Class: Xi Inorganic Chemistry DPP. NO.-8

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Dr .

Sh a r a d Ko t h a r i P iyu s h Ma h es h w a r i B r ij es h Jin da l
(SK SIR) (PMS SIR) (BJ SIR)

CLASS : XI INORGANIC CHEMISTRY DPP. NO.-8


S. Species  l.p. Hyb. e¯geometry shape B.A. Equivalent Planar Polar
No. All Hyb. Bonding
1. BeCl2 2 0 sp Linear Linear 180°

2. BeF42– 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

3. BF3 3 0 sp 2 Trigonal Planar Trigonal Planar 120°

4. BF4¯ 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

5. BO33– 3 0 sp2 Trigonal Planar Trigonal Planar 120°

6. CH4 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

7. CH3+ 3 0 sp2 Trigonal Planar Trigonal Planar 120°

8. CH3¯ 3 1 sp 3 Tetrahedral T.Py. <109°28’

9. CO32– 3 0 sp2 Trigonal Planar Trigonal Planar 120°

10. CO2 2 0 sp Linear Linear 180°

11. COCl2 3 0 sp2 Trigonal Planar D.T.Pl >120°,<120°

12. NH4+ 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

13. NH3 3 1 sp 3 Tetrahedral T.Py. <109°28’

14. NH2¯ 2 2 sp 3 Tetrahedral Bent <109°

15. NO2¯ 2 1 sp 2 T.Pl. Bent <120°

16. NO3¯ 3 0 sp 2 T.Pl. T.P. 120°

17. NO2+ 2 0 sp Linear Linear 180°

18. NOCl 2 1 sp 2 T.Pl. Bent <120°

19. NOF3 4 0 sp 3 Tetrahedral D.Tetrahedral <109°,>109°

20. H2O 2 2 sp 3 Tetrahedral Bent <109°28’

21. H3O+ 3 1 sp 3 Tetrahedral T.Py. <109°28’

22. O3 2 1 sp 2 T.Pl. Bent <120°

23. AlCl3 3 0 sp 2 T.Pl. T.Pl. 120°


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S. Species  l.p. Hyb. e¯geometry Shape B.A. Equivalent Planar Polar
No. All Hyb. Bonding

24. AlF63– 6 0 sp 3 d 2 O.H. O.H. 90°,180°

25. SiF4 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

26. SiF62– 6 0 sp 3 d 2 O.H. O.H. 90°,180°

27. SiO44– 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

28. PCl3 3 1 sp 3 Tetrahedral T.Py. <109°28’

29. PCl4+ 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

30. PCl5 5 0 sp 3 d T.B.P. T.B.P. 90º,120º,180º

31. PCl6¯ 6 0 sp 3 d 2 O.H. O.H. 90°,180°

32. PO43– 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

33. POCl3 4 0 sp 3 Tetrahedral D.T.H. >109°,<109°

34. SO2 2 1 sp 2 T.Pl. Bent <120°

35. SO3 3 0 sp 2 T.Pl. T.Pl. 120°

36. SO32– 3 1 sp 3 Tetrahedral T. Py. <109°

37. SO42– 4 0 sp 3 Tetrahedral Tetrahedral 109°28’

38. SOCl2 3 1 sp 3 Tetrahedral T.Py. <109°28’

39. SOF4 5 0 sp 3 d T.B.P. D.T.B.P. >90,<90, >120 <120 < 180°

40. SF2 2 2 sp 3 Tetrahedral Bent <109°28’

41. SF4 4 1 sp 3 d T.B.P. Sea-Saw <90°,<120°,


<180°
42. SF6 6 0 sp 3 d 2 O.H. O.H. 90°,180°

43. IF7 7 0 sp 3 d 3 P.B.P. P.B.P. 72º,90°,180°

44. IF6¯ 6 1 sp 3 d 3 P.B.P. D.O.H.  90°

45. BrF5 5 1 sp 3 d 2 O.H. S.Py. <90°<180°

46. BrF4¯ 4 2 sp 3 d 2 O.H. S.Pl. 90°,180°

47. ClF3 3 2 sp 3 d T.B.P. T-shape <90°<180°

48. ClF2+ 2 2 sp 3 Tetrahedral Bent <109°28’

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