0% found this document useful (0 votes)
209 views6 pages

Material Safety Data Sheet: 1 Identification

Download as pdf or txt
Download as pdf or txt
Download as pdf or txt
You are on page 1/ 6

Issue Date: 20-AUG-2012

Material Safety Data Sheet Supercedes: 03-FEB-2012

OPTISPERSE HP3100

1 Identification
Identification of substance or preparation
OPTISPERSE HP3100

Product Application Area


Water based internal boiler treatment chemical.

Company/Undertaking Identification
GE Betz, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355-3300, F 215 953 5524

Emergency Telephone
(800) 877-1940

Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 20-AUG-2012

2 Hazard(s) identification
********************************************************************************
EMERGENCY OVERVIEW

DANGER

Corrosive to skin. Corrosive to the eyes. Mists/aerosols may cause


irritation to upper respiratory tract.

DOT hazard: Corrosive to skin


Odor: None; Appearance: Colorless To Light Yellow, Liquid

Fire fighters should wear positive pressure self-contained breathing


apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
********************************************************************************

POTENTIAL HEALTH EFFECTS

ACUTE SKIN EFFECTS:


Primary route of exposure; Corrosive to skin.

ACUTE EYE EFFECTS:


Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:


Mists/aerosols may cause irritation to upper respiratory tract.

INGESTION EFFECTS:

Substance or Preparation: OPTISPERSE HP3100 Page 1


May cause gastrointestinal irritation.

TARGET ORGANS:
No evidence of potential chronic effects.

MEDICAL CONDITIONS AGGRAVATED:


Not known.

SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin, irritation, and/or tearing of
eyes (direct contact).

3 Composition / information on ingredients


Information for specific product ingredients as required by the
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to
additional sections of this MSDS for our assessment of the potential
hazards of this formulation. This product is subject to the Pennsylvania
and New Jersey Worker and Community Right to Know Law.

HAZARDOUS INGREDIENTS:

Cas# Chemical Name Range(w/w%)

1310-73-2 SODIUM HYDROXIDE 3-7


Corrosive; toxic (by ingestion)
NON-HAZARDOUS INGREDIENTS:

CAS# CHEMICAL NAME

7732-18-5 WATER
68915-31-1 SODIUM HEXAMETAPHOSPHATE

4 First-aid measures
SKIN CONTACT:
URGENT! Wash thoroughly with soap and water. Remove contaminated
clothing. Get immediate medical attention. Thoroughly wash clothing
before reuse.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water
for at least 20 minutes while removing contact lenses. Hold eyelids
apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air
and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 2-8 fluid ounces (60-240 mL) of
milk or water.
NOTES TO PHYSICIANS:
No special instructions

5 Fire-fighting measures

Substance or Preparation: OPTISPERSE HP3100 Page 2


FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
oxides of phosphorus
FLASH POINT:
> 200F > 93C P-M(CC)
MISCELLANEOUS:
Corrosive to skin
UN 3266;Emergency Response Guide #154

6 Accidental release measures


PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer
treatment facility,in accordance with any local agreement,a permitted
waste treatment facility or discharged under a permit. Product
as is - Incinerate or land dispose in an approved landfill.

7 Handling and storage


HANDLING:
Alkaline. Corrosive(Eyes). Do not mix with acidic material.
STORAGE:
Shelf life = 180 days. Keep containers closed when not in use.
Protect from freezing. If frozen, thaw and mix completely prior to
use. Store below 100F (38C).

8 Exposure controls / personal protection


EXPOSURE LIMITS
CHEMICAL NAME

SODIUM HYDROXIDE
PEL (OSHA): 2 MG/M3
TLV (ACGIH): TWA (Ceiling) = 2 MG/M3

ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA’S 29 CFR
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT A RESPIRATOR’S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED
WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use any of
the following particulate respirators: N95, N99, N100, R95,

Substance or Preparation: OPTISPERSE HP3100 Page 3


R99, R100, P95, P99 or P100.
SKIN PROTECTION:
gauntlet-type rubber, butyl or neoprene gloves, chemical
resistant apron -- Wash off after each use. Replace as
necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield

9 Physical and chemical properties


Spec. Grav.(70F,21C) 1.113 Vapor Pressure (mmHG) ~ 18.0
Freeze Point (F) 21 Vapor Density (air=1) < 1.00
Freeze Point (C) -6
Viscosity(cps 70F,21C) 12 % Solubility (water) 100.0

Odor None
Appearance Colorless To Light Yellow
Physical State Liquid
Flash Point P-M(CC) > 200F > 93C
pH As Is (approx.) > 13.0
Evaporation Rate (Ether=1) < 1.00
Percent VOC: 0.0

NA = not applicable ND = not determined

10 Stability and reactivity


CHEMICAL STABILITY:
Stable under normal storage conditions.
POSSIBILITY OF HAZARDOUS REACTIONS:
Contact with strong acids may cause a violent reaction releasing
heat.
INCOMPATIBILITIES:
May react with acids or strong oxidizers.
DECOMPOSITION PRODUCTS:
oxides of phosphorus

11 Toxicological information
Oral LD50 RAT: 2800 mg/kg
NOTE - Calculated value according to GHS additivity formula
Dermal LD50 RABBIT: >5000 mg/kg
NOTE - Calculated value according to GHS additivity formula
Skin Irritation Score RABBIT: Corrosive
NOTE - GHS Category 1B skin corrosive
Eye Irritation Score RABBIT: Corrosive
NOTE - GHS Category 1 causes serious eye damage

12 Ecological information
AQUATIC TOXICOLOGY

Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)

Substance or Preparation: OPTISPERSE HP3100 Page 4


LC50= 3300; No Effect Level= 1250 mg/L
Fathead Minnow 96 Hour Static Renewal Bioassay (pH adjusted)
LC50= 5020; No Effect Level= 2750 mg/L

BIODEGRADATION
Product contains only inorganics that are not subject to typical
biological degradation. Assimilation by microbes may occur in
waste treatment or the environment.

13 Disposal considerations
If this undiluted product is discarded as a waste, the US RCRA
hazardous waste identification number is :
D002=Corrosive(pH).

Please be advised; however, that state and local requirements for


waste disposal may be more restrictive or otherwise different from
federal regulations. Consult state and local regulations regarding
the proper disposal of this material.

14 Transport information
Transportation Hazard: Corrosive to skin
DOT: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.(SODIUM HYDROXIDE
SOLUTION)
8, UN3266, PG III, RQ
DOT EMERGENCY RESPONSE GUIDE #: 154
Note: Some containers may be DOT exempt, please check BOL for
exact container classification
IATA: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.(SODIUM HYDROXIDE
SOLUTION)
8, UN3266, PG III
IMDG: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.(SODIUM HYDROXIDE
SOLUTION)
8, UN3266, PG III

15 Regulatory information
TSCA:
All components of this product are included on or are in
compliance with the U.S. TSCA regulations.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
2,158 gallons due to SODIUM HYDROXIDE;
FOOD AND DRUG ADMINISTRATION:
ALL ingredients in this product are authorized in 21CFR173.310
for use as boiler water additives where the steam may contact
food.
NSF Registered and/or meets USDA (according to 1998 Guidelines):
Registration number: 146608
Category Code(s):
G6 Boiler treatment products - all food processing
areas/food contact
G5 Cooling and retort water treatment products - all
food processing areas
SARA SECTION 312 HAZARD CLASS:
Immediate(acute)

Substance or Preparation: OPTISPERSE HP3100 Page 5


SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds
SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds
CALIFORNIA REGULATORY INFORMATION

CALIFORNIA SAFE DRINKING WATER AND TOXIC


ENFORCEMENT ACT (PROPOSITION 65):
No regulated constituents present

MICHIGAN REGULATORY INFORMATION

No regulated constituent present at OSHA thresholds

16 Other information
HMIS vII CODE TRANSLATION

Health 3 Serious Hazard


Fire 0 Minimal Hazard
Reactivity 0 Minimal Hazard
Special CORR DOT corrosive
(1) Protective Equipment D Goggles,Face Shield,Gloves,Apron

(1) refer to section 8 of MSDS for additional protective equipment


recommendations.

CHANGE LOG

EFFECTIVE
DATE REVISIONS TO SECTION: SUPERCEDES
--------- --------------------- ----------
MSDS status: 07-JUN-2001 ** NEW **
13-MAY-2002 4,7 07-JUN-2001
26-MAY-2006 8 13-MAY-2002
23-FEB-2010 4,5,7,8,10,14 26-MAY-2006
02-NOV-2011 11 23-FEB-2010
03-FEB-2012 2,4,5,8,14,16 02-NOV-2011
20-AUG-2012 15 03-FEB-2012

Substance or Preparation: OPTISPERSE HP3100 Page 6

You might also like