IIT-JAM 2006 With Solution PDF

CHEM ACADEMY 1 IIT-JAM 2006
IIT-JAM 2006
Note: Attempt ALL the 44 questions. Question 1-30 (Objective questions) carry three marks each and
question 31-44 (Subjective Questions) carry fifteen marks each.
1. After the following interchanging of groups in the Fischer projection of 2-bromobutane, the con-
figuration of (X) and (Y) will be
(a) X = R, Y = S (b) X = R, Y = R (c) X = S, Y = R (d) X = S; Y = S

2. The major product of the reaction
CHEM ACADEMY
(a) (b) (c) (d)
2 5 C H ONa (i) OH

3. In the reaction sequence, CH3COCH2COOC2H5  (X)  (Y)
CH Br (ii) H O / H 
3 2
The product (Y) is

(a) CH3COCH2COOCH3 (b) CH3COCH(CH3)2
CH 3COCHCOOH
|
(c) (d) CH3COC2H5
CH 3
4. The major product (X) in the reaction
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(a) (b) (c) (d)
5. The product of the reaction

3 AlCl / Cu Cl
2 2
C6 H6  CO  HCl 
heat
gives positive test with Fehling’s solution. The product is

(a) C6H5OH (b) C6H4 (Cl) CHO (c) C6H4 (OH)CHO (d) C6H5CHO
6. The compound (X) in the reaction sequence
(a) (b) (c) (d)
CHEM ACADEMY
(a) (b) (c) (d)
8. The increasing order of the acidity of the hydrogen marked in bold italics among the following is:
(a) III < II < I (b) II < I < III (c) I < II < III (d) II < III < I
is
(a) (b) (c) (d)
10. The number of enantiomers of camphor
(a) Four (b) Two (c) Three (d) One

11. The decreasing order of the first ionization energy of the following element is
(a) He > H > Be > B (b) Be > B > H > He (c) H > He > Be > B (d) B > Be > He > H
12. If the values of Madelung constants of the following compounds are equal, then their lattice energy
values decreases in the order
(a) KCl > NaF > CaO > Al2O3 (b) Al2O3 > CaO > NaF > KCl
(c) NaF > KCl > CaO > Al2O3 (d) Al2O3 > CaO > KCl > NaF
13. The fluoride, whose value of dipole moment is not equal to zero, is
(a) XeF4 (b) CF4 (c) SF4 (d) PF5
14. The decreasing order of ionic nature of the following compound is:
(a) Lil > NaBr > KCl > CsF (b) Lil > KCl > NaBr > CsF
(c) CsF > NaBr > KCl > Lil (d) CsF > KCl > NaBr > Lil
15. The atomicity and the total number of bonds in the elemental white phosphorous molecule are
respectively
16.
CHEM ACADEMY
(a) 4 and 6 (b) 6 and 4 (c) 4 and 4 (d) 6 and 6
The octahedral crystal field splitting (0) of d orbital energies of the following metal ions decrease
in the order
(a) Co2+ > Co3+ > Rh3+ (b) Rh3+ > Co3+ > Co2+
(c) Rh3+ > Co2+ > Co3+ (d) Co3+ > Co2+ > Rh3+
17. The half-life of a radioactive nuclide is 20 years. If a sample of this nuclide has an activity of 6400
disintegrations per minute (dis/min) today, its activity (dis/min) after 100 years would be
(a) 850 (b) 1600 (c) 200 (d) 400
18. The average value of C-C bond in graphite is:
(a) 1 (b) 3/2 (c) 3/4 (d) 4/3
19. The optical absorption spectrum of [Ti(H2O)6] has its absorption maximum at 20300 cm–1. The
3+
magnitude of crystal field stabilization energy in cm–1 is

(a) 8120 (b) 16240 (c) 24360 (d) 50750
20. In inorganic qualitative analysis, H2S in acidic medium will Not precipitate
(a) HgS (b) ZnS (c) CuS (d) CdS
21. The phase diagram of a pure substance is sketched below.
The number of degrees of freedom at points P1, P2 and P3, respectively are
(a) 2, 1, 0 (b) 1, 2, 0 (c) 2, 0, 1 (d) 0, 2, 1
22. The solubility products (Ksp) for three salts MX, MY2 and MZ3 are 1 × 10–8 , 4 × 10–9 and
27 × 10–8, respectively. The solubility of these salts follows the order
(a) MX > MY2 > MZ3 (b) MZ3 > MY2 > MX
(c) MZ3 > MX > MY2 (d) MY2 > MX > MZ3
23. The temperature (T) dependence of the equilibrium constant (K) of a chemical reaction is correctly
described by the following statement:
(a) For an endothermic reaction, the slope of ln K vs 1/T plot is positive.
(b) For an exothermic reaction, K is proportional to T
(c) For an exothermic reaction, K at a higher temperature is lower than K at a lower temperature
24. CHEM ACADEMY

(d) If H is independent of temperature, the change in K with T is smaller at lower temperatures.
When the concentration of K+ across a cell membrane drops from 0.01 M to 0.001 M, the potential
difference across the membrane is:
(a) 0.0 V (b) 0.0059V (c) 0.059 V (d) 0.59 V
25. The statement that is correct for both electrochemical (galvanic) cells and electrolytic cell is :
(a) G = –nFE
(b) Free energy decreases in both cells
(c) The cell potential are temperature independent
(d) Chemical energy is converted into electrical energy in both cells
26. The molar heat capacity at constant volume of a colourless gas is found to be 25 J mol –1 K–1 at
room temperature. The gas must be
(a) N2 (b) O2 (c) CO2 (d) SO2
27. The wavelength for a particle (moving in a ring) is (2)–1/2 exp (2i), where  is the polar angle.
The probability of finding the particle in a small interval d when the value of  = /2 is
(a) d (b) d/ 2 (c) d exp (i) (d) d exp (i) / 2
28. An electric current of 0.965 ampere is passed for 2000 seconds through a solution containing
[Cu(CH3CN)4]+ and metallic copper is deposited at the cathode. The amount of Cu deposited is
(a) 0.005 mol (b) 0.01 mol (c) 0.02 mol (d) 0.04 mol
29. The Maxwell-Boltzmann distribution for molecular speeds is shown in the following figure.
In the figure, H is the height of the peak, L is the location of the maximum and W is the width at half
height. As the temperature is decreased,
(a) H increases, L decreases and W increases
(b) H increases, L decreases and W decreases
(c) H decreases, L decreases and W increases
(d) H decreases, L decreases and W decreases
30. A system undergoes two cyclic processes 1 and 2. Process 1 is reversible and process 2 is irreversible.
The correct statement relating to the two processes is
(a) S (for process 1) = 0, while S (for process 2) 0
(b) qcycle = 0 for process 1 and qcycle  0 for process 2
(c) More heat can be converted to work in process 1 than in process 2
(d) More work can be converted to heat in process 1 than in process 2
31. Identify reagent (P) and write the structure of products (Q, R, S and T) in the following series of the
CHEM ACADEMY
reactions.
32. For the reaction
(a) what is the optical activity of the product ?

(b) draw the energy profile for the reaction
(c) wrtie the structure of the intermediate
(d) what is the effect of doubling the concentration of KOH in the rate of the products?
(e) If aqueous KOH is replaced by alcoholic KOH. Write the structure of the products formed.
33. (a) Suggest a method for the following transformation involving minimum number of steps
Indicate the reagents/reaction conditions required at each step clearly.

(b) A dipeptide on hydrolysis gives two amino acids (X) and (Y). If the dipeptide is first treated
with HNO2 and then hydrolysis is carried out, (X) and lactic acid are obtained. (X) on heating gives
2, 5-diketopiperazine as shown below. Identify (X) and (Y), and write their sequence in the dipeptide.
34. Identify the compounds A, B, C, D and E in the following reactions.
35. (a) Why do the boiling points of the following compounds vary in order,
H2O > H2Se > H2S?
36. CHEM ACADEMY

(b) Identify the products in the reaction of CCl4 and SiCl4 with water. Justify your answer.
(a) Write the steps involved in the production of pure elemental silicon from silica.
(b) Both the products A and B in the following reactions, contain boron and nitrogen. identify A and
B
C H Cl
6 5  A 
4 B LiAlH
3NH 4Cl  3BCl3 
heat THF
37. (a) Addition of potassium oxalate solution to a hot solution of potassium dichromate containing
dilute sulfuric acid leads to effervescence and formation of potassium trisoxalatochromate (III).
(i) Write the chemical formula of the chromium complex formed.
(ii) Write the balanced chemical formula for the formation of the complex.
(iii) Calculate the room temperature spin-only magnetic moment, in Bohr magnetons, of the complex.
(b) Write the structure of possible isomers of [CoCl2(en)2]Cl.
38. (a) Draw the unit cell of CsCl lattice. Draw the (100) and (110) places separately and indicate the
position of ceasium and chloride ions.
(b) The hydration enthalpies of divalent metal ions of ten elements from calcium to zinc are plotted
against their atomic numbers. Why do the hydration enthalpies of only three elements, Ca, Mn and
Zn fall on a straight line, whereas values for other metal ions deviate from this line?
39. (a) 5 grams of a protein was hydrolysed into amino acids, one of which is alanine. To this mixture,
0.1 gram of partially deutrated alanine, H2N-CH(CD3)-COOH, was added. After thorough mixing,
some of the alanine was separated and purified by crystallization. The crystalline alanine contains
0.652 weight percent of D. How many grams of alanine were originally present in 5 grams of
protein?
(b) What is the role of ammoniacal buffer in the volumetric titration of zinc sulphate against EDTA,
using Solochrome black (Eriochrome black T) indicator? Write the structure of Zn-EDTA anionic
complex.
40. (a) Calculate the pH of a solution obtained by mixing 50.00 mL of 0.20 M weak acid HA
(Ka = 10–5) and 50.00 mL of 0.20 M NaOH at room temperature.
(b) One mole of a salt of type MX is dissolved in 1.00 kg of water. The freezing point of the solution
is –2.4°C. Calculate the percent dissociation of the salt in water.
41.
CHEM ACADEMY
(a) The rate constant of the reaction ClO + NO  Cl + NO2 varies with temperature as :
T(K)
k(cm–3s–1 )
200
2.0 × 10–11
400
1.0 × 10–11
Determine the Arrhenius activation energy forthe reaction, assuming that the frequency factor does
not change in this temperature range.
(b) Ozone seems to be formed in the atmosphere through the photolysis of diatomic molecule :
k0
O2 
hv
 2O
k1
O  O 2   O3
k2
O3  O   2O 2
Applying steady-state approximation, determine the rate law for the formation of ozone. Show that
the formation of ozone follows first order kinetics when the concentration of O3 is extremely small.
42. (a) The reaction N 2  3H 2  2NH 3 is carried out at 300 K by mixing N2 and H2. The standard
free energy of formation of NH3 is –16.4 kJ/mol. After one hour of mixing, the partial pressures of
N2, H2 and NH3 are 50 bars, 2 bars and 200 bars, respectively. What is the reaction free energy at
this stage of the reaction?
(b) Plot schematically the concentration dependence of molar conductivity of a strong electrolyte
and a weak electrolyte in the same figure. The limiting ionic molar conductivities of K+ and Cl– are
73.5 and 76.5 S cm2 mol–1, respectively. If the molar conductivity of 0.1 M KCl solution is 130.0 S
cm2 mol–1, calculate the Kohlrausch’s constant for KCl solution.
43. (a) The electronic wavefunction () for hydrogen atom in the 2s state is given as
 r   r 
   2   exp   
 a0   2a 0 
Determine the most probable radial distance for the electron in this state and also the position of the
node (in terms of a0)
(b) Calculate the wavelength corresponding to the lowest energy excitation of an electron confined
to a one-dimensional box of length 1 nm. (Energy levels for a particle in a one dimensional box are
given by En = n2h2/8ma2).
44. (a) Solve the differential equation y´´ = 5y´ + 6y = 0 with the initial conditions y(0) = –1 and y´(0)
= 0. Here y´ and y´´ refer to the first and the second derivatives, respectively, of y with respect to x.
Verify your answer.
 
(b) For a particle with position r  2iˆ  3jˆ  kˆ and momentum p  î  2ˆj  2kˆ in m and kgmS–1,
respectively, calculate the magnitude of the angular momentum L = r × p.
CHEM ACADEMY
SOLUTION
OBJECTIVE QUESTIONS
1.
Correct option is (c)

2. Chemical transformation involved in above reaction can be illustrated as:

3.
CHEM ACADEMY
Chemical transformation involved in above reaction can be illustrated as:

4. Chemical transformation involved in above reaction can be illustrated as:
Correct option is (b)

5.
Correct option is (d)

6. Correct option is (a)
7. This reaction is an examples of Pinacol – Pinacolone rearrangement be shown stepwise as
Correct option is (a)
8.
CHEM ACADEMY
Resonance energy of conjugate base of I, II and III has order. I > III > II
Resonance energy is proportional to stability of compound (strong acid has stable conjugate base).
III is less aromatic than I due to annulation effect.
9. In the above reaction, 1, 4 addition of H-Br takes place such that formation of most stable alkene is
obtained in major extent.
10.
Each bridgehead C is a chiral centre. Camphor, with two different chiral carbon must be expected
to have 2n or four stereoisomers existing as two racemic forms but only only is known, becuase, the
bridge carbon stereocentre cannot be inverted.
11. Elements IE1
H 13.6 eV (non-metal)
Be 9.3 eV
B 8.29 eV
He 24.58 eV (inert gas)
Here He and Be has more IE than corresponding H and B due to the completly filled 1s and 2s
subshell.
MZ Z
12. Lattice energy 
r
CHEM ACADEMY
Where, M = Madelung constant
r = distance between cation and anion-center
So, depending upon charge and distance correct order is (b)
13. SF4 has not zero dipole moment due to its unsymmetrical see-saw structure.

14. According to Fajan’s rule, if cation is large and anion is small, then ionic character is higher. So,
correct order is represented by (d)
15. White phosphorous (P4)
Total Bonds = 6
16. Higher the charge on central metal ion, higher will be CFSE.
As we go down the group of metal ion CFSE increases.
17. For the given radioactive nuclide
t1/2 = 20 years, Initial activity (A0) = N0 = 6400 dis/min
t = 100 years, = 5t1/2 Final activity (At) = ?
Nt At 1
We have, N  A  n
0 0 2
100
Number of t1/2 'n '  5
20
A0 6400 6400
 At     200dpm
2n 25 32
18. In graphite all carbon are sp2 hybridized and 1-electron lies in p-orbital of all carbon atoms which
4
are delocalized such that there is partial double bond character, such that bond order is .
3
CHEM ACADEMY OR
Total bond
Bond order = Total no. of resonating structure =
4
3
2 2
19. CFSE    0   20300 = 8120 cm–1
5 5
20. As ZnS has higher solubility product than HgS, CuS and CdS, So H2S in acidic medium do not
provide enough S2– to precipitate ZnS.
21. At Pl, F (degree of freedom) = C – P + 2 = 1 – 1 + 2 = 2
At P2, F (degree of freedom) = C – P + 2 = 1 – 2 + 2 = 1
At P3 (triple point), F (degree of freedom) = C – P + 2 = 1 – 3 + 2 = 0
22. MX(s)  M  (aq)  X  (aq)
ksp = S × S,  S  k sp  S = 10–4 M
MY2 (S)  M 2 (aq)  2Y  (aq)
1/ 3
 k sp 
k sp 2
 S  (2S) ; S    ; S  103 M
 4 
MZ3 (S)  M 3 (aq)  3Z  (aq)
1/ 4
 k sp 
3
k sp  S  (3S) ;  S    ; S  102 M
 27 
23. From Van’t hoff equation
H
ln K  C; where C = constant
RT
For endothermic reaction, H = +ve
1 K 2 H  1 1 
 ln K vs graph slope is –ve and ln K  R  T  T 
T 1  1 2
For exothermic reaction, H = –ve,
So, if T2 > T1, then K2 < K1
24. K   e  K
E  Eº 
CHEM ACADEMY
0.0591
1
log 
1
(K )
0.0591 1
E1  Eº  log 2
1 10
0.0591 1
E 2  Eº  log 3
1 10
E  E 2  E1
0.0591 102
 log 3 = 0.0591 V
1 10
25. Only statement (a) is correct
Free energy decreases only in case of galvanic cells
In case of electrolytic cells, a non spontaneous redox takes place
1
26. CV = 25 J mol–1 K– = 3R = fR
2
 Degree of freedom (f) = 6
Which is only possible for any non-linear molecule (SO2). (Neglecting vibrational degree of freedom
as at room temperature)
1 i2 1 i2
27.  e and *  e
2 2
Since,  *  |  |2 = Probability density
1
Probability in interval ‘d’ =  * d  d
2
28. W = Z.I.t
63.5
nM   0.965  2000
1 96500
63.5 0.965  2000

n  = 0.02 moles
1 96500 63.5
29. Correct option is (b)
30.
CHEM ACADEMY
From Clausius inequality, ds 
dq
T
Here equality holds for reversible process,
q cycle q cycle
  ds 
T
; 0
T
; q cycle  0
cycle
So for reversible process, qcycle = 0 and for irreversible process, qcycle < 0.
31.
32. (i) Since in aqueous medium reaction proceeds through SN1 mechanism. Therefore, product is
optically inactive and racemic mixture will be formed.
(ii)
(iii) 3º carbocation intermediate
(iv) Since reaction proceeds through SN1 mechanism. Therefore, rate of reaction will remain
CHEM ACADEMY
unaffected, w.r.t. to change in KOH concentration,
(b) In presence of alcoholic KOH reaction will undergo elimination reaction.
33. (a) Chemical transformation involved in above chemical reaction can be illustrated as
34.
35. (a) Higher the force of interaction between molecules, higher the energy (or temperature) will be
required to boil the molecule.
H2O contains intermolecular H-bonding but H2S and H2Se have vander waals force of interaction.
As H-bond strength > vander waals force of interaction.
 H2O has highest b.p. (H2O is liq. at room temperature)
But vander waals force  molecular wt.
M H2Se  M H 2S
 H2Se will have higher b.p. than H2S (both are gas at room temperature)
So, The b.p. order is,
H2O > H2Se > H2S
(b) CCl4 + H2O 
 No reaction
CHEM ACADEMY
SiCl4  4H 2O  Si(OH)4  4HCl (fast)
CCl4 is inert towards its reaction with H2O, because carbon is unable to expand its valency due to
lack of d-orbital in 2nd period.
But SiCl4 is extremely reactive with H2O, because Si can expand its octed/valency due to presence
of 3d orbital as shown below.
Due to smaller size of carbon and four chlorine group crowdly attached on carbon atom. So, hydroxyl
group cann’t group on carbon centre in SN2 manner.
36. (a) Production of elemental silicon from silica involves these steps:
(i) Reducing SiO2 with high purity coke
SiO2  2C  Si  2CO
(ii) Converting Si to SiCl4 and purifying this SiCl4 by distillation,
Si + 2Cl2  SiCl4
(iii) Reduction of SiCl4 by Mg or Zn.
SiCl4  2Mg  Si  MgCl2
SiCl4  2Zn  Si  ZnCl2
Ultra pure Si can be made from above obtained Si via Zone refining.
(b)
CHEM ACADEMY
37. (a) (i) Chromium complex  K3[Cr(Ox)3]
where Ox  C2O42–
(ii) K 2Cr2O7  9K 2C 2O 4  7H 2SO 4  2K 3[Cr(C2O 4 )3 ]  6CO 2  7K 2SO 4  7H 2O
(ii) In complex, K3[Cr(Ox)3], Cr+3 has 3d3 electrons in its t2g orbital.
Number of unpaired electron (n) = 3
Spin only magnetic moment (s )  n(n  2) B.M.  3  5 B.M.  15 B.M.
(b) [CoCl2(en)2]Cl
38. (a)
(b) Hydration of metal ions (M+2) produces an enthalpy change that is commensurate with the size,
charge of the ion and crystal field stabilisation energy (CFSE).
So, Hhydration shows non-linear variation if C.F.S.E.  0. If CFSE = 0 (i.e. for Ca, Mn and Zn
which has d0, d5 and d10 configuration respectively), then it lies on the straight line.
CHEM ACADEMY
39. (a) Let x gm of alanine is present in 5 gm of protein.
3
wt. of ‘D’ in 0.1 gm of deuterated alanine =  0.1g
92
wt. of D
A/q, wt % of D in alanine =  100
x  0.1
3
 0.1100
 0.652  92 ; x  0.4 gm
x  0.1
(b) Ammonical buffer maintains the pH such that the solution remains basic enough to deprotonate
all the 4-carboxylic hydrogens of EDTA, so that it can bind effectively to Zn+2.
Structure of [Zn EDTA]2– complex:
40. (a) HA + NaOH 

 Na+A– + H2O
(50 ml of 0.2 M) (50 ml of 0.2 M) 100 ml of 0.1 M Na+ A–
Now this weak acid salt will undergo hydrolysis.
CHEM ACADEMY
A   H 2O  HA  OH 
1 1
We have, pH  7  pK a  log c [C = concentration acid of weak salt]
2 2
1 1
 pH  7  (  log105 )  log 0.1
2 2
5 1
 pH  7  
2 2
 pH  9.0
(b) Given, kf  1.8º C / m
1
molality (m) =  1m
1
Tf  0  (2.4)  2.4º C
We have, Tf = imkf
 2.4 = i × 1.8 × 1  i  1.33

MX  Mn+ + Xn–
t=0 1 0 0
at eq. 1 –   
 i = (1 – ) +  +  = 1.5   = 0.50 = 50% dissociation
41. (a) We have
k 2 Ea  1 1 
ln     ... (1)
k1 R  T1 T2 
Where k2 and k1 are rate constant for the reaction at temperature T1(K) and T2(K) respectively.
Give, k2 = 1.0 × 10–11 and k1 = 2.0 × 10–11
T2 = 400 K and T1 = 200 K
So from equation (1),
1 Ea  1 1 
ln  
2 8.314  200 400 

 Ea  ( ln 2)8.314  400 J / mole  0.693  8.314  400 J / mole  2304.6 J / mole

= –2.304 kJ/mole
(b) For the reaction
0 k
O 2  2O
kv
1 O k
O  O 2  3
2 k
O3  O  2O 2
d[O3 ]
 k1[O][O 2 ]  k 2 [O3 ][O]
dt
CHEM ACADEMY
As ‘O’ is an intermediate, So, applying S.S.A on ‘O’.
d[O]
 0
dt
 2k0[O2] – k1[O][O2] – k2[O3][O] = 0
2k 0 [O 2 ]
 [O]  ... (2)
k1[O 2 ]  k 2 [O3 ]
Substituting [O] from equation (2) in equation (1),
d[O3 ] 2k 0 [O 2 ]
  (k1[O2 ]  k 2 [O3 ])
dt k1[O 2 ]  k 2 [O3 ]
When [O3] is extremely small, then [O3]  0
Then k1[O 2 ]  k 2 [O3 ]  k1[O 2 ] and k1[O 2 ]  k 2 [O3 ]  k1[O 2 ]
d[O3 ] k1[O 2 ]
  .2k 0 [O 2 ]
dt k1[O 2 ]
d[O3 ]
Rate of formation of O3   2k 0 [O 2 ]
dt
First order w.r.t. O2.
42. (a) N 2  3H 2  2NH 3 T = 300 K
G 0f  16.4kJ / mole
After 1 hr of mixig PN 2  50 bars
PH 2 = 2 bars and PNH3 = 200 bars

At constant temperature T, G for the above reaction can be written as,
 P 2 

  NH3  
  P0  
G  Gº  RT ln  3 0
  PN 2  PH 2   (where P = 1 barr)
  0  0  
  P  P  
 (200) 2 
 16.4  103  8.31 300 ln  3
 (50)(2) 
= –16400 + 8.31 × 300 × 2.303 log [100] = –16400 + 8.31 × 300 × 2.303 log 2
= –14672.3 J/mole = 14.67 × 103 J/mole = –14.67 kJ mole
CHEM ACADEMY
(b)
Kohlrausch law for variation of  with concentration (c).
  0  K c
Where  0 = molar conductivity at infinite dilution
K = Kohlrausch’s constant.
 0 (KCl)   0    0
k Cl
0  (73.5  76.5) S cm2 mol–1 = 150.0 S cm2 mol–1

mole
Given,  = 130.0 S cm2 mol–1; c = 0.1 M = 0.1 mole / 1000 cm3 = 10–4
cm3
 From equation (1), 130 = 150 – K 10 4
20 Scm 2 mol1
 K 2
  K = 2000 S cm7/2 (mol)–3/2
10 mol1/ 2cm 3/ 2
r
 r   2a 0
43. (a)   2  e
 a0 
r
 r  
   A  2   e 2a 0 , where A is proportionality constant.
 a0 
As  is function of ‘r’ only, so probability of finding electron at distance ‘r’ is given by
2 r
r   2 2
P(r) |  | 4r ; P(r)  4A r  2   e 2a 0
2 2
 a0 
dP(r)  d 2 P(r) 
0
For probability to be maximum, dr  = 0 and dr 
r  rmp  r r mp
dP(r)
 0
dr
2r 2 2
   r   1  2 r   1  2  r  
2 a0  2r  2    2    r  2       r  2     0
 4A e
  a0   a0   a0   a0   a0  
 
2r

2 a0  r   r  2r r  r 
 4A e r  2    2  2      2    0
CHEM ACADEMY  a0   
2r
a 0  a0 a0 
 r 2 6r
a 0 
 r   
 8r  2   e a 0  2   4  0
 a0   a 0 a 0 
 r  0, 2a 0 , (3  5)a 0 , (3  5)a 0
But r cannot be ‘0’ and  because at nucleus and at infinite distance P(r) = 0
   
r  2a 0 , 3  5 a 0 , 3  5 a 0 
d 2 (P(r)) 
 0
For P(r) to be maximum at any of the above values it must satisfy, dr 
r  rmp
d 2 (P(r)) 
 0
 dr   at r = 2a0; P(r) will be minimum
r  2a 0
d 2 P(r) 
 0
dr  ,  Maximum
r (3 5)a 0
d 2 P(r) 
 0
and dr   maximum
r (3 5)a 0
   
rmp  3  5 a 0 and 3  5 a 0 
r
 r  a
For node,   0 ; A2  e 0  0
 a0 
Only possible solution, r  2a 0  r(node)  2a 0
(b) Let  be the wavelength of wave required to exite electron from ground state to 1st exited state.
 E  E 2  E1
hc 22 h 2 12.h 2 hc 3h 2
   ; 
 8me L2 8me L2  8m e L2
8me L2c 8  9.11031  (109 ) 2  3 108
44.

CHEM ACADEMY

(a) Given
3h

3  6.625 1034
y´´ – 5y´ + 6y = 0;
m = 1.098 × 10–8 m = 0.11 nm
y(0) = –1 and y´(0) = 0

d2y dy
 2
5  6y  0
dx dx
d2 y dy
Integrating w.r.t.x.,  dx 2 dx  5 dx dx  6y dx  0
dy
  5y  6xy  c1 ; (where c1 = constant of integration) ... (1)
dx
As, y´(0)  0 and y(0) = –1
from equation (1)
0 –5 (–1) + 0 = c1  c1 = 5
From equation (1),
dy
  5y  6xy  5
dx
Again integrating w.r.t. x we get,
x2
y – 5xy + 6y = 5x + c2 ... (2)
2
(where c2 = constant of integration)
As, y´(0) = 0 and y(0) = – 1
From equation (2), y – 5xy + 3x2y = 5x –1
 3x 2 y  5xy  y  5x  1  0
Verification, 3x 2 y  5xy  y  5x  1  0 ... (1)

When, x = 0
0–0+y–0+1=0  y  1
And From equation (1), y(3x2 – 5x + 1) – 5x + 1 = 0

dy
Differentiating w.r.t. ‘x’, (3x2 – 5x + 1) + y(6x – 5) – 5 = 0
dx
dy
at x = 0, y = –1;  0 ; y '(0)  0
dx
 equation (1) is the solution of differential equation.
   
(b) r  2iˆ  3jˆ  kˆ and p  î  2ˆj  2kˆ ; L  r  P
i j k

 CHEM ACADEMY
L  2 3 1
1 2 2
 
ˆ  3) ; L  4iˆ  5jˆ  7kˆ
; L  î(6  2)  ˆj( 4  1)  k(4
 2 –1
 | L | 4 2  52  7 2  90 = 9.48 k gm s

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CHEM ACADEMY 1 IIT-JAM 2006

(a) X = R, Y = S (b) X = R, Y = R (c) X = S, Y = R (d) X = S; Y = S

2 5 C H ONa (i) OH

The product (Y) is

4. The major product (X) in the reaction

(a) (b) (c) (d)

5. The product of the reaction

gives positive test with Fehling’s solution. The product is

(a) (b) (c) (d)

7. The major product of the reaction

(a) (b) (c) (d)

(a) Four (b) Two (c) Three (d) One

magnitude of crystal field stabilization energy in cm–1 is

24. CHEM ACADEMY

32. For the reaction

(a) what is the optical activity of the product ?

Indicate the reagents/reaction conditions required at each step clearly.

34. Identify the compounds A, B, C, D and E in the following reactions.

36. CHEM ACADEMY

Correct option is (c)

Correct option is (c)

Correct option is (c)

Correct option is (b)

Correct option is (d)

Correct option is (a)

Correct option is (c)

Correct option is (c)

MY2 (S)  M 2 (aq)  2Y  (aq)

63.5 0.965  2000

(iii) 3º carbocation intermediate

39. (a) Let x gm of alanine is present in 5 gm of protein.

Structure of [Zn EDTA]2– complex:

40. (a) HA + NaOH 

 2.4 = i × 1.8 × 1  i  1.33

 Ea  ( ln 2)8.314  400 J / mole  0.693  8.314  400 J / mole  2304.6 J / mole

After 1 hr of mixig PN 2  50 bars

PH 2 = 2 bars and PNH3 = 200 bars

Kohlrausch law for variation of  with concentration (c).

0  (73.5  76.5) S cm2 mol–1 = 150.0 S cm2 mol–1

Only possible solution, r  2a 0  r(node)  2a 0

8me L2c 8  9.11031  (109 ) 2  3 108

y(0) = –1 and y´(0) = 0

Verification, 3x 2 y  5xy  y  5x  1  0 ... (1)

And From equation (1), y(3x2 – 5x + 1) – 5x + 1 = 0

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