CIE IGCSE Chemistry Organic A

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The passage discusses different types of hydrocarbons including alkanes, alkenes and their properties. It also talks about crude oil refining and polymerization reactions.

The three fractions obtained from crude oil refining are kerosene, petrol and bitumen.

Saturated hydrocarbons have only single bonds between carbon atoms while unsaturated hydrocarbons have one or more double or triple bonds. This affects their reactivity and properties.

1. Which one of the following compounds is not a hydrocarbon? Circle.

C2H4 C2H6O C6H6 C4H10

2. Which one of the hydrocarbons in the list is not an alkane? Circle.

C6H12 C7H16 C10H22 C40H82

3. Write down a use for each of the following alkanes:


a) Methane:

b) Propane:

c) Octane:

4. LPG is used as a fuel in cars as an alternative to petrol. How is it produced in refining process?

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5. A colorless gas X has a formula C3H6. It decolorizes bromine. X could be


a) Ethane
b) Ethene
c) Propane
d) Propene
6. Poly(vinylchoride) is made from a monomer called vinyl chloride:

H H
C C
Cl H
a) Draw the structure of poly(vinylchoride)

7. Three fractions from crude oil refinery are: kerosene, petrol and bitumen.
a) Put these three fractions in the correct order working down from the top of the column.

b) Suggest uses for each of the fractions

8. Decane, C10H22, can be cracked into a mixture of ethane and ethane. Write a balanced reaction for this.
9. This question is about two families of hydrocarbons – alkanes and alkenes
Ethane, C2H6 , is an alkane and ethane, C2H4 , is an alkene.

H H H H
H C C H C C

H H H H

a) Ethane is said to be a saturated hydrocarbon and ethene is an unsaturated hydrocarbon. Explain the
meaning of the terms saturated and unsaturated.

b) Ethene undergoes polymerization reactions to produce an addition polymer called poly(ethene).


i. Explain what is meant by the term ‘addition polymer’

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ii. Draw the structure of poly(ethene).

iii. Poly(ethene) is used for packaging materials. Before poly(ethene) , paper or cardboard would
have been used. Suggest advantages of poly(ethene) over paper and cardboard.

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10. 1 2 3

Crude oil Fractions Monomers Polymers


Crude oil is used as a raw material to make polymers.

Name the processes


1. ………………………………………………………….
2. ………………………………………………………….
3. …………………………………………………………
11. There are three hydrocarbons which have the molecular formula C5H12. The structural formula of one of
these is shown below (A).

(i) Draw the structural formula of the other two compounds (B and C).

(B ) (C )
(ii) What name is given to compounds which have the same molecular formula but different
structures? ..................................................................................................................
(iii) Which of the compounds, A, B or C, has the highest boiling point?
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Give reasons for your answer.
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12. A homologous series is a family of compounds with a general formula and similar chemical properties. The
saturated hydrocarbons form a homologous series with the general formula CnH2n+2.
a) Explain what the term saturated means

b) Name the series described above

c) i. Write the formula for the hydrocarbon in this series with two carbon atoms, and name it.
ii. Draw a molecule of the compound

d) i. Name a homologous series of unsaturated hydrocarbons, and write a general formula for it.
ii. Write a formula for the member of this series with 2 carbon atoms, and name it

iii. Draw the molecule of the compound.


13. Hex-1-ene is an unsaturated hydrocarbon. It melts at -140C and boils at 63C. its empirical formula is
CH2 and its molecular mass is 84g/mol.
a)
i. To what family of hydrocarbons does it belong?

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ii. What is its molecular formula?

……………………………………..

iii. What does the 1 in its name mean?

…………………………………………………………………………………………………………….

iv. Draw a molecule of hex-1-ene.

v. Now draw another isomer with this formula.

b)
i. In what state is hex-1-ene at room temperature?
……………………………………………….
ii. Make a guess at the boiling point of hept-1-ene, the next member of the series.
……………………………………………..
c)
i. Hex-1-ene reacts with bromine water. Write an equation to show this reaction.

…………………….+……………………..…………………………..

ii. What is this type of reaction called?

………………………………….

iii. What would you see during the reaction?

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