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used for this purpose (Figure 13.24). Loose biomass is placed inside it and the
air is distributed either by providing controlled air entries at various levels
(T E R I 1990) or by placing an inverted perforated cone inside the drum with
the chimney (Neinhuysm 2003). Loose dry biomass is placed around the in-
verted perforated cone placed inside the charring drum and is ignited. Once
the layer catches fire, more biomass is added layer by layer till the entire drum
is filled. White smoke vents out through the chimney extension. Once the
smoke turns from white (containing moisture) to grey colour, the chimney ex-
tension is removed and a lid is put on the drum to slowly extinguish the fire
inside it. It takes about two hours each for igniting the biomass and for cool-
ing down the drum for charcoal removal.
Biomass gasification
Thermochemical biomass gasification is a process of converting solid biomass
fuel into combustible gas (called producer gas) by means of partial oxidation
carried out in a reactor called gasifier. The first gasifier units were built in
France during 1850s. The first vehicle to be powered with producer gas was
made by J W Parker in Scotland in 1901. Producer gas plants (using coal or
peat), used during World War I, are described in detail in literature (Rambrush
Principle of gasification
Biomass gasification occurs through a sequence of complex thermochemical
reactions. In the first stage, partial combustion of biomass to produce gases
and char occurs along with the generation of heat. This heat is utilized in the
drying of biomass to evaporate its moisture as well as for pyrolysis reactions to
bring out volatile matter and to provide the heat energy necessary for further
endothermic reduction reactions to generate producer gas. This gas consists
of a mixture of combustible gases such as carbon monoxide, hydrogen, and
traces of methane and other hydrocarbons. Normally, air is used as a gasifying
agent; however, the use of oxygen can produce higher calorific value gas but is
not usually preferred due to the cost implications.
Gasification reactions
Gasification is a complex thermochemical process, which is difficult to un-
derstand. Splitting the gasifier into strictly distinct zones is not realistic, but
nevertheless conceptually essential. Various gasification reactions occur simul-
taneously in different parts of the gasifier. The broad stages involved in
gasification are described below.
Drying
Biomass fuels contain moisture ranging from 5% to 35%. At a temperature of
about 100 ºC, water from the fuel gets converted into steam. Fuels do not ex-
perience any kind of decomposition during the drying process.
Pyrolysis
Pyrolysis is the thermal decomposition of biomass fuels in the absence of
oxygen. It involves release of three kinds of products, namely, solid charcoal,
liquid tars, and gases whose proportion depends on the fuel type and the pre-
vailing operating conditions. It is to be noted that in any gasifier system, there
will be always a low temperature zone in which pyrolysis takes place generat-
ing condensable hydrocarbons (normally called tars).
Oxidation
Air introduced in the oxidation zone contains inert gases such as nitrogen be-
sides oxygen and water vapour, which are considered to be non-reactive with
fuel constituents during the gasification process. The oxidation takes place
at about 700–1400 ºC . A heterogeneous reaction takes place in the oxidation
zone between solid carbonized fuel and oxygen in the air producing carbon di-
oxide and releasing a substantial amount of heat.
H 2 + 21 O 2 = H 2 O + 242 kJ / g.mol
Reduction
In the reduction zone of all types of gasifiers, a number of high-temperature
chemical reactions take place in the absence of oxygen or under a reducing
atmosphere. The principal reduction reactions that take place are:
Bouduard reaction
Water–gas reaction
Shift reaction
(Weight of oxygen/weight
C +of2H
dry =fuel)
CHactual+ 75 kJ/g.mol
ER = 2 4
(Weight of oxygen/weight of dry fuel)stoichiometric
The sequence of these reactions in a typical downdraft gasifier is shown
in Figure 13.25. The equilibrium composition of a given solid fuel depends
upon the air supply per unit weight of the biomass. A dimensionless param-
eter, known as ER (equivalence ratio), is applied to characterize the air supply
conditions, and is usually defined as follows.
The denominator in the above equation is the oxygen required for com-
plete combustion of the fuel, and it varies from fuel to fuel. The mole fraction
(or volume fraction) of the various components of the producer gas as a func-
tion of ER is shown in Figure 13.26. It is generally observed that for effective
gasification, the ER should be in the range 0.2–0.4. If the ER value is less than
0.2, pyrolysis predominates the process and if it is above 0.4, combustion
predominates (Kaupp and Goss 1984).
reaction rate drops significantly to a low level. The typical values of KWE for
various reaction temperatures are given in Table 13.8.
Equilibrium gas composition from a gasifier can theoretically be calcu-
lated through the mass balance of the four major in-going elements (carbon,
hydrogen, oxygen, and nitrogen) and by assuming that the water–gas
equilibrium is reached at a given reactor temperature. An additional set of
relations can be obtained by further assuming that a constant amount of
methane is obtained in the producer gas per kilogram of dry fuel which
happens under prevailing operating conditions. This can help in calculat-
ing the gas composition for a wide range of input parameter such as the fuel
moisture content and the fraction of heat loss from the reactor (through con-
duction, convection, and radiation). Figures 13.27 and 13.28 show typical
equilibrium gas composition highlighting the effect of various operating
600 0.38
700 0.62
800 0.92
900 1.27
1000 1.60
conditions like the fuel moisture content and the fraction of heat loss from
the reactor, respectively.
In a real gasifier, however, the composition of the gas differs greatly from
the equilibrium value and is generally dependent on the gasifier design. The
factors affecting the gas composition are temperature distribution in the fuel
bed, average gas residence time, and the residence time distribution. These
are, in turn, dependent upon the mode of air entry, dimensions of the gasifier,
and the quantum of heat loss to the surroundings. The modelling of the vari-
ous processes occurring in the gasifier requires not only knowledge of kinetics
but also an understanding of the heat and mass transfer processes occurring in
various zones of the gasifier. A brief description of some important factors
that affect the quality of producer gas generation in gasifiers is given below.
Fuel size
Fuel size affects the fuel movement within the reactor as well as the rate of re-
action and the energy intensity per unit volume. Large wood pieces provide a
smaller surface area per unit volume of the reactor, which, in turn, affects the
quality of gas as volatilization or pyrolysis becomes less intense. Too small a
Figure 13.29 Fuel size requirements for various gasifier reactor types
Figure 13.30 Effect of fuel moisture on producer gas composition and quality
Reprinted from GTZ publications
Source GTZ (1986)
Fuel-bed temperature
A high fuel-bed temperature (above 800 ºC ) is preferred to achieve a high
carbon conversion of biomass and low tar content in the resultant product
gas. Figure 13.31 shows the importance of the presence of an active char bed
and higher temperature in the reactor zone for a theoretical situation in which
carbon dioxide reacts with char to produce carbon monoxide. As tempera-
tures increase, CO2 fraction will decrease and CO fraction will increase. In
reality, however, the shift reaction does not allow for zero levels of CO2. Tem-
perature affects not only the amount of tar formed but also the composition
of tar by influencing the chemical reactions involved in the gasification. High
temperatures help in achieving tar cracking under a reducing environment. It
is reported that higher temperatures favour the formation of fewer aromatic
tar species without substituting groups like benzene, naphthalene, etc.
Figure 13.31 Effect of reaction zone temperature on gas quality and composition
Reprinted from GTZ publications
Source Kaupp and Goss (1984)
(Kinoshita, Wang, and Zhou 1994). Besides, the temperature also influences
the formation of ammonia and nitrogen, the levels of which depend on various
temperature-dependent thermochemical reactions occurring inside the
gasifier reactor. With sawdust fuel, more than 50% reduction in ammonia was
reported when the gasifier reactor temperature was increased from 750 to
900 ºC (Wang, Padban, Ye, et al. 1999; Zhou, Masutani, Ishimura, et al. 2000).
However, several other factors like moisture content and properties of the
feed material limit the gasifier operating temperature that largely influences
the entire gasification process. Figure 13.32 shows a typical temperature range
for different feed materials that influence various important factors such as
the gas heating value, char conversion, and the risk of sintering apart from tar
content in the producer gas.
Figure 13.32 Typical gasification temperatures for various feedstocks and their influence
on some critical factors
forming in the fuel-bed, especially if the ash has a low fusion point. Also,
several inorganic matters such as mud, sand, and grit are picked up during
collection and harvesting. It is not unusual considering the practice of
handling agro-based biomass. This may not pose any problems in combustion
devices/furnaces but can cause serious blockage of the entire reactor due
to ash fusion inside at higher temperatures, thereby hampering the fuel
movement and the gasification process. The common belief that wood is low
in ash is not correct and there are several types of wood and agro-residues that
have a higher ash content than even some varieties of coal. Based on the ash
content, biomass can be classified as low ash (<5%), medium ash (5%–10%),
and high ash (>10%) material (Table 13.9).
The melting point of ash is more responsible for the slagging behaviour
of the fuel and the degree of slagging is more severe in biomass fuels having a
high ash content. High-ash content biomass residues such as rice husk and
similar fuels having a high ash fusion temperature generally do not pose the
problems of clinker formation. However, high ash content retards heat and
mass transfer rates, resulting in incomplete conversion of carbon in the case of
insufficient residence time within the reactor and/or lack of agitation of the
Powdery material
Eucalyptus sawdust 0.4 — — Industrial bamboo dust 9.8
Saw-mill dust 1.3 — — Jute dust 19.9
Sugarcane leaves 9.5
Coir pith 15.4
Granular material
Bagasse 1.8 Arecanut shell 5.1 Sweet sorghum bagasse 20.0
Coconut shell 1.9 Cotton shell 4.6 Rice husk 22.4
Groundnut shell 3.6 Coffee husk 5.8 Tea waste 19.8
Acacia 0.6 Sugarcane leaves 7.7 (decaffeinated)
Pine needle 1.5 — — MSW 27.5–70.0
Stalk-like material
Arhar stalks 3.4 Ragi stick 7.1 Jowar stalk 9.5
Corn cob 1.2 Sweet sorghum stalk 7.4 Rice straw 20.0
Jute stick 1.2 Castor stick 5.4 Ficus 10.9
Lantana camara 3.5 Congress grass 4.2
Mulberry sticks 2.5 (Parthenium
hystophorus)
fuel bed. On the other hand, fuels such as corncobs, groundnut shell, and co-
conut coir have a low to medium ash content but also have low ash
deformation temperatures in the range of 800–1200 ºC that can lead to
clinker formation. Materials such as cotton stalk, arhar stalk, acacia, bamboo,
and pine needle are more suitable as gasifier fuels due to their low to medium
ash content and very high ash deformation temperatures (Table 13.10). Meth-
ods of determining ash deformation and ash fusion temperatures are
described in Iyer, Rao, and Grover (2002).
General advantages
Dense phase gasifiers Lean phase gasifiers
High carbon conversion Very good gas–solid
Low ash carryover contact and mixing
Large residence time of solids High throughputs
Relatively simple construction High specific capacity
Specific advantages
Updraft Fluidized bed Entrained flow
Low gas outlet temperature Good temperature Produces low-tar gas
High thermal efficiency control and little methane
Suitable for direct firing Low-medium tar High feedstock
yield utilization due to
Tolerates variations high reaction rates
in fuel quality
Downdraft Can operate at
Low tar yield partial load
Easily started and
stopped
General disadvantages
Dense phase gasifiers Lean phase gasifiers
Low specific capacity Low feedstock inventory
Poor turn-down capability Extensive particulates
Uniformily sized feedstock clean-up required
required with minimum of fines
Ash fusion and clinker formation
on grate
Specific disadvantages
Updraft Fluidized bed Entrained flow
High tar yield Carbon loss High outlet gas
Downdraft with ash temperature
Unsuitable for high moisture fuels Low operating Slagging
temperature
The gas leaves at relatively high temperatures of about 400–500 ºC, hence
the gasifier operating thermal efficiency is less than that in the updraft
gasifier.
Not suitable for high-ash, high-moisture, and low-ash fusion temperature
fuels.
Cross-draft gasifier
In a cross-draft gasifier, air enters from one side of the gasifier reactor and
leaves from the other side (Figure 13.37). Cross-draft gasifiers have very few ap-
plications and can hardly be credited with any advantage beyond good
permeability of the bed.
Not much research occured. However, it probably produces lesser tar than
updraft gasifier and has a narrow turn-down ratio.
because of the low biomass hold-up in the bed. These systems are, however,
most appropriate for biomass whose particle sizes range from 0.1 to 1 cm (see
Figure 13.29) and are normally suitable for small applications comprising
high carbon loss with entrained ash. The loss of fluidization due to sintering
of ash is a common problem, which can be controlled by maintaining higher
bed temperatures of the order of 800–900 ºC. Sintering occurs due to the
agglomeration of alkali metals from biomass ash with the silica in the sand.
In the entrained flow gasifier reactors, no inert material is present but
finely reduced fuelstock is required. They are normally used for large-capacity
(30 tonnes/hour) fast-circulating bed gasifiers for the paper and pulp industry.
Tables 13.12 and 13.13 give typical operational data and the producer gas
composition and quality in different gasifier reactors. The performance char-
acteristics of various air gasifier reactors are compiled in Annexe 1.