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Estimation of Bleaching Powder

This document provides a procedure to estimate the amount of chlorine in a bleaching powder sample. It involves standardizing a sodium thiosulfate solution by titrating it against a potassium dichromate solution. Then, an aliquot of the bleaching powder sample is titrated against the standardized sodium thiosulfate solution. The volume used is used to calculate the normality of chlorine in the sample. Tables are provided to record the titration data from standardizing the sodium thiosulfate and titrating the bleaching powder sample. The percentage of chlorine in the sample is then calculated.

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660 views3 pages

Estimation of Bleaching Powder

This document provides a procedure to estimate the amount of chlorine in a bleaching powder sample. It involves standardizing a sodium thiosulfate solution by titrating it against a potassium dichromate solution. Then, an aliquot of the bleaching powder sample is titrated against the standardized sodium thiosulfate solution. The volume used is used to calculate the normality of chlorine in the sample. Tables are provided to record the titration data from standardizing the sodium thiosulfate and titrating the bleaching powder sample. The percentage of chlorine in the sample is then calculated.

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Chemical NITT
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© © All Rights Reserved
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2.

ESTIMATION OF BLEACHING POWDER

AIM

To determine the amount of chlorine present in a given sample of bleaching


powder.

PRINCIPLE

The available chlorine in the given sample is estimated in terms of iodine


liberated in the reaction. It is known as iodometric titration.

PROCEDURE

Standardization of Sodium Thiosulphate

About 0.1N (0.49gm) of potassium dichromate is weighed accurately and


transferred to 100ml standard flask and solution is made up to 100ml. The given
sodium thiosulphate is taken in burette. 10 ml of potassium dichromate is pipette
out into a conical flask and titrated against sodium thiosulphate after adding 10ml
of potassium iodide and 2N sulphuric acid when the yellow colour fades slightly,
2-3 drops of freshly prepared starch solution (indicator) is added and titration is
continued till disappearance of blue colour. Titration is repeated for concordant
values.

Estimation of Bleaching Powder

The given sample of bleaching powder is taken in a standard flask and made upto
100ml. 10ml of bleaching powder solution is pipette out into a clean dry conical
flask and 10ml of potassium iodide and sulphuric acid are added. It is then titrated
against sodium thiosulphate in a burette when yellow colour starts fading, 2-3
drops of freshly prepared starch indicator are added and titration is continued till
the blue colour disappears. The titration is repeated for concordant values.

RESULT
The percentage of chlorine in a given sample of bleaching powder is ________.
OBSERVATION:

Table 1: Standardization of Sodium Thiosulphate

S.N Volume of K2Cr2O7 Burette Reading (ml) Volume of Sodium


o (ml) Initial Final Thiosulphate (ml)
1.
2.

CALCULATION:

Volume of K2Cr2O7 used (V1) = ml

Volume of SodiumThiosulphate (V2) = ml

Normality of K2Cr2O7 (N1) = 0.1 N

V1*N1 = V2N2

N2 = V1*N1 / V2

Table 2: Estimation of Bleaching Powder

S.No Volume of Bleaching Burette Reading (ml) Volume of Sodium


Powder (ml) Initial Final Thiosulphate (ml)
1.
2.
CALCULATION:

Volume of bleaching powder used (V3) = ml

Volume of SodiumThiosulphate (V2) = ml

Normality of SodiumThiosulphate = 0.1 N

V3*N3 = V2N2

N3 = V2*N2 / V3

Amount of available chlorine in the given sample=

N3*Equalent weight of bleaching powder*volume/1000.

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