JEE MAINS MODEL PRACTICE TEST

JR. PART TEST-2

(KEY SHEET)

PHYSICS

01) 2 02) 3 03) 1 04) 2 05) 1

06) 3 07) 4 08) 3 09) 1 10) 2

11) 1 12) 4 13) 1 14) 1 15) 2

16) 4 17) 2 18) 3 19) 1 20) 4

21) 2 22) 2 23) 3 24) 1 25) 4

CHEMISTRY

26) 1 27) 1 28) 4 29) 2 30) 1

31) 3 32) 2 33) 3 34) 4 35) 3

36) 4 37) 4 38) 4 39) 2 40) 1

41) 2 42) 1 43) 2 44) 3 45) 2

46) 4 47) 3 48) 2 49) 4 50) 3

MATHEMATICS

51) 4 52) 2 53) 2 54) 3 55) 2

56) 1 57) 4 58) 1 59) 1 60) 1

61) 3 62) 2 63) 1 64) 2 65) 2

66) 4 67) 2 68) 2 69) 3 70) 4

71) 3 72) 1 73) 3 74) 1 75) 2

PHYSICS HINTS & SOLUTIONS
F mv 2
01. Hint: e  ; F  mg  .
Ay 

1 1 4Ae 2
02. Hint: Fe  mv 2 ;  mv 2 .
2 2 

e 104 F
03. Hint: From the graph, Slope   ; y .
F 20 Ae
 P 75  1 2 
04. Hint: Bulk modulus K  17. Hint:  I   J  mst .
 v  100  2 
 
 v 
18. Hint: dw  dQ  du  dw  CdT  CV dT
v 0.1 2T0 2T0 T
P  hdg ;  . 5R  T2  5R 2T0
v 100  dw   TdT   dT      [T]T0 .
T0 T0 2  2  T0 2
05. Hint: Energy released in the form of heat is
1 1  19. Hint: Amount of heat extracted is along line
Q  4 R 3    T DA and AB along DA, dw  0 , dQ  du
r R 
Amount of heat absorbed by drop Q  msT 3p0 v 0
dQ DA  nc v dTAB , TA 
nR
1 1 
J(mst)  4 R 3     T . 3R pv 3p  3v 0
r R  n  dTAB , TD  0 0 , TB  0
2 nR nR
06. Hint: Change in length decreases due to
buoyancy force 3R 2p0 v 0
dQDA  n. 
F 2 nR
e
Ay dQ along AB  ncpdTAB

F  Vg ; A  r 2 5R  9p0 v 0 3p0 v 0 

n 
C F 30 F 2  nR nR 
07. Hint:    .
100 180 100 180 dQ  dQDA  dQ AB .
1 20. Hint: Vrms  T
08. Hint: Length .

09. Conceptual/Basic Question.  v2   T 
  1    2  1  100
10. Conceptual/Basic Question.  v1   T1 
mass of liquid expelled
11. Hint:  A  / C . v 2  v1  T 
mass remaint  100   2  1  100 .
v1  T1 
12. Conceptual/Basic Question.
13. Conceptual/Basic Question. w
14. Hint: Rate of flow of heat energy 21. Hint:   Q  Q1  100
1

Q KA(Q1  Q2 )
 w  Q1  Q 2
t 
Q2  100  10  90 J .
 
Q
t 1

A1  2
  2
 
Q
t 2
A 2 1 . 22. Hint:    1   .
 n
T 23. Hint: I  R 2  R  
15. Hint: Vrms 
M
I R 
2 2
V1 T1 M2 I R R
 
V2 T2 M1 . I
 2  T .
16. Hint: du  nc v dT I
24. Hint: Weight of the drop = buoyancy force +
n  n1  n2 force due to surface tension
n1cv1  n2c v 2 5R 3R v v
cv   c v1  , cv2  . vg  dg  (2r)    vg  dg  2r  
n1  n2 2 2 2 2
 (2  d) 4 (2  d)
 vg  2r    r 3  2r 5 1 7 1 2 0
2 3 2 4CO3  C   3CO4 2H2O2  2H2O  O2
36. Sol.
Reduced
3 Reduced
r Oxidised Oxidised
g(2  d)
+4 +3 +5
12 . 2NO2  2OH   NO2  NO3  H2O
D  2r  D 
g(2  d) Reduced

pv Oxidised
25. Hint: We know that n 
RT
+4 0 0 +2
TiC 4  2Mg  Ti  2MgC 2
 4T  4 3  4T  4 3
nA   8    R1 ; nB   8    R 2 .
 R1  3  R2  3 Displacement reaction.
37. Conceptual/Basic Question.
CHEMISTRY HINTS & SOLUTIONS
38. Conceptual/Basic Question.
26. Sol. In (i), the p are at equatorial position 39. Conceptual/Basic Question.
so there are less p  bp repulsions as
n
compared to other positions. Hence, T-shape 40. Sol. P  RT
is most stable. V
27. Sol. Equilibrium can be attained by either side 3.2 4.4
of the reactions of equilibrium. n for CH4   0.2 ; n for CO2   0.1
16 44
28. Sol. HCOOH on dehydration gives CO. This
method is used for producing CO at a small n total  0.2  0.1  0.3
scale.
0.3  0.0821  300
29. Conceptual/Basic Question. P  0.82 atm .
9

30. Sol. Na 2B4O7 10H2O  
 Na 2B4O7    PC 3( g )  C 2( g )
41. Sol. PC 5( g ) 
Sod. metaborate
(X)
0.5  0.3
Qc   0.25
0.6
2NaBO2  B2O3
(Y) (Z) K c  0.2 , Since, Qc  K c reaction will proceed
31. Conceptual/Basic Question. in backward direction.
32. Conceptual/Basic Question. 42. Conceptual/Basic Question.
33. Sol. More the number of  -substituents, more C C

stable alkene it will give on  -elimination. 43. Sol.  AC 3 Zn/Hg

Conc. HC
 .
Since (i) has two, (iii) has one  -methyl
O [A] O
C
substituent while (ii) has no  -methyl
substituent, therefore, reactivity towards  - 44. Sol. Higher the critical temperature, faster is
elimination decreases in the order : the liquefaction of the gas. Hence, NH3 will
(i)  (iii)  (ii) . liquefy first and N2 at last.
34. Sol. For C2 the electronic configuration
2 2 2 2
is  1S   *1S , 2S2 ,  * 2S , 2Px 2Py2 , C
AC 3
2Pz0
[B] (C)
Hence the result follows.
C
45. Sol. Only addition of HBr gives anti-
35. Sol. 1-Chloro-2,4-dinitrobenzene . Markownikoff’s product in presence of
O2N NO2
peroxide. Presence of peroxide does not make
any difference while reacting with HC .
 y
 1 N 2  1 O2 ; K  0.25
46. Sol. NO  c
2 2
y  ax
B
1 1  1 A1
N 2  O2  NO ; K c   4.
2 2 0.25
47. Sol. Given: Mass of compound taken  0.50 g A x
Volume of H2SO 4  50 mL O xy a

Molarity of H2SO4  0.5 M 1 a 1 a2

OA 1B   (OB)  
2 1 a 2 1 a .
Volume of NaOH required  60 mL
Molarity of NaOH required  0.5 M 2  3 1
52. Sol: AB  
Method adopted : Kjeldahl’s method 2 2 2 2

 V 2a  1 2a a
1.4  M  2  V  1  PC  , PD  
Formula used: % of N   2  –– 2 2 2 2 2
m
2x  2y  2  0
–––––– (i)
A D
By substituting the values in the formula, we 90°
get,
1.4  0.5  2(50  60 / 2) P (1, a)
% of N   56
0.5
 % of N in the given compound  56% . 90°
B C
48. Hint: Complete Neutralisation. 2x  2y  3  0

Clearly,
 4S2( g )
S8( g ) 
1 0 2a  1 1
49. Sol. Initial pressure PC  AB    2a  1  1
25 2 2 2 2
25 4
At equilibrium 1
100 100  1  2a  1  1  0  a  1 ––––– (1)
 0.75 1
a 1 1
Also, PD  AB   a 
2 2 2 2
(PS2 )4 (1)4
KP    1.33 atm 3 . 1 1
PS8 0.75    a  –––––– (2)
2 2
50. Sol. K sp for Mg(OH)2  1.0  1011
1
From eqns. (1) and (2), 0  a  .
[Mg2 ][OH ]2  (0.1)  [OH]2  1.0  1011 2
53. Sol: For the curve
1 21  1011
[OH ]   1010 ax 2  2hxy  by 2  2gx  2fy  c  0
0.1
to represent a pair of straight lines
1014
 9
[OH  ]  10 5 ; [H ]  5  10  pH  9 . abc  2fgh  af 2  bg 2  ch2  0
10
k 5
In this case a  1 , b  1 , h  , g ,
MATHEMATICS HINTS & SOLUTIONS 2 2
7
 a a2  f , c6
A 
51. Sol: B  (0, a) , 1  ,  2
1 a 1 a 
2
 6  2    7     5   k  49  25  6k  0
 2  2 2 4 4 4
 10 5 Let P  (x, y, z) bet he point common to the
k , .
3 2 planes passing through A, B, c and parallel to
54. Sol: Let A(0, 0) co-ordinate planes, then
x  a 1 , y  b1 , z  c1
Co-ordinate of B are (2cot , 2) and co-
Locus of ‘P’ is
ordinate of C are {4 cot(60   ),  4}
a b c
yy2 B    1.
x y z
2 57 Sol: Equation of any plane containing the line

 x y 2 z 4
A   is
6 60  
x 1 3 1
(0,0)
ax  b( y  2)  c(z  4)  0
C Where a  3b  c  0 ––––––– (i)
y  4
y  x tan(   60)
This plane will also contain the second line if
2a  3b  c  0 ––––––––– (ii)
 AB  AC and 4a  b(0  2)  c(0  4)  0
 (AB)2  (AC)2 Solving thee equations, we get a  0 , b  0
c0
4 cot2   4  16cot2 (60   )  16
That means the given lines are non-coplanar.
4cosec2  16cosec2 (60   ) 58. Sol: We have 4  a  1  2  0  a  1
 sin(60  )  2sin  8  2  b 1 0  b  5 ,
12  3  2  c  0  c  7
 3 1 
  cos   sin    2sin 
 a 2  b2  c2  1  25  49  75 .
 2 2 
x
lim
3 59. Sol: lim(1  x)cot x  lim((1  x)1/x )x cot x  e x 0 tanx
e.
x 0 x 0
 tan  
5
1  cos x x
 The required length 60. Sol: Limit  lim 2
 x
x 0 x 2 1
28 4 7
 AB  (4 cot2   4)  2  . x
3 3 2sin2
 lim 2 x
55. Sol: Lines are x  az  b , y  cz  d x 0 2
x e
x loge 2 1
4 
x b y d z 2
   ––––––– (i)
a c 1 2
1  sin x  x
and x  a1z  b , y  c1z  d1 ––––––– (ii)  lim   x 2   2
x 0 2
 2  1  x log 2  x(log e x )  ...   1
 e 
x  b y  d1 z  n! 
 
a1 c1 1
1 1 1
   log 2 e .
 Lines (i) and (ii) are perpendicular, then 2 loge 2 2
aa1  cc1  1  0 .
n n
 4   1 
61. Sol: lim  tan  1  2   lim  tan  1  2 1 
x y z n 
r 1  4 r  3  n 
r 1  r  4  1 
56. Sol: Let the variable plane be a  b  c  1
1 1 1
  1  1 
Since, it passes through (a, b, c), therefore n  r  2   r  2  
 lim  tan 1      
a b c n
r 1   1  1 
  1
a1 b1 c1  1   r  2  r  2  
   

A  (a1 ,0, 0) , B  (0, b1, 0) , C  (0, 0, c1 )

 n
  1  1   f '(x ) 
1 32cos32x  sinx  cos x sin32x
 lim  tan1  r    tan 1  r    
n
r 1   2  2  32 sin2 x

  1  1  1 1
 lim tan 1  n    tan1   32   0

n
  2  2   f '    2 2  2.
2
4  1 
32   
1  1   2
 tan 1   tan 1     tan 1     cot 1 2
2 2 2 2
1
 tan1 2 . 64. Sol: 5f(x)  3f    x  2 ––––– (1)
x
62. Sol: At x  0
1
L.H. derivative of p sin x  p Replacing x by
x
R.H. derivative of p sinx  p
1 1
 5f    3f(x)   2 ––––– (2)
 For p sinx to be differentiable at x  0 , x x
p  p or p  0 at x  0
From eq. (1)  5
x
L.H. derivative of qe  q
1
25f(x )  15f    5x  10 ––––– (3)
R.H. derivative of qe x  q x

For qe x to be differentiable at x  0,  q  q , and from eq. (2)  5

3
or q  0 d.c. of r x at x  0 is 0 1 3
9f(x )  15f     6 ––––– (4)
 For f(x) to be differentiable at x  0
x x
Subtracting eq. (4) from (3), we get
p  0 , q  0 and r may be any real number..
Second method: 3
 16f(x)  5x  4
x
f(h)  f(0)
f '(0  0)  lim
h  0 0 h 5x 2  3  4x
 x f(x )  y
16
h 3
p sinh  qe  r h  q
 lim
h 0  0 h  dy  10x  4
dx 16
psinh qe  h  rh3  q
 lim dy 10  4 7
h 0  0 h   .
dx x 1 16 8
 sinh q(e h  1) 
 lim p   rh2   p  q x y
h0
 h h  65. Sol: Given line is   1 ––––– (1)
a b
Similarly, f '(0  0)  p  q
Curve is y  be  x /a ––––– (2)
Since, f(x) is differentiable at x  0
Let line (1) touch the curve (2) at P( ,  )
 f '(0  0)  f'(0  0)  p  q  p  q
dy b
 pq  0 From eq. (2),   e  x /a
dx a
Here r may be any real number.
 Equation of tangent to (2) at P( ,  ) is
 Correct choice is (b).
2sinx  cosx  cos2x  cos4x  cos8x  cos16x b
63. Sol: f(x )  y     e  /a (x   )  b e  /a
2 sinx a
sin32x  /a
or ay  a  be x

25 sinx
 a 2  be  /a [(1  cos )cos2  sin  sin2]
or be  /a x  ay  –––––– (3)
a 25
Eqns. (1) and (3) must be identical  [cos2  cos(2   )]
2(1  cos  )3
a 2  be  /a
 abe  /a  ab  25
a  3
(2cos2   cos   1)
2(1  cos  )
From eqns. (1) and (2),   0 and from eqns.
(2) and (3),   b . = a positive number (2cos2   cos   1)

66. Sol: Let BD1  x  

 0    2 
 BC1  (a  x )
A1 1
2cos2   cos   1  0  cos   1,
2

  
D C 
3  0    2 

B1 A D1 B C1 Sign scheme for 2cos2   cos   1 is

m ax
 0  ve   ve 
 BC  (a  x)tan  3(a  x )
3 3 2
Now area of rectangle ABCD,

 z is maximum when   .
  ( AB)(BC)  2 3 x(a  x) 3
2 68. Sol: Let BP  x .
 x ax  3 a2
   2 3   From similar triangles property, we get
 2  2
(Using A.M.  G.M.)
67. Sol: Let PR  a
A
Given, a(1  cos  )  5 –––––– (1)
Area of the triangle PQR
Q
1
z  a cos   a sin 
2 2

P B P O
1

a AO  2 
  AO  1 2
1 x X

 d(AO) 1 2 dx  dx 1 
Q a cos R

dt
 
x 2 dt
,  dt  10 given

1 d(AO) 2
25 1 When x  ,   2 m / sec .
 2
 sin  cos  2 dt 5
(1  cos  ) 2
69. Sol: Let the speed of the train be ‘v’ and
dz 25 (1  cos  )2 (cos2   sin2  )  sin2  cos   2(1  cos  ) distance to be covered be ‘s’ so that total time
 
d 2 (1  cos  )4 taken is s/v hours, cost of fuel per hour  kv 2
25 (k is constant).
  (1  cos  )
2(1  cos  )4 Also, 48  k  162 by given condition.
 3 (cos x  1)(cosx  e x )
 k 73. Sol: lim
16 x 0 xn
 Cost of fuel per hour  (3 /16) v 2 (1  cos x)(e x  cos x )
 lim
Other charger per hour  300 x 0 xn
3 2 s 300s (1  cos x){(e x  1)  (1  cos x)}
Total charge  v    lim
16 v v x 0 xn
(1  cos x )(1  cos x ){(e x  1)  (1  cos x )}
or C  s  3 v  300   lim
 16 v  x 0 x n (1  cos x )

2
dC  3 300   sinx    e x  1   1  cosx  
  s  2      
dv  16 v   x   x   x 
 lim n3
x 0 x (1  cosx )
dC
For max. or min. 0
dv
(1)2 {(1)  0} 1
 v  40miles / h For n  3    non-zero finite.
1  (2) 2
d2 C Thus the draw line cuts the plane at
Then 0
dv 2
2 3 6   9 11 15 
 Most economical speed v  40 miles / h .   1,  2,   3  i.e.,  ,  , 
7 7 7  7 7 7 

70. Sol: f '1 (x 1 )  2x 1  1 , f '2 (x 2 )  3x 22  2x 2  2 Required distance

2 2 2
Let tangents drawn to the curves y  f1 ( x ) and  9   11   15 
   1    2    3
 7   7   7 
y  f2 (x ) at ( x 1 , f(x 1 )) and (x 2 , f(x 2 )) are
parallel, then 2x1  1  3x 22  2x 2  2 , which is 4 9 36
    1units .
possible for infinite number of ordered pair 49 49 49
( x1 , x 2 ) .
74. Sol: y  log x  2log x x  2  dy  0 .
x
NUMERICAL VALUE QUESTIONS: dx
71. Sol: Let the slope of the two lines be m and
4 75. Sol: x 2  4y  dy  x
3m, then 4m   ––––––– (1) dx 2
a
Let P( ,  ) be a point on the curve, then
21
3m  ––––––– (2) 2  4 ––––––– (1)
a
Putting the value of m form eq. (1) in eq. (2), Equation of normal at ( ,  ) is
we get
2
y   (x   ) ––––– (2)
3 1 
 a  3. [ a  0]
a2 a Since, eq. (2) passes through (1, 2)
72. Sol: Equation of any line drawn through (1, –
2
2, 3) and parallel to given line is  2  (1   )    2 ––––– (3)

x 1 y  2 z  3
  2 8
2 3 6 From eq. (1),   2

Any point on it can be taken as ( 2r  1 , 3r  2 ,
From eq. (3),   1
6r  3 )
Putting this point in the equation of plane, we  Required points is (2, 1) and number of
get normal is 1.

1 ***THE END***
(2r  1)  (3r  2)  (3  6r)  5  0  r  .
7