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 Use the table below to answer the questions that follow.

Chapter 6

Entropy, Free Gibbs

Energy

General Chemistry-Problem 2

2) The combustion of acetylene in the presence of excess 8) The combustion of ethene in the presence of excess
oxygen yields carbon dioxide and water: oxygen yields carbon dioxide and water:
2C2 H 2 (g) 5O 2 4CO 2 (g) 2H 2O(l) C2 H 4 (g) 3O 2 (g) 2CO 2 (g) 2H 2O(l)

The value of S0 for this reaction is __________ J/K∙ mol. The value of ΔS° for this reaction is __________ J/K∙ mol.
A) +689.3 A) -267.4
B) +122.3 B) -140.9
C) +432.4 C) -347.6
D) -122.3 D) +347.6
E) -432.4 E) +140.9

General Chemistry-Problem 3 General Chemistry-Problem 4

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41) The value of G0 at 373 K for the oxidation of solid 45. Consider the reaction:
elemental sulfur to gaseous sulfur dioxide,
NH3 (g) HCl(g) NH 4 Cl(s)
S(s,rhombic) O 2 (g) SO 2 (g) Given the following table of thermodynamic data at 298 K:
The value of K for the reaction at 25oC is __________.
is __________ kJ/mol. At 298 K, H0 for this reaction is - A) 150
269.9 kJ/mol, and S0 is +11.6 J/(mol.K).
B) 9.2 1015
C) 8.4 104
A) -300.4 16
D) 1.1 10
B) +300.4 8
E) 1.4 10
C) -4,597
D) +4,597
E) -274.2

General Chemistry-Problem 5 General Chemistry-Problem 6

7) The thermodynamic quantity that expresses the degree

of disorder in a system is __________.
1) The first law of thermodynamics can be given as
__________.
A) enthalpy
A) ΔE = q + w B) internal energy
B) H rxn n H (products)
f
m H (reactants)
f
C) bond energy
C) for any spontaneous process, the entropy of the D) entropy
universe increases E) heat flow
D) the entropy of a pure crystalline substance at absolute
zero is zero
E) S = qrev/T at constant temperature

General Chemistry-Problem 7 General Chemistry-Problem 8

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8) For an isothermal process, ΔS = __________. 11) The second law of thermodynamics states that
__________.
A) q
B) qrev/T A) ΔE = q + w
C) qrev B) ΔH°rxn = Σ nΔH°f (products) - Σ mΔH°f (reactants)
D) Tqrev C) for any spontaneous process, the entropy of the
E) q + w universe increases
D) the entropy of a pure crystalline substance is zero at
absolute zero
E) ΔS = qrev/T at constant temperature

General Chemistry-Problem 9 General Chemistry-Problem 10

12) The normal boiling point of water is 100.0 °C and its 16) Entropy is positive for the reaction __________.
molar enthalpy of vaporization is 40.67 kJ/mol. What is
the change in entropy in the system in J/K when 39.3 A) 2H 2 (g) O2 (g) 2H 2O(g)
grams of steam at 1 atm condenses to a liquid at the
normal boiling point? B) 2NO 2 (g) N 2 O 4 (g)
C) CO2 (g) CO 2 (s)
A) 88.8 D) BaF2 (s) Ba 2+ (aq) 2F (aq)
B) -88.8 E) 2Hg(l) O 2 (g) 2HgO(s)
C) -238
D) 373
E) -40.7

General Chemistry-Problem 11 General Chemistry-Problem 12

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17) Which one of the following processes produces a 18) S is positive for the reaction __________.
decrease in the entropy of the system?
A) CaO(s) CO 2 (g) CaCO3 (s)
A) boiling water to form steam B) N 2 (g) 3H 2 (g) 2NH 3 (g)
B) dissolution of solid KCl in water C) 2SO3 (g) 2SO 2 (g) O 2 (g)
C) mixing of two gases into one container D) Ag (aq) Cl (aq) AgCl(s)
D) freezing water to form ice E) H 2 O(l) H 2 O(s)
E) melting ice to form water

General Chemistry-Problem 13 General Chemistry-Problem 14

20) Which reaction produces an increase in the entropy of 21) Which one of the following processes produces a
the system? decrease of the entropy of the system?

A) Ag (aq) Cl (aq) AgCl(s) A) dissolving sodium chloride in water

B) CO 2 (s) CO 2 (g) B) sublimation of naphthalene
C) H 2 (g) Cl2 (g) 2HCl(g) C) dissolving oxygen in water
D) N 2 (g) 3H 2 (g) 2NH 3 (g) D) boiling of alcohol
E) H 2 O(l) H 2 O(s)

General Chemistry-Problem 15 General Chemistry-Problem 16

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15. For the reaction

28) Of the following, the entropy of __________ is the C(s) H 2 O(g) CO(g) H 2 (g)
largest. H 131.3 kJ / mol and S 133.6 J / Kmol at 298 K. At
temperatures greater than __________°C this reaction is
A) HCl (l) spontaneous under standard conditions.
B) HCl (s)
C) HCl (g) A) 273
D) HBr (g) B) 325
E) HI (g) C) 552
D) 710
E) 983

General Chemistry-Problem 17 General Chemistry-Problem 18

36) For the reaction 44) With thermodynamics, one cannot determine
__________.
C 2 H 6 (g) C 2 H 4 (g) H 2 (g)

H is 137 kJ / mol and S is 120 J / Kmol . This reaction A) the speed of a reaction
is __________. B) the direction of a spontaneous reaction
C) the extent of a reaction
A) spontaneous at all temperatures D) the value of the equilibrium constant
B) spontaneous only at high temperature E) the temperature at which a reaction will be spontaneous
C) spontaneous only at low temperature
D) nonspontaneous at all temperatures

General Chemistry-Problem 19 General Chemistry-Problem 20

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45) If for a reaction is greater than zero, then __________. 5) For a given reaction, H 35.5kJ / mol and S 83.6J / K mol
. The reaction is spontaneous __________. Assume that
A) K = 0 ΔH and ΔS do not vary with temperature.
B) K = 1
C) K > 1 A) at T < 425 K
D) K < 1 B) at T > 425 K
E) More information is needed. C) at all temperatures
D) at T > 298 K
E) at T < 298 K

General Chemistry-Problem 21 General Chemistry-Problem 22