present is less
    than this therefore phosphate is limiting. Put another way, if phosphate was
    limiting it would react with (3/2)0.00200 = 0.00300 mol of zinc – the amount of zinc
    present is more than this therefore phosphate is limiting.

    4. Based on the amount (moles) of phosphate present, the maximum amount of


    product formed is: ½ × 0.00200 mol = 0.00100 mol

    5. The molar mass of zinc phosphate is:


    (3 × 65.39 (Zn)) + 2 × (30.97 (P) + 4 × 16.00 (O)) = 386.11g mol-1-
    The mass of zinc phosphate produced is therefore:
    mass = number of moles × molar mass = 0.00100 × 386.11 = 0.386 g

    Answer: 0.386 g

    What is the final concentration of zinc ions in solution after the above reaction?

    The number of moles of Zn2+ removed by precipitation: 3 × 0.00100 = 0.00300 mol

    The amount remaining is therefore: 0.00500 – 0.00300 = 0.00200 mol

    The total volume of the solution after mixing is (20.0 + 25.0) = 45.0 mL so the
    concentration is:
    [Zn2+] = number of moles/volume in L
    = 0.00200 mol /(45.0 × 10-3 L) = 0.0444 M

    Answer: 0.0444 M
    Tutorial 1 - answers

    What is the final concentration of sodium ions in solution after the above reaction?

    20.0 mL of a 0.100 M solution of Na3PO4 contains:


    3 × 0.100 × 20 × 10-3 = 0.00600 mol of Na+

    After mixing, this amount is contained in a volume of 45.0 mL so the


    concentration is:

    [Na+] = number of moles/volume in L


    = 0.00600 mol /(45.0 × 10-3 L) = 0.133 M

    Answer: 0.133 M

    Marks
    • Complete the following table, giving either the systematic name or the molecular 2
    formula as required.
    Formula Systematic name
    SO2 sulphur dioxide
    cobalt(II) chloride-6-water
    CoCl2⋅6H2O
    (cobalt dichloride hexahydrate also OK)
    Ag2CrO4 silver chromate

    KHCO3 potassium hydrogencarbonate

    • What is the correct atomic symbol for an atom with 15 protons and 17 neutrons? 1

    17
    A 15 Cl
    17
    B 15 P
    32
    C P
    15 C is correct
    15
    D 17 Cl
    32
    E 17 Cl

    • Which one of the following elements exhibits semi-metallic (metalloid) behaviour? 1

    A Ar
    B Na
    C Ge
    C is correct
    D F
    E Xe
    Tutorial 1 - answers

    • Human haemoglobin has a molar weight of 6.45 × 104 g mol-1 and contains 3.46 g of Marks
    iron per kg. Calculate the number of iron atoms in each molecule of haemoglobin. 3

    Steps: 1) Determine number of moles of haemoglobin (Hb) in 1 kg of haemoglobin; 2)


    Determine number of moles of iron in 1 kg of haemoglobin; 3) Compare ratio of moles
    to give number of moles of iron per mole of haemoglobin or atoms of iron per molecule
    of haemoglobin.

    1. Number of moles of Hb in 1 kg of Hb is mass/molar mass


    = 1000 g / 6.45 x 104 g mol-1 = 0.0155 mol

    2. Number of moles of Fe in 1 kg of Hb is
    3.46 g / 55.85 g mol-1 = 0.0620 mol

    3. Ratio of moles of Fe to moles of Hb is 0.0620 : 0.0155 = 4 : 1

    There are 4 Fe atoms in every molecule of haemoglobin.

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