MATERIAL SAFETY DATA SHEET Page 1 of 6

HYDROCHLORIC ACID

1. Product And Company Identification

Supplier Manufacturer
Rite-Kem, Inc. Rite-Kem, Inc.
703 Westmoreland Drive 703 Westmoreland Drive
Tupelo, MS 38801 USA Tupelo, MS 38801 USA
Company Contact: Tyrone James Company Contact: Tyrone James
Telephone Number: 662-840-6060 Telephone Number: 662-840-6060
FAX Number: 662-840-7007 FAX Number: 662-840-7007
E-Mail: [email protected] E-Mail: [email protected]
Web Site: Ritekem.com Web Site: Ritekem.com

Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800 424 9300 CHEMTREC: 800 424 9300

GSA GS-07F-0283J
CAGE CODE: OVVNO
Issue Date: 03/09/2011
Product Name: HYDROCHLORIC ACID
CAS Number: 7647-01-0
MSDS Number: 106
Product Code: HYDROGEN CHLORIDE
Product/Material Uses
Process chemical, metal cleaning, water purification, petroleum industry.

2. Composition/Information On Ingredients

Ingredient CAS Percent Of

Name Number Total Weight
HYDROGEN CHLORIDE 7647-01-0

3. Hazards Identification
Primary Routes(s) Of Entry
Inhalation, skin, eyes, and ingestion.
Eye Hazards
Burns, eye damage, blindness.
Skin Hazards
Burns, ulceration, and dermatitis.
Ingestion Hazards
May cause burns to the gastrointestinal tract.
Inhalation Hazards
Burns, cough, pulmonary edema, and erosion of teeth.

4. First Aid Measures

Eye
Immediately flush eyes with direct stream of water for at least 15 minutes, holding eyelids apart. Get medical
attention.

Skin
Immediately flush contaminated areas with water. Remove contaminated clothing, jewelry, and shoes
immediately. Wash all contaminated areas with soap and water. Clean and dry clothing before reuse. Get
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4. First Aid Measures - Continued

Skin - Continued
immediate medical attention.
Ingestion
Never give anything by mouth to an unconscious or convulsive person. If swallowed, do not induce vomiting. Give
large amounts of water. If vomiting occurs spontaneously, keep airway clear. Give more water when vomiting
stops. GET IMMEDIATE MEDICAL ATTENTION.
Inhalation
Remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should
be administered by qualified personnel. If raspiration or pulse has stopped, have a trained person administer
Basic Life Support and CALL FOR EMERGENCY SERVICES IMMEDIATELY.
Note To Physician
The absence of visible signs or symptoms of burns does NOT reliably exclude the presence of actual tissue
damage.

5. Fire Fighting Measures

Flammability Class: Not flammable
Fire And Explosion Hazards
May release toxic gases.
Extinguishing Media
Use extinguishing agents appropriate for surrounding fire.
Fire Fighting Instructions
Keep unnecessary people away, isolate hazard area and deny entry. Wear NIOSH approved positive-pressure
self-contained breathing apparatus. Move container from fire area if it can be done without risk. Avoid inhalation
of material or combustion by-products. Stay upwind and keep out of low areas. Cool containers with water.

6. Accidental Release Measures

Wear appropriate personal protective equipment recommended in Section 8 of the MSDS. Completely contain spilled
material with dikes, sandbags, etc. Shut off ventilation system if needed. Reprocess or reuse if possible. Neutralize with
soda ash or dilute caustic soda. Collect with appropriate absorbent and place into suitable container. Liquid material
may be removed with a vacuum truck. Keep out of water supplies and sewers. This material is acidic and may lower the
pH of the surface waters with low buffering capacity. Releases should be reported, if required, to appropriate agencies.

7. Handling And Storage

Handling Precautions
Avoid breathing vapor or mist. Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. When
mixing, slowly add to water to minimize heat generation and spattering.
Storage Precautions
Store in rubber-lined steel, acid-resistant plastic or glass containers. Keep container tightly closed and properly
labeled. Store in a cool, dry place. Store in well-ventilated area. Do not store in aluminum container or use
aluminum fittings or transfer lines. Dike and vent storage tanks. Keep separated from incompatible substances.

8. Exposure Controls/Personal Protection

Engineering Controls
Provide local exhaust ventilation where vapor or mist may be generated. Eyewash fountain and a quick drench
shower is required.
Eye/Face Protection
Wear safety glasses with side shields. Wear chemically safety goggles with a faceshield or chemical splash hood.
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8. Exposure Controls/Personal Protection - Continued

Skin Protection
Wear appropriate chemical resistant gloves.
Respiratory Protection
When concentration exceeds exposure limits, a NIOSH approved respirator with acid gas canister is required.
When air-purifying respirator is not adequate or for spills and/or emergencies of unknown concentrations, a
NIOSH approved self-contained breathing apparatus or airline respirator with full-face piece is required.
Other/General Protection
Wear chemical resistant clothing and rubber boots when potential for contact with the material exists. Always
place pants legs over boots.

9. Physical And Chemical Properties

Appearance
Colorless, clear liquid
Odor
Pungent odor
Chemical Type: Mixture
Physical State: Liquid
Boiling Point: 140-221 °F 60-105 °C
Specific Gravity: 1.05 - 1.18
Molecular Weight: 36.46
Packing Density: 8.75 - 9.83 lbs/gal
Vapor Pressure: 14.6 - 80 mmHg @ 20 C
Vapor Density: 1.3 20 C
pH Factor: 2
Solubility: 100%
Evaporation Rate: <1

10. Stability And Reactivity

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
Avoid heat, flames, sparks and other sources of ignition. Contact with water may produce a strong exothermic
reaction with spattering. Contact with metals may evolve flammable hydrogen gas. Hydrogen chloride may react
with cyanide, forming lethal concentrations of hydrocyanic acid.
Incompatible Materials
Metals, alkalis, mercuric sulfate, perchloric acid, carbides of calcium, cesium, rubidium,acetylides of cesium and
rubidium, phosphides of calcium and uranium, lithium silicide.
Hazardous Decomposition Products
Thermal decomposition products or combustion: hydrogen chloride.

11. Toxicological Information

Eye Effects
Contact with eyes causes immediate severe irritation with possible burns, permanent visual impairment, or total
loss of sight.
Skin Effects
Contact with fumes or liquid may produce corrosive burns. Dermal exposure also results in irritation, pain,
dermatitis, and ulceration.
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11. Toxicological Information - Continued

Acute Oral Effects
Ingestion may cause immediate burns of the mouth, esophagus, and stomach. Ingestion may cause intense pain,
nausea, vomiting, bleeding, circulating collapse, shock and death.

Acute Inhalation Effects

Inhalation will cause severe irritation and possible burns with coughing and choking. If inhaled deeply, edema and
hemorrhage of the lungs may occur. Levels of 10-35 ppm may cause irritation of throat and 50-100 ppm is
unbearable for 1 hour. Inflammation, destruction of nasal passages and breathing difficulties may occur with
higher concentrations and may be delayed in onset. 1000-2000 ppm may be fetal. Prolonged exposure may
cause discoloration and/or erosion of teeth.
Conditions Aggravated By Exposure
Respiratory system

12. Ecological Information

Acute Toxicity - Fish And Invertebrates
This material is believed to be toxic to aquatic life.
Toxicity - Aquatic And Terrestrial Plants
This material is believed not to persist in the environment.
Soil: Hydrogen chloride will sink into the soil. The acid will dissolve some solid material and will be somewhat
neutralized.
Water: Dissociates almost completely and will; be neutralized by natural alkalinity and carbon dioxide.

13. Disposal Considerations

Reuse or process if possible. Dispose in accordance with all applicable regulations.

14. Transport Information

Proper Shipping Name
HYDROCHLORIC ACID SOLUTION
Hazard Class
8
Additional Shipping Paper Description
None

15. Regulatory Information

U.S. Regulatory Information
CERCLA Sections 102a/103 hazardous substances (40 CFR 302.4) : Hydrogen chloride (hydrochloric acid) :
5000 lbs rq (liquid) Chlorine: 10 lbs rq
FDA: This material has Generally Recognized as Safe (GRAS) status under specific FDA regulations. Additional
information is available from the Code of Federal Register which is accessible on the FDA's website.

SARA Hazard Classes

Acute Health Hazard
SARA Section 313 Notification
SARA Title III Section 302 extremely hazardous substances (40 CFR 355.30)
HYDROGEN CHLORIDE: aerosol form only
This product contains a toxic chemical or chemicals subject to the reportingrequirements of Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372.
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15. Regulatory Information - Continued

Canadian Regulatory Information
Shipping name: Hydrochloric acid solution
Un number: UN1789
Class: 8
Packing group/risk group: II
NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW:
REPORTING REQUIREMENTS:
WATER 7732-18-5 63-91%
HYDROGEN CHLORIDE 7647-01-0 9-36%

RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST:

HYDROGEN CHLORIDE 7647-01-0 9-36%
CHLORINE 7782-50-5 0-50 ppm

SPECIAL HEALTH HAZARD SUBSTANCE LIST:

HYDROGEN CHLORIDE 7647-01-0 9-36%

PENNSYLVANIA RIGHT TO KNOW:

REPORTING REQUIREMENT:
WATER 7732-18-5 63-91%
HYDROGEN CHLORIDE 7647-01-0 9-36%

HAZARDOUS SUBSTANCE LIST:

HYDROGEN CHLORIDE 7647-01-0 9-36%

ENVIRONMENTAL HAZARDOUS SUBSTANCE LIST:

HYDROGEN CHLORIDE 7647-01-0 9-36%

SPECIAL HAZARDOUS SUBSTANCE LIST:

Not regulated.

CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: E

NATIONAL INVENTORY STATUS:

U.S INVENTORY: All the components of this substance are listed on or are exempt from the inventory.

CANADA INVENTORY: All components of this product are listed on the DSL.

16. Other Information

NFPA Rating
H eal th: 3
F i re : 0
Reactivity: 1
HMIS Rating
Health: 03
F i re : 0
Reactivity: 1
Revision/Preparer Information
MSDS Preparer: KK
MSDS Preparer Phone Number: 662-840-6060
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HYDROCHLORIC ACID

Disclaimer
These data are based on tests and information which we believe to be reliable whether or not these data are
used is within the sole discretion and judgment of the costumer. Having no control over conditions of use, we
make no warranty of representation concerning your possible liability incident to the use of the product being
delivered, and further disclaim any responsibility for damage or injury, claim or the like resulting or allegedly
resulting therefrom.

Rite-Kem, Inc.
Printed Using MSDS Generator™ 2000