4.3 Isothermal Process
4.3 Isothermal Process
4.3 Isothermal Process
Four pounds of air gain 0.491 BTU/°R of entropy during a non-flow isothermal process. If initial
pressure is 120 psia and the final volume is 42.5 ft3, find the following:
4. Heat in BTU
Given:
m = 4 lbm
P1 = 120 psia
V2 = 42.5 ft3
Required:
1. V1 = ? ft3
2. T = ? °F
3. WNF = ? BTU
4. Q = ? BTU
5. ΔU = ? BTU
Solution:
The gas undergoes an isothermal process, so we will use the conditions under this process.
𝑃1
∆𝑠 = 𝑚𝑅𝑙𝑛
𝑃2
But we are looking for V1, so let’s use the relationship of volume and pressure at isothermal
process:
𝑃1 𝑉1 = 𝑃2 𝑉2
𝑃1 𝑉2
=
𝑃2 𝑉1
𝑏𝑦 𝑠𝑢𝑏𝑠𝑡𝑖𝑡𝑢𝑡𝑖𝑜𝑛:
𝑃1
𝑓𝑟𝑜𝑚: ∆𝑠 = 𝑚𝑅𝑙𝑛
𝑃2
𝑉2
∆𝑠 = 𝑚𝑅𝑙𝑛
𝑉1
∆𝑠 𝑉2
= 𝑙𝑛
𝑚𝑅 𝑉1
∆𝑠 𝑉2
𝑒 [𝑚𝑅] =
𝑉1
𝑉2
𝑉1 = ∆𝑠
𝑒 [𝑚𝑅]
𝑤ℎ𝑒𝑟𝑒:
𝐵𝑇𝑈
∆𝑠 = 0.491
°𝑅
𝑚 = 4 𝑙𝑏𝑚
𝑓𝑡 ∙ 𝑙𝑏𝑓
𝑅 = 53.34 (𝑡ℎ𝑒 𝑔𝑎𝑠 𝑖𝑠 𝑎𝑖𝑟)
𝑙𝑏𝑚 ∙ °𝑅
𝑉2 = 42.5 𝑓𝑡 3
42.5 𝑓𝑡 3
𝑉1 =
𝐵𝑇𝑈
0.491
°𝑅
𝑓𝑡∙𝑙𝑏𝑓 1 𝐵𝑇𝑈
[4 𝑙𝑏𝑚][53.34 ][ ]
[ 𝑙𝑏𝑚∙°𝑅 778.16 𝑓𝑡∙𝑙𝑏𝑓 ]
𝑒
𝑽𝟏 = 𝟕. 𝟎𝟗 𝒇𝒕𝟑 (𝑨𝑵𝑺𝑾𝑬𝑹)
NOTES:
Therefore, to find the temperature, we can use the ideal gas equation:
𝑓𝑟𝑜𝑚: 𝑃𝑉 = 𝑚𝑅𝑇
𝑃𝑉
𝑇=
𝑚𝑅
To be more specific, let’s use the initial values of pressure and volume. On the other hand,
m, R, and T are constants.
𝑃1 𝑉1
𝑇=
𝑚𝑅
𝑤ℎ𝑒𝑟𝑒:
𝑃1 = 120 𝑝𝑠𝑖𝑎
𝑉1 = 7.09 𝑓𝑡 3
𝑚 = 4 𝑙𝑏𝑚
𝑓𝑡 ∙ 𝑙𝑏𝑓
𝑅 = 53.34
𝑙𝑏𝑚 ∙ °𝑅
𝑙𝑏𝑓 2
[120 ] [7.09 3 ] [12 𝑖𝑛]
𝑓𝑡
𝑖𝑛2 1 𝑓𝑡
𝑇=
𝑓𝑡 ∙ 𝑙𝑏𝑓
[4 𝑙𝑏𝑚 ] [53.34 ]
𝑙𝑏𝑚 ∙ °𝑅
𝑇 = 574.2182227°𝑅
𝑇 = 574.2182227°𝑅 − 460
𝑉2
𝑊𝑁𝐹 = 𝑃1 𝑉1 𝑙𝑛
𝑉1
𝑤ℎ𝑒𝑟𝑒:
𝑃1 = 120 𝑝𝑠𝑖𝑎
𝑉2 = 42.5 𝑓𝑡 3
𝑙𝑏𝑓 3] [
12 𝑖𝑛 2 1 𝐵𝑇𝑈 42.5 𝑓𝑡 3
𝑊𝑁𝐹 = [120 ] [7.09 𝑓𝑡 ] [ ] ln [ ]
𝑖𝑛2 1 𝑓𝑡 778.16 𝑓𝑡 ∙ 𝑙𝑏𝑓 7.09 𝑓𝑡 3
𝑉2
𝑄 = 𝑃1 𝑉1 𝑙𝑛 = 𝑊𝑁𝐹
𝑉1
𝑡ℎ𝑒𝑟𝑒𝑓𝑜𝑟𝑒:
∆𝑼 = 𝟎 𝑩𝑻𝑼 (𝑨𝑵𝑺𝑾𝑬𝑹)