USPCAS-E Manual
USPCAS-E Manual
USPCAS-E Manual
Training Manual
(UNIDO)
Foreword
(NUST)
National University of Sciences & Technology (NUST) is executing a project component
“Capacity Building & Strengthening of Biomass Gasification Technology Support Systems” to
contribute for the promotion of “Biomass to energy technologies in Pakistan” through a
UNIDO-GEF project “Promoting sustainable energy production and use from biomass in
Pakistan”.
The vitality part in Pakistan is portrayed by low levels of access to present day vitality
benefits, a high reliance on customary fills and an unsustainable reliance on transported in
fossil energizes for power generation. Biomass, a natural constituent obtained from
agriculture waste predominantly includes rice husk, wheat straw, bagasse, cotton and wood
shredding’s (saw dust) and other carbonaceous waste materials including municipal waste.
UNIDO has taken an initiative to strengthen the industrial sector in Pakistan by using
biomass/crop residue as an efficient energy material through advanced Biomass
Gasification Technologies (BGTs).
As compared to biomass gasification for energy purposes, direct burning of biomass causes
severe environmental pollution and health problems among workers. Keeping in view the
advance nature and beneficial aspects of biomass gasification, capacity building is a key
element to spread awareness and establish optimized and skilled technical services to
promote training centers and research institutions, and promotion and maintenance of
installation of BGTs at industrial sector. The project will be of great help to create awareness
and set the trends towards “Biomass to Energy” among industrial networks. The venture is
required to bring critical financial and natural advantages both at neighborhood and
worldwide level.
This manual consists of seven sections, comprising numerous units and draws upon the
working operation, monitoring & maintenance of installed Biomass Gasifier. The training of
BGT broadly cover fundamentals Small & Medium Enterprises (SMEs) and Technology
Providers from all over Pakistan. While the manual aims to provide market driven services
of biomass gasification technologies to SMEs and to establish the enhanced capacity of key
market players in the local supply chain.
We are sure that the manual will be useful for all cooperative trainers towards facilitating
BGTs and thereby ensuring the participation and understanding of all the trainees in
biomass gasification technologies (BGTs) at all levels of cooperatives.
Note: This manual is in draft form, errors and omissions are expected. Any feedback will be
highly appreciated. It can be sent on [email protected]
1 INTRODUCTION 1
2 FUELS 3
3.7.1 Powdering 16
4.1.2 Gasification 21
4.1.3 Pyrolysis 22
4.2.2 Fermentation 23
5 BIOMASS GASIFIERS 25
6 AUXILIARY EQUIPMENT 37
7.5.1 Sampling 47
10.5 Typical Operational instructions for a fluidized-bed biomass gasifier and power generation plant
68
11 SAFETY GUIDELINES 75
Exhibits
EXHIBIT 2–1: PROPERTIES OF DIFFERENTBIOMASS RESOURCES 9
EXHIBIT 5–10: SIZES OF BIOMASS GASIFIER FOR DIFFERENT DESIGNS FOR APPLICATION RANGES 35
EXHIBIT 6–3: SCHEMATIC DIAGRAM OF SAND BED FILTER TO CLEAN PRODUCER GAS (PATHAK ET AL., 2007)
42
EXHIBIT 8–4: 51
Gasification has been reliably used on a commercial scale worldwide for more than 60 years
in the refining, fertilizer, and chemical industries, and for more than 35 years in the electric
power industry.
It is a flexible, reliable, and commercial technology that can turn a variety of low-value
feedstock into high-value products, help reduce a country's dependence on imported oil and
natural gas, and can provide a clean alternative source of base load electricity, fertilizers,
fuels, and chemicals.
To be expanded, as needed.
This manual uses the SI (Le Systeme International d’Unites) metric units of measure.
The manual covers the basics of biomass as fuel, biomass conversion technologies,
gasification, applications of gasification, gasifiers, design guidelines, operational and
maintenance guidelines, and safety measures.
Chapter 1 is the brief introduction to this manual. Chapter 2 introduces the fossil and
biomass fuels, and characteristics of biomass fuels. Chapter 3 describes biomass conversion
technologies. Chapter 4 discusses .
The manual aims to prompt the managers, professionals, technical staff, and service
providers to adopt sustainable, viable, environment friendly, and economically feasible
technologies. However, it must be well understood that it is not a replacement of textbooks
and handbooks on the subject. It will serve as a useful guide for energy engineers, service
providers, and small and medium scale entrepreneurs.
To be updated.
The main function of the fuels is to provide thermal energy, which is used directly in the
form of heat or transformed into other forms of energy, i.e. mechanical or electrical energy
according to the needs. The major sources of thermal energy, at this point in time, are fossil
fuels and biomass fuels. These are briefly discussed in here.
Fuels such as coal, oil and natural gas were formed over millions of years from organic
matter like plankton, plants and other life forms. Over time, sand, sediment and rock buried
the organic matter and it eventually formed large quantities of fuels. These underground
resources, known as fossil fuels, are still the primary fuel source for electricity, heating and
powering vehicles around the globe.
There are three major forms of fossil fuels: coal, oil and gas.
Coal is a combustible black or brown sedimentary rock made mostly of organic carbon. It is
typically found as layers (coal beds) or veins (coal seams).
There are two main types of coal: ‘thermal’ coal is mostly used for power generation, and
‘metallurgical’ coal is mostly used for steel production. Thermal coal is more abundant, has
lower carbon content and is higher in moisture than metallurgical coal.
Natural gas is a combustible mix of hydrocarbon gases. It is colorless and consists mainly of
methane (CH4). ‘Conventional gas’ is easily extracted; ‘unconventional gas’ requires more
sophisticated extraction technologies.
Conventional natural gas is found in permeable sandstone reservoirs and is easy to get out
of the ground through traditional well drilling techniques.
Unconventional gas is just standard natural gas, but found in places other than permeable
sandstone reservoirs. There are two main types of ‘unconventional gas’: (1) coal seam gas
(CSG), found in coal deposits, usually 200 to 1,000 meters below the ground; and (2) shale
gas, found in shale rock deposits. The wells for extracting this gas are generally a lot deeper
than those for CSG.
Oil is liquid fuel made of hydrocarbons. It is mostly known as crude oil or condensate, but
includes all liquid hydrocarbon fossil fuels and other liquid organic compounds. Petroleum
and liquefied petroleum gas (LPG) are the most common types of fuel obtained from oil
extraction and refining. LPG is heavier than natural gas. The term petroleum refers to both
naturally occurring unprocessed crude oils and petroleum products made of refined crude
oil.
Biomass is biological material derived from living, or recently living organisms. In the
context of biomass for energy this is often used to mean plant based material, but biomass
can equally apply to both animal and vegetable derived materials.
It is any organic matter-wood, crops, forestry residues, seaweed, animal wastes – that can be
used as an energy source. Biomass is probably our oldest source of energy after the sun. For
thousands of years, people have burned wood to heat their homes and cook their food.
Biomass Gasification Systems
3
Biomass is a renewable energy source because its supplies are not limited. People can
always grow trees and agriculture crops and waste will always exist.
A generally accepted definition is difficult to find. However, the one used by the United
Nations Framework Convention on Climate Change (UNFCCC, 2005) is relevant here:
(Biomass is a) non-fossilized and biodegradable organic material originating from plants,
animals and microorganisms. This shall also include products, by-products, residues and waste
from agriculture, forestry and related industries as well as the non-fossilized and
biodegradable organic fractions of industrial and municipal wastes.
These processes have happened for as long as there have been plants on earth and is part of
what is known as the carbon cycle. A continuous program of replanting with the new growth
will take up CO2 from the atmosphere at the same time as it is released by combustion of the
previous harvest. This maintains a closed carbon cycle with no net increase in atmospheric
CO2 levels. However, biomass also includes plant or animal matter used for production of
fibers or chemicals.
The vital difference between biomass and fossil fuels is one of time scale.
Each type of biomass has specific properties that determine its performance as a fuel in
combustion or gasification devices or both. The most important properties relating to the
thermal conversion of biomass are as follows:
Moisturecontent
Ashcontent
Volatile matter content
Elemental composition
Heating value
Bulkdensity
Proximate analysis of biomass or any solid fuel measures its four parameters, i.e. moisture
content (MC), ash (A), volatile matter (VM) and fixed carbon (FC), all expressed as %age.
The moisture content of biomass is the quantity of water in the material, expressed as a
percentage of the material’s weight. This weight can be referred to as the following:
Wetbasis,
Drybasis,and
Dry andash-freebasis
The terminology used is:
MCwet
× 100
MCdry % =
1 - MC wet
MCdry
MCwet =
1 + MC
dry
MCdry
MCwet % = × 100
1 + MC dry
Finally, the moisture content can be expressed as percentage for the “dry-and-ash-free”
matter content basis, as the following:
Wmc
MCdafb % = × 100
Wwet - Wmc - Wash
Wmc
MCdafb % = × 100
Wdaf
Since, the moisture content affects the quality of biomass as a fuel, the basis on which the
moisture content is measured must always be mentioned. This is of particular importance
because biomass materials exhibit a wide range of moisture content (on a wet basis),
ranging from less than 10 percent for cereal grain straw up to 50-70 percent for forest
residues.
Ash (A)
It is the residual mass obtained after combustion in the air, under controlled conditions of
time and temperature.
The inorganic component (ash content) can be expressed in the same way as the moisture
content on a wet, dry and dry-and-ash-free basis. In general, the ash content is expressed on
a dry basis as shown below.
Wash
Adry =
Wdry
Wash
Adry % = × 100
Wdry
Volatile matter refers to the part of the biomass that is released when the biomass is heated
(up to 400 to 500ᵒC) in the absence of oxygen and in strictly controlled conditions. It is
calculated using the following equation:
W1- W2
VM % = × 100
W1
Where:
FC % = 100 – (MC % +A % + VM %)
All quantities in percentage are taken on wet basis.
Further, the % content of Moisture, Ash (A), Volatile Matter (VM), Fixed Carbon (FC) – also
Sulfur (S) and Calorific Value (CV) – can be expressed on any of the above basis.
The composition of the ash-free organic component of biomass is relatively uniform. The
major components are carbon, oxygen and hydrogen. Most biomass also contains a small
proportion of nitrogen, sulfur and other inorganic constituents. Following table presents the
average range of percentages.
Elementary composition of typical biomass as derived from Ultimate Analyses:
Hydrogen H 5.5-6.7
Oxygen O 41-50
Sulfur S 0.0-0.2
Ultimate analysis is lengthy, laborious and costly, while proximate analysis is easy and cost
effective. In most cases, the proximate analysis suffices and serves the purpose for
understanding the properties of the feedstock (raw material) specific to its use as a source
of thermal energy.
The heating value of a fuel is an indication of the energy chemically bound in the fuel with
reference to a standardized environment. The standardization involves the temperature,
state of water (vapor or liquid) and the combustion products (CO2, H2O etc.). The energy
chemically bound in the fuel is given by the heating value of the fuel in energy (Joules) per
unit amount of matter (kg). This energy cannot be measured directly but only with respect
to a reference state. Reference states may differ, so a number of different heating values
exist. The best knowns are the higher heating value (HHV) and lower heating value(LHV).
HHV
For the HHV, the reference state of water is liquid. It is the amount of heat released by the
unit mass or volume of fuel at “reference state” (say initially at 25°C) when it is combusted,
and the products of combustion are returned to the “reference state” (initial temperature of
25°C in this case). In fact, it includes the latent heat of vaporization of water.
LHV
For the LHV, the reference state of water is steam (vapor state). In practice, the products of
combustion are rarely cooled to the initial temperature of the fuel, which is generally below
the condensation temperature of steam. So the water vapor in the flue gas does not
condense, and therefore the latent heat of vaporization of water is not recovered. The
effective heat available for use, therefore, is a lower amount. Simply, it is defined as the
amount of heat released by fully combusting a unit quantity of fuel less the heat of
vaporization of the water in exhaust flue gases.
The glaring example is that the temperature of exhaust flue gas of a boiler is normally
maintained in the range of 120 - 180°C.
The relationship between HHV and LHV is given by (Basu, )
9H % MC %
LHV = HHV – 540 × ( + )
100 100
Where LHV, HHV, H, and M are lower heating value, higher heating value, hydrogen
percentage, and moisture percentage, respectively, on as-received basis. Here, the units of
LHV and HHV in kcal/kg. The value 540 is the heat of evaporation of water in kcal/kg.
Other commonly used substitutes for LHV and HHV are:
LHV = Net heating value (NHV), net calorific value (NCV), low calorific value (LCV)
HHV = Gross heating value (GHV), gross calorific value (GCV), high calorific value (HCV)
Biomass always contains some water, which is released as vapor upon heating. This implies
that some of the heat liberated during the chemical reactions is absorbed by the evaporation
process. For this reaction, the net heating value (LHV) decreases as the moisture content of
Bulk density refers to the weight of material per unit of volume. For biomass, this is
commonly expressed on an oven-dry-weight (moisture content= 0 percent) or an as-is basis,
with a corresponding indication of moisture content (MCwet). Similar to biomass moisture
contents, biomass bulk densities show extreme variation from lows of 150-200 kg/m3 to
600-900 kg/m3. Together, heating value and bulk density determine the energy density, i.e.
the potential energy available per unit volume of the biomass. In general, biomass energy
densities are approximately one-tenth that of fossil fuels, e.g. petroleum or high quality coal.
Bulk density of biomass is expressed as:
kg Weight Weight of Biomass, kg
Bulk Density, 3 = =
m Volume Volume of Biomass, m3
Note: List may be expanded, in line with the relevance to the requirements of the Manual.
Prior to its use, the biomass fuel needs to be conditioned according to its application, and
optimum utilization. The conditioning of the biomass fuel involves the processes such as:
Drying,
Powdering,
Pelleting, and
Briquetting
These processes are discussed in the following sections.
There are several established methods, plus some promising technology, for drying biomass
fuels for use in combustion boilers and gasifiers. Drying biomass fuel provides significant
benefits to boiler operation, but they must be balanced against increased capital and
operating costs. Using dry fuel in a direct combustion boiler results in improved efficiency,
increased steam production, reduced ancillary power requirements, reduced fuel use, lower
emissions, and improved boiler operation. (NREL, 1998)
Dryers can be broadly divided into two categories based on how heat is provided for drying.
In direct dryers, the material gets heat from direct contact with a fluid providing the heat--
either hot air or hot steam. With indirect drying, the material being dried is separated from
the heat source by a heat exchange surface. One important consequence of indirect drying is
that it is possible to recover the latent heat of evaporated water because the water vapor is
not diluted by air.
There are several steps to drying. First, the material must be heated from the temperature at
which it entered the dryer, up to the wet bulb temperature, to produce a driving force for
water to leave the wet material (see Glossary for the description of dry bulb and wet bulb
temperatures). Next, any surface moisture on the material is evaporated--this occurs fairly
quickly. Once all the surface moisture is removed, the material must be heated to drive
water from the inside of the biomass to the surface so it can evaporate. This occurs during
the "falling rate period" when the rate of drying drops as the material becomes drier. During
Rotary dryers are the most common type used for biomass drying. There are several
variations of rotary dryers, but the most widely used is the directly heated single-pass
rotary dryer. In this dryer, hot gases come into contact with biomass material inside a
rotating drum. Rotation of the drum, with the aid of flights, lifts the solids in the dryer so
they tumble through the hot gas, promoting better heat and mass transfer. If contamination
is not a concern, hot flue gas can be fed directly into the dryer. Other options include using a
burner or a steam heater to raise the temperature of incoming air.
The biomass and hot air normally flow co-currently through the dryer so the hottest gases
come in contact with the wettest material, but for materials where temperature is not a
concern, the flue gas and solids flow in opposite directions, so the driest solids are exposed
to the hottest gases with the lowest humidity. This latter configuration produces the lowest
moisture leaving the dryer, but for biomass this exposes essentially dry material to a high
flue gas temperature, which would increase the fire risk.
Exhibit 3–1: Single-Pass Rotary Dryer
The exhaust gases leaving the dryer may pass through a cyclone, multicyclone, baghouse
filter, scrubber or electrostatic precipitator (ESP) to remove any fine material entrained in
the air. An ID (induced draft) fan may or may not be required depending on the dryer
configuration. If one is needed, it is usually placed after the emissions control equipment to
reduce erosion of the fan, but may also be placed before the first cyclone to provide the
pressure drop through downstream equipment.
Single-pass dryers can take larger material. The basic single-pass rotary dryer design can be
modified to allow three passes of the air and material through the dryer.
Indirectly heated rotary dryers use a heat source--steam or hot air--passing through the
outer wall of the dryer or through an inner central shaft to heat the dryer by conduction.
This is more common with materials that would be contaminated by direct contact with flue
gases or with materials that react with air.
Biomass Gasification Systems
12
The inlet gas temperature to rotary biomass dryers can vary from (5O - 80°C). Outlet
temperatures from rotary dryers vary from (25° - 30°C), with most of the dryers having
outlet temperatures higher than 30°C to prevent condensation of acids and resins. Retention
times in the dryer can be less than a minute for small particles and 2-3 minutes for larger.
In a flash or pneumatic dryer, the solids are mixed with a high-velocity hot air stream. The
intimate contact of the solids with the air results in very rapid drying. The solids and air are
separated using a cyclone, and the gases continue through a scrubber to remove any
entrained particulate material. Exhibit 3–2 shows a simple flash dryer (without a scrubber).
Because of the short drying time in a flash dryer, the equipment is more compact than for a
rotary dryer. However, the electricity consumption is higher because of the faster air flows
through the unit, and because biomass must pass through a shredder or grinder to reduce
its size so it can be suspended in the air stream. For wet or sticky materials, such as sludge,
some of the dry material can be recycled back and mixed with the incoming wet material to
improve material handling.
Exhibit 3–2: Typical Flash Dryer Configuration
For smaller flows of material, a disk dryer or "porcupine" dryer (Exhibit 3–3) is an option. In
a disk dryer, solids are heated by condensing steam inside of a central shaft with many
hollow disks that increase the area for heat transfer. Fingers or "breaker bars" mix the
material and act to keep the heat transfer surfaces free of buildup. The disk dryer can be
operated under a vacuum or under pressure, and the condensate from inside the heating
shaft can be recovered and returned to the boiler.
Cascade or spouted dryers (Exhibit 3–4) are commonly used for drying grain, but they can
also be used for other types of biomass. Material is introduced to a flowing stream of hot air
as it enters an enclosed chamber. The material is thrown into the air, then falls, or cascades,
back to the bottom to be lifted again. Some of the material is drawn out through openings in
the side of the chamber that control the residence time and amount of drying. The typical
residence time for a cascade dryer is a couple of minutes.
Exhibit 3–4: Side View of a Cascade Dryer
Source:
Drying tends to be energy intensive because, in addition to the heat of vaporization of the
water removed, energy goes into heating the biomass solids and into heating the air or
steam used for drying. Recovery of some of this heat improves the overall efficiency of the
drying process and boiler, but usually requires a significant capital investment.
The choice of dryers will depend on the characteristics of the material being dried, the
source of heat for the dryer, and integration options available.
An important consideration is the size of the material to be dried. For flash dryers and most
SSDs, a small particle size is needed to suspend the material in a moving air or steam stream.
Triple-pass rotary dryers will accept larger material, but may experience plugging with very
large material. Cascade dryers need a very uniform particle size. For large or variable
material, a single-pass rotary dryer might be best. For some materials, reducing the size of
the material may be an option, but often this is an energy-intensive operation.
The heat source and temperature for drying are important considerations. Flue gas is an
efficient source of heat, but the temperature may be too low to provide enough heat for
complete drying. Using a process stream for heating may be energy efficient, but will require
the capital investment in a heat exchanger and the interactions between the dryer and
process must be considered. SSDs typically require a high-temperature heat source. If
saturated steam is available, the disk dryer or modified SSD dryer would be an option. The
goal should be to determine what excess heat is available in the system, then design the
drying system to take advantage of it. If all else fails, a burner can be installed with an
auxiliary fuel source to provide the heat for drying.
High-pressure operation can improve material handling in many cases when dealing with
gasifiers. In those cases, the basic or modified superheated dryer would be favored. Again,
SSDs have advantages when used for combined heat and power plants or combined cycle
plants.
As mentioned earlier, the choice of dryers depends on many factors. A brief summary of the
benefits and disadvantages of each type of dryer follows. The particular type of dryer, its
configuration, and operating conditions should be determined case-by-case.
Rotary Dryers
Rotary dryers are less sensitive to particle size and can accept the hottest flue gases of any
type of dryer. They have low maintenance costs and the greatest capacity of any type of
dryer. However, material moisture is hard to control in rotary dryers because of the long lag
time for material in the dryer. Rotary dryers also present the greatest fire hazard and
require the most space. Compared to single-pass dryers, triple-pass dryers have higher
capital costs, higher maintenance costs, higher blower costs and pose more of a fire hazard.
Flash Dryers
Flash dryers are much more compact than rotary dryers, but have higher installation costs.
They can be used on most types of biomass, but have high blower power costs in addition to
The main advantage of disk dryers is that saturated steam can be used for heating. Because
they are indirectly heated, condensing the vapor from the dryer is possible to recover some
of the latent heat of vaporization. Operation is fairly straightforward and maintenance costs
are reasonable. The main disadvantage is the limited capacity because of the relatively low
operating temperature compared to other dryers.
Cascade Dryers
Cascade dryers are similar to flash dryers, except they can handle slightly larger particles.
However, for a good cascading effect in the dryer, the particle size must be fairly uniform.
Like other air-heated dryers, heat recovery is difficult and expensive.
Exhibit 3–5 summarizes the main considerations in choosing among the dryer types.
Exhibit 3–5: Summary of the Advantages and Disadvantages of Each Dryer
Dryer Type Requires Small Requires Ease of Heat Fire Steam Use
Material? Uniform Size? Recovery Hazard
Depending on the combustion technology used fuel products must fulfill different
requirements. The demand to get the fuel product either powdered or as fluff, in pelletized
form, or as briquettes or chips of defined size is not uncommon.
3.7.1 Powdering
Fuel material of small particle size (e.g. sawdust) is being generated by many production
processes. With the appropriate utilization technology in place, such fuels can be directly
utilized. The storage of fuel products with a small particle size can be done in flat bunkers
and in silos. However, special provisions are also made with respect to fire protection and
prevention of explosions during the storage of these materials.
However, in case the size of available material needs to be reduced, it can be done by using
suitable equipment.
Pellets are a solid biomass fuel with consistent quality – low moisture content, high energy
density and homogeneous size and shape. The problems of conventional biomass fuels as an
alternative to coal, oil or gas, which are attributed mainly to their low energy density, high
moisture content and heterogeneity, can be lessened or even prevented altogether by the
use of pellets. Consistent fuel quality makes pellets a suitable fuel type for all areas of
application, from stoves and central heating systems to large-scale plants, and with
practically complete automation in all these capacity ranges.
Advantages of solid biomass fuels are:
Reduced storage volume through an increased bulk density of the losefuelmaterial,
Better flow properties and dosage,
Avoidance of bridges and clumping in silos and conveyoraggregates
Enhancement of the energy density and calorific content by pressure andheat.
Aside from compression pressure and grain size, also water content plays an essential role
in the process. Adding binding agents can help to improve the physical and chemical quality
and enhance the burnout.
The shape and particle size of a fuel usually determine the correct choice of feeding and
furnace technologies as they influence the conveying and combustion behavior of the fuel.
The bigger the fuel particles are, the more robust feeding appliances have to be and the
longer becomes the required time for complete combustion.
Biomass pellets are usually 6-8mm diameter cylindrical high density sticks, while briquettes
can be 22-70mm diameter cylindrical blocks, or cuboid and hexagon shape with a hole in the
middle.
Pellets Briquettes
The image to the right depicts the basic design and process of the flat die pellet mill. A solid
metal plate sits below a series of compression rollers. Material enters from above and falls
The image to the right depicts the basic design and operation of the ring die pellet mill.
Unlike the flat die pellet mill design the ring die is positioned vertically instead of
horizontally. The raw material enters the center of the die and is compressed through the
die with a series of compression rollers. Most ring die pellet mills have two compression
rollers, however some ring die pellet mills have three maybe four compression rollers. The
most common design of ring die pellet mill is where the die is powered and rotating, and the
rollers move due to the friction and movement of the die.
Briquetting presses operate as piston compressors with a fly wheel, slider crank, crosshead
and plunger or with a hydraulic drive. After initial compression in a screw conveyor the
material passes under pressure batch wise through the compression tools, cone for pre-
compression and the press nipper. Within the press nipper a heating or cooling can be done.
The briquette is wedged from the pneumatic press nipper in a pressure variable way
Piston rod presses are being used for the compression of sawdust, splinter, straw, paper
fibers and similar materials.
Through the production of briquettes in various shapes, an optimal burning (burnout,
burning duration) of the fuel material can be achieved.
The conversion of biomass to energy (also called bioenergy) encompasses a wide range of
different types and sources of biomass, conversion options, end-use applications and
infrastructure requirements.
Biomass conversion technologies are broadly divided into the following prime categories:
Thermochemical conversion
Biochemical conversion
4.1.1 Combustion
Combustion is basically an oxidation process, in which the flammable materials burn in the
presence of air or oxygen, and as a result produce heat. Reactions producing heat are termed
as exothermic.
In the combustion process, the oxidation carbon (C) and hydrogen (H2) predominantly
present in the biomass takes place, and they are converted to dioxide (CO2) and water (H2O).
Biomass also contains traces of other elements. Some of these are also oxidized, and
released as gas in the flue gasses, or as solid as ash or slag.
The biomass is burnt in stoves, furnaces, and boilers. The temperature of hot gases
produced is around 800 1000°C. The heat generated, as a result of combustion of biomass, is
utilized over a side range of applications, such as, cooking, heating of materials, and
producing steam. Steam produced is then utilized for heating purposes in industrial and
commercial facilities, for producing mechanical or electrical power by operating steam
turbines and turbo-generators.
It is possible to burn any type of biomass but in practice combustion is feasible only for
biomass with moisture content <50%. Therefore, in case of very high moisture content, the
biomass is pre-dried.
4.1.2 Gasification
Gasification is a partial oxidation process whereby a carbon source such as coal, natural gas
or biomass, is broken down into carbon monoxide (CO) and hydrogen (H 2), plus carbon
dioxide (CO2) and possibly hydrocarbon molecules such as methane (CH4).
This mixture of gases is known as ‘producer gas’ or product gas (or wood gas or coal gas,
depending on the feedstock), and the precise characteristics of the gas will depend on the
Biomass Gasification Systems
21
gasification parameters, such as temperature, and also the gasification agent used, such as
air or steam or oxygen or a mixture of these.
When using air as the gasification medium, the resulting high nitrogen (N2) content doubles
the volume of the product gad and increase the size of the downstream gas cleaning
equipment.
Low temperature gasification
If the gasification takes place at a relatively low temperature, such as 700°C to 1000°C, the
product gas will have a relatively high level of hydrocarbons compared to high temperature
gasification (see below). As a result it may be used directly, to be burned for heat or
electricity generation via a steam turbine or, with suitable gas clean up, to run an internal
combustion engine for electricity generation.
High temperature gasification
This is commonly known as synthesis gas as it can be used to synthesize longer chain
hydrocarbons using special conversion techniques.
Gasification technology can be used for:
Steam generation
4.1.3 Pyrolysis
Anaerobic digestion
Fermentation
Anaerobic digestion (AD) is the process whereby bacteria break down organic material
(biomass) in the absence of air into methane, carbon dioxide, and solid residue. In this
process, the bacteria utilize oxygen from biomass itself instead of from the ambient air. Its
product gas is called biogas.
There are three basic AD processes, which take place over different temperature ranges.
Psychrophilic digestion
It takes place between 20°C and 40°C and can take 30 to 40 days to complete.
Thermophilic digestion
It takes place from 50-65°C and is faster, but the bacteria are more sensitive. This process
takes 15 to 20 days to complete.
Parameters affecting the anaerobic digestion are temperature, pH (acidity/alkalinity) of the
digestate, and concentration of ammonia. High concentration of ammonia inhibits the
digestion process.
The methane can be burned for heat or electricity generation.
The solid residue of the AD process can be used as a soil conditioner. In fact, it is an excellent
fertilizer
The digesters are simple, cheap, robust, easy to operate and maintain, and can be
constructed with local produced materials. Usually, there are no control instruments and no
process heating (psychrophilic or mesophilic operation temperatures).
4.2.2 Fermentation
In this process, biomass is converted into sugar using acid or enzyme. Sugar is then
converted into ethanol or other chemicals with the help of yeast.
Two principal types of gasifiers have emerged: fixed bed and fluidized bed. Fixed bed gasifiers
are typically simpler, easy to operate and less expensive. They produce a higher heat content
producer gas. Fluidized bed gasifiers are more complicated and more expensive. However, they
produce a product gas with a higher heating value.
Fixed bed gasifiers typically have a fixed grate inside a refractory-lined shaft. The fresh
biomass fuel is typically placed on top of the pile of fuel, char, and ash inside the gasifier.
Fixed bed gasifiers typically offer 5 - 15 % pressure drops based on feed size and gasifier
type. A further distinction is based on the direction of flow of the gasifying agent (air or
oxygen).
Schematics of the primary section of the fixed bed gasifier types are described and shown in
the following sections.
In the downdraft gasifier (Exhibit 5–1), the air flows down through the bed and leaves as
producer gas under the grate, while the feedstock is charged from the top.
Exhibit 5–1: Typical Downdraft or concurrent gasifier
Source: Kaupp
In this type of gasifier (Exhibit 5–2), the air enters into the gasifier below the grate, flows up
through the grate, and producer gas is collected above the bed.
In the cross-draft gasifier (Exhibit 5–3), the air flows across the bed, exiting as product gas,
i.e. gasifying agent enters from one side of the gasifier and leaves from the other side.
Exhibit5–2: Updraftgasifier
Source: Kaupp
Source: Kaupp
Type of gasifier
Downdraft Updraft Crossflow
Biomass is introduced
Biomass is introduced
Biomass is introduced from from the top and moves
from the top and moves
the top and moves downward.Syngas is
downward. Some
downward. Syngas is extracted opposite the
drying occurs. Syngas is
Operation extracted at the bottom at air nozzle at the
extracted at the top.
grate level. grate.
Fluidized bed gasifiers utilize the same gasification processes and offer higher performance
than fixed bed systems, but with greater complexity and cost. Similar to fluidized bed
boilers, the primary gasification process takes place in a bed of hot inert materials
suspended by an upward motion of oxygen-deprived gas (Exhibit 5–6). As the amount of gas
is augmented to achieve greater throughput, the bed will begin to levitate and become
“fluidized.” Sand or alumina is often used to further improve the heat transfer. Fluidized bed
gasifiers have the certain disadvantage of higher pressure drops usually ranging from 20 -
25 %. Notable benefits of fluidized bed devices are their high productivity (per area of bed)
and flexibility. Fluidized bed gasifiers can also handle a wider range of biomass feedstock
with moisture contents up to 30 percent on average.
Source: Andritz AG
At the lower end of fluidization, the bed expands and begins to act as a fluid. As the velocity
is increased, the bed will begin to “bubble.” With a further increase in airflow, the bed
material begins to lift off the bed. This material is typically separated in a cyclone and “re-
circulated” to the bed. With still higher velocities, the bed material is entrained (i.e., picked
up and carried off in the airflow).
Fluidized bed gasifiers can be designed to use a portion of the pyrolysis gases to generate
the heat to drive the process, or they can be externally fired. Operating the gasifier at higher
pressures increases the throughput; however, this also increases the gasifier’s complexity
and cost. In these units, the biomass is fully converted after going through the pyrolysis and
char conversion processes.
By reducing the quantity of air and process temperature, it is possible to operate fluidized
bed boilers as gasifiers. In this operating mode, the gasifiers produce a gas with a heating
value of slightly more than 100 Btu/ft3. This gas is burned above the bed as additional air
supply is injected upstream of the boiler tube section.
Exhibit 5–7 lists typical physical characteristics of a fluidized bed gasifier. A number of
advanced-concept fluidized bed gasifiers aiming to produce a syngas with a heating value
between 250 and 400 Btu/ft3 are under development. This type of syngas would be more
appropriate for use in gas turbines, fuel cells, and reciprocating internal combustion
engines; however, these advanced concept gasifiers have not reached the point where they
are proven in commercial operation.
Control Average
Turn-down ratio 3
Fixed bed and fluidized bed gasifiers have specific operating advantages and disadvantages
with biomass fuels depending on the biomass characteristics and site requirements. Exhibit
5–8 provides a qualitative comparison of gasifier characteristics and operating issues for
fixed bed and fluidized bed systems.
Large-scale applications
Feed characteristics
Medium tar yield Higher
Bubbling fluid bed Direct/indirect heating Can
particle loading
produce higher heating
value gas
Large-scale applications
Feed characteristics Can Medium tar yield Higher
Circulating fluid bed
produce higher heating particle loading
value gas
Can be scaled Potential for
Large amount of carrier gas
low tar Potential for low
Entrained flow fluid bed Higher particle loading
methane Can produce
Particle size limits
higher heating value gas
Source: EPA Combined Heat and Power Partnership Biomass CHP Catalog
Equivalence ratio
Hearth load
Turndown ratio
Superficial gasvelocity
Operating temperature
Operating pressure
These factors are discussed in the following sections and other chapters as appropriate.
ER is defined as the ratio of oxygen supplied per kg wood to the stoichiometric requirement.
ER fixes the amount of air supplied for gasification. The equation for calculating ER is
(Kaupp, 1984):
(𝑂𝑥𝑖𝑑𝑎𝑛𝑡)
⁄ (𝐷𝑟𝑦 𝐹𝑢𝑒𝑙) (𝐴𝑐𝑡𝑢𝑎𝑙 𝑊𝑒𝑖𝑔ℎ𝑡 𝑅𝑎𝑡𝑖𝑜)
𝐸𝑞𝑢𝑖𝑣𝑎𝑙𝑒𝑛𝑐𝑒 𝑅𝑎𝑡𝑖𝑜 (𝐸𝑅) =
(𝑂𝑥𝑖𝑑𝑎𝑛𝑡)⁄
(𝐷𝑟𝑦 𝐹𝑢𝑒𝑙) (𝑆𝑡𝑜𝑖𝑐ℎ𝑖𝑜𝑚𝑒𝑡𝑟𝑖𝑐 𝑊𝑒𝑖𝑔ℎ𝑡 𝑅𝑎𝑡𝑖𝑜)
As the ER value approaches 1.0, combustion reaction is predominant, and as it tends to zero,
pyrolysis is the major process.
The ER for gasification processes as they take place in practice lies between those two
extremes and within a range of 0.2 to o.4 for steady state operation. This range refers to the
partial combustion zone of the gasification process. A value of 0.3 ER is the theoretical
optimum (Jenkins, B.M. 1980) [FAO; 19].
All the gasifier designs are based on the above-mentioned optimum. For a given biomass
consumption rate, the volumetric rate of air can be calculated from ER value (Kaupp, A. and
Goss, J.R. 1981) [FAO; 20].
For example, normally, the value of ER for wood is 0.255.
It is defined as the amount of producer gas to be obtained in a unit time per unit cross-
sectional area of the gasifier throat, which is the smallest cross-sectional area in the gasifier.
It is also referred as specific gasification rate (SGR).
It is expressed as: Nm3/cm2-h (normal cubic meters of producer gas produced per cm2
minimum cross-sectional area of the gasifier (throat) in one (1) hour. Mathematically,
𝑁𝑚3
𝑆𝐺𝑅 =
𝑐𝑚2 × ℎ
The hearth load varies between an upper limit, SGRmax, above which the gas quality is poor
because of charcoal dusting in the combustion zone and a lower limit, SGRmin below which
due to too low temperature in the hearth, the gas will contain unacceptably large quantities
Biomass Gasification Systems
31
of tar. For the satisfactory and continuous operation of specifically Imbert gasifiers, and
other similar reactors, the limits for SGRmax and SGRmin are:
0.9 𝑁𝑚3 0.3 ~ 0.35 𝑁𝑚 3
𝑆𝐺𝑅𝑚𝑎𝑥 =
𝑐𝑚2 × ℎ
𝑆𝐺𝑅𝑚𝑖𝑛 = 𝑐𝑚2 × ℎ
Fuel consumption rate (FCR) is defined as the amount of fuel consumed in a unit time per
unit cross-sectional area of the gasifier throat, which is the smallest cross-sectional area in
the gasifier.
It is expressed as: kg/cm2-h (kg of fuel consumed in the gasifier per cm2 minimum cross-
sectional area of the gasifier (throat) in one (1) hour. Mathematically,
𝑘𝑔
𝐹𝐶𝑅 =
𝑐𝑚2 × ℎ
Depending on properties of fuel used, one (1) kg of biomass fuel consumed in a gasifier,
under normal operating conditions, generated producer gas in the range of 2 -2.5 Nm3 of
producer gas. Accordingly, the relationship between SGR and FCR is expressed as:
The relationship is the function of amount of gas generated per kg of fuel consumed.
When 2.5 Nm3 gas produced per kg of fuel, and SGRmax is 0.9, rearranging the equation:
𝑆𝐺𝑅 = 2.5 × 𝐹𝐶𝑅
𝐹𝐶𝑅𝑚𝑎𝑥 = 0.4 × 𝑆𝐺𝑅𝑚𝑎𝑥
𝑘𝑔
𝐹𝐶𝑅𝑚𝑎𝑥 = 0.4 × 0.9 = 0.36
𝑐𝑚2 × ℎ
For the other extreme case, when 2.0 Nm3 gas produced per kg of fuel, and SGRmax is 0.9,
rearranging the equation:
𝑆𝐺𝑅 = 2.0 × 𝐹𝐶𝑅
𝐹𝐶𝑅𝑚𝑎𝑥 = 0.5 × 𝑆𝐺𝑅𝑚𝑎𝑥
𝑘𝑔
𝐹𝐶𝑅𝑚𝑎𝑥 = 0.5 × 0.9 = 0.45
𝑐𝑚2 × ℎ
The maximum dilution of gas takes place because of presence of nitrogen. Almost 50-60%
of gas is composed of non-combustible nitrogen.It may be beneficial to use oxygen instead of
air for gasification but the cost effectiveness of the process comes under scrutiny.
However the cost and availability of oxygen may be a limiting factor in this regard.
Nevertheless where the end product is methanol – a high-energy quality item, then the cost
and use of oxygen can be justified.
On an average 1 kg of biomass produces about 2.5 m3 of producer gas at normal conditions
In this process it consumes about 1.5 m3 of air for combustion. For complete combustion of
Biomass Gasification Systems
32
wood about 4.5 m3 of air is required. Thus biomass gasification consumes about 33% of
theoretical stoichiometric ratio for wood burning.
The average energy conversion efficiency of biomass gasifiers (especially wood based
gasifiers) is about 60-70% and is defined as:
𝐶𝑎𝑙𝑜𝑟𝑖𝑓𝑖𝑐 𝑉𝑎𝑙𝑢𝑒 𝑜𝑓 𝑔𝑎𝑠 𝑝𝑒𝑟 𝑘𝑔 𝑜𝑓 𝑓𝑢𝑒𝑙
𝜂𝑔𝑎𝑠 =
𝐴𝑣𝑔. 𝐶𝑎𝑙𝑜𝑟𝑖𝑓𝑖𝑐 𝑉𝑎𝑙𝑢𝑒 𝑜𝑓 1 𝑘𝑔 𝑜𝑓 𝑓𝑢𝑒𝑙
It is the ratio between SGRmax and SGRmin. Its range under these conditions can be
calculated as the following for SGRmax = 0.9 and SGRmin = 0.3 – 0.35:
𝑆𝐺𝑅𝑚𝑎𝑥
𝑇𝐷𝑅 =
𝑆𝐺𝑅𝑚𝑖𝑛
0.9 𝑆𝐺𝑅𝑚𝑎𝑥
𝑇𝐷𝑅 = =3
0.3 𝑆𝐺𝑅𝑚𝑖𝑛
0.9 𝑆𝐺𝑅𝑚𝑎𝑥
𝑇𝐷𝑅 = = 2.57 (𝑠𝑎𝑦 2.5)
0.35 𝑆𝐺𝑅𝑚𝑖𝑛
So, in this case, the TDR ranges between 2.5 and 3.0.
It is expressed in m/s. SGR is the velocity of gas at the throat of the gasifier in the
gasification zone considering the throat to be empty. The relationship between hearth load
(SGR) and SGV is:
𝑆𝑉𝐺 = 0.36 𝑆𝐺𝑅
The superficial velocity corresponding to a hearth load (SGR) of 0.9 Nm3/cm2-h is 2.5 m/s,
calculated as:
0.9 𝑁𝑚3 10,000 𝑐𝑚2 × ℎ 𝑚
𝑆𝐺𝑉 = 𝑐𝑚2 × ℎ × 𝑚2 × 3,600 𝑠
= 2.5
𝑠
The actual gas velocity at the throat of the gasifier is much more compared to this value due
to presence of char/biomass particles and high temperature in the oxidation zone of the
gasifier.
Hence, the optimum temperature generally ranges from 650°C to 720°C. In fact, while
depending upon other variables, it is very much biomass specific to fuel properties.
Downdraft gasifiers are most common (Exhibit 5–9). The population of various types of
gasifiers is:
Exhibit 5–9: Population of gasifiers by design
Downdraft 75%
Fluidized bed 20%
Updraft 2.5%
Other designs 2.5%
Source: Knoef, 2000 (Basu)
Gasifiers are very fuel specific and they are tailored according to the fuel. There is no such
thing as a universal gasifier. Further, fuel used, gasifier design and operating conditions
influence the quality and quantity of product gas. For a specific fuel, a well-designed and
properly operated gasifier will tend to produce good quality product gas with fewer
impurities. Impurities usually present in the product gas are discussed below.
The product gas leaving the gasifier is hot and may contain a number of impurities,
including:
Moisture
Particulates
Tar
Traceimpurities
It is desirable to use fuel with low moisture content because heat loss due to its evaporation
before gasification is considerable and the heat balance of the gasification reaction is
disturbed. High moisture content also puts extra load on cooling and filtering equipment by
increasing the pressure drop across these units because of condensing of moisture vapors.
Thus, as the situation demands, the fuel should be pre-dried / treated to reduce / limit its
moisture content. Generally, moisture content for fuel should be less than 20%, preferably
15%.
All gasifier fuels produce dust particulates in varying quantity. It is a nuisance since it can
clog the end-use equipment, where the product gas is used. Hence, it must be removed to
the permissible limits specified for end-use of the product gas. Through gasifier design and
control of operating parameters, it should be ensured that the gasifier does not produce
more than 2-6 g/m3 of dust. Higher dust levels pose additional load on cleaning systems,
therefore, necessitating their large size and frequent maintenance.
Tar is another most unpleasant constituent of the gasification process. On cooling of product
gas, it condenses, and tends to deposit and clog the system, e.g. the carburetor and intake
valves of internal combustion engine causing sticking and troublesome operations. The
physical property of tar depends upon temperature and heat rate of the gasifier and the
appearance ranges from brown and watery (60% water) to black and highly viscous (7%
water).
Trace impurities present in the product gas depend on the composition of biomass fuel used.
They are mostly, nitrogen compounds, sulfur compounds, and alkali compounds, besides
oxides of other heavy metal present in the biomass gasified. Nitrogen compounds are
present mainly as ammonia. Alkali components consist of particularly Na and K compounds.
Oxides of sulfur and hydrochloric acid are other impurities. These impurities cause many
problems including corrosion.
Gasification systems are employed in integrated configuration. The product gas may be used
for heating purposes in a furnace or steam generation, driving an internal combustion
engine, and in a gas turbine. Depending on the application of the producer gas, a certain
level of gas conditioning (cleaning and cooling) is required.
When a gasifier system is used in conjunction with an internal combustion engine or cold
gas transfer is used, it is important that the engine is supplied with a gas that is sufficient
free from dust, tars and acids. The tolerable amounts of these substances will vary
depending on the types and outfit of the engine. Average tolerable values of impurities for
currently available engines are as the following (Tiedema et al., 1983):
Gas turbines also require high quality product gas. However, gas turbines are less sensitive
to tar as compared to internal combustion engines, because the gas entering the gas turbine
is usually at high temperature and therefore the tar is in vapor state.
Meanwhile, higher limits of impurities are tolerable for the heating applications.
It is invariably done in water scrubbers, where partial cleaning takes place simultaneously
along with cooling of gas.
As discussed earlier, the end-use of the gas determines the degree of cleanup required and
can be achieved by either of the following two options:
Hot gas cleaning
The benefit of hot-gas cleaning is that more energy is gained from the gas but the process
poses significant technical challenges.
Biomass Gasification Systems
38
Cold gas cleaning
The cold-gas cleaning is technically simpler but produces a wastewater contaminated with
tar, which is likely to pose a disposal problem. It is discussed in the following section.
There are two options of the removal of tar present in the product gas.
Tar cracking
Tar can be cracked into lower molecular weight compounds using either catalytic or thermal
processes.
Catalytic cracking takes place at 800-900°C and thermal cracking at 900-1100°C. As
gasification is usually in the range 800-900°C, thermal cracking requires additional energy
to heat the gas, which is usually achieved by introducing a small volume of air to enable
combustion of part of the gas to raise the temperature. While an effective method, thermal
cracking reduces the overall efficiency of conversion of biomass-to-energy gasification
process. Catalytic cracking is therefore preferred, using catalysts such as dolomite, olivine
and nickel compounds. A uniform and high temperature has been found to be the ideal
combination to achieve the total cracking of tar.
Removal of tar by cleaning unit
Production of a very low tar content gas is best achieved by cooling the gas to 60-80°C with
water and using electrostatic precipitators to capture any aerosols. However this approach
also collects water condensed from the gas phase during cooling, resulting in a wastewater
heavily contaminated with dissolved organic substances, which require appropriate
treatment and/or disposal.
Depending on the size of gasification system and quality of product gas needed, the cooling
and cleaning train may consist of the following units:
As system requires, the gas just leaving the gasifier is sent to the cyclone separator to
separate dust particulates, before the gas enters the water based cooling and scrubbing unit.
Temperature of the product gas leaving the gasifier is normally in the range of 350°C to
450°C. When the gas cools to 150°C, the tar condenses, solidifies and settles.
Cooling and scrubbing unit is cylindrical vessel as shown in Exhibit 6–2. Raw hot gas enters
the unit from bottom and cool scrubbed gas leaves from the top. Gas. While, from the top,
pressurized water is sprayed through nozzles in the form of mist (fine water droplets).
Contaminated hot water flows downward and is collected from the bottom. The flow of
water and gas is countercurrent.
Exhibit 6–2: Cylindrical unit of scrubbing and cooling
For small sized gasification systems, the gas cleaning filter units are simple, cost effective
and can be easily operated. A reliable filter medium should meet the following criteria:
1. Neutralandnon-reactive
2. Easilyavailablein differentgrainsizegrades
3. Inexpensive andeasilyavailable
4. Canwithstandhighgas temperature
5. Easy tocleanand recyclei.e. regenerativematerial
The filter consists of following five compartments (Pathak et al., 2007) as shown in Exhibit
6–3:
1. First compartment: Rawgascollection
2. Second compartment: 1stfiltrationmaterial
3. Third compartment: 2ndfiltrationmaterial
4. Fourth compartment: 3rdfiltrationmaterial
5. Fifthcompartment: Cleanproducergascollection
The second, third and fourth compartment are filled with, wood sheaves, small pieces of
charcoal and sawdust respectively.
The area of gas cleaning filter is designed for superficial velocity of 0.1 m/s and for
maximum designed gas flow rate of the gasifier in m3/h. Area of the filter, in m2, can be
easily calculated for the two known quantities. (Pathak et al., 2007)
The sand/biomass bed filter can be designed and fabricated in rectangular shape from 3 mm
thick mild steel or stainless steel sheet. Wire meshes fabricated from stainless steel may be
used to separate filter bed. Most of the gas contaminants (particulates and tar) are deposited
in the initial 20 to 30 mm layers of bed height (Pathak et al., 2007). Therefore, to be on safe
side, the height of each bed in the filter should be increased 2 to 3 times the actual size.
In the three respective stages of the filter: (1) sun dried wood shave is used to remove the
moisture from the producer gas, (2) coal is used to remove coarse particulates and tar, and
(3) wood saw dust or fine sand is used to remove fine particulates and tar. Wire meshes
having size equivalent to that of respective material size is used to separate the beds. The
three beds of wood shaves, charcoal and fine wood saw dust should be easily removed and
replaced by fresh material by opening the door provided at the upper side of the filter. As
shown in the exhibit, the entrance and exit of the producer gas is on oppositesides.
Pressure drop across the filtration units will indicate their status. It can be measured by
using a suitable manometer. Excessive pressure drop calls for the maintenance.
Special note
For continuous operation, the cooling / scrubbing units and filtering units should have
standby units (placed in parallel). The arrangement will facilitate, the flushing, maintenance
and replacement of the cooling and filtering mediums and regular intervals.
Instruments and controls are essential for a gasification system to assume safe, efficient and
reliable operation. The subject of instruments and controls is extremely broad, and this
section limits itself to some brief concepts and underlying fundamentals.
Controls range from simple manual systems to completely automatic computer-assisted
systems, and hence the type of control system used in a gasification system would depend
upon the requirements of the total operation and the cost involved. The following sections
cover many of the typical instruments and controls.
Normally pressure gauges are used to measure pressure at different points. Pressure gauge
is a device to indicate the pressure of a fluid. Commonly Bourdon-Tube gauges are for
pressure measurements. It indicates the amount of deflection under internal pressure of an
oval tube bent in an arc of circle and closed at one end.
Other modes of pressure measurements are:
Manometermethod
Elastic ElementMethod
Bellows Elements
Diaphragm Elements
Electrical / ElectronicMethods
Fixed bed gasifiers mostly operate under vacuum (negative pressure), close to atmospheric pressure. Under
these conditions, the use of manometers is proper and useful. Other alternative is the use of sensetive
vacuum gauge.
Where access to hot surface or pipe-work is not easy, it is often possible to achieve good
results using a non-contact temperature measuring instruments such as an infrared
thermometer, illustrated in Exhibit 7–3.
Analysis of the producer gases is a very useful mean to optimize and control the gasifier
operation. For this purpose, digital based and very handy analyzers can be used. A typical
portable producer gas analyzer is shown in Exhibit 7–4.
Exhibit 7–4: A portable producer gas analyzer
For flue gas analysis, there are a number of methods available. The traditional method is the
"Orsat" apparatus (Exhibit 7–5a), which uses chemical solutions to absorb carbon monoxide,
carbon dioxide and oxygen from a flue gas sample. Changes in volume of the sample indicate
the gas composition. A simplified version of the Orsat is shown in Exhibit 7–5b. This
particular model is the "Fyrite" analyzer (other proprietary names are used by other
manufacturers). Each Fyrite kit contains two plastic containers, each with an appropriate
chemical fluid, one for oxygen analysis and one for carbon dioxide analysis. A gas sample is
introduced into the container through a non-return valve and thoroughly mixed with the
absorbing solution. A change in volume indicates directly the volume percentage of the
particular component in the flue gas.
While the wet chemical test methods are quite inexpensive to use there are many new
instruments available for oxygen measurement based on sensors which give an electronic
signal proportional to the oxygen content of the gas. Examples of a typical electronic
instrument are shown in Exhibit 7–6. These particular models use a sensor based on an
electrolytic cell (similar to a battery): the sensor is inexpensive and robust, and relatively
insensitive to contaminants in the flue gas such as sulfur dioxide. The life of a sensor is
typically nine months to one year. Similar sensors are available for carbon monoxide (and
also other gases, such as hydrogen sulfide and nitrogen oxides).
Exhibit 7–5: Orsat Apparatus and Fyrite Gas Analyzer
Other instruments for oxygen measurement are based on zirconium oxide (zirconia), which
conducts oxygen ions at temperatures above 650ᵒC. The sensor is maintained at a high
temperature, ideally about 800ᵒC, and consists of a heated cell with two electrodes: one
electrode is surrounded by a reference gas (usually air) and the other electrode has the
sample gas passed over it. Any difference in oxygen content at the electrodes is translated
into a potential difference and hence an electronic signal
Because a zirconia cell must have a heater and controls to ensure operation at affixed high
temperature, instruments based on zirconia tend to be bulky and heavy. Portable analyzers
are available, but the zirconia system is normally restricted to fixed gas analyzers mounted
in the stack of medium to large boilers and furnaces, and more recently, package boilers. The
life of a zirconia probe in a typical boiler stack should be five years or more.
In addition to ease of operation, the main advantage of the electronic analyzers is the ability
to obtain continuous instant feedback on excess air and boiler efficiency while the sensor is
in the stack. This greatly facilitates the boiler tuning process.
7.5.1 Sampling
Regardless of what stack measurement is being made, whether it is CO, CO2, excess O2,
smoke, temperature, etc., it is imperative that the measurement be made on a representative
sample of the bulk of the gas flow. The location of the site at which the sample of flue gas and
the stack temperature are obtained is as important as the measurement itself
Safety devices should be installed wherever the maximum allowable working pressure
(MAWP) of a system or pressure-containing vessel is likely to be exceeded.
In case of small gasifiers, the use of rupture disc, also called as burst disc is suitable and
must be used.
Since, the population of downdraft gasifiers is approximately 75%, and they are employed in
the small sized applications. They are simple, cost effective and easy to operate. However,
they are less efficient. With the passage of time specially designed gasifiers for large
applications have been successfully developed, installed and being operated. However, they
are expensive, costly, specialized, and fully automatic with electronic control. In fact, they
are efficient. Exhibit 8–1 illustrates the gasifier sizes and theirapplication.
Exhibit 8–1: Technology options with gasification
Therefore, the guidelines for the sizing of downdraft biomass gasifier are discussed in the
following sections. However, it is imperative to have some fundamental information.
If one ignores the components, which are present in the range of parts per million (ppm),
the air mainly consists of about 0.9% by volume argon, 78.1% nitrogen and 20.9% oxygen
(ignoring water vapor). Carbon dioxide is present at0.038%.
For the purposes of combustion calculations the composition of air is approximated as a
simple mixture of oxygen and nitrogen:
Oxygen 21%
Nitrogen 79%
The ratio of oxygen and nitrogen in the air is 1:3.76 (79 divided by 21); while the ratio
between oxygen and air is 1:4.76 (100 divided by 21)
For example, the stoichiometric relationship for complete combustion is:
Exhibit 8–2 contains information on the properties of gases commonly present in the
product gas. The last two columns provide the information on air requirement for complete
combustion of respective gasses in volumetric ratio and the heating value in kcal per normal
cubic meter. Heating value of the combustion mixture is obtained by dividing the heating
value of gas by the sum of the amount of gas and the air required, i.e., 1 + the amount of air
required.
Exhibit 8–2: Properties of gases present in the producer gas
Source: Generator gas, the Swedish experience from 1939 to 1945, SERI, US Department of Energy
The equations for the complete combustion of various gases with air are:
Exhibit 8–3: Complete combustion of various gases with air
The values from Exhibit 8–3 can be used in Exhibit 8–4 for the producer gas of known
composition to obtain heating value and density of the air gas mixture.
Exhibit 8–5 contains information on theoretical air required for complete combustion of
given producer gas.
So, the air required is 0.984 Nm3 per Nm3 of dry producer gas. For general calculations, the
stoichiometric air -fuel-ratio (AFR) for complete combustion can be assumed as 1:1.
Source: Generator gas, the Swedish experience from 1939 to 1945, SERI, US Department of Energy
a CnHm denotes so-called heavy hydrocarbons present in the producer gas. In calculations,
the values for ethylene may be used.
Exhibit 8–5: Air required for complete combustion
Exhibit 8–6 is the nomograph for determining the effective heat value for the produced gas.
It shows the use of the nomograph for above example.
Exhibit 8–6: Nomograph for determining effective heat value of producer gas
Source: Generator gas, the Swedish experience from 1939 to 1945, SERI, US Department of Energy
Heating values of producer gas and air mixtures are around 2500 kJ/m3, while the heating
value of a stoichiometric mixture of gasoline (petrol) and air, which is about 3800 kJ/m3.
When these values are compared with each other, the difference in power output between a
given engine fuelled by gasoline and by producer gas becomes obvious. Therefore, a power
reduction of about 35% can be expected as a result of the lower heating value of a producer
gas and air mixture. (FAO, 1986)
The following example demonstrates the electrical power output of the given ICE running on
producer gas for small-scale applications.
3,000 cc internal combustion engine (SI) 3 liter
The calculations for the gasifier for producing 11.57 kWelec are illustrated, where the kWth
(thermal) in terms of 57.14 kJ/s have been calculated in the above sheet.
Hence, the downdraft gasifier is to be sized based on 20.27 kg/h of biomass fuel gasified.
Note: Calculations for hearth diameter and other parameters are to be included in the
manual. For this purpose the following exhibits are to be used on the basis of biomass
consumption (20.27 kg/h).
Due to its convenience in use like other gaseous or liquid fuels, producer gas finds many
applications, particularly where the process specifically demands the use of gaseous of
liquid types of fuels. It is being successfully used in a variety of thermal processes, and
mechanical / electrical power generation systems.
The producer gas can be conveniently applied in various applications, such as:
Utilization in kilns, such as, for firing of tiles, potteries and refractories requiring hot
environment in temperature range of 800–950°C.
Industrial thermal applications requiring high flame temperatures, such as, heating
medium in steel re-rolling mills, non-ferrous metallurgical foundry industries, and
high temperatures furnace / heating operations
Co-firing applications
Used as replacement fuel in natural gas and gasoline engines with some necessary
modifications
Power generation applications where the producer gas is being utilized efficiently and
environment friendly atmosphere are presented below. There are some challenges in
applying producer gas in the power generation systems.
As with all engine fuels, there are specific limits to different components present in the input
fuel gas. Gas contaminants in producer gas, most notably dust, tar and humidity, are a key
technical challenge to its utilization in power generation applications. The contaminant
limitations for turbines are even narrower as compare to internal combustion engines (ICE).
It is schematically presented in Exhibit 9–1. For achieve better performance and efficiency of
such systems, it is desirable that the load on the gasifier should be nearly constant.
Exhibit 9–1: BIG/ICE power generating system
Varying compositions, as well as calorific values and the combustion behavior of the gases
present in the producer gas, put greater demands on engine design. Special features of the
engines, operated on producer gas, may include flame arrestors for the prevention of
backfiring, special gas mixers to improve gas mixing and to be more robust to dirt. In
general, the stable composition of producer gas makes it advantageous as an engine fuel.
The high hydrogen content of a producer gas however, means the combustion process is
very fast, which increases the danger of engine pre-ignition, knocking or engine backfiring.
To avoid this risk, an engine control system is needed that is able to fuel the engine with a
very lean mixture and, at the same time, react very quickly to variations in the engine load.
Producer gas can be used to create hot water, steam and electricity. The hot water and
exhaust gases from the engines are fed into boilers. The resulting steam can be used within
other localized industrial processes. Producer gas electrical efficiencies in the range of 25 %
to 37% can be achieved.
High electrical efficiency compared to other power generation technology (i.e. steam
or gas turbines)
Source: EPA Combined Heat and Power Partnership Biomass CHP Catalog
CHP is the sequential or simultaneous generation of multiple forms of useful energy (usually
mechanical and thermal) in a single, integrated system. CHP systems consist of a number of
individual components—prime mover (heat engine), generator, heat recovery, and electrical
interconnection— configured into an integrated whole. The type of equipment that drives
the overall system (i.e., the prime mover) typically identifies the CHP system. Prime movers
for CHP systems include steam turbines, gas turbines (also called combustion turbines),
spark ignition engines, diesel engines, microturbines, and fuel cells. These prime movers are
capable of burning a variety of fuels, including biomass/biogas, natural gas, or coal to
produce shaft power or mechanical energy. Additional technologies are also used in
configuring a complete CHP system, including boilers, absorption chillers, desiccants,
engine-driven chillers, and gasifiers. Boilers and gasifiers are discussed in Chapter 5 of this
document.
Although mechanical energy from the prime mover is most often used to drive a generator
to produce electricity, it can also be used to drive rotating equipment such as compressors,
pumps, and fans. Thermal energy from the system can be used in direct process applications
or indirectly to produce steam, hot water, hot air for drying, or chilled water for process
cooling.
The industrial sector currently produces both thermal output and electricity from biomass
in CHP facilities in the paper, chemical, wood products, and food processing industries.
These industries are major users of biomass fuels—utilizing the heat and steam in their
processes can improve energy efficiencies by more than 35 percent. In these applications,
the typical CHP system configuration consists of a biomass-fired boiler whose steam is used
to propel a steam turbine in addition to the extraction of steam or heat for processuse.
Exhibit 9–2 shows a typical biomass integrated gasification and combined cycle (BIG/CC)
system.
Source: en.wikipedia.org
The product gas produced in the biomass gasification section is used as fuel for the
gas turbine in the combined cycle, and
Steam produced by the syngas coolers in the gasification section is used by the
steam turbine in the combined cycle.
In this example the product gas produced is used as fuel in a gas turbine, which produces
electrical power. In a normal combined cycle, so-called "waste heat" from the gas turbine
exhaust is used in a Heat Recovery Steam Generator (HRSG) to make steam for the steam
turbine cycle. BIG/CC plant improves the overall process efficiency by adding the higher-
temperature steam produced by the gasification process to the steam turbine cycle. This
steam is then used in steam turbines to produce additional electrical power.
The gasifiers operate at negative pressure, which result from the suction of either the engine
or a blower. The stepwise guide to the operation of a gasifier is as follows:
For better results fuels having moisture content more high should be dried before
feeding.
To accelerate the drying process it is advantageous to spread the fuel in open air.
Using wood fuel a fresh cut wood has a moisture content of 40-42 % and it dries in
sixty days to moisture content about 20 % it means for safety at least wood fuel
should be stored for roughly three months consumption in the site.
The fuel was fed into the gasifier from the top and it descended through the gasifier
by gravity.
At start-up, some charcoal was loaded in and below the hearth zone for quick gas
production. It was recommended to put charcoal in the gasifier from the bottom
grate to 10 cm above the nozzle plane, with wood or other biomass on top.
It was better and advantageous to fill the gasifier up to full capacity. In this way the
oxygen present in the empty place of fuel hopper was removed and the risk of
blasting was decreased.
For lightening first the blower was started, it run for some time for that the excess
air in the gasifier was removed, then the air regulating inlet valves were opened and
a cloth soaked with kerosene oil is lighted with a simple match and it was brought
near the air inlets.
Due to negative pressure in the reactor it sucked the air inward and the burning of
the fuel was fully started in about 4-5 minutes.
Fill the water in the water channel provided on the top of thegasifier
Water filling must be done to the position so that it may not tip down from the
gasifier top
At the start of the gasifier and also before shutting down the gasifier, check the
water level to avoid any kind of gas leakage
First, the gasifier was filled with the fuel to its full capacity.
Fasten the airtight covers (top cover and ash removal cover) with the help of screws.
Closing of valve which was on the gas delivery pipe to engine and opening of valve of
blower suction pipe. The both valves were manually operated.
An induced blower with speed regulator was provided for start up the gasifier.
Waited about 2 to 3 minutes so that all the accumulated gases in the gasifier should
release.
After ignition of the biomass in the gasifier fire chamber, place the torch at the flare
port
Open the one side valve and brought the torch near it, as there will be negative
pressure in the gasifier so it sucks the fire inside the gasifier and the fuel will be
started to burn.
The flame sustains for about 10-15 minutes in the flare port otherwise the high
impurity gas may enter in the gasifier chamber.
Producer gas was escaped through the blower exhaust with whitish appearance.
The fire was burn very bright because of the plenty of the suction. The suction rate
was also controlled by the flow regulating valves.
Open the valve of cleaning and cooling train when a refined quality starts coming in
the flare port
Allow the gas to pass through the train for cooling process
Open the gas line valves gradually and close the airline valve simultaneously to
maintain the frequency in between 48-52 Hz.
Biomass Gasification Systems
64
Step 7: Grate Shaking
Grate shaking can also reduce the accumulation of ash, this is how thegas
production rate can be made efficient
Bulk Density
Auxiliary Consumption
Regular system maintenance is also required to keep the gasifier working for long and
continuous operation. Maintenance can be categorized as follows:
Clean the heat exchanger by removing the dust penetrated in it by opening the end
plug from the bottom of the heat exchanger
Clean the centrifugal part (cyclone separator) of the gasifier chamber by removing
the dust
Clean the sawdust filter, gravel bed filter and venturi scrubber ash pit
Before refilling and fitting the filter media which is composed of gravel, sawdust
should be taken out
Remove the biomass present in the gasifier before cleaning the grate of agasifier
Installed cleaning and cooling systems must be cleaned thoroughly and fit those
back
The HE can be cleaned if the pressure dropped across it is raised up to certain limits
By opening the end plug at the bottom of the HE, the inlet ad outlet gas ducts should
be cleaned at regular intervals
The end plug of cyclone can be opened with spanner and can be refitted after
cleaning
The venturi scrubber removes the tar through condensation that gets collected in
the water pit
The cleaning of venturi scrubber doesn’t require much attention, but the mesh fitted
in the pit to segregate the dust particles etc.
Venturi scrubber should be cleaned after every four days to prevent any blockage
The bed of gravels does not create much pressure drop in the gas line, but needs to
be cleaned after every 100 hours
The cleaning can be done after opening the top flange of the filter with one and half
inched spanner, taking out the gravels on the mesh
Before refitting the gravels in the filter casing, sun drying of gravel isobligatory
The required maintenance for this type of filter should be done after 100 hours in
case the pressure drop across the filter increases
Engine Maintenance
Check for leaks and observe the air cleaner restriction indicator
Check coolant level and top up with pre mixed coolant if required
Miscellaneous Checks
Check governor and mixture valves and gas valves linkages are free
Keep the water level up to the mark in ash pit, water seals and venturiscrubber
When the temperature limit reaches 450C, drain off the water and simultaneously
fill the fresh water in venture by opening the waterpump
While charging the gasifier make sure that the main blower is switched off and only
suction blower is working
Close the gasifier lid and place it so that it sits in the annular groove or water seal
provided on top of the gasifier
The gasifier installation must provide with the following features, which helped to minimize
the usual hazards of gasifier operation:
Pressure relief valve must be provided at the top of the gasifier to reduce the
excessive internal pressure because in most cases pressure builds up in the bunker
section.
The gasifier should house and operated in an open shed so that concentration of the
carbon monoxide cannot develop.
Gas produced and takes out from the gasifier by suction of the blower/engine, as
they created the negative pressure in the gasifier, so there is no risk of blasting.
The gasifier must be sited at a sufficient distance from the exploding material.
Care must be taken to avoid inhaling smoke and fumes of the system.
The gasifier should be started after being filled completely up to the top.
Gasifier should be sealed completely by using the silicon in such a way that the air
cannot entered in to the system except through regulated valves.
The hot gasifier should always be refilled by keeping the blower running.
The black color is used on the gasifier for checking heat losses into the surrounding
atmosphere.
Cold system should always be carefully ventilated by running the blower for 2 to 3 minutes
before igniting the fuel.
Source for the operational guidelines for a fluidized-bed biomass gasifier and power
generation plant is Chongqing Fengyu Electric Equipment Co., Ltd., China.
Generic operational procedure for the fluidized bed gasification plant shown in Exhibit -------
are described below:
Operators should be imparted training and they should fully understand the operation.
Preparation for the gasifier start is listed as follows:
1. Turn on gasification control unit and check whether all instruments and functioning
properly.
2. Startwatersupplypumpandcheck if theflow rateis normal.
3. Start water return pump and regulate its flow rate through the ;water return valve to keep
theflow to waterbalancedacrosstheplant.
4. Check thewaterlevel of flocculating tankand supplementit in timeon regularbasis.
5. Check whether there is sufficient feedstock in the feeding hopper. (Delay in supply delay
andfuelshortagearenotallowedduring therunning);
6. Ashunloadershouldbeputout of the ashremovegroove;
7. Start ashremovefan;
8. Checkwaterlevel of gas tankandgivesupplement timely;
9. Checkwater level of safetywatersealfor over-pressureand alkali waterwasher G/W
(gas/water) separator, andkeepthem normal;
10. Checkwater level of safetywaterseal , observewhethertherearedepositedat the
bottom;
11. Release condensate water deposited in lower level of gas pipes, shut off water discharge
valve.
1. Open the gasifier door, add appropriate woodchip and oilpaper to gasifier, and then begin
ignition.
2. Afterthewoodchipstart toburn , closethegasifierdoorand keepitsealed
3. StartRootsfan, keepthelowestrotationspeedat 100rpm
4. Startforcefanandspeed upit gradually.
5. Start screw feeder until the temperature at the bottom of gasifier reach 500C, to add fuel
properly, and regulate air flux at the same time so that the temperature in dense phase
sectioncanberangedfrom 680C to800C
6. Thepressureat thetopshouldbekeptnormal( 200pa ~ 600pa) by aboveoperation
7. If there is glow ash at the bottom before ignition, the blower can be started directly,
meanwhile feed properly. The step1 and step 2 are unnecessary, just follow othersteps.
8. When the temperature in the bottom of gasifier reaches at 550C, operators must start
screwashconveyerandrotaryvalveto removeash
The temperature in gasifier is influenced by air flux and fuel quantity, the temperature in
tense phase sector is claimed from 680C to 800C strictly. It is easy to form clinker at the
bottom above 800C, while the tar will take more proportion in gas below 680C. In normal
running, the tense phase sector should range from 680C to 800C. Increase gas capacity at
the time of load rise, air flux increase will cause temperature rise, so at the same time more
fuel should be added for controlling temperature. It will cause temperature rise if the
feeding is reduced due to load decline, consequently, air flux should be reduced at the same
time.
Pressure change in gasifier caused by many factors such as draft air flux, burnt products,
fuel pyrolysis and gasification speed, and so on.
For normal running, atmospheric pressure in gasifier is required, and at the bottom of
gasifier has slight positive pressure, the pressure at the top is not allowed to exceed slight
negative pressure of -1200pa, the exceeded one will cause accident like dry-type cyclone
doesn’t work and numerous small ash involve in water, as well as increase wear and tear of
ash conveyer and the load of cooling system.
Generally at the bottom the positive pressure should be kept comparative high so that it do
good to the fluidized burning, it is allowed ranging from +100Pa to +3000Pa.
Pay more attention: air flux should be decreased for safety in the process of dredging
gasifier. The pressure should be adjusted ranging from -600Pa to +200Pa in the gasifier.
1. Check feeding situation: guard feeding delay, once feeding delay meanwhile air flux does
not decrease in time, it will cause sharp temperature rise even forming clinker, and the
worseis the comparativehighnegativepressurein gasifierwilllead to deflagration.
2. Check electric current of feeder, if exceeded, maybe some sundries are involved in or
moisture content of fuel is so high that causes high resistance, operators must clean timely
andpreventsundries andrainfromfeeder
3. Check electric current of Ash conveyor screw, if exceeded which indicates overload, take
actionimmediately.
4. Check electric current of Roots fan, if exceeded, it indicates there is one or more block in
thecleaning & coolingequipment, clearworkshould betakentimely
5. Check the electric current of blower, water supply pump and water return pump to make
sure theyareproper.
6. Check gas pressure difference of U-shape pipe between entrance and exit of Venturi
scrubber, if there is big difference, it indicates there is block at larynx of the Venturi,
operators shoulddredgeitafterfurnacestop.
Furnace shutdown
1. Decrease gas capacityat the time of load falling, stop feeder and shut off hopper
flashboardtokeepfurnacefrom hopper.
2. In the process of above operation, intake and drain air flux should be decreased relatively
to decrease temperature to about 600C, after stopping intake blower, the rotary speed of
Rootfan willbedecreased to150rpm.
3. After the above operation are finished, stop feeder(after furnace stopped and flashboard
closed, the low load running should last 1~2 minutes, make the small hopper half full,
keep fuelfromhopper).
4. Closeintakevalve of gastankanddischargeallgas.
5. StopRootfan after6~8 minutes of stoppingfeeding
Operation of recovering
1. After supplying power of equipment, firstly to start water supply and return pump, then
start Rootsfanat the speedof 150 rpm in order to dischargeallgas of air drainsystem
2. To add water to safety waterseal.
3. Others follow the ignition section.
1. Forbid opening furnace door and clinker drain door until stopping intake blower
completely.
2. Keep caution leave back way for operators at the moment of opening furnace door, it is
not allowed to face furnace door at the time of opening in case fire is out. Operator must
remindworker around furnace for prevent hurt by positive pressure anddeflagration
3. During dredging ash, pressure should be regulated as slight negative pressure for safety
reason.
4. Afterstopping furnace, allgasshould bedischargedfrom gastank
5. Forbid firearoundfurnace
6. Forbid to lap ground electrode of welder through electric facilities or mechanical
equipment.
7. If workers don’t know whether there is surplus gas left or not, they are forbidden to lap
ground electrode through gasification system equipment as well as using gas cutting and
electricweldingandfireonit.
8. Do notusehigh moisturecontentfeedstock(themax. moisturecontentis 15%).
Routine maintenance
Periodically check all nuts on the gasifier unit, the fuel hopper, the filter unit, and the carburetor for
snugness; check all penetrations and fittings for airtightness. In addition, perform the following
maintenance activities as scheduled:
Daily maintenance
Open the ash cleanout port of the gasifier housing drum and remove the ashes after shaking the grate
for at least thirty seconds. Replace the cover of the port after coating the threads with high-temperature
silicone to ensure airtightness. Open the drain tube at the bottom of the filter container and allow any
liquid condensate to drain out; remember to close the drain tube when finished.
Make sure that all pipe connections are secure and airtight. Check and tighten all mounting
connections to the vehicle chassis. Check for rust on the outside of the gas generator housing
drum, especially on the lower region. Coat with high-temperature protective paint as
necessary.
Source: femagasifier.com
Damage or destruction
Locate fire systems in safe areas of the facility. Protect
of the gasifier plant
them from fire by distance or by fire walls
and/or building
2. Explosive Atmosphere
Location of Potential
Origin of Hazard Measure Recommended counter measures Possible reduction
Hazard consequences What
When? No. measures
Where? happens?
Technical or
operational
Implement measures to avoid explosions including: -
problemleading
The whole Flooding with inert gas - Avoid ignition source - Removal
to: 1. Under Air ingress Gas escape 2.1
plant of dust deposits - Avoid dust clouds - Maintain clean
pressure, 2.
working floor - Grounding of the plant sections
Overpressure, 3.
Dust clouds
Spillage of
Explosion can Using a water seal acting as a flame arrestor Leak
flammable 2.5
initiate fire detection (gas sensors)
liquids
Plant
sections
where fine
dust and Organizational precautions to comply cleanliness,
particles avoid dust depositions and contamination, avoid
Fine dust and
are handled Explosion, fire 2.6 dust clouds and maintain clean working flours
particles
(fuel Good housekeeping is the key to avoid dust
storage, ash explosions Ban smoking, no smoking signs
or dust
removal
systems)
3. Substance Hazards
Location Potential Measure
Origin of Measu Recommended counter measures Possible
of Hazard consequences implement
Hazard When? re No. reduction measures
Where? What happens? ed (yes/no)
CO leakage
outside the plant
3.3 Installation of CO monitors in the plant
and environmental
pollution
Fire ignition,
The whole Explosion, which Operators should be instructed not to stay
plant, at can lead to more unnecessarily close to system components
Flammable
start-ups explosions (i.e. 3.4 (gasifier, cyclone bins, filters, etc.) with
materials
and shut- dust explosions), flammable materials during start-up, normal
downs plant destruction, operation and shut-down
fire, etc.
Fire ignition
Explosion, which
Glowing carbon
Ash can lead to more Install a humidification system at the ash removal
particles and
removal explosions (i.e. 3.8 in order to prevent fire hazards from glowing
high
section dust explosions), particles
temperatures
plant destruction,
fire, etc.
Fire ignition
Explosion, which
Install either: a water seal or a cyclone combined
Gas Glowing particles can lead to more
with a settling chamber in order to prevent
cleaning Leakages Storage explosions (i.e. 3.10
glowing particles from entering the gas cleaning
section or holding tanks dust explosions),
section.
plant destruction,
fire, etc.
Wet
Scrubbi
ng
Material toxicity +
systems Environmental Installation of a bin/tank to collect andtreat the
carcinogenicity
and pollution by 3.11 toxic liquids (treatment by a certified company,
resulting from tar
Particle scrubbing water prescribed in permit documents)
removal/recycling
filter for
fly- ash
removal
5. Thermal Hazards
Locatio
n of Origin of Potential Measur Recommended counter measures Possible Measure
Hazard Hazard When? consequences e No. reduction measures implement
What happens? ed (yes/no)
Where?
Fuel
storage,
transport Temperature Feedstock self- Monitor temperature in big piles of feedstock,
5.1
and rise ignition Install CO monitors,Install sprinkler installations
feeding
Malfunctioning of
the process due to
overheating of
Hot materials like Water spraying at ash discharge, Set maintenance
surfaces Chemical refractory lining, intervals, Corrosion resistant steel material, Detect
5.2
of gas reactions valve settings, etc. leakages by indication of temperature increase in
cooler which may cause all case auto-ignition temperature exceed set limits
sorts of dangers in
particular gas
escape
Pressures build-up
leading to gas
escape and its
Power failure 6.1 Safety emergency stop
consequences
(please refer to
section 3)
The whole
plant Fire ignition
Static electricity Use proper grounding to avoid static electricity
Explosion, which 6.2
build up can lead to more build up and lightning hazards
explosions (i.e.
dust explosions),
plant destruction, Use of intrinsically safe electrical installations and
Sparks fire, etc. 6.3 non-sparking tools Screw conveyors should have
shaft speed monitor and speed control
Fire ignition
Explosion, which
Gas can lead to more
All gas conducting part should be electrically
conducting Sparks explosions (i.e. 6.5
grounded
part dust explosions),
plant destruction,
fire, etc.
7. Mechanical Hazards
Location of Potential Measure
Origin of Measu Recommended counter measures Possible
Hazard consequences implement
Hazard When? re No. reduction measures
Where? What happens? ed (yes/no)
Conveyors,
Sharp edges, Safety switches and local circuit breakers on
electro Operator injuries
sharp parts rotating parts and switches, on access panels, on
motors
7.2 pressure relieve equipment, on critical valves with
access to gas containing equipment such as
feeders, cyclones and ash outlets
The Global Environment Facility approved a project under its Climate Change Focal Area
entitled, “Promoting sustainable energy production and use of biomass in Pakistan.” The
general target of the venture is to advance business sector based selection of biomass
vitality change innovations for process heat and power generation in Small and Medium
Scale Enterprises (SMEs) and electrify rural areas in Pakistan. The project aims at building
the capacity of SMEs through alternative means of power generation and promoting
biomass gasification technology in the country.
The power condition in Pakistan is categorized by a wide gap between demand and supply.
The order of magnitude of unmet demand in peak demand months is over 25% of peak
demand. This situation adversely affects the economy. Many SMEs have problems in
retrieving contemporary energy services due to the regular electricity supply stoppage in
the country, and have convinced to the diesel generators usage. Shortage of energy not only
effects the production and profit but also depresses the capacity and opportunity to rise.
The energy shortage results in lowering of their production, profit and capacities and
opportunities to grow.
UNIDO is implementing a GEF funded project entitled “Promoting Sustainable Energy
Production and Use from Biomass in Pakistan”. The conversion of biomass into producer gas
can be carried out under controlled conditions of temperature and oxygen during the
process of gasification and more of the heat content of the biomass is captured.
Under this project UNIDO is trying to establish the economic probability and marketable
practicality through pilot projects and doing efforts in building capacity of local
manufacturers/fabricators. This international conference on BGTs application in SMEs and
rural areas is bringing in renowned energy experts from around the globe, technology
providers, manufacturer, policy makers, financial institutions and other key market players
in Islamabad. Through this technology transfer of BGTs in Pakistan, UNIDO aims at
promoting the concept of “inclusive and sustainable industrial development”–ISID.
In Pakistan, most common biomass fuels are cotton stalk, wheat straw, rice husk, sugarcane
trash, bagasse and other crops residues. Currently, most of these biomass products are
treated as biomass waste and is usually burned in the fields. Biomass burning has a
significant impact on global atmosphere chemistry since it provides large sources of carbon
monoxide, nitrogen oxides and hydrocarbons.
The waste products which are the main contributors to biomass burning are bagasse, rice
straw and husk, cotton wastes, barley residue, maize stalks and leaves, and millet and
sorghum stalks. Sugar cane provides the next sizeable residue with two major crop wastes;
barbojo or the leaves and stalk and bagasse, the crop-processing residue from sugar mills.
The cotton crop also gives significant residue in the form of stalks and husks.
Biomass resources, particularly residues from wood processing, agricultural crops and agro-
processing, are under-utilized in Pakistan. These resources are renewable, environmentally
friendly in energy production and sustainable in terms of supply.
Some of these residues are already used as raw materials for other products (e.g. particle
board and fiber-board) as fodder and fertilizer or as household and industrial fuels.
However, large portions are still unused and represent potential sources of energy. Energy
generation technologies specifically designed to use biomass residues are available and are
becoming more and more economical. Pakistan has yet to make optimum use of the
additional power generation potential from its biomass residue resources, which could help
it to partially overcome the long-term problem of energy supply.
Statistical data on the production of various types of biomass in Pakistan refers to the data
mention in .
13.1 Bagasse
Sugarcane top and trash is usually used as a fodder for animals. Presently, almost all power
requirements of sugar mills are met by using bagasse as a fuel but it is pertinent to mention
that some of sugar mills are producing surplus power to the grid. In fact, sugar mills in
Pakistan either have established the improved technology in their existing facilities or these
are in process for generating surplus power to the National Grid at the moment.
Approximately 96-98% bagasse produced from cane is consumed in all sugar mills
(operating) in the country to meet the steam requirements for sugar and for in house and
surplus power requirements.
Annual production of sugar cane top and trash, and bagasse is in the range of:
Average sugar cane top and trashper annum: million tonnes
Rice husks are one of the commonest global agricultural residues and by-products of rice
paddy milling industries. Rice husks have 45-53% cellulose and hemicelluloses, lignin and
protein ranges 25-30%.
As per the research, 100 kg of paddy contains almost 67 kg of rice and 33 kg of bran powder,
and husk and dust.
Average Rice husk producedper annum: million tonnes
Average Annual quantity of Paddy straw: million tonnes
Cereal straw from small cereal crops as wheat is produced at around 2.5-5/ha depending on
crop type, variety and the growing season. It is estimated that equivalent yield of wheat
straw is produced by weight from wheat crops. Wheat straw is almost 40% cellulosic in
nature. It is also pertinent to mention that almost all the wheat straw is generated in the
field when the wheat crops are to be processed through ripper machines, combined
harvesters or manually cutting tools and readily available to Flour Mills for producing flour.
No countable/significant wastages are produced in Flour Mills or in the field that can be
used as a burning fuel because all wheat is converted into flour and farina (cream of wheat).
In terms of comparative gross energy values, 1 tonne of straw equates approximately 0.5
tonne of coal or 0.3 tonne of oil. It has higher silica content than other forms of biomass,
leading to ash contents of up to 10% by weight.
Wheat straw produced in Pakistan is heavily consumed as fodder to about 88% of its overall
production. Approximately 5% wheat straw of its overall production is utilized in the
manufacture of pulp for producing paper and paperboard in the country.
It is to be considered that wheat straw is also abundantly used as fodder for animals, raw
material for pulp, paper and paperboard manufacturing; and fuel for brick manufacturing.
2. Technical Specifications:
No
. Item / Power 400KW 800 KW 1MW 1.5MW 2MW
Conversions of SI and other commonly used units are presented in this appendix.
Energy Units
Power Units
W = Watt = 1 J/second
kilowatt = kW = 1000 W
Megawatt = MW = 1000 kW
Gigawatt = GW = 1 million kW
HP = Horse Power = 745.7 W
kVA = kilo Volt-Ampere
Force Units
N = Newton
Pressure Units
Pa = Pascal = 1 N/m²
Bar = 105 Pa
1 millibar = 100 Pa
Length Units
m = meter
km = 1000 m
cm = 0.01 m
mm = 0.001 m
m = 10^-6 m
Surface Units
Mass Units
kg = kilogram
t = tonne = 1000 kg
g = 0.001 kg
mg = 10^-6 kg
Time Units
s = second
min = minute = 60 s
h = hour = 3600 s
yr = year
m³ = cubic meter
1 cubic meter (m³) = 1 000 liter (l)
dm³ = 0.001 m³
mm³ = 10^-9 m³
1 = liter = 1 dm³
Temperature Units
K = Kelvin
°C = degree Celsius
1° C = 1 °K
Miscellaneous
Other Units
Hz = Hertz (frequency)
V = Volt
17.1 Abbreviations
17.2 Glossary
Carburetting
Carburetting air or gas generally comprises passing it in contact with liquid fuel and
thereby mixing the air/gas and fuel. This often involves lowering the air pressure e.g. in a
venturi.
Destructive distillation
The Dry Bulb Temperature refers basically to the ambient air temperature. It is called "Dry
Bulb" because the air temperature is indicated by a thermometer not affected by the
moisture of the air.
Endothermic Reaction
It describes a reaction in which the system absorbs energy from its surroundings in the
form of heat. Expressed in a chemical equation: reactants → products - energy.
Exothermic reaction
It is a chemical reaction that releases energy in the form of light or heat. Expressed in a
chemical equation: reactants → products + energy.
Gasification
Producer gas
It is a mixture of gases containing carbon monoxide (CO), hydrogen (H2), carbon dioxide
(CO2) and nitrogen (N2). In the USA, producer gas is a generic term referring to wood gas,
town gas, synthesis gas, syngas or raw gas. In the UK, producer gas, also known as suction
gas, means a fuel gas made from coke or other carbonaceous material. Air is passed over
the red-hot fuel and carbon monoxide is produced in an exothermic reaction which reads
2C + O2 → 2CO. The nitrogen in the air remains unchanged and dilutes the gas, so it has a
low calorific value. The gas may be used to power gas turbines which are suited to fuels of
low calorific value.
Pyrolysis
A gas mixture that contains varying amounts of carbon monoxide (CO) and hydrogen (H2)
generated by the gasification of a carbon-containing material to a gaseous product with a
heating value (but less than half the energy density of natural gas). When used as a fuel, it
is produced by gasification of coal or municipal waste by the following reactions: C + O2 →
CO2; CO2 + C → 2CO; C + H2O → CO + H2. The name comes from the gas's use as an
intermediate in creating synthetic natural gas (SNG) and in producing ammonia or
methanol.
Torrefaction
It is a thermal process that involves heating the biomass to temperatures between 250
and 300 degrees Celsius in an inert atmosphere. When biomass is heated at such
temperatures, the moisture evaporates and various low-calorific components contained in
the biomass are driven out.
Town gas
Also known as coal gas, and contains hydrogen (H2), carbon monoxide (CO), carbon
dioxide (CO2), methane (CH4), nitrogen (N2) and volatile hydrocarbons. It is made by
blowing air and steam over an incandescent fuel bed, usually of coke or coal. The words
"coal gas" could also be used to mean gas made by the destructive distillation of coal. The
gas was used inter alia for lighting before the advent of electric lighting, and for heating
and cooking before natural gas became widely available.
Water-gas
A mixture of carbon monoxide (CO) and hydrogen (H2) produced by passing steam over
red-hot coke using the endothermic reaction C + H2O → CO + H2. This product had a lower
calorific value than coal gas so the gas was often passed through a heated retort into which
oil was sprayed; the resulting mixed gas was called carburetted water gas.
This is the temperature indicated by a moistened thermometer bulb exposed to the air
flow. It can be measured by using a thermometer with the bulb wrapped in wet muslin.
The rate of evaporation from the wet bandage on the bulb, and the temperature difference
between the dry bulb and wet bulb, depends on the humidity of the air. The evaporation is
reduced when the air contains more water vapor. The wet bulb temperature is always
lower than the dry bulb temperature but will be identical with 100% relative humidity
(the air is at the saturation line).
Wood gas
The product of thermal gasification of biomass (e.g. coal, wood chips, sawdust, charcoal) in
a gasifier or wood gas generator. It is the result of a high temperature reaction (> 700
degrees C) where carbon reacts with steam or a limited amount of air producing carbon
monoxide (CO), carbon dioxide (CO2), hydrogen (H2) and methane (CH4). It can be
filtered, purified or scrubbed and used to power internal combustion engines, gas
turbines, Stirling engines or fuel cells.
To be expanded as needed.
Prepared by
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US-Pakistan Center for Advanced Studies in Energy
(USPCAS-E)
National University of Sciences and Technology
Islamabad, Pakistan