Molyklenz - English SDS - I24feb2017

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SAFETY DATA SHEET

1. Identification
Product identifier Molyklenz
Other means of identification None
Recommended use Industrial Water Treatment
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Klenzoid Canada Inc.
Address 245 Matheson Blvd East
Units 1- 4
Mississauga, ON L4Z 3C9
Canada
Telephone 1-905-712-4000
Website www.klenzoid.com
e-mail Not available.
Emergency phone number 1-613-996-6666 (CANUTEC)
Supplier See above.

2. Hazard identification
Physical hazards Corrosive to metals Category 1
Health hazards Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Reproductive toxicity Category 1B
Environmental hazards Not classified.

Label elements

Signal word Danger


Hazard statement May be corrosive to metals.
Causes severe skin burns and eye damage.
May damage fertility or the unborn child.
Precautionary statement
Prevention Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep only in original packaging.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
Response Absorb spillage to prevent material-damage.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER/doctor. Wash contaminated clothing before reuse. Specific
treatment (see information on this label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
IF INHALED: remove person to fresh air and keep comfortable for breathing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Storage Store in a corrosion resistant container with a resistant inner liner.
Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards None known.
Supplemental information None

3. Composition/information on ingredients
Mixtures

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Chemical name Common name and synonyms CAS number %
Sodium molybdate 7631-95-0 1-5
Potassium hydroxide 1310-58-3 0.5 - 1.5
Sodium borate 1330-43-4 0.5 - 1.5
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures
Inhalation IF INHALED: remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
Skin contact IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER/doctor. Wash contaminated clothing before reuse.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON
CENTER/doctor.
Most important Burning pain and severe corrosive skin damage.
symptoms/effects, acute and Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
delayed blurred vision. Permanent eye damage including blindness could result.
Indication of immediate Symptoms may be delayed.
medical attention and special
treatment needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance. Avoid contact with eyes and skin. Wear rubber gloves and chemical splash goggles.
Keep out of reach of children.

5. Fire-fighting measures
Suitable extinguishing media Treat for surrounding material.
Unsuitable extinguishing Not available.
media
Specific hazards arising from Not available.
the chemical
Hazardous combustion May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of boron. Oxides
products of molybdenum.
Special protective equipment Firefighters should wear full protective clothing including self contained breathing apparatus.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate protective clothing. Do not
emergency procedures breathe mist or vapour. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8.
Methods and materials for Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Cover with
containment and cleaning up plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth
to soak up the product and place into a container for later disposal. Never return spills in original
containers for re-use. Following product recovery, flush area with water. Clean surface thoroughly
to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry
into waterways, sewers, basements or confined areas.
Environmental precautions Do not discharge into lakes, streams, ponds or public waters.

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7. Handling and storage
Precautions for safe handling Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not get in eyes, on skin, or on clothing.
Do not breathe mist or vapour.
Use only with adequate ventilation.
Pregnant or breastfeeding women must not handle this product.
Avoid prolonged exposure.
Observe good industrial hygiene practices.
Wash thoroughly after handling.
When using do not eat or drink.
Conditions for safe storage, Store in a cool, dry place out of direct sunlight.
including any incompatibilities Store in corrosive resistant container with a resistant inner liner.
Store away from incompatible materials (see Section 10 of the SDS).
Keep out of reach of children.
Store locked up.

8. Exposure controls/Personal protection


Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value Form
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Sodium borate (CAS 1330- STEL 6 mg/m3 Inhalable fraction.
43-4)
TWA 2 mg/m3 Inhalable fraction.
Sodium molybdate (CAS TWA 0.5 mg/m3 Respirable fraction.
7631-95-0)
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Components Type Value Form
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Sodium borate (CAS 1330- STEL 3 ppm
43-4)
TWA 1 mg/m3
Sodium molybdate (CAS TWA 0.5 mg/m3 Respirable.
7631-95-0)
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Components Type Value Form
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Sodium borate (CAS 1330- STEL 6 mg/m3 Inhalable
43-4)
TWA 2 mg/m3 Inhalable
Sodium molybdate (CAS TWA 0.5 mg/m3 Respirable.
7631-95-0)
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Components Type Value Form
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Sodium borate (CAS 1330- STEL 6 mg/m3 Inhalable fraction.
43-4)
TWA 2 mg/m3 Inhalable fraction.
Sodium molybdate (CAS TWA 0.5 mg/m3 Respirable fraction.
7631-95-0)
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components Type Value Form
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)

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Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components Type Value Form
Sodium borate (CAS STEL 6 mg/m3 Inhalable fraction.
1330-43-4)
TWA 2 mg/m3 Inhalable fraction.
Sodium molybdate (CAS TWA 0.5 mg/m3 Respirable fraction.
7631-95-0)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Sodium borate (CAS 1330- TWA 1 mg/m3
43-4)
Sodium molybdate (CAS TWA 5 mg/m3
7631-95-0)
Canada. Saskatchewan OELs (Occupational Health and Safety Regulations, 1996, Table 21)
Components Type Value
Potassium hydroxide (CAS Ceiling 2 mg/m3
1310-58-3)
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines See above
Appropriate engineering Ensure adequate ventilation.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Wear chemical goggles.
Skin protection
Hand protection Rubber gloves. Confirm with a reputable supplier first.
Other As required by employer code.
Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respirator should be selected by and used under the direction of a trained health and safety
professional following requirements found in OSHA's respirator standard (29 CFR 1910.134),
CAN/CSA-Z94.4 and ANSI's standard for respiratory protection (Z88.2).
Thermal hazards Not applicable.
General hygiene Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
considerations and immediately after handling the product. When using do not eat or drink.

9. Physical and chemical properties


Appearance Liquid
Physical state Liquid.
Form Liquid
Colour Clear colourless
Odour Characteristic
Odour threshold Not available.
pH 12.2 (100%)
Melting point/freezing point Not available.
Initial boiling point and boiling 110 °C (230 °F)
range
Flash point Not available.
Evaporation Rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit – upper Not available.
(%)

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Vapour pressure Not available.
Vapour density Not available.
Relative density Not available.
Solubility(ies)
Solubility (Water) Complete
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Water thin
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidising.
Specific gravity 1.05

10. Stability and reactivity


Reactivity May react with incompatible materials.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous Hazardous polymerisation does not occur.
reactions
Conditions to avoid Do not mix with other chemicals.
Incompatible materials Acids. Oxidising agents. Soft metals.
Hazardous decomposition May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of boron. Oxides
products of molybdenum.

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion May cause stomach distress, nausea or vomiting.
Symptoms related to the Burning pain and severe corrosive skin damage.
physical, chemical and Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
toxicological characteristics blurred vision. Permanent eye damage including blindness could result.
Information on toxicological effects
Acute toxicity
Components Species Test results
Potassium hydroxide (CAS 1310-58-3)
Acute
Inhalation
LC50 Not available
Oral
LD50 Rat 388 mg/kg, ECHA
365 mg/kg, ECHA
333 mg/kg, ECHA
273 mg/kg
Sodium borate (CAS 1330-43-4)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rat > 2 mg/L, 4 Hours
> 2 mg/L, 5 Hours
Oral
LD50 Dog 2000 mg/kg

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Components Species Test results
Mouse 3450 mg/kg
1060 mg/kg
Rat > 250 mg/kg
2403 mg/kg
Sodium molybdate (CAS 7631-95-0)
Acute
Dermal
LD50 Not available
Inhalation
LC50 Rat > 5.1 mg/l/4h
Oral
LD50 Rat 4000 mg/kg
Skin corrosion/irritation Causes severe skin burns and eye damage.
Exposure minutes Not available.
Erythema value Not available.
Oedema value Not available.
Serious eye damage/eye Causes serious eye damage.
irritation
Corneal opacity value Not available.
Iris lesion value Not available.
Conjunctival reddening Not available.
value
Conjunctival oedema value Not available.
Recover days Not available.
Respiratory or skin sensitisation
Canada - Alberta OELs: Irritant
Potassium hydroxide (CAS 1310-58-3) Irritant
Sodium borate (CAS 1330-43-4) Irritant
Sodium molybdate (CAS 7631-95-0) Irritant
Respiratory sensitisation Not a respiratory sensitizer.
Skin sensitisation This product is not expected to cause skin sensitisation.
Germ cell mutagenicity Not classified.
Carcinogenicity See below.
ACGIH Carcinogens
Sodium borate (CAS 1330-43-4) A4 Not classifiable as a human carcinogen.
Sodium molybdate (CAS 7631-95-0) A3 Confirmed animal carcinogen with unknown relevance to
humans.
Canada - Manitoba OELs: carcinogenicity
BORATE COMPOUNDS, INORGANIC, INHALABLE Not classifiable as a human carcinogen.
FRACTION (CAS 1330-43-4)
MOLYBDENUM, SOLUBLE COMPOUNDS, AS MO, Confirmed animal carcinogen with unknown relevance to humans.
RESPIRABLE FRACTION (CAS 7631-95-0)
Reproductive toxicity May damage fertility or the unborn child.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful. Animals on high dietary levels of molybdenum showed
anemia and deformities of the joints.
Further information Not available.

12. Ecological information


Ecotoxicity See below

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Ecotoxicological data
Components Species Test results
Potassium hydroxide (CAS 1310-58-3)
Aquatic
Fish LC50 Western mosquitofish (Gambusia affinis) 80 mg/L, 96 hours
Sodium borate (CAS 1330-43-4)
Aquatic
Fish LC50 Western mosquitofish (Gambusia affinis) 104 mg/L, 96 hours
Sodium molybdate (CAS 7631-95-0)
Aquatic
Crustacea EC50 Tubificid worm (Tubifex tubifex) 42.48 - 65.64 mg/L, 48 hours
Fish LC50 Striped bass (Morone saxatilis) > 79.8 mg/L, 96 hours
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Mobility in general Not available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Empty containers or liners may retain some product residues. This material and its container must
products be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


General Canada: TDG Proof of Classification: In accordance with Part 2.2.1 (SOR/2014-152) of the
Transportation of Dangerous Goods Regulations, we certify that the classification of this product
is correct as of the SDS date of issue. If applicable, the technical name and the classification of
the product will appear below.
Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
UN number UN3266
Proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
Technical name Potassium hydroxide
Hazard class 8
Packing group II
Special provisions 16
TDG

15. Regulatory information


Canadian federal regulations This product has been classified in accordance with the hazard criteria of the HPR and the SDS
contains all the information required by the HPR.
Export Control List (CEPA 1999, Schedule 3)
Not listed.

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Greenhouse Gases
Not listed.
Precursor Control Regulations
Not regulated.
WHMIS status Controlled
International regulations

Inventory Status
Country(s) or region Inventory Name On Inventory (Yes/No)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

16. Other information

LEGEND HEALTH * 3
0
Severe 4 FLAMMABILITY 0
Serious 3 3 0
Moderate 2 PHYSICAL HAZARD 0
Slight 1 PERSONAL
Minimal 0 X
PROTECTION

Issue date 24-February-2017


Revision date 24-February-2017
Version # 02
Other information For an updated SDS, please contact the supplier/manufacturer listed on the first page of the
document.
Disclaimer Information contained herein was obtained from sources considered technically accurate and
reliable. While every effort has been made to ensure full disclosure of product hazards, in some
cases data is not available and is so stated. Since conditions of actual product use are beyond
control of the supplier, it is assumed that users of this material have been fully trained according to
the requirements of all applicable legislation and regulatory instruments. No warranty, expressed
or implied, is made and supplier will not be liable for any losses, injuries or consequential damages
which may result from the use of or reliance on any information contained in this document.
Prepared by Dell Tech Laboratories Ltd. Phone: (519) 858-5021

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