Problems

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Problems

Q1/ You are designing a spherical tank to hold water for a small village in a
developing country. The volume of liquid it can hold, can be computed as
(𝟑𝑹 − 𝒉)
𝑽 = 𝝅 𝒉𝟐
𝟑
3
Where V = volume (m ), h = depth of water in tank (m), and R = the tank radius
(m). If R = 3 m, to what depth must the tank be filled so what it holds 30 m 3 ?
Determine the approximate relative error after each iteration? Solve the problem
using:-
1- Bi-section method.
2- Newton’s Raphson method.
3- Fixed point method.
4- False position method.
5- Secant method.

Q2/ A mass balance for a pollutant in a well-mixed lake can be written as


𝒅𝒄
𝑽 = 𝑾 − 𝑸𝒄 − 𝒌𝑽 √𝒄
𝒅𝒕
Given the parameter values V = 1*106 m3, Q = 1*105 m3/yr, W = 1*106 g/yr, and k
= 0.25 m0.5/g0.5/yr, Employ an initial guess of c = 4 g/m3, Solve for the steady state
concentration using:-
1- Bi-section method.
2- Newton’s Raphson method.
3- Fixed point method.
4- False position method.
5- Secant method.
Perform three iterations and determine the percent relative error after each
iteration?

Q3/ Solve the following equation using direct method

𝒇(𝒙) = 𝟎. 𝟕 𝒙𝟓 − 𝟖𝒙𝟒 + 𝟒𝟒𝒙𝟑 − 𝟗𝟎𝒙𝟐 + 𝟖𝟐𝒙 − 𝟐𝟓

Determine the percent relative error after each iteration?

1
Q4/ Solve the following equation using direct method

𝒇(𝒙) = 𝟐𝟓𝒙𝟑 − 𝟔𝒙𝟐 + 𝟕𝒙 − 𝟖𝟖

Determine the percent relative error after each iteration?

Q5/ A chemical engineering design project requires that you accurately estimate
the molar volume (v) of carbon dioxide at T = 300 K and P = 1 atm so the
appropriate containment vessel can be selected. The molar volume of the gas can
be estimated from the following equation of state
𝒂
( 𝑷 + 𝟐 ) (𝒗 − 𝒃) = 𝑹𝑻
𝒗
It is also interest to examine how well the gas conforms to the ideal gas law. Use
the following data:-
R = 0.082054 L.atm /(mol.K), a = 3.592 atm.L2/mol2 , b = 0.04267 L/mol.

Q6/ In chemical engineering, plug flow reactors are often used to convert
reactants into products. It has been determined that the efficiency of the conversion
can sometimes be improved by recycling a portion of the product stream so that it
returns to the entrance for an additional pass through the reactor. The recycling
rate is defined as
𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒇𝒍𝒖𝒊𝒅 𝒓𝒆𝒕𝒖𝒓𝒏𝒆𝒅 𝒕𝒐 𝒆𝒏𝒕𝒓𝒂𝒏𝒄𝒆
𝑹=
𝒗𝒐𝒍𝒖𝒎𝒆 𝒍𝒆𝒂𝒗𝒊𝒏𝒈 𝒕𝒉𝒆 𝒔𝒚𝒔𝒕𝒆𝒎
Suppose that we are processing a chemical A to generate a product B. For this
case, it can be shown that an optimal recycle rate must satisfy
𝟏 + 𝑹 (𝟏 − 𝒙𝑨𝒇 ) 𝑹+𝟏
𝐥𝐧 =
𝑹 (𝟏 − 𝒙𝑨𝒇 ) 𝑹 (𝟏 + 𝑹 (𝟏 − 𝒙 ))𝑨𝒇
Where xAf = the fraction of reactant A that is converted to product B. R the optimal
recycle rate corresponding to the minimum sized reactor needed to attain the
desired level of conversion. Determined the recycle ratio needed for xAf = 0.95.

Q7/ Of the following three sets of linear equations, identify the set(s) that you
could not solve using an iterative method. Show that using any number of
iterations that is necessary.

2
Set one Set two Set three
9𝑥 + 3𝑦 + 𝑧 = 13 𝑥 + 𝑦 + 6𝑧 = 8 −3𝑥 + 4𝑦 + 5𝑧 = 6
−6𝑥 + 8𝑧 = 2 𝑥 + 5𝑦 − 𝑧 = 5 −2𝑥 + 2𝑦 − 3𝑧 = −3
2𝑥 + 5𝑦 − 𝑧 = 6 4𝑥 + 2𝑦 − 2𝑧 = 4 2𝑦 − 𝑧 = 1

Q8/ The following figure show three reactors linked by pipes. If the system is at
steady state, the transfer into each reactor will balance the transfer out. Develop
mass balance equations for the reactors and solve the three simultaneous linear
algebraic equations for their concentrations.

500 mg/s Q13 Q33

1 3

Q12
Q23
Q21 200 mg/s Q33 = 120
Q13 = 40
2 Q12 = 90
Q23 = 60
Q21 = 30

Q9/ The heat duty of shell and tube heat exchanger is given by
∆𝑻𝟐 − ∆𝑻𝟏
𝒒=𝑼𝑨
∆𝑻
𝐥𝐧 ( 𝟐 )
∆𝑻𝟏
𝒒 𝒒
∆𝑻𝟏 = 𝑻𝟏 − 𝒕𝟏 − ( . 𝑪𝒑𝟏 ) ∆𝑻𝟐 = 𝑻𝟐 − 𝒕𝟐 − ( . 𝑪𝒑𝟐 )
𝑴𝟏 𝑴𝟐

Given the following data


M1 = 43800, M2 = 149000, Cp1 = 0.605, Cp2 = 0.490, U = 55, A = 662, T1 = 390,
t1 = 100. Calculate the heat duty using an iteration method?

Q10/ a mass balance equation for a CSTR has the form


𝟐𝒙 (𝟎. 𝟓 + 𝒙)
𝟏−𝒙=
𝟏 + 𝟐𝒙 (𝟎. 𝟓 + 𝒙)

Calculate the conversion of the reaction using an iteration method?

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