8 Second PDF
8 Second PDF
8 Second PDF
Solutions to JEE(Main)-2019
Test Date: 8th April 2019 (Second Shift)
2. This Test Paper consists of 90 questions. The maximum marks are 360.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct
response.
4. Out of the four options given for each question, only one option is the correct answer.
5. For each incorrect response 1 mark i.e. ¼ (one-fourth) marks of the total marks allotted to the question
will be deducted from the total score. No deduction from the total score, however, will be made if no
response is indicated for an item in the Answer Box.
6. Candidates will be awarded marks as stated above in instruction No.3 for correct response of each
question. One mark will be deducted for indicating incorrect response of each question. No deduction
from the total score will be made if no response is indicated for an item in the answer box.
7. There is only one correct response for each question. Marked up more than one response in any
question will be treated as wrong response and marked up for wrong response will be deducted
accordingly as per instruction 6 above.
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-2
PART – A (PHYSICS)
1. A solid sphere and solid cylinder of identical radii approach an incline with the same
linear velocity (see figure). Both roll without slipping all throughout. The two climb
h
maximum heights hsph and hcyl on the incline. The radio sph is given by:
hcyl
4
(A) 1 (B)
5
2 14
(C) (D)
5 15
2. In the circuit shown, a four wire potentiometer is made of a 400 cm long wire, which
extends between A and B. The resistance per unit length of the potentiometer wire is r =
0.01 /cm. If an ideal voltmeter is connected as shown with jockey J at 50 cm from end
A, the expected reading of the voltmeter will be:
3. A parallel plate capacitor has 1F capacitance. One of its two plates is given + 2C
charge and the other plate, +4C charge. The potential difference developed across the
capacitor is:
(A) 3V (B) 1V
(C) 5V (D) 2V
4. If Surface tension (S), Moment of Inertia (I) and Planck’s constant (h), were to be taken
as the fundamental units, the dimensional formula for linear momentum would be:
(A) S1 / 2 I1 / 2 h0 (B) S1 / 2 I3 / 2 h1
(C) S3 / 2 I1 / 2 h0 (D) S1 / 2 I1 / 2 h1
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5. Two magnetic dipoles X and Y are placed at a separation d, with their axes
perpendicular to each other. The dipole moment of Y is twice that of X. A particle of
charge q is passing through their mid-point P, at angle = 450 with the horizontal line as
shown in the figure. What would be the magnitude of force on the particle at that instant?
(d is much larger than the dimensions of the dipole)
M
(A) 0 3
q (B) 0
4 d / 2
2M M
(C) 0 3
q (D) 2 0 3
q
4 d / 2 4 d / 2
7. A convex lens (of focal length 20 cm) and a concave mirror, having their principal axes
along the same lines, are kept 80 cm apart from each other. The concave mirror is to the
right of the convex lens. When an object is kept at a distance of 30 cm to the left o the
convex lens, its image remains at the same position even if the concave mirror is
removed. The maximum distance of the object for which this concave mirror, by itself
would produce a virtual image would be:
(A) 20 cm (B) 10 cm
(C) 30 cm (D) 20 cm
8. A cell of internal resistance r drives current through an external resistance R. The power
delivered by the cell to the external resistance will be maximum when:
(A) R = 0.001 r (B) R = 1000 r
(C) R = 2r (D) R = r
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10. The temperature, at which the root mean square velocity of hydrogen molecules equals
their escape velocity from the earth is closest to:
[Boltzmans Constant kB 1.38 1023 J / K
Avogadro number NA 6.02 10 26 / kg
Radius of Earth: 6.4 10 6 m
Gravitation acceleration on Earth = 10 ms-2]
(A) 800k (B) 104 K
5
(C) 3 10 (D) 650 K
11. A particle starts from origin O from rest and moves with a uniform acceleration along the
positive x – axis. Identify all figures that correctly represent the motion qualitatively.
(a = acceleration, v = velocity, x = displacement, t = time)
(a) (b)
(c) (d)
(A) a, b, c (B) a
(C) b, c (D) a, b, d
12. The election field in a region is given by E Ax B ˆi where E is in NC-1 and x in
meters. The values of constants are A = 20 SI unit and B = 10 SI unit. If the potential at x
=1 is V1 and that at x = – 5 is V2 then V1 – V2 is:
(A) 320 V (B) – 48 V
(C) – 520 V (D) 180 V
13. Young’s moduli of two wires A and B are in the ratio 7 : 4. Wire A is 2 m long and has
radius R. Wire A is 2 m long and has radius R. Wire B is 1.5 m long and has radius 2
mm. If the two wires stretch by the same length for a given load, then the value of R is
close to:
(A) 1.3 mm (B) 1.5 mm
(C) 1.7 mm (D) 1.9 mm
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14. A body of mass m1 moving with an unknown velocity of v1ˆi undergoes a collinear
collision with a body of mass m2 moving with a velocity v 2 ˆi . After collision m1 and m2
move with velocities of v ˆi and v ˆi respectively.
3 4
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19. A common emitter amplifier circuit, built using an npn transistor, is shown in the figure.
Its dc current gain is 250, RC = 1k and VCC = 10V. What is the minimum base current
for VCE to reach saturation?
20. A positive point charge is released from rest at a distance r0 from a positive line charge
with uniform density. The speed (v) of the point charge, as a function of instantaneous
distance r from line charge, is proportional to
r
(A) v e r /ro (B) v In
r0
r r
(C) v In (D) v
r0 r0
21.
Let A 1 3, A 2 5, and A 1 A 2 5. The value of 2A 1 3A 2 3A 1 2A 2 is:
(A) –106.5 (B) –112.5
(C) –118.5 (D) –99.5
22. In the figure shown, what is the current (in Ampere) drawn from the battery? You are
given
R1 15,R2 10, R3 20, R4 5,R5 25, R6 30, E 15V
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23. In a line of sight radio communication, a distance of about 50 km is kept between the
transmitting and receiving antennas. If the height of the receiving antenna is 70m, then
the minimum height of the transmitting antenna should be: (Radius of the Earth =
6.4 10 6 m)
(A) 32 m (B) 40 m
(C) 51 m (D) 20 m
24. A rocket has to be launched from each in such a way that it never returns. If E is the
minimum energy delivered by the rocket launcher, what should be the minimum energy
that the launcher should have if the same rocket is to be launched from the surface of
the moon? Assume that the density of the earth and the moon are equal and that the
earth’s volume is 64 times the volume of the moon.
E E
(A) (B)
32 16
E E
(C) (D)
64 4
25. A circuit connected to an ac source of emf e = e0 sin (1000t) with t in seconds, gives a
phase difference of between the emf e and current i. Which of the following circuits
4
will exhibit this?
(A) RC circuit with R = 1 k and C = 1 F (B) RL circuit with R = 1 k and L = 10 mH
(C) RL circuit with R = 1 k and L = 1 mH (D) RC circuit with R = 1 k and C = 10 F
26. A nucleus A, with a finite de – broglie wavelength A, undergoes spontaneous fission
into two nuclei B and C of equal mass. B flies in the same direction as that of A, while C
flies in the opposite direction with a velocity equal to half of that of F. The de – Broglie
wavelength B and C of B and C are respectively :
(A) A , 2 A (B) 2 A , A
(C) A , A (D) A , A
2 2
27. Calculate the limit of resolution of a telescope objective having a diameter of 200 cm, if it
has to detect light of wavelength 500 nm coming from a star.
(A) 457.5 10 9 radian (B) 610 10 9 radian
(C) 305 109 radian (D) 152.5 10 9 radian
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28. Two very long, straight and insulated wires are kept at 900 angle from each other In xy –
plane as shown in the figure.
These wires carry currently of equal magnitude I, whose directions are shown in the
figure. The met magnetic field at point P will be:
I 0I
(A) 0 xˆ yˆ (B) ẑ
2d d
I
(C) Zero (D) 0 xˆ yˆ
2d
29. The given diagram shows four processes i.e., isochoric, isothermal and adiabatic. The
correct assignment of the processes, in the same order is given by:
(A) a d c b (B) a d b c
(C) d a c b (D) d a b c
30. A uniform rectangular thin sheet ABCD of mass M has length a and breadth b, as shown
in the figure. If the shaded portion HBGO is cut off, the coordinates of the centre of mass
of the remaining portion will be:
5a 5b 2a 2b
(A) , (B) ,
3 3 3 3
3a 3b 5a 5b
(C) , (D) ,
4 4 12 12
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PART –B (CHEMISTRY)
31. The statement that is INCORRECT about the interstitial compound is:
(A) they have metallic conductivity (B) they have high melting points
(C) they are chemically reactive (D) they are very hard
(A) (B)
(C) (D)
(A) (B)
(C) (D)
34. If p is the momentum of the fastest electron ejected from a metal surface after the
irradiation of light having wavelength , then for (A)5 p momentum of the photoelectron,
the wavelength of the light should be:
(Assume kinetic energy of ejected photoelectron to be very high in comparison to work
function)
3 1
(A) (B)
4 2
4 2
(C) (D)
9 3
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35. The ion that has sp3d2 hybridization for the central atom is:
(A) IF6 – (B) ICI4 –
(C) ICI2 – (D) BrF2 –
(A) (B)
(C) (D)
k k
37. For a reaction scheme. A 1
B 2
C if the rate of formation of B is set to be zero
then the concentration of B is given by
k1
(A) A (B) k1 k 2 A
k
2
(C) k1k 2 A (D) k1 k 2 A
38. For the following reactions, equilibrium constants are given:
S s O2 g
SO2 g ;K1 10
52
2S s 3O2 g
2SO3 g;K 2 10
129
The equilibrium constant for the reaction 2SO2 g O2 g
2SO3 g is:
(A) 1077 (B) 1025
(C) 10181 (D) 10154
39. Calculate the standard cell potential (in V) of the cell in which following reaction takes
place:
Fe2 aq Ag aq Fe3 aq Ag s
Given that:
E 0 Ag'/ Ag xV
E 0Fe2 /Fe yV
E 0Fe3 /Fe zV
(A) x – z (B) x + y – z
(C) x – y (D) x + 2y – 3z
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-11
(C) (D)
42. The IUPAC symbols for the element with atomic number 119 would be:
(A) uun (B) uue
(C) unh (D) une
43. Which of the following compounds will show the maximum ‘enol’ content?
(A) CH3COCH3 (B) CH3COCH2CONH2
(C) CH3COCH2COCH3 (D) CH3COCH2COOC2H5
44. 0.27 g of a long chain fatty acid was dissolved in 100 cm3 of hexane. 10 mL of this
solution was added dropwise to the surface of water in a round watch glass. Hexane
evaporates and a monolayer is formed. The distance from edge to centre of the watch
glass is 10 cm. What is the height of the monolayer?
[Density of fatty acid = 0.9 g cm-3, = 3]
(A) 10-4 m (B) 10-8 m
-2
(C) 10 m (D) 10-6 m
48. 5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its
temperature becomes 200 K. If C V 28 JK 1 mol1 , calculate U and pV for this
process. (R = 8.0 J K–1 mol-1)
(A) U 2.8kJ; pV 0.8kJ (B) U 14 kJ; pV 4kJ
(C) U 14kJ; pV 18kJ (D) U 14kJ; pV 0.8J
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-12
49. The calculated spin only magnetic moments (BM) of the anionic and cationic species of
Fe H2O 6 and Fe CN 6 , respectively, are:
2
(A) 0 and 5.92 (B) 2.84 and 5.92
(C) 0 and 4.9 (D) 4.9 and 0
(A) (B)
(C) (D)
53. The strength of 11.2 volume solution of H2 O 2 is: [Given that molar mass of H = 1 g mol-1
and O = 16 g mol-1]
(A) 3.4% (B) 1.7%
(C) 13.6% (D) 34%
54. For the solution of the gases w, x, y and z in water at 298 K, the Henrys law constants
(KH) are 0.5, 2 35 and 40 kbar, respectively. The correct plot for the given data is:
(A) (B)
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-13
(C) (D)
(A) (B)
(C) (D)
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60. Consider the bcc unit cells of the solid 1 and 2 with the position of atoms as shown
below. The radius of atom B is twice that of atom A. The unit cell edge length is 50%
more in solid 2 than in 1. What is the approximate packing efficiency in solid 2?
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-15
PART–C (MATHEMATICS)
61. Let S x, y : y 2
x,0 and A is area of the regions S . If for a
, 0 4, A : A 4 2 : 5 then equals:
1 1
2 3 2 3
(A) 4 (B) 2
5 5
1 1
4 3 4 3
(C) 4 (D) 2
25 25
x x
62. Let f x g t dt, were g is a non zero even function. If f(x+5) =g(x) , then f t dt
0 0
equals
5 x5
(A) g t dt (B) 2 g t dt
x 5 5
x 5 5
(C) g t dt
5
(D) 5 g t dt
x5
63. Suppose that the points (h, k), (1, 2) and (–3, 4) lie on the line L1. If a line L2 passing
k
through the points (h, k) and (4, 3) is perpendicular to L1, then equals:
h
1 1
(A) (B)
7 3
(C) 3 (D) 0
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3 i 9
66. If z
2 2
i 1 , then 1 iz z5 iz8 is equal to:
(A) –1 (B) 1
(C) (–1 + 2i)9 (D) 0
69.
If f 1 1,f ' 1 3 , then the derivative of f f f x f x
2
at x = 1 is:
(A) 33 (B) 15
(C) 9 (D) 12
70. The number of four – digit numbers strictly greater than 4321 that can be formed using
the digits 0, 1, 2, 3, 4, 5 (repetition of digits is allowed) is:
(A) 360 (B) 288
(C) 310 (D) 306
71. If a point R (4, y, z) lies on the line segment joining the points P (2, –3, 4) and Q (8, 0,
10), then the distance of R from the origin is:
(A) 53 (B) 6
(C) 2 14 (D) 2 21
73. A student score the following marks in five tests : 45, 54, 41, 57, 43. His score is not
known for the sixth test. If the mean score is 48 in the six tests, then the standard
deviation of the marks in six tests is:
10 100
(A) (B)
3 3
100 10
(C) (D)
3 3
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74. The vector equation of the plane through the line of intersection of the planes x + y + z =
1 and 2x + 3y + 4z = 5 which is perpendicular to the plane x – y + z = 0 is:
(A) r ˆi kˆ 2 0 (B) r. ˆi kˆ 2 0
(C) r. ˆi kˆ 2 0 (D) x ˆi kˆ 2 0
75. If the lengths of the sides of a triangle are in A.P. and the greatest angle is double the
smallest, then a ratio of lengths of the sides of this triangle:
(A) 4:5:6 (B) 5:6:7
(C) 3:4:5 (D) 5:9:13
76. In an ellipse, with centre at the origin, if the difference of the lengths of major axis and
minor axis is 10 and one of the foci is at (0, 5 3 ), then the length of its latus rectum is:
(A) 6 (B) 5
(C) 8 (D) 10
77. The minimum number of times one has to toss a fair coin so that the probability; of
observing at least one head is at least 90% is:
(A) 2 (B) 3
(C) 4 (D) 5
78. If the eccentricity of the standard hyperbola passing, through the point (4, 6) is 2, then
the equation of the tangent to the hyperbola at (4, 6) is:
(A) 2x – 3y + 10 = 0 (B) x – 2y + 8 = 0
(C) 2x – y – 2 = 0 (D) 3x – 2y = 0
20
1
80. Then sum k 2
k 1
k
is equal to:
11 11
(A) 2 (B) 1
219 220
21 3
(C) 2 20 (D) 2 17
2 2
81. Let a 3iˆ 2ˆj xkˆ and b ˆi ˆj k,
ˆ for some real x. Then a b r is possible if:
3 3 3
(A) r 5 (B) 3 r 5
2 2 2
3 3 3
(C) r3 (D) 0 r
2 2 2
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-18
83. The tangent to the parabola y2 = 4x at the point where it intersects the circle x2 + y2 = 5
in the first quadrant, passes through the point:
1 4 3 7
(A) , (B) ,
3 3 4 4
1 1 1 3
(C) , (D) ,
4 2 4 4
84. The height of a right circular cylinder of maximum volume inscribed in a sphere of radius
3 is:
(A) 3 (B) 6
2
(C) 2 3 (D) 3
3
1 1 1
85. Let the numbers 2, b, c be in an A.P and A 2 b c . If det A 2,16 then ce lies
4 b 2 c 2
in the interval
(A) 3,2 22/4
(B) 2 23/4 , 4
(C) {2,3) (D) [4, 6]
1
dx
87. If x 6 2/3
xf x 1 x 6 3
C where C is a constant of integration, then the
3
1 x
function f(x) is equal to:
1 1
(A) 2 (B)
2x 2x 3
1 3
(C) 3 (D) 2
2x x
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-19
88. Two vertical poles of heights, 20 m and 80m stand a apart on a horizontal plane. The
height (in meters) of the point of intersection of the lines joining the top of each pole to
the foot of the other, from his horizontal plane is:
(A) 18 (B) 12
(C) 16 (D) 15
6
1 1
89. If the fourth term in the binomial expansion of 1 log x x 12 is equal to 200, and x >
x 10
1, then the value of x is:
(A) 104 (B) 100
(C) 103 (D) 10
90. If three distinct number a, b, c are in G.P. and the equations ax2 + 2bc + c = 0 and
dx2 + 2ex + f = 0 have a common root, then which one of the following statements is
correct?
d e f
(A) , , are in A.P (B) d, e, f are in A.P
a b c
d e f
(C) , , are in G.P (D) d, e, f are in G.P
a b c
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-20
PART B – CHEMISTRY
PART C – MATHEMATICS
61. C 62. A 63. B 64. B
65. A 66. A 67. A 68. D
69. A 70. C 71. C 72. B
73. D 74. C 75. A 76. B
77. C 78. C 79. A 80. A
81. A 82. D 83. B 84. C
85. D 86. B 87. B 88. C
89. All options are incorrect 90. A
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-21
4. p = k saIbhc
Where k is dimensionless constant
MLT–1 = (MT–2)a(ML2)b(ML2T–1)c
a+b+c=1
2b + 2c = 1
–2a – c = –1
1 1
a b c 0
2 2
S1/2II/2h0
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-22
5. M 2M
B1 2 0 3
; B2 0 3
4 (d / 2) 4 (d / 2)
B1 = B2
Bnet is at 45° ( = 45°)
6. A = A0e–t
A
A 0 after 10 oscillations
2
After 2 seconds
A0
A 0 e (2) ; 2 = e2
2
n2
n2 2 ;
2
A = A0e –t
A n2
n 0 t ; n1000 t
A 2
3n10 6n10
2 t ; t
n2 n2
t = 19.931 sec
t 20 sec
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-23
E
8. Current i =
r R
Power generated in R
P = i2R
E2R
P
(r R)2
dP
For maximum power 0
dR
(r R)2 1 R 2(r R)
E2 0
(r R)4
r=R
30 sec 1
9. T T sec,
20 20
L = 55 cm L = 1 mm = 0.1 cm
2
4 L
g=
T2
percentage error in g is
g L 2T
100 100%
g L T
1
0.1 2
= 20 100% 6.8%.
55 30
20
3RT
10. v rms v escape 2gRe
m
v rms v escape
3RT
2gRe
m
3 1.38 10 23 6.02 10 26
10 103 104 k
2
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-24
V1 V2 (20x 10)dx
5
V1 V2 (10x 2 10x)15
V1 – V2 = 10(25 – 5 – 1 – 1)
V1 – V2 = 180 V
13. Given:
YA 7
LA = 2m AA = R2
YB 4
LB = 1.5 m AB = (2mm))2
F
Y
A L
AY
given F and are same is same
L
A A YA A B YB
LA LB
7
( R2 ) YB 2
4 (2 mm) YB
2 1.5
R = 1.74 mm
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-25
1
20. mV 2 q(Vf Vi )
2
E
20r
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-26
r
V n 0
20 r
1 q r0
mv 2 n
2 2 0 r
r
v n
r0
21. A 1 3, A 2 5, and A1 A 2 5.
2 2
A 1 A 2 A 1 A 2 2 A 1 A 2 cos
3
cos
10
2A 1 3A 2 3A 1 2A 2
2 2
= 6 A1 9A1 A 2 4A 1 A 2 6 A 2
= –118.5
22.
25 45 25 90 160
Req 15 30
3 3 3
E 15 3 9
I amp.
Req 160 32
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-27
25. Given phase difference = and = 100 rad/s
4
Reactance (X) = Resistance (R)
Now by checking option.
Option (A)
1
R = 1000 and XC 6
= 104
10 100
Option (B)
R = 103 and XL = 10 × 10–3 × 100 = 1
Option (C)
R = 103 and XL = 10–3 100 = 10–1
Option (D)
1
R = 103 and XC = 103
10 10 6 100
26.
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-28
1.22
27. Limit of resolution of telescope =
D
1.22 500 10 9
= 305 × 10—9 radian
200 10 2
30. a M 3a
M
x 2 4 4
M
M
4
a 3a 3a 5a
= 2 16 4 16 5a
3 3 12
4 4
b M 3b
M
5b
y= 2 4 4
M 12
M
4
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-29
PART B – CHEMISTRY
31. In case of interstial compounds there is presence of small atoms (or impurity) in the
lattice of metal. So interstial compounds are hard, high melting point and chemically
inert.
32.
O O
t BuO
t BuOH
Cl Cl
O
H OH
O
O-H
(c)
Cl CH2 Cl Cl CH2Cl
(d) H O
2
Cl CH2Cl Cl CH2OH
(e)
2 2 Cl /H O
Cl CH2OH Cl CHO
O
1 1 m 2u2 1 P 2
34. K.E mu2
2 2 m 2 m
hc 1 P2
Wo K.E 1 Wo
1 2m
2
hc 1 1.5P
Wo K.E 2 Wo
2 2 m
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-30
On solving
4
2 1
9
Since the K.E is very high is comparison to work function, then we can assume that
K.E + Wo = K.E
36.
K eq
SO3
2
O2 SO2
K 2 10129
1025
K1 10104
39. Oxidation
Fe
2 aq Ag aq Fe3 aq Ag s E0Cell 3
Reduction
Given:
E0 Ag'/ Ag x 1
E0Fe2 /Fe y 2
E0Fe3 /Fe z 3
Using equation:
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-31
G0 nFE0
G01 Fx
G02 2Fy
G03 3Fz
Fe2 2e Fe 2Fy
Fe3 3e Fe 3Fz
41. The direct monomer of Nylon-6 is caprolactum which polymerises to give Nylon-6 as
follows:
H
N O
533 K
N2 inert
Nylon-6
42 The IUPAC name of element having atomic number 119 is “Ununennium”. So its symbol
is uue.
43. O O
C C
H3C CH2 CH3
Due to presence of active methylene group and stabilization of enol by intramoelcular H
bond forming 6 membered ring structure.
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-32
45. In CH4
Mole of carbon nC = 1
Mole of hydrogen = nH = 4
% of nC = nC 1
100 100 20%
nC nH 5
46. The mond’s process is used for refining of nickel as per following reaction.
Ni CO g
330350K
Ni CO 4 Ni s 4CO g
450 470K
Impure
Pure
47. In this case antimarkonikov product will be formed as major product because
carbocation formed at a double bonded carbon having lesser number of H atom will be
unstable due to presence of an electron withdrawing group (CF3) attached to it.
HCl
F3C CH CH2
CF3 CH CH3 CF3 CH2 CH2
min or major
Cl
CF3 CH2 CH2 CF3 CH2 CH2
Cl
(major product)
48. ∆U = nCvm ∆T
= 5 28 100 = 14 kJ
∆PV = nR∆T
= 5 8 100 = 4 kJ
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-33
N N
N N
CH3 I
Base
N N N N
H (Adenine) CH3
The nitrogen atom marked with * contain high electron density. It is attached to one H-
atom which can be removed by base OH– and the CH3 group gets attached there.
2 2 2
C 2 1s 1s 2s 2s 2p x 2Py 2Pz
55. 2 * 2 2 * 2 2
10 4
B.O 3 diamagnetic
2
2 2 2 2 1
1s 1s 2s 2s 2p x 2Py 2Pz 2p x 2Py
2 * 2 2 * 2 1 *
N2
10 6
B.O 2 paramagnetic
2
2 2 2 2
1s 1s 2s 2s 2Pz 2p x 2Py 2p x 2Py
2 * 2 2 * 2 2 2 *
O2
10 8
B.O 1 diamagnetic
2
2 2 1
1s 1s 2s 2s 2Pz 2p x 2Py 2p x 2Py
2 * 2 2 * 2 2 1 *
O2
10 6
B.O 2 paramagnetic
2
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-34
56. The reaction involves carbylamine reaction of 1o amine with CHCl3/KOH followed by
reduction with Pd/C/H2.
NH2 NC
CHCl3 /KOH
H
CN O CN O
Pd/C/H2
N - CH3
CH2NH2 OH
57. Maximum prescribed concentration of copper in drinking water is 3 ppm. Above this
concentration water becomes toxic.
58.
Cl Cl
ICl4 sp3 d2 I
Cl Cl
Cl
Cl Cl
I
ICl5 sp3d2
Cl Cl
4
Vol. occupied by atom r 3
3
60. % packing efficiency 100 3 100
Vol. of unit cell a
Let radius of corner atom is r and radius of central atom is 2r
So, 3a 2 2r 2r 6r
6r
a 2 3r
3
Now
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-35
4 4 3
3
r 3 3 2r
% P.E = 3
100
2 3r
4
3
r 3 8r 3 100
8 3 3 r3
4 9r 3
100 90.6% 90%
3 8 3 3 r3
PART C – MATHEMATICS
4 3/ 2
61. S 2 x dx
0 3
S 2 3/2 2
3/2
S 4 5 4 5
1/3 (, 0)
4
4
25
f t dt g t 5 dt
0 0
x 5
g t dt
5
5
g t dt
x 5
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-36
L1
L2
x x x x
a a a a
64. f1 x and f2 x
2 2
f1 x y f1 x y
1 xy
2
a a x y a x y a x y
1
ax ay a y a x a y a y
2
ax a x ay a y
2.
2 2
2f1 x f1 y
x 1 x 1,0
x x 0,1
65. f x
2x x 1,2
x 2 x 2, 3
f x is discontinuous at x 0,1
i
3 i
66. z e6
2
8 9
1 iz z iz
5
9
1 e e e
i /2 i /6 i5 /6
ei /2ei8 /6
11 9
i
1 ei 2 /6 ei5 /6 e 6
9
1 3 9
i
2 2
e
i /3
ei3 1
67.
(A) p q p ~ q
~ p q p ~ q
~ p ~ q p ~ q
T
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-37
(B) p q p
~ p q p ~ p ~ q p
~ p p ~ q
=T
(C) ~ p p q
~ p p q T
(D) ~ p q ~ p q
~ p ~ q ~ p q
~ p T T
dy 2y
68.
dx x 2
2
n y nC
x
Passes through (1, 1)
0 2 n C
2
n y 2
x
xn y 2 x 1
2
69.
f f f f x f x
dy
dx
f ' f f x f ' f x f ' x 2f x f ' x
Put x = 1
dy
27 6 33
dx
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-38
41 45 54 57 43 x
73. AM = 48
6
x 48
1
2 482 412 452 542 572 432 482
6
14024
2 2304
6
100
3
74. P1 : x y z 1
P2 :2x 3y 4z 5
Required plane is P1 P2 0
1 2 x 1 3 y 1 4 z 1 5 …..(i)
which is perpendicular to x y z 0
1 2 1 3 1 4 0
1
3
(i) x z 2 0
r . ˆi kˆ 2 0
75. Given 2b a c
Let A , B 3, C 2
2 sinB sin A sin C
2 sin3 sin sin 2
2 3 4 sin2 1 2cos
2
8 cos 2cos 3 0
3
cos
4
sin A :sinB :sin C
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-39
1: 4 3 sin2 :2 cos
5 6
1: :
4 4
4:5:6
76. be 5 3
b2 e2 75
b a b a 75 b a 15
b 10, a 5
2a2
LR 5
b
1 9
77. 1 n
2 10
1 1
10 2n
2n 10
n4
x2 y2
78. Let equation of hyperbola be 1
a 2 b2
passes through (4, 6)
16 36
2 2 1 (i)
a b
b2
Also e2 1 2 b2 3a 2 (ii)
a
From (i) and (ii)
a2 4, b2 12
x2 y2
Equation 1
4 12
y
Tangent at (4, 6) is x 1
2
Or
2x y 2
2
79.
D 4 1 3m 4 1 m2 1 8m
4 1 9m 6m 1 8m m2 8m3
2
2
8m 4m 4m 1
2
8m 2m 1 0
Infinitely many values of m.
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-40
20
k
80. S k
k 1 2
1 2 3 20
S 2 3 ..... 20
2 2 2 2
1 1 2 20
S 2
3 ....... 21
2 2 2 2
1 1 1 1 1 20
S 2 3 ...... 20 21
2 2 2 2 2 2
1 1
1 20
2 2 20
21
1 2
2
21
1 21
2
11
s 2 19
2
ˆi ˆj kˆ
81. ab 3 2 x
1 1 1
2 x ˆi 3 x ˆj 5kˆ
a b 2 x 2 x 19
2 5 3
2 x 1/ 2 191/4
2
1
82. Slope of OP
3
Equation of PQ is
y 1 3 x 3 P
3, 1
y 3x 4
4
Q , 0 O
3 Q
2
Area
3
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-41
83. x 2 4x 5
x 5, x 1
P 1, 2 P (1, 2)
Tangent at P is y x 1
3 7
4 , 4 lies on this.
1 1 1
85. 2 b c
2
4 b c2
C2 C2 C1, C3 C3 C1
1 0 0
2 b2 c 2
4 b 4 c2 4
2
1 1
b 2 c 2
b2 c2
A b 2 c 2 c b
2,b,c are in AP 2,2 d, 2 2d
A d 2d d 2d3 2, 16
d3 1, 8
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-42
2d 2, 4
2 2d 4, 6
86. 1 Form
f 3 x f 2x f 3 f 2
k lim
x 0
x 1 f 2 x f 2
f ' 3 x f ' 2 x
lim
x f ' 2 x
x 0 1 f 2 x f 2
0
ek 1
dx
87. I 2/3
x 1 x6
3
dx
2/3
1
x7 1 6
x
dx dt
Put 1 x 6 t
x7 6
1/3
1 dt 1 1
I 2/ 3 1 6 C
6 t 2 x
1/3
1 1 x
6
1/3
2 x 2
x f x 1 x6 C
1
f x 3
2x
h 20 h 80
88. ,
y x xy x
h y h xy
,
20 x 80 x
h h 80
1
20 80
100 h
h
1
1600
h 16
x–y y
6 3
89. C3 x 1 log x . x1/4 200
2
1 3
1 logx
x4 2
10
1 3
1 log10 x .log10 x 1
4 2
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JEE-MAIN-2019 (8th Apr-Second Shift)-PCM-43
6t 2 5t 4 0, t log10 x
D0
So no real solution
All options are incorrect
90. b2 ac
Also roots of ax 2 2bx c 0 are equal
b
x , common root
a
2
b b
d 2e 0
a a
db2 2aeb fa2 0, b2 ac
dac 2eab fa2 0
dc 7eb fa 0
Dividing by ac
d 2e f
0
a b c
d f e
2.
a c b
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