Safety Data Sheet Clorox® Total 360 Disinfecting Spray: According To Regulation (EC) No 1907/2006, Annex II, As Amended
Safety Data Sheet Clorox® Total 360 Disinfecting Spray: According To Regulation (EC) No 1907/2006, Annex II, As Amended
Safety Data Sheet Clorox® Total 360 Disinfecting Spray: According To Regulation (EC) No 1907/2006, Annex II, As Amended
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Disinfectant.
Pictogram
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3.2. Mixtures
Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Eye Dam. 1 - H318
Classification
Aquatic Acute 1 - H400
Aquatic Chronic 3 - H412
Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
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Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Classification
Skin Corr. 1A - H314
Eye Dam. 1 - H318
Classification
Flam. Liq. 2 - H225
Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
The full text for all hazard statements is displayed in Section 16.
Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Maintain an open airway.
Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Place unconscious person on
their side in the recovery position and ensure breathing can take place.
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Ingestion Rinse mouth thoroughly with water. Do not induce vomiting unless under the direction of
medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Never give anything by mouth to an unconscious person. Move affected
person to fresh air and keep warm and at rest in a position comfortable for breathing. Place
unconscious person on their side in the recovery position and ensure breathing can take
place. Maintain an open airway. Loosen tight clothing such as collar, tie or belt.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Continue to
rinse for at least 15 minutes. Get medical attention if symptoms are severe or persist after
washing.
Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Get medical attention if symptoms are severe or persist after washing.
Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Wash
contaminated clothing thoroughly with water before removing it from the affected person, or
wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation Irritation of nose, throat and airway. Prolonged inhalation of high concentrations may damage
respiratory system.
Ingestion May cause stomach pain or vomiting. Fumes from the stomach contents may be inhaled,
resulting in the same symptoms as inhalation.
Skin contact Prolonged and frequent contact may cause redness and irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Toxic gases or vapours.
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Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.
Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash it
occupational hygiene before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each
work shift and before eating, smoking and using the toilet. Change work clothing daily before
leaving workplace.
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Protective equipment
Appropriate engineering Provide adequate ventilation. All handling should only take place in well-ventilated areas.
controls Avoid inhalation of vapours and spray/mists.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Unless the assessment indicates a higher degree of protection is
required, the following protection should be worn: Tight-fitting safety glasses. Personal
protective equipment for eye and face protection should comply with European Standard
EN166.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. The most suitable glove should be
chosen in consultation with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. To protect hands from chemicals, gloves
should comply with European Standard EN374. Considering the data specified by the glove
manufacturer, check during use that the gloves are retaining their protective properties and
change them as soon as any deterioration is detected. Frequent changes are recommended.
Other skin and body Appropriate footwear and additional protective clothing complying with an approved standard
protection should be worn if a risk assessment indicates skin contamination is possible.
Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be
allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment
and the work area every day. Good personal hygiene procedures should be implemented.
Wash at the end of each work shift and before eating, smoking and using the toilet. When
using do not eat, drink or smoke. Warn cleaning personnel of any hazardous properties of the
product.
Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective
equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits
tightly and the filter is changed regularly.
Environmental exposure Keep container tightly sealed when not in use. Residues and empty containers should be
controls taken care of as hazardous waste according to local and national provisions.
Colour Colourless.
pH pH (concentrated solution): 12
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Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Alkalis.
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Skin corrosion/irritation
Skin corrosion/irritation Based on available data the classification criteria are not met.
Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.
Genotoxicity - in vivo Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity - Based on available data the classification criteria are not met.
development
Aspiration hazard
Aspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure.
Tetrasodium ethylenediaminetetraacetate
Species Rat
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Notes (oral LD₅₀) Acute Tox. 4 - H302 Harmful if swallowed. Converted acute toxicity point estimate
(cATpE)
Skin corrosion/irritation
Animal data Skin Corr. 1B - H314 Causes severe skin burns and eye damage.
Notes (oral LD₅₀) Acute Tox. 4 - H302 Harmful if swallowed. Converted acute toxicity point estimate
(cATpE)
Notes (dermal LD₅₀) Acute Tox. 4 - H312 Harmful in contact with skin. Converted acute toxicity point
estimate (cATpE)
Skin corrosion/irritation
Animal data Skin Corr. 1B - H314 Causes severe skin burns and eye damage.
sodium hydroxide
Skin corrosion/irritation
Serious eye Dose: 0.1 ml (2%), 1 second, Rabbit REACH dossier information. Eye Dam. 1 -
damage/irritation H318
Skin sensitisation
Skin sensitisation Patch test - Human: Not sensitising. REACH dossier information.
Aspiration hazard
Aspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure.
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Ethanol
Species Rat
Species Rat
Skin corrosion/irritation
Animal data Dose: 0.2 ml, 24 hours, Rabbit Primary dermal irritation index: 0 REACH dossier
information. Not irritating.
Carcinogenicity
Reproductive toxicity
Reproductive toxicity - Maternal toxicity: - NOAEL: 16000 ppm, Inhalation, Rat REACH dossier information.
development
Amines, C12-18-alkyldimethyl
Species Rat
12.1. Toxicity
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Toxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.
M factor (Acute) 1
M factor (Acute) 10
M factor (Acute) 10
sodium hydroxide
Acute toxicity - fish LC₅₀, 48 hours: 189 mg/l, Leuciscus idus (Golden orfe)
Ethanol
Acute toxicity - fish LC₅₀, 96 hours: 14200 mg/l, Pimephales promelas (Fat-head Minnow)
LC₀, 96 hours: 7960 mg/l, Pimephales promelas (Fat-head Minnow)
REACH dossier information.
Amines, C12-18-alkyldimethyl
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M factor (Chronic) 1
Ethanol
sodium hydroxide
Ethanol
Ethanol
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General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements. When handling waste, the safety precautions applying to
handling of the product should be considered. Care should be taken when handling emptied
containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners
may retain some product residues and hence be potentially hazardous.
Disposal methods Neutralise waste with diluted hydrochloric acid. Avoid the spillage or runoff entering drains,
sewers or watercourses. Waste, residues, empty containers, discarded work clothes and
contaminated cleaning materials should be collected in designated containers, labelled with
their contents. Dispose of surplus products and those that cannot be recycled via a licensed
waste disposal contractor. Incineration or landfill should only be considered when recycling is
not feasible.
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations EH40/2005 Workplace exposure limits.
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EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March
2004 on detergents (as amended).
Abbreviations and acronyms ADR: European Agreement concerning the International Carriage of Dangerous Goods by
used in the safety data sheet Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by
Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.
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The information supplied here is accurate to the best knowledge and belief of the supplier, it is however, not intended as a
warranty or representation, and should not be construed as such, for which the supplier assumes any legal responsibility.
Any information or advice obtained from the supplier other than by means of this publication, and whether relating to the
supplier's products or other materials is also given in good faith. It remains at all times the responsibility of the customer, and
user, to ensure that the materials are suitable for the particular purpose intended. Materials not manufactured, or supplied, by
the supplier when used instead of, or in conjunction with materials supplied by the supplier, it is the customer's responsibility
to ensure that all technical, and other information related to such materials is obtained from the manufacturer or supplier. the
supplier accepts no liability for the data contained within this document, as the information herein may be applied under
conditions beyond our control, and in situations with which we may be unfamiliar. The information contained within this
document is furnished upon condition that the customer and user of this product makes his own determination of the suitability
of the product for his particular purpose.
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