Sample Number Sample Time Elapsed Time Sodium Hydroxide Concentaion (Mol/dm ) Ethyl Acetate Concentraio N (Mol/dm )

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Ethyl

Sample Sample Elapsed Sodium


Acetate
Number Time Time Hydroxide
Concentraio
Concentaion
n
[mol/dm³]
[mol/dm³]
1 02:16:58 00:00:00 0.100 0.100
6 02:21:57 00:05:00 0.100 0.100
11 02:26:57 00:10:00 0.100 0.100
16 02:31:57 00:15:00 0.100 0.100
21 02:36:57 00:20:00 0.100 0.100
26 02:41:58 00:25:00 0.100 0.100

Time (min) Measured Conductivity Conversion of NaOH Specific Rate Constant Ln K


00:00:00 12.99 0.0110 0.0020 -6.2146
00:05:00 13.62 0.0110 0.0020 -6.2146
00:10:00 14.60 0.0120 0.0030 -5.8091
00:15:00 15.66 0.0130 0.0030 -5.8091
00:20:00 16.52 0.0140 0.0030 -5.8091
00:25:00 17.21 0.0140 0.0030 -5.8091
Flowrate Flowrate Stirrer Reactor Reactor
Measured
of Sodium of Ethyl Speed Temp. Volume Note
Conductivity
Hydroxide Acetate s
0 - 20 [mS]
[cm³/min] [cm³/min] [rpm] [°C] [dm³]
40.0 40.0 12.99 0 34.6 1.00
40.0 40.0 13.62 0 37.8 1.00
40.0 40.0 14.60 0 42.4 1.00
40.0 40.0 15.66 0 47.6 1.00
40.0 40.0 16.52 0 51.8 1.00
40.0 40.0 17.21 0 55.1 1.00

1/T T K 1/K Chart Title


0.0289 34.6 307.7203 0.0032
0.0265 37.8 310.9430 0.0032 -5.6000
0.0030 0.0031 0.0031 0.0032 0.0032
0.0236 42.4 315.5328 0.0032
-5.7000
0.0210 47.6 320.7086 0.0031
0.0193 51.8 324.9078 0.0031 f(x) = − 2229.93628294654
-5.8091 -5.8091 x + 1.07164778455
-5.8091 -5.8091
-5.8000
0.0182 55.1 328.2281 0.0030
-5.9000

-6.0000

-6.1000

-6.2000

-6.3000
NaOH EtAC Initial Final Final
Feed Feed Feed NaOH NaAC
Concentration Concentration Conductivity Concentration Concentration
[mol/dm³] [mol/dm³] [mS] [mol/dm³] [mol/dm³]
0.05 0.05 12.2 0.00 0.05
0.05 0.05 12.8 0.00 0.05
0.05 0.05 13.6 0.00 0.05
0.05 0.05 14.5 0.00 0.05
0.05 0.05 15.3 0.00 0.05
0.05 0.05 15.9 0.00 0.05

Chart Title
1 0.0031 0.0032 0.0032 0.0033 0.0033

x) = − 2229.93628294654
5.8091 -5.8091 x + 1.07164778455153
-5.8091 -5.8091

-6.2146 -6.2146
Calculated Current Current Conversion Production Specific
Final NaOH NaAC of of Rate
Conductivity Concentration Concentration NaOH NaAC Constant
[mS] [mol/dm³] [mol/dm³] [%] [%] K
4.7 0.06 -0.01 -0.11 -0.11 -0.002
5.0 0.06 -0.01 -0.11 -0.11 -0.002
5.4 0.06 -0.01 -0.12 -0.12 -0.003
5.8 0.06 -0.01 -0.13 -0.13 -0.003
6.2 0.06 -0.01 -0.14 -0.14 -0.003
6.5 0.06 -0.01 -0.14 -0.14 -0.003
Measured Optional Optional
ln ((a - a1)/
Conductivity Temperature Temperature
(a - a0))
0 - 5 [mS] T2 [°C] T3 [°C]

0.102 0.00 35.64 199.90


0.105 0.00 40.04 199.90
0.116 0.00 45.41 199.90
0.124 0.00 50.78 199.90
0.129 0.00 54.69 199.90
0.134 0.00 57.62 199.90

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