SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

SECTION 1. IDENTIFICATION

Product name : Skydrol® LD4 Fire Resistant Hydraulic Fluid

Product code : P3410201

Manufacturer or supplier's details

Company name of supplier : Eastman Chemical Company

Address : 200 South Wilcox Drive

Kingsport TN 37660-5280

Telephone : (423) 229-2000

Emergency telephone number : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

For emergency transportation information, in the United States:
call CHEMTREC at 800-424-9300 or call 423-229-2000.
Recommended use of the chemical and restrictions on use
Recommended use : Hydraulic fluids

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Skin irritation : Category 2

Carcinogenicity : Category 2

GHS label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H315 Causes skin irritation.

H351 Suspected of causing cancer.

Precautionary statements : Prevention:

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P332 + P313 If skin irritation occurs: Get medical advice/ atten-
tion.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Components
Chemical name CAS-No. Concentration (% w/w)
Tributyl phosphate 126-73-8 55 - 65
Dibutylphenylphosphate 2528-36-1 20 - 30
Butyl diphenyl phosphate 2752-95-6 5 - 10
7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2- 62256-00-2 < 10
ethylhexyl ester
butylated hydroxytoluene 128-37-0 1

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.

If breathing is difficult, give oxygen.
Consult a physician if necessary.

In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
Get medical attention if symptoms occur.
Wash contaminated clothing before reuse.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Get medical attention if symptoms occur.

If swallowed : Call a physician or poison control centre immediately.

Do not induce vomiting without medical advice.
Rinse mouth.
Never give anything by mouth to an unconscious person.

Most important symptoms : Causes skin irritation.

and effects, both acute and Suspected of causing cancer.
delayed

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray

Carbon dioxide (CO2)
Dry chemical
Foam

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

Hazardous combustion prod- : carbon dioxide, carbon monoxide

ucts oxides of phosphorus

Further information : Use a water spray to cool fully closed containers.

Do not allow run-off from fire fighting to enter drains or water
courses.

Special protective equipment : Wear an approved positive pressure self-contained breathing

for firefighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Ventilate the area.

tive equipment and emer- Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
gency procedures Avoid contact with skin and eyes.
Material can create slippery conditions.
Wear appropriate personal protective equipment.
Local authorities should be advised if significant spillages
cannot be contained.

Environmental precautions : Clear up spills immediately and dispose of waste safely.

Avoid release to the environment.
Collect spillage.

Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not breathe vapours or spray mist.

Handle product only in closed system or provide appropriate
exhaust ventilation at machinery.
In case of insufficient ventilation, wear suitable respiratory
equipment.
Wear appropriate personal protective equipment.
Avoid contact with skin, eyes and clothing.

3 / 19
SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Wash thoroughly after handling.

Wash contaminated clothing before reuse.
Drain or remove substance from equipment prior to break-in
or maintenance.
Handle in accordance with good industrial hygiene and safety
practice.

Conditions for safe storage : Store locked up.

Keep container tightly closed in a dry and well-ventilated
place.
Keep in a cool place away from oxidizing agents.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Tributyl phosphate 126-73-8 TWA (Inhal- 5 mg/m3 ACGIH
able fraction
and vapor)
TWA 0.2 ppm NIOSH REL
2.5 mg/m3
TWA 5 mg/m3 OSHA Z-1
TWA 0.2 ppm OSHA P0
2.5 mg/m3
Dibutylphenylphosphate 2528-36-1 TWA 0.3 ppm ACGIH
butylated hydroxytoluene 128-37-0 TWA (Inhal- 2 mg/m3 ACGIH
able fraction
and vapor)
TWA 10 mg/m3 NIOSH REL
TWA 10 mg/m3 OSHA P0
Hazardous components without workplace control parameters
Components CAS-No.
7-Oxabicyclo[4.1.0]heptane-3- 62256-00-2
carboxylic acid, 2-ethylhexyl
ester
Engineering measures : Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to con-
ditions. If applicable, use process enclosures, local exhaust
ventilation, or other engineering controls to maintain airborne
levels below recommended exposure limits. If exposure lim-
its have not been established, maintain airborne levels to an
acceptable level.

Personal protective equipment

Respiratory protection : Use a properly fitted, particulate filter respirator complying
with an approved standard if a risk assessment indicates this
is necessary.

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Respirator selection, use, and maintenance must be in ac-

cordance with regulatory requirements, if applicable.
If engineering controls do not maintain airborne concentra-
tions below recommended exposure limits (where applicable)
or to an acceptable level (in countries where exposure limits
have not been established), an approved respirator must be
worn.

Hand protection

Remarks : Wear suitable gloves. Please observe the instructions regard-

ing permeability and breakthrough time which are provided
by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used,
such as the danger of cuts, abrasion, and the contact time.
After contamination with product change the gloves immedi-
ately and dispose of them according to relevant national and
local regulations.

Eye protection : Wear safety glasses with side shields (or goggles).

Skin and body protection : Wear suitable protective clothing.

Protective measures : Ensure that eye flushing systems and safety showers are
located close to the working place.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : oily

Colour : purple

Odour : odourless

pH : No data available

Melting point/range : < -62 °C

Flash point : 160 °C

Method: Cleveland open cup

Vapour pressure : 0.27 hPa (25 °C)

Relative density : 1.004 - 1.014 (25 °C)

Viscosity
Viscosity, kinematic : < 2000 mm2/s (-54 °C)

11.15 mm2/s (38 °C)

3.83 mm2/s (99 °C)

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

SECTION 10. STABILITY AND REACTIVITY

Reactivity : None reasonably foreseeable.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : None known.

tions

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Emits acrid smoke and fumes when heated to decomposition.
products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product
Acute oral toxicity : LD50 (Rat, Male and Female): 2,100 mg/kg

Acute inhalation toxicity : LC50 (Rat, male): > 5.8 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: (highest concentration tested)

Acute dermal toxicity : LD50 Dermal (Rabbit, Male and Female): > 3,160 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity

Tributyl phosphate:
Acute oral toxicity : LD50 Oral (Rat, Male and Female): 1,553 mg/kg
Method: Acute Oral Toxicity
Assessment: Harmful if swallowed.

Acute inhalation toxicity : LC50 (Rat, Male and Female): > 4.242 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity

Acute dermal toxicity : LD50 Dermal (Rabbit, Male and Female): > 3,100 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity

Dibutylphenylphosphate:

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Acute oral toxicity : Acute toxicity estimate (Rat, Male and Female): 2,400 - 3,000
mg/kg
Assessment: Not classified

Acute inhalation toxicity : LCLo (Rat, Male and Female): > 5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist

LC50 (Rat, Male and Female): > 5 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: Not classified

Acute dermal toxicity : LD50 Dermal (Rabbit, Male and Female): > 5,000 mg/kg
Assessment: Not classified

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Acute oral toxicity : LD50 Oral (Rat, Male and Female): 4,470 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit, Male and Female): > 7,940 mg/kg

butylated hydroxytoluene:
Acute oral toxicity : LD50 Oral (Rat): > 6,000 mg/kg

Acute dermal toxicity : LD50 Dermal (Guinea pig): > 20,000 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Product
Species: Rabbit
Exposure time: 24 h
Assessment: irritating
Result: moderate irritation

Tributyl phosphate:
Species: Rabbit
Exposure time: 4 h
Assessment: Causes skin irritation.
Method: Acute Dermal Irritation / Corrosion
Result: irritating

Dibutylphenylphosphate:
Species: Rabbit
Assessment: Not classified

Species: Humans
Exposure time: 24 h
Assessment: Not classified

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Species: Rabbit

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Exposure time: 24 h
Assessment: Not classified as hazardous.
Result: slight to moderate irritation

butylated hydroxytoluene:
Species: Rabbit
Exposure time: 24 h
Result: very slight

Serious eye damage/eye irritation

Not classified based on available information.
Product
Species: Rabbit
Result: slight
Exposure time: 24 h
Assessment: Not classified

Tributyl phosphate:
Species: Rabbit
Result: slight irritation
Exposure time: 24 h
Assessment: Not classified
Method: Acute Eye Irritation / Corrosion

Dibutylphenylphosphate:
Species: Rabbit
Result: slight
Assessment: Not classified

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Species: Rabbit
Result: slight irritation
Exposure time: 24 h
Assessment: Not classified

butylated hydroxytoluene:
Species: Rabbit
Result: none

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Product
Test Type: Human experience
Assessment: Not classified
Method: Human Repeat Insult Patch Test
Result: Does not cause skin sensitisation.

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Tributyl phosphate:
Test Type: Skin Sensitization
Species: Guinea pig
Assessment: Not classified
Result: Does not cause skin sensitisation.

Test Type: Skin Sensitization

Species: Humans
Assessment: Not classified
Result: Does not cause skin sensitisation.

Dibutylphenylphosphate:
Test Type: Human experience
Species: Humans
Assessment: Not classified
Result: non-sensitizing

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Test Type: Skin Sensitization
Species: Guinea pig
Result: May cause sensitisation by skin contact.

butylated hydroxytoluene:
Test Type: Skin sensitisation
Species: Guinea pig
Result: non-sensitizing

Germ cell mutagenicity

Not classified based on available information.
Product
Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test)
Metabolic activation: +/- activation
Result: negative

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Method: In vitro Mammalian Chromosome Aberration Test
Result: negative

Tributyl phosphate:
Genotoxicity in vitro : Test Type: Mutagenicity - Bacterial
Metabolic activation: +/- activation
Method: Bacterial Reverse Mutation Assay
Result: negative

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Method: In vitro Mammalian Chromosome Aberration Test
Result: equivocal

Genotoxicity in vivo : Species: Rat (Male and Female)

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Application Route: oral: gavage

Method: Mammalian Bone Marrow Chromosome Aberration
Test
Result: negative

Dibutylphenylphosphate:
Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test)
Metabolic activation: +/- activation
Method: Bacterial Reverse Mutation Assay
Result: negative

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Method: In vitro Mammalian Cell Gene Mutation Test
Result: negative

: Test Type: Chromosome aberration test in vitro

Metabolic activation: +/- activation
Method: In vitro Mammalian Chromosome Aberration Test
Result: negative

: Test Type: Mutagenicity - Mammalian

Metabolic activation: - activation
Method: Genetic Toxicology: DNA Damage and Repair, Un-
scheduled DNA Synthesis in Mammalian Cells In Vitro
Result: negative

Genotoxicity in vivo : Species: Rat (Male and Female)

Application Route: intraperitoneal injection
Result: negative

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test)
Metabolic activation: +/- activation
Method: Bacterial Reverse Mutation Assay
Result: negative

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Method: In vitro Mammalian Chromosome Aberration Test
Result: equivocal

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Method: In vitro Mammalian Cell Gene Mutation Test
Result: negative

Genotoxicity in vivo : Species: Rat (Male and Female)

Application Route: intraperitoneal injection
Method: Mammalian Bone Marrow Chromosome Aberration
Test
Result: equivocal

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Carcinogenicity
Suspected of causing cancer.

Tributyl phosphate:
Species: Rat, (Male and Female)
Application Route: Ingestion
Method: EPA OTS 798.3300
Remarks: Limited evidence of a carcinogenic effect.
May cause cancer.

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.

Tributyl phosphate:
Effects on fertility :
Test Type: Two Generation Reproductive Toxicity Study
Species: Rat
Sex: Male and Female
Application Route: Ingestion
NOAEL: 225 mg/kg,
Method: EPA OTS 798.4900

Effects on foetal develop- : Species: Rat

ment Application Route: Oral
750 mg/kg
Method: EPA OTS 798.4900

Dibutylphenylphosphate:
Effects on fertility :
Species: Rat
Sex: Male and Female
Application Route: Ingestion
NOAEL: 5 mg/l,
F1: Lowest observed adverse effect level 50 mg/kg,
F2: Lowest observed adverse effect level 50 mg/kg,
Method: EPA OTS 798.4900

Effects on foetal develop- : Species: Rat

ment Application Route: oral (gavage)

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

300 mg/kg
3 mg/kg

STOT - single exposure

Not classified based on available information.

Tributyl phosphate:
Assessment: Based on available data, the classification criteria are not met.

Dibutylphenylphosphate:
Assessment: Not classified

STOT - repeated exposure

Not classified based on available information.

Tributyl phosphate:
Assessment: Based on available data, the classification criteria are not met.

Dibutylphenylphosphate:
Exposure routes: inhalation (dust/mist/fume)
Target Organs: Respiratory system
Assessment: Not classified

Repeated dose toxicity

Product
Species: Rat, Male and Female
NOAEL: 40 mg/m3
Application Route: Inhalation
Exposure time: 28 days
Target Organs: Blood, Respiratory system
Remarks: Irritating to eyes and respiratory system.

Tributyl phosphate:
Species: Mouse, Male and Female
NOEL: 75 mg/kg
Application Route: in feed
Exposure time: 90 days

Dibutylphenylphosphate:
Species: Rat, Male and Female
NOAEL: 5 mg/kg
LOAEL: 50 mg/kg
Application Route: oral (feed)
Exposure time: 90 days

Species: Rat, Male and Female

NOAEC: 5 mg/m3
Application Route: Inhalation

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Exposure time: 90 days

Species: Rabbit, Male and Female

No observed adverse effect level: 100 mg/kg bw/day
Application Route: Dermal Study
Exposure time: 21 d

Aspiration toxicity
Not classified based on available information.
Product
Not applicable

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Not applicable

Experience with human exposure

Product
Inhalation : Remarks: None known.

Skin contact : Remarks: Causes skin irritation.

Eye contact : Remarks: Contact with the eyes may be very painful but does
not cause damage.

Ingestion : Remarks: None known.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5.2 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 5.8 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): 8.2 mg/l

Exposure time: 96 h

Components:
Tributyl phosphate:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 4.2 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.8 mg/l

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Desmodesmus subspicatus (Scenedesmus

subspicatus)): 1.1 mg/l
Exposure time: 72 h

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): 0.82 mg/l
icity) Exposure time: 95 d

1.7 mg/l

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 1.3 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)

Dibutylphenylphosphate:
Toxicity to fish : LL50 (Cyprinus carpio (Carp)): 1.8 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.4 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EL50 (Selenastrum capricornutum (green algae)): 9.6 mg/l

Exposure time: 72 h
Method: EL50 method of the water accommodated fraction
(W.A.F.)

NOELR (Selenastrum capricornutum (green algae)): 3.5 mg/l

Exposure time: 72 h
Method: EL50 method of the water accommodated fraction
(W.A.F.)

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): > 0.11 mg/l
icity) Exposure time: 60 d

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.106 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)

butylated hydroxytoluene:
Toxicity to fish : LC50 (Fish): 0.199 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia (water flea)): 0.48 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Chlorella pyrenoidosa (aglae)): 0.758 mg/l

Exposure time: 96 h

Persistence and degradability

Product:
Biochemical Oxygen De- : Remarks: not determined
mand (BOD)

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Chemical Oxygen Demand : Remarks: not determined

(COD)

Components:
Tributyl phosphate:
Biodegradability : Result: Readily biodegradable

Dibutylphenylphosphate:
Biodegradability : Method: Ready Biodegradability: Manometric Respirometry
Test
Remarks: Readily biodegradable

Method: Ready Biodegradability: Modified MITI Test (I)

Remarks: Not readily biodegradable.

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester:

Biodegradability : Concentration: 100 mg/l
Method: Ready Biodegradability: Modified MITI Test (I)
Remarks: Readily biodegradable

Bioaccumulative potential

Components:
Tributyl phosphate:
Bioaccumulation : Species: Cyprinus carpio (Carp)
Bioconcentration factor (BCF): 20
Exposure time: 56 d
Method: OECD Test Guideline 305

Bioconcentration factor (BCF): 35

Exposure time: 38 d

Partition coefficient: n- : Pow: 10,100

octanol/water

Dibutylphenylphosphate:
Bioaccumulation : Species: Cyprinus carpio (Carp)
Bioconcentration factor (BCF): 35
Method: OECD Test Guideline 305

Mobility in soil
No data available
Other adverse effects

Product:
Ozone-Depletion Potential :

Regulation: 40 CFR Protection of Environment; Part 82 Pro-

tection of Stratospheric Ozone - CAA Section 602 Class I
Substances

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Remarks: This product neither contains, nor was manufac-

tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : This product meets the criteria for a synthetic used oil under
the U.S. EPA Standards for the Management of Used Oil (40
CFR 279). Those standards govern recycling and disposal in
lieu of 40 CFR 260 -272 of the Federal hazardous waste pro-
gram in states that have adopted these used oil regulations.
Consult your attorney or appropriate regulatory official to be
sure these standards have been adopted in your state. Recy-
cle or burn in accordance with the applicable standards.
Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

SARA 311/312 Hazards : Acute Health Hazard

Chronic Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307

The components of this product are reported in the following inventories:

DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

KECI : Not listed

PICCS : Not listed

IECSC : On the inventory, or in compliance with the inventory

TSCA : On TSCA Inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-
tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-
monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-
trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-
istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conserva-
tion and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and
of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemi-
cals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative

Further information

NFPA: HMIS III:

Flammability

HEALTH 2*
1
Instability
Health

2 0 FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Sources of key data used to : www.EastmanAviationSolutions.com

compile the Safety Data
Sheet
Revision Date : 08/09/2016

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

Skydrol® LD4 Fire Resistant Hydraulic Fluid

Version Revision Date: SDS Number: Date of last issue: 06/02/2015

2.2 08/09/2016 150000093409 Date of first issue: 10/24/2013
SDSUS / PRD / 0001

US / EN

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