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    NMR Aromatic Proton Coupling: Doublet

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    Carlo Santos
    1) In aromatic compounds, significant splitting occurs not only between ortho protons but also between meta and para protons due to conjugated pi bonds. 2) Coupling constants between protons are helpful for analyzing complicated aromatic regions of NMR spectra and distinguishing between overlapping peaks. 3) Typical coupling constants are ~6-9 Hz for ortho, ~2-3 Hz for meta, and ~0-1 Hz or peak broadening for para protons.

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    NMR Aromatic Proton Coupling: Doublet

    Uploaded by

    Carlo Santos
    96 views1 page
    1) In aromatic compounds, significant splitting occurs not only between ortho protons but also between meta and para protons due to conjugated pi bonds. 2) Coupling constants between protons are helpful for analyzing complicated aromatic regions of NMR spectra and distinguishing between overlapping peaks. 3) Typical coupling constants are ~6-9 Hz for ortho, ~2-3 Hz for meta, and ~0-1 Hz or peak broadening for para protons.

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    Tables

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    NMR-coupling

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    1) In aromatic compounds, significant splitting occurs not only between ortho protons but also between meta and para protons due to conjugated pi bonds. 2) Coupling constants between protons are helpful for analyzing complicated aromatic regions of NMR spectra and distinguishing between overlapping peaks. 3) Typical coupling constants are ~6-9 Hz for ortho, ~2-3 Hz for meta, and ~0-1 Hz or peak broadening for para protons.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    96 views1 page

    NMR Aromatic Proton Coupling: Doublet

    Uploaded by

    Carlo Santos
    1) In aromatic compounds, significant splitting occurs not only between ortho protons but also between meta and para protons due to conjugated pi bonds. 2) Coupling constants between protons are helpful for analyzing complicated aromatic regions of NMR spectra and distinguishing between overlapping peaks. 3) Typical coupling constants are ~6-9 Hz for ortho, ~2-3 Hz for meta, and ~0-1 Hz or peak broadening for para protons.

    Copyright:

    © All Rights Reserved
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    of 1

    2495.

    45
    2486.60
    •split by b (J ~9 J=8.85 Hz
    NMR AROMATIC PROTON COUPLING
    Hz, characteristic
    OH
    In aliphatic organic ortho)
    compounds, the only coupling that
    you need to worry about is from
    adjacent protons (J =0 between any
    Z EXPECTED PEAK:
    doublet
    non-adjacent protons)...
    In aromatic compounds, Y a
    however, significant splitting
    does not only come from ortho J=9.14 Hz
    protons coupled to each other, but •split by a (J ~9 J=2.04 Hz
    c b

    2221.43

    2212.55
    2223.73

    2214.59
    also from meta (even para) protons Hz, characteristic
    due to conjugated π bonds. ortho)
    Thus, coupling constants are •split by c (J ~2,
    a helpful tool for deciphering
    complicated aromatic regions, and
    X characteristic meta)

    are especially vital when the EXPECTED PEAK:


    chemical shifts (δ ) between doublet of doublets
    aromatic protons are uncertain or •split by b (J ~2,
    overlapping. characteristic

    2259.64
    meta)

    2257.44
    J=2.20 Hz
    Characteristic J constants
    for: EXPECTED PEAK:
    Ortho: ~6-9 Hz doublet
    Meta: ~2-3 Hz
    Para: ~0-1 Hz
    (or pk. broadening)

    *for further detail, please see G&M pg. 272-274.

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