Slides Unit-I
Slides Unit-I
Silicon is one of the most abundant elements in the universe and it is the
second most abundant in the planet after oxygen.
It is also a semiconductor.
Over 80% of the earth’s crust is made of silicate material.
Si has larger bandgap than Ge
Si has more thermal stability
Si has very good natural oxide
Si has lower reveres saturation current
Contd…
SiO2 is a very good insulator (Resistivity > 120 Ω-cm, Energy gap ~ 9eV, High
breakdown strength >10MV/cm)
It is a good masking agent. It can be removed very easily by using HF acid.
It can be used for electrical isolation.
Metal layer are separated by SiO2.
It used for device isolation and field oxide.
The intrinsic resistivity of silicon is about 230,000 Ω-cm compared to Ge (47 Ω-
cm)
Contd…
Si is available in 3 form:
Amorphous silicon (poor mobility<1)
Polycrystalline silicon
Single crystalline silicon (it has perfect layer and very costly )
The standard technology stages for making chips
Suppose covalent bond number 1 contains a hole after losing an electron some time
before t = t1. At t = t2, an electron breaks away from bond number 2 and recombines with the
hole in bond number 1. Similarly, at t = t3, an electron leaves bond number 3 and falls into the
hole in bond number 2. Looking at the three “snapshots,” we can say one electron has traveled
from right to left, or, alternatively, one hole has moved from left to right. This view of current
flow by holes proves extremely useful in the analysis of semiconductor devices.
Bandgap Energy
A minimum energy is required to dislodge an electron from a covalent bond. Called the
“bandgap energy” and denoted by Eg, this minimum is a fundamental property of the material.
For silicon, Eg = 1.12eV
Contd…
The density (or concentration) of electrons, i.e., the number of electrons per unit volume, ni, for
silicon:
Where T is in Kelvin
Intrinsic and Extrinsic Semiconductors
The “pure” silicon an example of “intrinsic semiconductors,” suffering from a very high
resistance.
Fortunately, it is possible to modify the resistivity of silicon by replacing some of the atoms in
the crystal with atoms of another material.
In an intrinsic semiconductor, the electron density, n (= ni), is equal to the hole density, p. Thus,
As a result, the fourth bond contains a hole, ready to absorb a free electron.
The doped silicon crystal is now called a “p-type” semiconductor
The boron atom is called an “acceptor” dopant.
Contd…
Since typical doping densities fall in the range of 1015to 1018 atoms/cm3
Summary of charge carriers in silicon
Transport of Carriers
Drift
We know from basic physics and Ohm’s law that a material can conduct current in response to
a potential difference and hence an electric field.
The field accelerates the charge carriers in the material, forcing some to flow from one end to
the other. Movement of charge carriers due to an electric field is called “drift.”
Drift in semiconductors
Semiconductors behave in a similar manner. As shown in figure, the charge carriers are
accelerated by the field and accidentally collide with the atoms in the crystal, eventually
reaching the other end and flowing into the battery.
Contd…
The acceleration due to the field and the collision with the crystal counteract, leading to a
constant velocity for the carriers.
The velocity, v, to be proportional to the electric field strength, E:
where μ is called the “mobility” and usually expressed in cm2/(Vs). For example in silicon,
the mobility of electrons, μn = 1350 cm2/(Vs) and that of holes, μp= 480 cm2/(Vs).
Of course, since electrons move in a direction opposite to the electric field, we must express
the velocity vector as
For holes
Contd…
where v.W.h represents the volume, n.q denotes the charge density in coulombs, and the
negative sign accounts for the fact that electrons carry negative charge.
Contd…
Let us now reduce to a more convenient form. Since for electrons, v = −μnE, and since W.h is
the cross section area of the bar, we write
where Jn denotes the “current density,” i.e., the current passing through a unit cross section
area, and is expressed in A/cm2
In the presence of both electrons and holes, above equation is modified to
or 𝐽𝑡𝑜𝑡 = 𝜎𝐸 Resistivity ρ is given by
1
𝜎 = 𝑞 𝑝𝜇𝑝 + 𝑛𝜇𝑛 𝜌=
𝜎
Online resource.
𝜎 = 𝑐𝑜𝑛𝑑𝑢𝑐𝑡𝑖𝑣𝑖𝑡𝑦
S.No Title Link Duration
1. Razavi Electronics 1, Lec 2. Doping, Drift Click here Complete 1 hour
Problem: Find the resistivity of (a) intrinsic silicon and (b) p-type silicon with NA = 1016/cm3. Use
ni = 1.5 ×1010/cm3, and assume that for intrinsic silicon μn = 1350 cm2/Vs and μp = 480 cm2/Vs,
and for the doped silicon μn = 1110 cm2/Vs and μp = 400 cm2/Vs. (Note that doping results in
reduced carrier mobilities.)
Solution
(a) For intrinsic silicon, p = n = ni = 1.5×1010/cm3
1
Thus, 𝜌 =
𝑞 𝑝𝜇𝑝 +𝑛𝜇𝑛
𝜌 = 2.28 × 105 Ω. 𝑐𝑚
𝜌 = 1.56 Ω. 𝑐𝑚
Note: Observe that the resistivity of the p-type silicon is determined almost entirely by the doping
concentration and reduces its resistivity.
Velocity Saturation
We have thus far assumed that the mobility of carriers in semiconductors is independent of the
electric field and the velocity rises linearly with E according to v = μE.
In reality, if the electric field approaches sufficiently high levels, v no longer follows E linearly.
This is because the carriers collide with the lattice so frequently and the time between the
collisions is so short that they cannot accelerate much.
As a result, v varies “sublinearly” at high electric fields, eventually reaching a saturated level,
vsat as shown in figure. Called “velocity saturation,” this effect manifests itself in some modern
transistors, limiting the performance of circuits.
Final Expression
The drift velocity of electrons in silicon, for example, saturates at approximately 107 cm/s at an
electric field of approximately 30 kV/cm.
If the drift velocity of a charge carrier saturates, then the drift current density also saturates and
becomes independent of the applied electric field.
The low-field electron mobility in gallium arsenide is much larger than in silicon
approximately 8500 cm2/Vs.
Diffusion
Suppose a drop of ink falls into a glass of water. Introducing a high local concentration of ink
molecules, the drop begins to “diffuse,” that is, the ink molecules tend to flow from a region of
high concentration to regions of low concentration. This mechanism is called “diffusion.”
𝑑𝑛
𝐽∝
𝑑𝑥
where n denotes the carrier concentration at a given point along the x-axis.
We call dn/dx the concentration “gradient” with respect to x, assuming current flow only in the
x direction.
As with the convention used for the drift current, obtaining the current density as
𝐷𝑛 𝐷𝑝
= = 𝑉𝑇
𝜇𝑛 𝜇𝑝
𝑘𝑇
Note that 𝑉𝑇 = ≈ 26 𝑚𝑉 at T = 300 K. The parameter VT is known as the thermal voltage.
𝑞
𝐷𝑛 𝐷𝑝
Einstein Relation = = 𝑉𝑇
𝜇𝑛 𝜇𝑝
pn Junction
Significance of the pn junction.
The device finds application in many electronic systems, e.g., in adaptors that charge the
batteries of cellphones.
The pn junction is among the simplest semiconductor devices, thus providing a good
entry point into the study of the operation of such complex structures as transistors.
The pn junction also serves as part of transistors.
pn junction
pn Junction in Equilibrium
The pn junction with no external connections, i.e., the terminals are open and no voltage is
applied across the device. The junction is in “equilibrium.”
The sharp concentration gradient for both electrons and holes across the junction leads to two
large diffusion currents: electrons flow from the n side to the p side, and holes flow in the
opposite direction.
Formation of depletion region
For every electron that departs from the n side, a positive ion is left behind, i.e., the junction
evolves with time as conceptually shown in figure below.
In this illustration, the junction is suddenly formed at t = 0, and the diffusion currents continue
to expose more ions as time progresses.
Consequently, the immediate vicinity of the junction is depleted of free carriers and hence
called the “depletion region/space charge region/transition region.”
Electric field in a pn junction.
From basic physics that a particle or object carrying a net (nonzero) charge creates an electric
field around it.
Thus, with the formation of the depletion region, an electric field emerges as shown in figure
below
The field tends to force positive charge flow from left to right whereas the concentration
gradients necessitate the flow of holes from right to left (and electrons from left to right).
The junction reaches equilibrium once the electric field is strong enough to completely stop the
diffusion currents.
Alternatively, we can say, in equilibrium, the drift currents resulting from the electric field
exactly cancel the diffusion currents due to the gradients.
Contd…
Under equilibrium, the drift and diffusion currents are equal, i.e.
If the number of the electrons flowing from the n side to the p side is equal to that of the holes
going from the p side to the n side, then each side of this equation is zero while electrons
continue to accumulate on the p side and holes on the n side.
Therefore impose the equilibrium condition on each carrier:
Energy Band diagram of pn junction
This potential difference across the junction cannot be measured with a voltmeter because
new potential barriers will be formed between the probes and the semiconductor that will
cancel Vbi.
The potential Vbi maintains equilibrium, so no current is produced by this voltage.
Contd..
The intrinsic Fermi level is equidistant from the conduction band edge through the junction;
thus, the built-in potential barrier can be determined as the difference between the intrinsic
Fermi levels in the p and n regions, i.e,
where ni and EFi are the intrinsic carrier concentration and the intrinsic Fermi energy, respectively.
Contd..
The potential ∅𝐹𝑛 in the n region can be defined as
Or
Taking the natural log of both sides of above Equation, setting n0 = Nd, and solving for the
potential, we obtain
Contd..
The potential ∅𝐹𝑃 in the p region can be defined as
Or
Finally, the built-in potential barrier for the step junction is:
Built-in Potential
The existence of an electric field within the depletion region suggests that the junction may
exhibit a “built-in potential.” Using the following equation we can compute the built in
potential, we know that
or
Since the electric field E = −dV/dx, and above equation can be written as:
Contd…
where pn and pp are the hole concentrations at x1 and x2, respectively(as shown in figure below) .
Thus,
The right side represents the voltage difference developed across the depletion region and
will be denoted by V0. Also, from Einstein’s relation, we can replace Dp/μp with kT/q:
𝐾𝑇 𝑝𝑝 𝐷𝑛 𝐷𝑝
𝑉0 = ln = = 𝑉𝑇
𝑞 𝑝𝑛 𝜇𝑛 𝜇𝑝
Contd… P-Type
N-Type
The built-in potential is developed to oppose the flow of diffusion currents (and is, in fact,
sometimes called the “potential barrier”).
Problem:
A silicon pn junction employs NA = 2 × 1016 cm-3 and ND = 4 × 1016 cm-3. Determine the built-in
potential at room temperature (T = 300 K). 𝑈𝑠𝑒 𝑛𝑖 = 1.5 × 1010 𝑐𝑚−3
Answer: 𝑉0 = 751.39 𝑚𝑉
Problem:
(a) Calculate the built-in potential barrier in a silicon pn junction at T =300 K for (i) Na = 5× 1015
cm −3 , Nd =1017 cm−3 and (ii) Na= 2×1016 cm −3, Nd =2×1015 cm −3.
(b) Repeat part (a) for a GaAs pn junction. [𝑛𝑖𝐺𝑎𝐴𝑠 = 1.79 × 106 𝑐𝑚−3 ]
[Ans. (a) (i) 0.736 V, (ii) 0.671 V; (b) (i) 1.20 V, (ii) 1.14 V]
Charge Density
Figure: The space charge density in a uniformly doped pn junction assuming the abrupt junction
approximation.
Note: The space charge region abruptly ends in the n region at x = + xn and abruptly ends in the p
region at x = − xp.
Electric Field
The electric field is determined from Poisson’s equation, which, for a one dimensional analysis, is
(1)
where ∅ 𝑥 is the electric potential, E(x) is the electric field, 𝜌(x) is the volume charge density, and
𝜖𝑠 is the permittivity of the semiconductor. The charge densities are
(2)
(3)
Contd…
The electric field in the p region is found by integrating Equation (1). We have
(4)
The constant of integration is determined by setting E = 0 at x =− xp. The electric field in the p
region is then given by
(5)
(6)
Contd…
Setting equation 5 and 6 equal to each other at x = 0, gives
(7)
Equation (7) states that the number of negative charges per unit area in the p region is equal to the
number of positive charges per unit area in the n region.
Figure shows a plot of the electric field in the depletion
region. For the uniformly doped pn junction, the E-field is
a linear function of distance through the junction, and the
maximum (magnitude) electric field occurs at the
metallurgical junction (at x = 0). From Eq.(5) or (6), we
can write:
𝑒𝑁𝑑 𝑥𝑛 𝑒𝑁𝑎 𝑥𝑝 𝐸𝑚𝑎𝑥
𝐸𝑚𝑎𝑥 = − =−
𝜖𝑠 𝜖𝑠
Figure: Electric field in the space charge region
of a uniformly doped pn junction.
Contd…
V0 or
Figure: Electric potential through the space charge region of a uniformly doped pn junction.
Contd…
or
Depletion Layer Width (W) under forward bias Depletion Layer Width (W) under reverse bias
2 ∈𝑠 1 1 2 ∈𝑠 1 1
𝑊= + 𝑉0 − 𝑉𝑓 𝑊= + 𝑉0 + 𝑉𝑅
𝑞 𝑁𝐴 𝑁𝐷 𝑞 𝑁𝐴 𝑁𝐷
Problem: Consider a pn junction in equilibrium at room temperature (T = 300 K) for which the
doping concentrations are NA = 1018/cm3 and ND = 1016/cm3 and the cross-sectional area A = 10−4
cm2. Calculate pp, np, nn, pn, Vo, W, xn, xp , QJ and Emax .Use ni = 1.5×1010/cm3.
Solution
𝑛𝑖2 W = 0.327 𝜇𝑚
𝑛𝑝 ≅ = 2.25 × 102 𝑐𝑚−3
𝑁𝐴
𝑛𝑛 ≅ 𝑁𝐷 = 1016 𝑐𝑚−3 𝑥𝑛 = 0.324 𝜇𝑚
𝑛𝑖2 𝑥𝑝 = 0.003 𝜇𝑚
𝑝𝑛 ≅ = 2.25 × 104 𝑐𝑚−3
𝑁𝐷
𝑄𝐽 = 5.18 𝑝𝐶
Figure: A pn junction and its associated energy-band diagram for (a) zero bias, (b) reverse bias,
and (c) forward bias.
pn Junction Under Reverse Bias
An external voltage is applied across the device as shown in figure, where the voltage source
makes the n side more positive than the p side. .
The junction is under “reverse bias” to emphasize the connection of the positive voltage to the
n terminal.
Contd…
Figure: Variation of depletion width and junction capacitance with reverse bias.
Since under equilibrium, 𝐸is directed from the n side to the p side, VR enhances the field.
But, a higher electric field can be sustained only if a larger amount of fixed charge is provided,
requiring that more acceptor and donor ions be exposed and, therefore, the depletion region be
widened.
Contd…
Since the external voltage has strengthened the field, the barrier rises even higher than that in
equilibrium, thus prohibiting the flow of current.
In other words, the junction carries a negligible current under reverse bias.
With no current conduction, a reverse-biased pn junction operates as a capacitor.
Increasing values of VR, revealing that the capacitance of the structure decreases as the two
plates move away from each other.
The junction therefore displays a voltage-dependent capacitance.
Where Cj0 denotes the capacitance corresponding to zero bias (VR = 0) and V0 is the built in
potential.
Contd…
The value of Cj0 is in turn given by
where 𝜖𝑠𝑖 represents the dielectric constant of silicon and is equal to 11.7 ×8.85 × 10−14 F/cm.
Figure: Carrier profiles (a) in equilibrium and (b) under forward bias
Contd…
In forward bias, the potential barrier is lowered by an amount equal to the applied voltage:
where the subscript f denotes forward bias. Since the exponential denominator drops considerably,
we expect pn,f to be much higher than pn,e (it can be proved that pp,f ≈ pp,e ≈ NA).
In other words, the minority carrier concentration on the p side rises rapidly with the forward
bias voltage while the majority carrier concentration remains relatively constant. This statement
applies to the n side as well.
The change in the hole concentration on the n side is given as:
Contd…
or
Where A is the cross section area of the device, and Ln and Lp are electron and hole “diffusion
lengths,” respectively. Diffusion lengths are typically in the range of tens of micrometers.
Diffusion length is the average length a carrier moves between generation and recombination.
Semiconductor materials that are heavily doped have greater recombination rates and
consequently, have shorter diffusion lengths.
The diffusion length is related to the carrier lifetime by the diffusivity according to the
following formula: 𝐿 = 𝐷𝜏
where: L is the diffusion length; D is the diffusivity and τ is the lifetime in seconds.
Problem: Determine IS for the junction with NA = 2 × 1016 cm-3 and ND = 4 × 1016 cm-3 at
T = 300K if A = 100 μm2, Ln = 20 μm, and Lp = 30 μm.
02
Marks
The electrons enter the p side and roll down the gradient, they gradually recombine with the
holes, which are abundant in this region.
Similarly, the holes entering the n side recombine with the electrons. Thus, in the immediate
vicinity of the depletion region, the current consists of mostly minority carriers, but towards the
far contacts, it is primarily comprised of majority Carriers.
I/V Characteristics
In forward bias, the external voltage opposes the built-in potential, raising the diffusion
currents substantially.
In reverse bias, on the other hand, the applied voltage enhances the field, prohibiting current
flow. We hereafter write the junction equation as:
As VD becomes positive and exceeds several VT, the exponential term grows rapidly and
ID ≈ IS exp(VD/VT).
Contd…
Note that IS and hence the junction current are proportional to the device cross section area.
The temperature dependence of the reverse current is that it doubles for every 10°C rise in
temperature.
Contd…
Two identical devices placed in parallel (as shown in figure) behave as a single junction with
twice the IS.
The breakdown resulting from a high voltage (and hence a high electric field) can occur
in any material.
Once freed, the electrons are accelerated by the field and swept to the n side of the junction.
This effect occurs at a field strength of about 106 V/cm (1 V/μm).
In order to create such high fields with reasonable voltages, a narrow depletion region is
required, which requires high doping levels on both sides of the junction . Called the “Zener
effect,” this type of breakdown appears for reverse bias voltages on the order of 3-8 V.
Avalanche Breakdown
Junctions with moderate or low doping levels (<1015 cm3) generally exhibit no Zener breakdown. But, as the
reverse bias voltage across such devices increases, an avalanche effect takes place.
Even though the leakage current is very small, each carrier entering the depletion region experiences a very high
electric field and hence a large acceleration, thus gaining enough energy to break the electrons from their covalent
bonds. Called “impact ionization,” this phenomenon can lead to avalanche: each electron freed by the impact may
itself speed up so much in the field as to collide with another atom with sufficient energy, thereby freeing one
more covalent-bond electron.
Now, these two electrons may again acquire energy and cause more ionizing collisions, rapidly raising the number
of free carriers.
Charge Storage and Diode Transients
In forward bias, referred to as the on state, a relatively large current can be produced by a small
applied voltage.
In reverse bias, referred to as the off state, only a very small current will exist.
Of primary interest in circuit applications is the speed of the pn junction diode in switching
states.
The Turn-off Transient
Figure, shows a simple circuit that will switch the applied bias at t = 0. For t <0, the forward-bias
current is
Contd…
The minority carrier concentrations in the device, for the applied forward voltage VF, are
shown in Figure (a) below.
(1) the junction capacitance (Cj) due to the dipole in the transition region and
(2) the charge storage capacitance (Cs) or diffusion capacitance (Cd) arising due to charge
storage effects.
The junction capacitance is dominant under reverse-bias conditions, and the charge storage
In many applications of p-n junctions, the capacitance is a limiting factor in the usefulness of
the device.
Contd…
Figure: Transition and diffusion capacitance versus applied bias for a silicon diode
Diffusion Capacitance (Cd or Cs)
For a forward biased junction, holes diffuse
from p-side to the n-side.
Consequently, in the vicinity of the junction on
the n-side, we have a greater hole concentration
than normally exists because of the diffusion as
shown in figure.
This “excess” hole density can be considered as
charge storage in the neighborhood of the Figure: Steady-state forward-bias minority
junction. carrier concentrations;
Where, 𝜏 𝑇 = mean transit time or it is the average time it takes for a hole/electron injected into
the n/p- region to recombine with a majority electron/hole
𝜀𝑠 𝐴 𝐶𝑗0 ∈𝑠 𝑞 𝑁𝐴 𝑁𝐷 1
𝐶𝑇 𝑜𝑟 𝐶𝑗 = Or 𝐶𝑗 = where 𝐶𝑗0 =
𝑊𝑑𝑒𝑝 𝑉𝑅 2 𝑁𝐴 + 𝑁𝐷 𝑉0
1+
𝑉0
Schottky Barrier Diode
One of the first practical semiconductor devices used in the early 1900s was the metal–
semiconductor diode. This diode, also called a point contact diode.
It was made by touching a metallic whisker to an exposed semiconductor surface.
These metal–semiconductor diodes were not easily reproduced or mechanically reliable and
were replaced by the pn junction in the 1950s.
However, semiconductor and vacuum technology is now used to fabricate reproducible and
reliable metal–semiconductor contacts.
It is also called “hot carrier diode” because when the materials are joined, the electrons in the
n-type silicon semiconductor material immediately flow into the adjoining metal, establishing a
heavy flow of majority carriers.
Since the injected carriers have a very high kinetic energy level compared to the electrons of
the metal, they are commonly called “hot carriers.”
Contd…
The ideal energy-band diagram for a particular metal
and n-type semiconductor before making contact is
shown in figure.
The vacuum level is used as a reference level.
The parameter ∅m is the metal work function
(measured in volts), ∅s is the semiconductor work
function, ∅𝑚 > ∅𝑠 and 𝜒is known as the electron
affinity. (a)
Before contact, the Fermi level in the semiconductor
was above that in the metal.
In order for the Fermi level to become a constant
through the system in thermal equilibrium, electrons
from the semiconductor flow into the lower energy
states in the metal.
Positively charged donor atoms remain in the
semiconductor, creating a space charge region.
On the semiconductor side, Vbi is the built-in potential barrier. This barrier, similar to the case
of the pn junction, is the barrier seen by electrons in the conduction band trying to move into
the metal. The built-in potential barrier is given by
If we apply a positive voltage to the semiconductor with respect to the metal, the
semiconductor-to-metal barrier height increases, while ∅𝐵𝑂 remains constant. This bias
condition is the reverse bias.
If a positive voltage is applied to the metal with respect to the semiconductor, the
semiconductor-to-metal barrier Vbi is reduced while ∅𝐵𝑂 again remains essentially constant.
In this situation, electrons can more easily flow from the semiconductor into the metal since
the barrier has been reduced. This bias condition is the forward bias.
Contd…
Figure: Ideal energy-band diagram of a metal–semiconductor junction (a) under reverse bias and (b) under forward
bias.
Contd…
The current mechanism here, however, is due to the flow of majority carrier electrons.
In forward bias, the barrier seen by the electrons in the semiconductor is reduced, so majority
carrier electrons flow more easily from the semiconductor into the metal.
The forward-bias current is in the direction from metal to semiconductor: It is an exponential
function of the forward-bias voltage Va .
The electric field can be calculated using the following formula:
This electric field is a linear function of distance, for the uniformly doped semiconductor, and
reaches a peak value at the metal–semiconductor interface.
Since the E-field is zero inside the metal, a negative surface charge must exist in the metal at
the metal–semiconductor junction.
Contd…
The space charge region width, W, can be calculated as:
Table 1:Work function of some elements Table 2: Electron affinity of some semiconductors
Problem:
Determine the theoretical barrier height, built-in potential barrier, and maximum electric field in a
metal–semiconductor diode for zero applied bias. Consider a contact between tungsten and n-type
silicon doped to Nd =1016 cm−3 at T = 300 K.
The metal work function for tungsten (W) from Table 1 is ∅𝑚 = 4.55 𝑉and the electron affinity
for silicon from Table 2 is 𝜒 = 4.01 𝑉. The barrier height is then
Solution:
Characteristics
Source: Wikipedia contributors. "Schottky diode." Wikipedia, The Free Encyclopedia. Wikipedia, The Free Encyclopedia, 21 Jun.
2020. Web. 27 Aug. 2020.
Note:
Before leaving the subject of Schottky-barrier diodes, it is important to note that not every
metal–semiconductor contact is a diode.
In fact, metal is commonly deposited on the semiconductor surface in order to make terminals
for the semiconductor devices and to connect different devices in an integrated-circuit chip.
Such metal–semiconductor contacts are known as ohmic contacts to distinguish them from the
rectifying contacts that result in SBDs.
Ohmic contacts are usually made by depositing metal on very heavily doped (and thus low-
resistivity) semiconductor regions.
For more details go to the following online resource.
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1. Schottky Junction and Ohmic Contacts NPTEL Click here
Self Study
Photo Diode